{"id":535,"date":"2016-08-08T13:54:33","date_gmt":"2016-08-08T05:54:33","guid":{"rendered":"http:\/\/www.chemhui.com\/?p=535"},"modified":"2016-10-28T13:18:17","modified_gmt":"2016-10-28T05:18:17","slug":"535","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/535\/","title":{"rendered":"Pd(II)\u50ac\u5316\u7684\u70ef\u4e19\u57fa\u4e0d\u5bf9\u79f0C-H\u6d3b\u5316\u7814\u7a76"},"content":{"rendered":"<p><script src=\"http:\/\/static.websiteonline.cn\/website\/plugin\/unslider\/js\/html5zoo.js?v=20151226\"><\/script>Pd(II)\u50ac\u5316\u7684\u70ef\u4e19\u57fa\u4e0d\u5bf9\u79f0C-H\u6d3b\u5316\u7814\u7a76\u8fdb\u5c55 <!--\u8bed\u8a00\u7279\u6b8a\u7684css--><\/p>\n<div id=\"scroll_container\" class=\"scroll_contain\">\n<div id=\"canvas\">\n<div id=\"layer2742AE08F055996D371FE48229D5916B\" class=\"cstlayer\">\n<div class=\"wp-article_detail_content\">\n<div class=\"artview_content\">\n<div class=\"artview_detail\"><span style=\"color: #3e3e3e; line-height: 30px; font-family: 'helvetica neue', helvetica, 'hiragino sans gb', 'microsoft yahei', arial, sans-serif; font-size: 18px; background-color: #ffffff;\"><span style=\"font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei';\">Pd<\/span><span style=\"font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei'; font-size: 18px;\"><sup>0<\/sup><\/span><\/span><span style=\"color: #3e3e3e; line-height: 1.6; font-family: 'helvetica neue', helvetica, 'hiragino sans gb', 'microsoft yahei', arial, sans-serif; font-size: 18px; background-color: #ffffff;\"><span style=\"color: #3e3e3e; line-height: 1.6; font-family: 'helvetica neue', helvetica, 'hiragino sans gb', 'microsoft yahei', arial, sans-serif; font-size: 18px; background-color: #ffffff;\"><span style=\"line-height: 1.6; font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei';\">\u50ac\u5316\u7684\u70ef\u4e19\u57fa\u5316\u53cd\u5e94\uff08\u53c8\u540dTsuji-Trost\u53cd\u5e94\uff09\u63d0\u4f9b\u4e86\u91cd\u8981\u7684\u78b3-\u78b3\u952e\u5f62\u6210\u65b9\u6cd5\u3002\u53cd\u5e94\u4e2d\uff0c\u70ef\u4e19\u57fa\u8bd5\u5242\u901a\u5e38\u9700\u8981\u9884\u5b98\u80fd\u5316\uff0c\u5373\u70ef\u4e19\u4f4d\u5e26\u6709\u79bb\u53bb\u57fa\u56e2\uff08\u5982\u78b3\u9178\u916f\u3001\u78f7\u9178\u916f\u3001\u5364\u7d20\uff0c\u80fa\u57fa\u3001\u7f9f\u57fa\u7b49\uff09\uff0c\u4ee5\u4fc3\u8fdb\u5176\u4e0ePd<\/span><span style=\"line-height: 1.6; font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei'; font-size: 18px;\">0<\/span><span style=\"line-height: 1.6; font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei';\">\u7684\u6c27\u5316\u52a0\u6210\u53cd\u5e94\uff0c\u751f\u6210\u03c0-\u70ef\u4e19\u57faPd<\/span><span style=\"line-height: 1.6; font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei'; font-size: 18px;\">II<\/span><span style=\"line-height: 1.6; font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei';\">\u4e2d\u95f4\u4f53\uff1b\u800c\u901a\u8fc7\u76f4\u63a5\u7684\u70ef\u4e19\u57faC-H\u6d3b\u5316\u6765\u4ea7\u751f\u03c0-\u70ef\u4e19\u57faPd<\/span><span style=\"line-height: 1.6; font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei'; font-size: 18px;\">II<\/span><span style=\"line-height: 1.6; font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei';\">\u4e2d\u95f4\u4f53\uff0c\u5177\u5907\u5b8c\u7f8e\u7684\u6b65\u9aa4\u7ecf\u6d4e\u6027\u548c\u539f\u5b50\u7ecf\u6d4e\u6027\u3002<br \/>\n<\/span><\/span><\/span><\/p>\n<p