{"id":52343,"date":"2024-09-21T08:03:22","date_gmt":"2024-09-21T00:03:22","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=52343"},"modified":"2024-09-12T10:06:02","modified_gmt":"2024-09-12T02:06:02","slug":"%e6%96%b0%e7%96%86%e5%a4%a7%e5%ad%a6%e7%8e%8b%e9%b2%81%e9%a6%99%e7%a0%94%e7%a9%b6%e5%91%98%e8%af%be%e9%a2%98%e7%bb%84%ef%bc%9a%e5%8f%8c%e7%a9%ba%e4%bd%8ds-scheme%e5%85%89%e5%82%ac%e5%8c%96%e5%89%82","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/%e6%96%b0%e7%96%86%e5%a4%a7%e5%ad%a6%e7%8e%8b%e9%b2%81%e9%a6%99%e7%a0%94%e7%a9%b6%e5%91%98%e8%af%be%e9%a2%98%e7%bb%84%ef%bc%9a%e5%8f%8c%e7%a9%ba%e4%bd%8ds-scheme%e5%85%89%e5%82%ac%e5%8c%96%e5%89%82\/","title":{"rendered":"\u65b0\u7586\u5927\u5b66\u738b\u9c81\u9999\u7814\u7a76\u5458\u8bfe\u9898\u7ec4\uff1a\u53cc\u7a7a\u4f4dS-scheme\u5149\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u53ca\u5176\u5149\u50ac\u5316CO2\u8fd8\u539f\u7684\u6027\u80fd\u7814\u7a76"},"content":{"rendered":"<section>\u25b2\u7b2c\u4e00\u4f5c\u8005\uff1a\u8c2d\u5ddd<\/section>\n<section>\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff1a\u827e\u793c\u8389\u3001\u738b\u9c81\u9999<\/section>\n<section>\u901a\u8baf\u5355\u4f4d\uff1a\u65b0\u7586\u5927\u5b66\u00a0<\/section>\n<section>\u8bba\u6587DOI\uff1a10.1039\/d4ta04825c\u00a0\uff08\u70b9\u51fb\u6587\u672b\u300c\u9605\u8bfb\u539f\u6587\u300d\uff0c\u76f4\u8fbe\u94fe\u63a5\uff09<\/section>\n<section><\/section>\n<section data-mpa-template=\"t\">\n<section data-mpa-template=\"t\">\n<section>\n<section data-mpa-category=\"\u6a21\u677f\" data-mid=\"\">\n<section data-mid=\"\">\n<section data-mid=\"\"><\/section>\n<section data-mid=\"\">\u00a0\u00a0<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section><strong>\u5168\u6587\u901f\u89c8<\/strong><\/section>\n<section>\u672c\u6587\u6240\u8bbe\u8ba1\u7684\u53cc\u7a7a\u4f4dS-scheme CdS\/BiOCl\u590d\u5408\u6750\u6599\u5728CO<sub>2<\/sub>\u5149\u8fd8\u539f\u9886\u57df\u5c55\u73b0\u51fa\u4e86\u4e00\u5b9a\u7684\u6f5c\u529b\u548c\u5e94\u7528\u524d\u666f\u3002\u8fd9\u4e00\u7814\u7a76\u6210\u679c\u4e0d\u4ec5\u4e3a\u9ad8\u6548\u3001\u9ad8\u9009\u62e9\u6027CO<sub>2<\/sub>\u5149\u8fd8\u539f\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\u548c\u65b9\u6cd5\uff0c\u4e5f\u4e3a\u63a8\u52a8\u8be5\u9886\u57df\u7684\u8fdb\u4e00\u6b65\u53d1\u5c55\u5960\u5b9a\u4e86\u575a\u5b9e\u7684\u57fa\u7840\u3002<\/section>\n<section><\/section>\n<section data-mpa-template=\"t\">\n<section data-mpa-template=\"t\">\n<section>\n<section data-mpa-category=\"\u6a21\u677f\" data-mid=\"\">\n<section