{"id":52390,"date":"2024-09-28T08:49:50","date_gmt":"2024-09-28T00:49:50","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=52390"},"modified":"2024-09-18T15:51:48","modified_gmt":"2024-09-18T07:51:48","slug":"%e3%80%90jacs%e3%80%91%e5%8f%8c%e9%85%8d%e4%bd%93%e5%8d%8f%e5%90%8c%e9%92%af%e5%82%ac%e5%8c%96%ef%bc%9a%e7%a2%98%e4%bb%a3%e8%8a%b3%e7%83%83%e9%82%bb%e4%bd%8d%e7%83%b7%e5%9f%ba%e5%8c%96%e7%9a%84","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/%e3%80%90jacs%e3%80%91%e5%8f%8c%e9%85%8d%e4%bd%93%e5%8d%8f%e5%90%8c%e9%92%af%e5%82%ac%e5%8c%96%ef%bc%9a%e7%a2%98%e4%bb%a3%e8%8a%b3%e7%83%83%e9%82%bb%e4%bd%8d%e7%83%b7%e5%9f%ba%e5%8c%96%e7%9a%84\/","title":{"rendered":"\u3010JACS\u3011\u53cc\u914d\u4f53\u534f\u540c\u94af\u50ac\u5316\uff1a\u7898\u4ee3\u82b3\u70c3\u90bb\u4f4d\u70f7\u57fa\u5316\u7684\u5168\u65b0\u7b56\u7565"},"content":{"rendered":"

\"1\"<\/p>\n

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\u4f20\u7edf\u7684\u94af\/\u964d\u51b0\u7247\u70ef<\/span>\uff08Catellani\u53cd\u5e94\uff09\u662f\u591a\u529f\u80fd\u5316\u82b3\u9999\u5316\u5408\u7269\u7684\u4e3b\u8981\u624b\u6bb5\uff0c\u80fd\u591f\u540c\u65f6\u5728\u78b3-\u7898\u952e\u7684\u90bb\u4f4d\uff08ortho\uff09\u548c\u539f\u4f4d\uff08ipso\uff09\u8fdb\u884c\u5b98\u80fd\u56e2\u5316\u3002\uff08\u56fe1a\uff09\u7136\u800c\uff0c\u5728\u8fd9\u4e00\u50ac\u5316\u4f53\u7cfb\u4e0b\uff0c\u82b3\u7898\u7684C(sp2<\/sup>)-I\u8fd8\u539f\u6d88\u9664\u53cd\u5e94<\/span>\u5e94\u7528\u8f83\u5c11\uff0c\u9650\u5236\u4e86\u8be5\u65b9\u6cd5\u7684\u5e7f\u6cdb\u9002\u7528\u6027\u3002\u56e0\u6b64\uff0c\u5f00\u53d1\u80fd\u591f\u91cd\u65b0\u6784\u5efa\u78b3-\u7898\u952e\u7684\u53cd\u5e94\u6a21\u5f0f\u5177\u6709\u6781\u5927\u7684\u6f5c\u529b\uff0c\u7279\u522b\u662f\u5728\u4e0d\u7834\u574f\u8be5\u952e\u7684\u524d\u63d0\u4e0b\u8fdb\u884c\u90bb\u4f4d\u529f\u80fd\u5316\uff0c\u53ef\u4ee5\u4e3a\u590d\u6742\u591a\u53d6\u4ee3\u82b3\u9999\u5206\u5b50\u7684\u5408\u6210\u63d0\u4f9b\u5168\u65b0\u9014\u5f84\u3002<\/section>\n

\"2\"<\/p>\n

\u56fe\u7247\u6765\u6e90\uff1aJACS<\/p>\n

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\"8\"\u200b<\/p>\n

\u56fe\u7247\u6765\u6e90\uff1aJACS<\/p>\n

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\u8fd9\u4e00\u521b\u65b0\u6027\u50ac\u5316\u4f53\u7cfb\u5728\u5408\u6210\u591a\u53d6\u4ee3\u82b3\u9999\u5316\u5408\u7269\u65b9\u9762\u8868\u73b0\u51fa\u72ec\u7279\u7684\u4f18\u52bf\uff0c\u7279\u522b\u662f\u5728\u836f\u7269\u5316\u5b66\u548c\u6750\u6599\u79d1\u5b66\u9886\u57df\uff0c\u80fd\u591f\u4e3a\u590d\u6742\u5206\u5b50\u7ed3\u6784\u7684\u9ad8\u6548\u6784\u5efa\u63d0\u4f9b\u65b0\u7684\u8def\u5f84\u3002\u540c\u65f6\uff0c\u8be5\u7814\u7a76\u6240\u63ed\u793a\u7684\u53cc\u914d\u4f53\u534f\u540c\u673a\u5236\u4e5f\u4e3a\u5176\u4ed6\u91d1\u5c5e\u50ac\u5316\u53cd\u5e94\u7684\u8bbe\u8ba1\u548c\u5f00\u53d1\u63d0\u4f9b\u4e86\u6709\u529b\u7684\u7406\u8bba\u57fa\u7840\uff0c\u8fdb\u4e00\u6b65\u63a8\u52a8\u4e86\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u4f53\u7cfb\u7684\u591a\u6837\u5316\u5e94\u7528\u3002\u56e0\u6b64\uff0c\u672c\u7814\u7a76\u4e0d\u4ec5\u5728\u57fa\u7840\u6709\u673a\u5408\u6210\u7814\u7a76\u4e2d\u5177\u6709\u91cd\u8981\u4ef7\u503c\uff0c\u8fd8\u4e3a\u5b9e\u9645\u5e94\u7528\u63d0\u4f9b\u4e86\u53ef\u64cd\u4f5c\u7684\u521b\u65b0\u65b9\u6cd5\u3002<\/section>\n

\u6807\u9898\uff1aDual Ligand Enabled Pd-Catalyzed Ortho-Alkylation of Iodoarenes<\/p>\n

\u4f5c\u8005\uff1aXiao-Xia Wang and Lei Jiao*<\/p>\n

\u94fe\u63a5\uff1ahttps:\/\/doi.org\/10.1021\/jacs.4c06544<\/p>\n","protected":false},"excerpt":{"rendered":"

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