style=\"color: #3e3e3e; text-indent: 28px; font-family: 'helvetica neue', helvetica, 'hiragino sans gb', 'microsoft yahei', arial, sans-serif; font-size: 14px;\"><strong><span style=\"font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei'; font-size: 18px;\">1. \u65e9\u671f\u7814\u7a76<\/span><\/strong><\/p>\n<p style=\"color: #3e3e3e; text-indent: 28px; font-family: 'Microsoft Yahei', 'Helvetica Neue', Helvetica, Arial, sans-serif; font-size: 14px;\"><span style=\"font-family: 'helvetica neue', helvetica, 'hiragino sans gb', 'microsoft yahei', arial, sans-serif; font-size: 18px;\"><span style=\"font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei';\">Pd<\/span><span style=\"font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei'; font-size: 18px;\">II<\/span><\/span><span style=\"line-height: 1.6; font-family: 'helvetica neue', helvetica, 'hiragino sans gb', 'microsoft yahei', arial, sans-serif; font-size: 18px;\"><span style=\"line-height: 1.6; font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei';\">\/\u82ef\u918c\u662f\u5b9e\u73b0\u70ef\u4e19\u57faC-H\u5b98\u80fd\u5316\/\u7684\u6709\u6548\u4f53\u7cfb\u4e4b\u4e00\u3002<\/span><strong><span style=\"line-height: 1.6; font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei';\">\u4f0a\u5229\u8bfa\u4f0a\u5927\u5b66\u5384\u5df4\u7eb3-\u9999\u69df\u5206\u6821<\/span><\/strong><span style=\"line-height: 1.6; font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei';\">\u7684<\/span><strong><span style=\"line-height: 1.6; font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei';\">M. Christina White\u6559\u6388<\/span><\/strong><span style=\"line-height: 1.6; font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei';\">\u7684\u7814\u7a76\u5c0f\u7ec4\u53d1\u73b0\uff0c\u5728\u53cd\u5e94\u4e2d\u52a0\u5165\u4e0d\u540c\u7684\u4e9a\u781c\u914d\u4f53\uff0c\u53ef\u4ee5\u8c03\u8282\u53cd\u5e94\u7684\u533a\u57df\u9009\u62e9\u6027<\/span><span style=\"line-height: 1.6; font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei';\">\uff1b\u5c1d\u8bd5\u5728\u53cd\u5e94\u4e2d\u52a0\u5165\u624b\u6027Lewis\u9178[(Salen)Cr<\/span><span style=\"line-height: 1.6; font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei'; font-size: 18px;\">III<\/span><span style=\"line-height: 1.6; font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei';\">F]\u65f6\uff0c\u53ef\u4ee5\u5f97\u5230\u4e2d\u7b49\u7684ee\u503c<\/span><span style=\"line-height: 1.6; font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei';\">\u3002<br \/>\n<\/span><\/span><\/p>\n<p style=\"color: #3e3e3e; text-indent: 28px; font-family: 'helvetica neue', helvetica, 'hiragino sans gb', 'microsoft yahei', arial, sans-serif; font-size: 14px;\"><strong><span style=\"font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei'; font-size: 18px;\">2. \u624b\u6027\u914d\u4f53\u7684\u53d1\u5c55<\/span><\/strong><\/p>\n<p style=\"color: #3e3e3e; text-indent: 28px; font-family: 'helvetica neue', helvetica, 'hiragino sans gb', 'microsoft yahei', arial, sans-serif; font-size: 14px;\"><span style=\"font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei';\">\u7406\u8bba\u4e0a\uff0c\u4e09\u4ef7\u81a6\u914d\u4f53\u4e0d\u9002\u7528\u4e8ePd<\/span><span style=\"font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei'; font-size: 18px;\">II<\/span><span