data-mid=\"\">\n<section data-mid=\"\"><\/section>\n<section data-mid=\"\">\u00a0\u00a0<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section><strong>\u80cc\u666f\u4ecb\u7ecd<\/strong><\/section>\n<section>\u968f\u7740\u5168\u7403\u80fd\u6e90\u5371\u673a\u548c\u73af\u5883\u6c61\u67d3\u95ee\u9898\u7684\u65e5\u76ca\u4e25\u5cfb\uff0c\u5f00\u53d1\u9ad8\u6548\u3001\u53ef\u6301\u7eed\u7684CO<sub>2<\/sub>\u8f6c\u5316\u6280\u672f\u6210\u4e3a\u79d1\u5b66\u7814\u7a76\u7684\u70ed\u70b9\u3002\u5149\u50ac\u5316CO<sub>2<\/sub>\u8fd8\u539f\u4f5c\u4e3a\u4e00\u79cd\u7eff\u8272\u3001\u73af\u4fdd\u7684CO<sub>2<\/sub>\u8f6c\u5316\u9014\u5f84\uff0c\u80fd\u591f\u5c06\u6e29\u5ba4\u6c14\u4f53CO<sub>2<\/sub>\u8f6c\u5316\u4e3a\u6709\u4ef7\u503c\u7684\u5316\u5b66\u54c1\u6216\u71c3\u6599\uff0c\u5177\u6709\u5de8\u5927\u7684\u5e94\u7528\u6f5c\u529b\u3002\u7136\u800c\uff0c\u4f20\u7edf\u5149\u50ac\u5316\u5242\u5728\u5149\u751f\u8f7d\u6d41\u5b50\u5206\u79bb\u6548\u7387\u548c\u8868\u9762\u53cd\u5e94\u6d3b\u6027\u7b49\u65b9\u9762\u5b58\u5728\u4e0d\u8db3\uff0c\u9650\u5236\u4e86\u5176\u5149\u50ac\u5316\u6027\u80fd\u7684\u63d0\u5347\u3002\u4e3a\u4e86\u514b\u670d\u8fd9\u4e9b\u6311\u6218\uff0c\u672c\u8bfe\u9898\u7ec4\u81f4\u529b\u4e8e\u8bbe\u8ba1\u65b0\u578b\u5149\u50ac\u5316\u5242\uff0c\u5176\u4e2d\u53cc\u7a7a\u4f4dS-scheme\u5f02\u8d28\u7ed3\u6784\u56e0\u5176\u72ec\u7279\u7684\u7535\u8377\u8f6c\u79fb\u673a\u5236\u548c\u589e\u5f3a\u7684\u6c27\u5316\u8fd8\u539f\u80fd\u529b\u800c\u5907\u53d7\u5173\u6ce8\u3002\u7279\u522b\u662f<span class=\"\">CdS<\/span>\/BiOCl\u4f53\u7cfb\uff0c\u8be5\u4f53\u7cfb\u4e2d\uff0cCdS\u5177\u6709\u4f18\u5f02\u7684\u5149\u5438\u6536\u6027\u80fd\uff0cBiOCl\u5177\u6709\u9ad8\u7a33\u5b9a\u6027\u53ca\u826f\u597d\u7684\u6c27\u5316\u8fd8\u539f\u6027\u80fd\uff0c\u4e24\u8005\u7ed3\u5408\u5f62\u6210\u7684S-scheme\u5f02\u8d28\u7ed3\u6784\u6709\u671b\u5c55\u73b0\u51fa\u66f4\u4f18\u5f02\u7684\u5149\u50ac\u5316\u8fd8\u539f\u80fd\u529b\u3002\u56e0\u6b64\uff0c\u672c\u7814\u7a76\u805a\u7126\u4e8e\u201cS-scheme\u53cc\u7a7a\u4f4dCdS\/BiOCl\u5149\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u53ca\u5176\u5149\u50ac\u5316CO<sub>2<\/sub>\u8fd8\u539f\u7684\u6027\u80fd\u7814\u7a76\u201d\uff0c\u65e8\u5728\u901a\u8fc7\u5f15\u5165\u6c27\u7a7a\u4f4d\u548c\u786b\u7a7a\u4f4d\u53cc\u7f3a\u9677\uff0c\u8fdb\u4e00\u6b65\u4f18\u5316CdS\/BiOCl\u5f02\u8d28\u7ed3\u6784\u7684\u7535\u8377\u5206\u79bb\u6548\u7387\u548c\u8868\u9762\u53cd\u5e94\u6d3b\u6027\uff0c\u4ece\u800c\u663e\u8457\u63d0\u5347\u5176\u5149\u50ac\u5316CO<sub>2<\/sub>\u8fd8\u539f\u7684\u6027\u80fd\u3002\u8fd9\u4e00\u7814\u7a76\u4e0d\u4ec5\u4e3a\u9ad8\u6548\u5149\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\uff0c\u4e5f\u4e3a\u63a8\u52a8\u5149\u50ac\u5316CO<sub>2<\/sub>\u8fd8\u539f\u6280\u672f\u7684\u5b9e\u9645\u5e94\u7528\u5960\u5b9a\u4e86\u7406\u8bba\u57fa\u7840\u3002<\/section>\n<section><\/section>\n<section data-mpa-template=\"t\">\n<section data-mpa-template=\"t\">\n<section>\n<section data-mpa-category=\"\u6a21\u677f\" data-mid=\"\">\n<section data-mid=\"\">\n<section data-mid=\"\"><\/section>\n<section data-mid=\"\">\u00a0\u00a0<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section><strong>\u7814\u7a76\u51fa\u53d1\u70b9<\/strong><\/section>\n<section>\u9274\u4e8e\u4f20\u7edf\u5149\u50ac\u5316\u5242\u5728\u5149\u50ac\u5316CO<sub>2<\/sub>\u8fd8\u539f\u8fc7\u7a0b\u4e2d\u9762\u4e34\u7684\u5149\u751f\u8f7d\u6d41\u5b50\u590d\u5408\u7387\u9ad8\u3001\u8868\u9762\u53cd\u5e94\u6d3b\u6027\u4e0d\u8db3\u7b49\u5173\u952e\u95ee\u9898\uff0c\u672c\u7814\u7a76\u901a\u8fc7\u8bbe\u8ba1\u4e00\u79cd\u65b0\u578b\u7684S-scheme\u53cc\u7a7a\u4f4dCdS\/BiOCl\u5149\u50ac\u5316\u5242\uff0c\u5229\u7528\u6c27\u7a7a\u4f4d\u548c\u786b\u7a7a\u4f4d\u7684\u53cc\u91cd\u4f5c\u7528\uff0c\u4ee5\u53caS-scheme\u5f02\u8d28\u7ed3\u6784\u7684\u72ec\u7279\u7535\u8377\u8f6c\u79fb\u673a\u5236\uff0c\u6765\u589e\u5f3a\u5149\u50ac\u5316\u5242\u7684\u7535\u8377\u5206\u79bb\u6548\u7387\u3001\u63d0\u5347\u8868\u9762\u53cd\u5e94\u6d3b\u6027\uff0c\u5e76\u6700\u7ec8\u5b9e\u73b0\u9ad8\u6548\u3001\u9ad8\u9009\u62e9\u6027\u7684\u5149\u50ac\u5316CO<sub>2<\/sub>\u8fd8\u539f\u6027\u80fd\u3002\u8fd9\u4e00\u7814\u7a76\u51fa\u53d1\u70b9\u65e8\u5728\u7a81\u7834\u73b0\u6709\u5149\u50ac\u5316\u5242\u7684\u6027\u80fd\u74f6\u9888\uff0c\u4e3a\u5f00\u53d1\u65b0\u578b\u9ad8\u6548\u5149\u50ac\u5316\u6750\u6599\u63d0\u4f9b\u79d1\u5b66\u4f9d\u636e\u548c\u6280\u672f\u652f\u6301\u3002<\/section>\n<section><\/section>\n<section data-mpa-template=\"t\">\n<section data-mpa-template=\"t\">\n<section>\n<section data-mpa-category=\"\u6a21\u677f\" data-mid=\"\">\n<section data-mid=\"\">\n<section data-mid=\"\"><\/section>\n<section data-mid=\"\">\u00a0\u00a0<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section><strong>\u56fe\u6587\u89e3\u6790<\/strong><\/section>\n<section><strong>4.1\u3001\u7269\u76f8\u548c\u8868\u9762\u5143\u7d20\u5206\u6790<\/strong><\/section>\n<section><img decoding=\"async\" title=\"1\" src=\"https:\/\/10110.seohost.cn\/storage\/10110\/article\/20240912\/1726106671812051.png\" alt=\"1\" \/>Figure 