style=\"font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei';\">\u50ac\u5316\u7684\u70ef\u4e19\u57faC-H\u6d3b\u5316\u53cd\u5e94\uff0c\u56e0\u5176\u5bb9\u6613\u88ab\u5bf9\u4e8c\u82ef\u918c\u6c27\u5316\uff0c\u5f31\u5316\u6216\u5931\u53bb\u4e0ePd<\/span><span style=\"font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei'; font-size: 18px;\">II<\/span><span style=\"font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei';\">\u7684\u914d\u4f4d\u80fd\u529b\u3002<\/span><strong><span style=\"font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei';\">\u7136\u800c\u201c\u4e8b\u5b9e\u201d\u5374\u5728\u4e0d\u505c\u5730\u6253\u201c\u7406\u8bba\u201d\u7684\u8138<\/span><\/strong><span style=\"font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei';\">\uff1a2012\u5e74\uff0c\u65af\u5766\u798f\u5927\u5b66\u7684Barry. M. Trost\u6559\u6388\u5c0f\u7ec4\u9996\u6b21\u53d1\u73b0\uff0c\u4e09\u82ef\u57fa\u81a6\u5bf9Pd<\/span><span style=\"font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei'; font-size: 18px;\">II<\/span><span style=\"font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei';\">\u50ac\u5316\u76841, 4-\u4e8c\u70ef\u7684\u70ef\u4e19\u57faC-H\u70f7\u57fa\u5316\u53cd\u5e94\u5177\u6709\u660e\u663e\u7684\u4fc3\u8fdb\u4f5c\u7528<\/span><span style=\"font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei';\">\u3002<\/span><\/p>\n<p style=\"color: #3e3e3e; text-indent: 28px; font-family: 'helvetica neue', helvetica, 'hiragino sans gb', 'microsoft yahei', arial, sans-serif; font-size: 14px;\"><span style=\"font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei';\">2013\u5e74\uff0c<\/span><strong><span style=\"font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei';\">Trost\u6559\u6388<\/span><\/strong><span style=\"font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei';\">\u5c0f\u7ec4\u6210\u529f\u5730\u5c06\u624b\u6027\u4e9a\u81a6\u9170\u80fa\u914d\u4f53\u5e94\u7528\u4e8ePd<\/span><span style=\"font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei'; font-size: 18px;\">II<\/span><span style=\"font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei';\">\u50ac\u5316\u7684\u70ef\u4e19\u57fa\u4e0d\u5bf9\u79f0C-H\u70f7\u57fa\u5316\u53cd\u5e94<\/span><span style=\"font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei';\">\u3002\u7814\u7a76\u5c0f\u7ec4\u9009\u7528Pd(OAc)<\/span><span style=\"font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei'; font-size: 18px;\">2<\/span><span style=\"font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei';\">\/2,6-\u4e8c\u7532\u57fa\u82ef\u918c\u4f53\u7cfb\uff0c\u4ee51,3-\u4e8c\u916e\u4e3a\u4eb2\u6838\u8bd5\u5242\uff0c\u901a\u8fc7\u8bbe\u8ba1\u3001\u6539\u8fdb\u8054\u8418\u915a\u884d\u751f\u7684\u975e<em>C<\/em><span style=\"line-height: 0; font-family: 'helvetica neue', helvetica, 'hiragino sans gb', 'microsoft yahei', arial, sans-serif; font-size: 13.5px; vertical-align: baseline;\">2<\/span>\u5bf9\u79f0\u7684\u624b\u6027\u4e9a\u81a6\u9170\u80fa\u914d\u4f53\uff0cee\u6700\u9ad8\u53ef\u8fbe85%\u3002\u53cd\u5e94\u6210\u529f\u7684\u539f\u56e0\u53ef\u80fd\u6709\u4ee5\u4e0b\u4e24\u70b9\uff1a\uff081\uff09\u4e25\u683c\u6392\u9664\u53cd\u5e94\u4f53\u7cfb\u7684\u6c27\u6e90\uff08\u4e3b\u8981\u4e3a\u6c27\u6c14\uff09\uff0c\u6700\u5927\u9650\u5ea6\u964d\u4f4e\u914d\u4f53\u5728\u53cd\u5e94\u4f53\u7cfb\u4e2d\u88ab\u6c27\u5316\u7684\u53ef\u80fd\u6027\uff1b\uff082\uff09\u914d\u4f53\u7684\u7cbe\u7ec6\u7ed3\u6784\u4fee\u9970\u4fdd\u8bc1\u4e86\u50ac\u5316\u5242\u7684\u9ad8\u6d3b\u6027<\/span><span