1. (a) XRD patterns, (b-e) XPS spectra of the OV-B, SV-C and OV-B\/SV-C samples: (b) Cl 2p, (c) O 1s, (d) Bi 4f, (e) Cd 3d; (f) EPR spectra of the as-prepared samples<\/section>\n<section><\/section>\n<section>\u7ed3\u5408XRD\u548cXPS\u6280\u672f\uff0c\u76f4\u63a5\u8bc1\u660e\u4e86CdS\/BiOCl\u590d\u5408\u5149\u50ac\u5316\u7684\u6210\u529f\u5236\u5907\u3002\u901a\u8fc7\u5206\u6790Bi\u3001Cd\u548cO\u5143\u7d20\u7684\u7cbe\u7ec6\u8c31\uff0c\u6211\u4eec\u53d1\u73b0\u5728CdS\u548cBiOCl\u4e24\u76f8\u7684\u4ea4\u754c\u9762\u5904\u53ef\u80fd\u5f62\u6210\u4e86\u65b0\u7684\u5316\u5b66\u952e\uff08Bi-O-Cd-S\uff09\uff0c\u65b0\u952e\u7684\u5f62\u6210\u4e0d\u4ec5\u53ef\u4ee5\u4f5c\u4e3a\u8f7d\u6d41\u5b50\u4f20\u8f93\u901a\u9053\uff0c\u800c\u4e14\u8fd8\u80fd\u964d\u4f4e\u754c\u9762\u7535\u5b50\u8fc1\u79fb\u7684\u80fd\u5792\u548c\u8ddd\u79bb\uff0c\u4ece\u800c\u52a0\u901f\u4e86\u8f7d\u6d41\u5b50\u7684\u4f20\u8f93\u548c\u5206\u79bb\uff0c\u63d0\u9ad8\u4e86\u5149\u50ac\u5316\u5242\u7684\u6027\u80fd\u3002EPR\u7ed3\u679c\u8868\u660e\uff0c\u53cc\u7a7a\u4f4dCdS\/BiOCl\u5149\u50ac\u5316\u5242\u62e5\u6709\u6bd4\u5176\u4ed6\u6837\u54c1\u66f4\u9ad8\u7684EPR\u4fe1\u53f7\uff0c\u8bc1\u660e\u540c\u65f6\u4ea7\u751f\u4e86\u6c27\u548c\u786b\u4e24\u79cd\u7a7a\u4f4d\u3002<\/section>\n<section><\/section>\n<section><strong>4.2\u3001\u5f62\u8c8c\u548c\u6676\u76f8\u5206\u6790<\/strong><\/section>\n<section><img decoding=\"async\" title=\"2\" src=\"https:\/\/10110.seohost.cn\/storage\/10110\/article\/20240912\/1726106683144584.png\" alt=\"2\" \/>Figure 2. (a-c) FESEM and (d) TEM and (e) HRTEM images of (a) OV-B, (b) SV-C and (c-e) OV-B\/SV-C; (f) EDS elemental mapping images of OV-B\/SV-C: red Bi, green Cl, cyan O, blue S and purple Cd<\/section>\n<section><\/section>\n<section>FESEM\u548cTEM\u7ed3\u679c\u8868\u660e\uff0c\u6211\u4eec\u6210\u529f\u5730\u5408\u6210\u4e86\u5177\u6709\u82b1\u72b6\u7ed3\u6784\u7684CdS\/BiOCl\u5149\u50ac\u5316\u5242\u3002HRTEM\u56fe\u4e2d\u53ef\u6e05\u695a\u5730\u89c2\u5bdf\u5230\u95f4\u8ddd\u4e3a0.28 nm\u548c0.21 nm\u7684\u6676\u683c\u6761\u7eb9\uff0c\u5176\u5206\u522b\u5bf9\u5e94\u4e8eBiOCl\u7684\uff08110\uff09\u6676\u9762\u548cCdS\u7684\uff08110\uff09\u6676\u9762\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u5728CdS\u548cBiOCl\u4e4b\u95f4\u53ef\u4ee5\u6e05\u6670\u770b\u5230\u7d27\u5bc6\u7684\u754c\u9762\u8fde\u63a5\u7ed3\u6784\uff0c\u6781\u5927\u4fc3\u8fdb\u4e86\u5b83\u4eec\u4e4b\u95f4\u7684\u7535\u8377\u8f6c\u79fb\uff0c\u8fd9\u5bf9\u4e8e\u6291\u5236\u6750\u6599\u4e2d\u8f7d\u6d41\u5b50\u7684\u5feb\u901f\u590d\u5408\u5177\u6709\u79ef\u6781\u7684\u4f5c\u7528\u3002<\/section>\n<section><\/section>\n<section><strong>4.3\u3001\u50ac\u5316\u6027\u80fd\u7814\u7a76<\/strong><\/section>\n<section><img