style=\"font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei';\">\u3002\u540e\u7eed\u7684\u5e95\u7269\u9002\u7528\u8303\u56f4\u7814\u7a76\u53d1\u73b0\uff1a\u8f83\u5927\u5e45\u5ea6\u7684\u6539\u53d8\u70ef\u70c3\u82b3\u57fa\u53d6\u4ee3\u57fa\u7684\u7535\u5b50\u6548\u5e94\uff0c\u90fd\u4f1a\u5bfc\u81f4\u53cd\u5e94\u5931\u8d25\uff1b\u800c1,3-\u4e8c\u916e\u5e95\u7269\u82ef\u73af\u53d6\u4ee3\u57fa\u7684\u6027\u8d28\u5bf9\u53cd\u5e94\u5f71\u54cd\u8f83\u5c0f\u3002<span style=\"color: #3e3e3e; line-height: 25.6px; font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei'; font-size: 18px; background-color: #ffffff;\">2015\u5e74\uff0c<\/span><strong><span style=\"font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei';\">\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66<\/span><\/strong><span style=\"color: #3e3e3e; line-height: 25.6px; font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei'; font-size: 18px; background-color: #ffffff;\">\u7684<\/span><strong><span style=\"font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei';\">\u9f9a\u6d41\u67f1\u6559\u6388\u5c0f\u7ec4<\/span><\/strong><span style=\"color: #3e3e3e; line-height: 25.6px; font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei'; font-size: 18px; background-color: #ffffff;\">\u62a5\u9053\u4e86Pd<\/span><span style=\"color: #3e3e3e; line-height: 0; font-family: 'helvetica neue', helvetica, 'hiragino sans gb', 'microsoft yahei', arial, sans-serif; font-size: 13.5px; vertical-align: baseline; background-color: #ffffff;\"><span style=\"font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei'; font-size: 18px;\">II<\/span><\/span><span style=\"color: #3e3e3e; line-height: 25.6px; font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei'; font-size: 18px; background-color: #ffffff;\">\u50ac\u5316\u7684\u5206\u5b50\u5185\u70ef\u4e19\u57fa\u4e0d\u5bf9\u79f0C-H\u6c27\u5316\u53cd\u5e94<\/span><span style=\"color: #3e3e3e; line-height: 25.6px; font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei'; font-size: 18px; background-color: #ffffff;\">\u3002\u57fa\u4e8e\u63d0\u9ad8\u53cd\u5e94\u6d3b\u6027\u4e0e\u5929\u7136\u4ea7\u7269\u5408\u6210\u7684\u8003\u8651\uff0c\u4f5c\u8005\u9009\u7528\u4e861,4-\u4e8c\u70ef\u4e3a\u5e95\u7269\uff0c\u5bf9\u53cd\u5e94\u6761\u4ef6\u8fdb\u884c\u4f18\u5316\u65f6\u53d1\u73b0\uff1a\u624b\u6027\u4e9a\u81a6\u9170\u80fa\u914d\u4f53\u662f\u5f71\u54cd\u53cd\u5e94\u7acb\u4f53\u9009\u62e9\u6027\u7684\u4e3b\u8981\u56e0\u7d20\uff1b\u66f4\u6709\u8da3\u7684\u662f\uff0c\u975e\u624b\u6027\u5e03\u6717\u65af\u7279\u9178\uff08\u90bb\u6c1f\u82ef\u7532\u9178\uff09\u4e5f\u5bf9\u53cd\u5e94\u7684\u7acb\u4f53\u9009\u62e9\u6027\u81f3\u5173\u91cd\u8981\u3002\u5e95\u7269\u9002\u7528\u6027\u7814\u7a76\u8868\u660e\uff0c\u82ef\u73af\u4e0a\u53d6\u4ee3\u57fa\u7684\u7535\u5b50\u6027\u8d28\u5bf9\u7acb\u4f53\u9009\u62e9\u6027\u63a7\u5236\u5f71\u54cd\u8f83\u5c0f\uff0c\u800c\u53d6\u4ee3\u57fa\u7684\u4f4d\u7f6e\u4e0d\u540c\u65f6\uff0c\u4ea7\u7269\u7684ee\u503c\u4e5f\u4f1a\u4ea7\u751f\u8f83\u5927\u6ce2\u52a8\u3002<\/span><br \/>\n<\/span><\/p>\n<p><span style=\"color: #3e3e3e; line-height: 1.6; font-family: 'helvetica neue', helvetica, 'hiragino sans gb', 'microsoft yahei', arial, sans-serif; font-size: 18px; background-color: #ffffff;\"><span style=\"color: #3e3e3e; line-height: 1.6; font-family: 'helvetica neue', helvetica, 'hiragino sans gb', 'microsoft yahei', arial, sans-serif; font-size: 18px; background-color: #ffffff;\"><span style=\"line-height: 1.6; font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei';\">\u00a0 \u00a0 \u00a0 \u00a0<span style=\"color: #3e3e3e; line-height: 25.6px; font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei'; font-size: 18px; background-color: #ffffff;\">2016\u5e74\uff0c<\/span><strong><span style=\"font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei';\">White\u8bfe\u9898\u7ec4<\/span><\/strong><span style=\"color: #3e3e3e; line-height: 25.6px; font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei'; font-size: 18px; background-color: #ffffff;\">\u62a5\u9053\u4e86Pd<\/span><span style=\"color: #3e3e3e; line-height: 0; font-family: 'helvetica neue', helvetica, 'hiragino sans gb', 'microsoft yahei', arial, sans-serif; font-size: 13.5px; vertical-align: baseline; background-color: #ffffff;\"><span style=\"font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei'; font-size: 18px;\">II<\/span><\/span><span style=\"color: #3e3e3e; line-height: 25.6px; font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei'; font-size: 18px; background-color: #ffffff;\">\/\u624b\u6027\u4e9a\u781c-\u5641\u5511\u5549\u914d\u4f53\u50ac\u5316\u7684\u5206\u5b50\u5185\u70ef\u4e19\u57fa\u4e0d\u5bf9\u79f0C-H\u6c27\u5316\u53cd\u5e94\uff0c\u9ad8\u6548\u5408\u6210\u4e86\u7cfb\u5217\u624b\u6027\u5f02\u8272\u6ee1\u884d\u751f\u7269\uff0c\u4e0e\u9f9a\u6d41\u67f1\u6559\u6388\u5c0f\u7ec4\u7684\u62a5\u9053<\/span><span style=\"color: #3e3e3e; line-height: 25.6px; font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei'; font-size: 18px; background-color: #ffffff;\">\u4e92\u4e3a\u8865\u5145\u3002\u8be5\u53cd\u5e94\u7684\u4eae\u70b9\u662f\u624b\u6027\u4e9a\u781c-\u5641\u5511\u5549\u914d\u4f53\u7684\u4f7f\u7528\uff0c\u5728\u6c27\u5316\u6761\u4ef6\u4e0b\u53ef\u4ee5\u7a33\u5b9a\u5b58\u5728\uff0c\u56e0\u6b64\u53cd\u5e94\u4e0d\u9700\u8981\u65e0\u6c34\u65e0\u6c27\u5904\u7406\uff0c\u6781\u5927\u7684\u7b80\u5316\u4e86\u5b9e\u9a8c\u64cd\u4f5c<\/span><span style=\"color: #3e3e3e; line-height: 25.6px; font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei'; font-size: 18px; background-color: #ffffff;\">\u3002<br \/>\n<\/span><\/span><\/span><\/span><\/p>\n<p style=\"color: #3e3e3e; text-indent: 28px; font-family: 'helvetica neue', helvetica, 'hiragino sans gb', 'microsoft yahei', arial, sans-serif; font-size: 14px;\"><strong><span style=\"font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei'; font-size: 18px;\">3. \u624b\u6027\u9634\u79bb\u5b50\u7b56\u7565<\/span><\/strong><\/p>\n<p style=\"color: #3e3e3e; text-indent: 28px; font-family: 'helvetica neue', helvetica, 'hiragino sans gb', 'microsoft yahei', arial, sans-serif; font-size: 14px;\"><span style=\"font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei';\">\u03c0-\u70ef\u4e19\u57faPd<\/span><span style=\"font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei'; font-size: 18px;\">II<\/span><span style=\"font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei';\">\u4e2d\u95f4\u4f53\u7684\u9634\u79bb\u5b50\u5bf9\u53cd\u5e94\u7684\u6d3b\u6027\u6709\u5f88\u5927\u7684\u5f71\u54cd\uff0c\u5f53\u5f15\u5165\u624b\u6027\u9634\u79bb\u5b50\u65f6\uff0c\u8fd8\u53ef\u80fd\u63a7\u5236\u53cd\u5e94\u7684\u7acb\u4f53\u9009\u62e9\u6027\u30022007\u5e74\uff0c<\/span><strong><span style=\"font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei';\">\u5fb7\u56fd\u9a6c\u666e\u6240<\/span><\/strong><span style=\"font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei';\">\u7684<\/span><strong><span style=\"font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei';\">B. List\u6559\u6388\u5c0f\u7ec4<\/span><\/strong><span style=\"font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei';\">\u6700\u5148\u62a5\u9053\u4e86\u624b\u6027\u9634\u79bb\u5b50\u63a7\u5236\u7684\u4e0d\u5bf9\u79f0\u70ef\u4e19\u57fa\u70f7\u57fa\u5316\u53cd\u5e94<\/span><span style=\"font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei';\">\u3002\u5728\u53cd\u5e94\u4e2d\uff0c\u4f18\u5f02\u7684\u7acb\u4f53\u9009\u62e9\u6027\u63a7\u5236\u6765\u81ea\u4e24\u4e2a\u65b9\u9762\uff1a\uff081\uff09\u03c0-\u70ef\u4e19\u57faPd<\/span><span style=\"font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei'; font-size: 18px;\">II<\/span><span style=\"font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei';\">\u4e2d\u95f4\u4f53\u9634\u79bb\u5b50\u7684\u624b\u6027\u73af\u5883\uff1b\uff082\uff09\u624b\u6027\u78f7\u9178\u9634\u79bb\u5b50\u7684\u81a6\u6c27\u5b98\u80fd\u56e2\u4e0e\u70ef\u80fa\u4e2d\u95f4\u4f53\u7684\u6c22\u952e\u4f5c\u7528\u30022011\u5e74\uff0cList\u6559\u6388\u5c0f\u7ec4\u5c06\u53cd\u5e94\u7684\u539f\u5b50\u7ecf\u6d4e\u6027\u8fdb\u4e00\u6b65\u63d0\u9ad8\uff1a\uff081\uff09\u4ee5\u4e3a\u70ef\u4e19\u9187\u4f5c\u4e3a\u70ef\u4e19\u57fa\u8bd5\u5242\uff1b\uff082\uff09\u4f7f\u7528\u50ac\u5316\u91cf\u7684\u4e8c\u82ef\u7532\u80fa\u6765\u6d3b\u5316\u919b\u7c7b\u5e95\u7269<\/span><span style=\"font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei'; font-size: 18px;\">[9]<\/span><span style=\"font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei';\">\u3002<span style=\"color: #3e3e3e; line-height: 25.6px; font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei'; font-size: 18px; background-color: #ffffff;\">2014\u5e74\uff0c<\/span><strong><span style=\"font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei';\">\u9f9a\u6d41\u67f1\u6559\u6388\u5c0f\u7ec4<\/span><\/strong><span style=\"color: #3e3e3e; line-height: 25.6px; font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei'; font-size: 18px; background-color: #ffffff;\">\u5c1d\u8bd5\u624b\u6027\u9634\u79bb\u5b50\u7b56\u7565\u5e94\u7528\u4e8ePd<\/span><span style=\"color: #3e3e3e; line-height: 0; font-family: 'helvetica neue', helvetica, 'hiragino sans gb', 'microsoft yahei', arial, sans-serif; font-size: 13.5px; vertical-align: baseline; background-color: #ffffff;\"><span style=\"font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei'; font-size: 18px;\">II<\/span><\/span><span style=\"color: #3e3e3e; line-height: 25.6px; font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei'; font-size: 18px; background-color: #ffffff;\">\u50ac\u5316\u7684\u70ef\u4e19\u57faC-H\u70f7\u57fa\u5316\u53cd\u5e94\uff0c\u5728\u590d\u6742\u7684\u50ac\u5316\u4f53\u7cfb\u4e0b\uff0c\u4f9d\u7136\u6210\u529f\u5b9e\u73b0\u4e86\u4f18\u79c0\u7684\u7acb\u4f53\u9009\u62e9\u6027\u63a7\u5236\u3002\u8be5\u53cd\u5e94\u7684\u57fa\u672c\u7b56\u7565\u4e0e\u4e0a\u8ff0List\u5c0f\u7ec4\u7684\u62a5\u9053\u4e00\u81f4\uff0c\u4fdd\u6301\u624b\u6027\u9634\u79bb\u5b50\u7ed3\u6784\u4e0d\u53d8\u7684\u60c5\u51b5\u4e0b\uff0c\u975e\u624b\u6027\u7684\u4f2f\u80fa\u50ac\u5316\u5242\u53ef\u4ee5\u6781\u5927\u7684\u5f71\u54cd\u53cd\u5e94\u6d3b\u6027\u4e0e\u7acb\u4f53\u9009\u62e9\u6027\u63a7\u5236<\/span><span style=\"color: #3e3e3e; line-height: 0; font-family: 'helvetica neue', helvetica, 'hiragino sans gb', 'microsoft yahei', arial, sans-serif; font-size: 13.5px; vertical-align: baseline; background-color: #ffffff;\"><span style=\"font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei'; font-size: 18px;\">[10]<\/span><\/span><span style=\"color: #3e3e3e; line-height: 25.6px; font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei'; font-size: 18px; background-color: #ffffff;\">\u3002<\/span><br \/>\n<\/span><\/p>\n<p style=\"color: #3e3e3e; text-indent: 28px; font-family: 'helvetica neue', helvetica, 'hiragino sans gb', 'microsoft yahei', arial, sans-serif; font-size: 14px;\"><strong><span style=\"font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei';\">\u7ed3\u8bed\uff1a<\/span><\/strong><\/p>\n<p style=\"color: #3e3e3e; text-indent: 28px; font-family: 'helvetica neue', helvetica, 'hiragino sans gb', 'microsoft yahei', arial, sans-serif; font-size: 14px;\"><span style=\"font-family: \u5fae\u8f6f\u96c5\u9ed1, 'microsoft yahei'; font-size: 18px;\"><span style=\"line-height: 28.8px; font-family: 'helvetica neue', helvetica, 'hiragino sans gb', 'microsoft yahei', arial, sans-serif;\">Pd<\/span><span style=\"line-height: 0; font-family: 'helvetica neue', helvetica, 'hiragino sans gb', 'microsoft yahei', arial, sans-serif; font-size: 13.5px; vertical-align: baseline;\">II<\/span>\u50ac\u5316\u7684\u70ef\u4e19\u57fa\u4e0d\u5bf9\u79f0C-H\u6d3b\u5316\u5df2\u7ecf\u53d6\u5f97\u4e86\u4e00\u4e9b\u7a81\u7834\u8fdb\u5c55\uff0c\u67d0\u79cd\u7a0b\u5ea6\u4e0a\uff0c\u662f\u5168\u4e16\u754c\u6709\u673a\u5316\u5b66\u5de5\u4f5c\u8005\u4e0d\u65ad\u8ffd\u6c42\u6781\u81f4\u7684\u4e00\u79cd\u4f53\u73b0\u3002\u7136\u800c\uff0c\u8fd9\u79cd\u65b9\u6cd5\u76ee\u524d\u4ecd\u5b58\u5728\u5f88\u591a\u5c40\u9650\u6027\uff0c\u5982\uff081\uff09\u9002\u7528\u7684\u4eb2\u6838\u8bd5\u5242\u79cd\u7c7b\u975e\u5e38\u6709\u9650\uff1b\uff082\uff09\u76f8\u5bf9\u4e8e\u4f20\u7edf\u7684\u70ef\u4e19\u57fa\u5316\u53cd\u5e94\uff0c\u7acb\u4f53\u9009\u62e9\u6027\u63a7\u5236\u666e\u904d\u4f1a\u7a0d\u5dee\u4e00\u70b9\u3002<\/span><\/p>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n","protected":false},"excerpt":{"rendered":"<p>Pd(II)\u50ac\u5316\u7684\u70ef\u4e19\u57fa\u4e0d\u5bf9\u79f0C-H\u6d3b\u5316\u7814\u7a76\u8fdb\u5c55 Pd0\u50ac\u5316\u7684\u70ef\u4e19\u57fa\u5316\u53cd\u5e94\uff08\u53c8\u540dTsuji-Trost\u53cd\u5e94\uff09\u63d0 [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1],"tags":[],"class_list":["post-535","post","type-post","status-publish","format-standard","hentry","category-dingzhiganhuo"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/535","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=535"}],"version-history":[{"count":2,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/535\/revisions"}],"predecessor-version":[{"id":5424,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/535\/revisions\/5424"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=535"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=535"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=535"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}