decoding=\"async\" title=\"3\" src=\"https:\/\/10110.seohost.cn\/storage\/10110\/article\/20240912\/1726106694746835.png\" alt=\"3\" \/>Figure 3. (a) CO evolution rate of OV-B\/SV-C sample under H<sub>2<\/sub>O:MeCN system with different volume ratio; (b) Evolution rates of products for all samples; (c) CO evolution rate of OV-B\/SV-C sample under different conditions; (d) Recycle experiment of as-prepared samples; (e) Degradation curves and (f) apparent rate constant of as-prepared samples over Cr(\u2165); (g) Degradation curves in the present of different capture reagents of Cr(\u2165) over OV-B\/SV-C<\/section>\n<section><\/section>\n<section>\u6240\u5236\u5907\u7684\u53cc\u7a7a\u4f4dCdS\/BiOCl\u5149\u50ac\u5316\u5242\u4e0d\u4ec5\u80fd\u591f\u5728\u65e0\u4efb\u4f55\u727a\u7272\u5242\u6761\u4ef6\u4e0b\u9ad8\u9009\u62e9\u6027\uff0897%\uff09\u5730\u5c06CO<sub>2<\/sub>\u5149\u8fd8\u539f\u4e3aCO\uff0c\u800c\u4e14\u80fd\u9ad8\u6548\u5730\u53bb\u9664\u6c34\u4e2d\u7684\u91cd\u91d1\u5c5e\u79bb\u5b50\u3002\u5176\u4f18\u5f02\u7684\u5149\u50ac\u5316\u6027\u80fd\u4e3b\u8981\u5f52\u7ed3\u4e8e\u4ee5\u4e0b\u51e0\u70b9\uff1a1\uff09\u72ec\u7279\u7684S-scheme\u5f02\u8d28\u7ed3\u6784\u6781\u5927\u5730\u4fc3\u8fdb\u4e86\u5149\u751f\u8f7d\u6d41\u5b50\u7684\u5206\u79bb\uff1b2\uff09\u53cc\u7a7a\u4f4d\u7684\u5f15\u5165\u4e0d\u4ec5\u4fc3\u8fdb\u4e24\u76f8\u754c\u9762\u95f4\u7684\u7535\u5b50\u8f6c\u79fb\uff0c\u800c\u4e14\u4f5c\u4e3a\u53cd\u5e94\u6d3b\u6027\u70b9\uff0c\u6781\u5927\u5730\u964d\u4f4e\u5149\u53cd\u5e94\u4e2d\u5173\u952e\u4e2d\u95f4\u4ea7\u7269\u751f\u6210\u65f6\u6240\u9700\u8981\u7684\u80fd\u91cf\u52bf\u5792\u3002<\/section>\n<section><\/section>\n<section><strong>4.4\u3001S-scheme\u7535\u5b50\u8f6c\u79fb\u673a\u7406<\/strong><\/section>\n<section><img decoding=\"async\" title=\"4\" src=\"https:\/\/10110.seohost.cn\/storage\/10110\/article\/20240912\/1726106705120188.png\" alt=\"4\" \/>Figure\u00a04. EPR spectra of (a) \u00b7OH<sup>&#8211;<\/sup>\u00a0and (b) \u00b7O<sub>2<\/sub><sup>&#8211;<\/sup>\u00a0for OV-B, SV-C and OV-B\/SV-C; (c-d) Electrostatic potential of (c) OV-B and (d) SV-C; (e) Charge density difference of BiOCl\/CdS and OV-B\/SV-C; (f) Band structure of the heterostructure between OV-B and SV-C<\/section>\n<section><\/section>\n<section>\u7531DFT\u8ba1\u7b97\u548c\u77ac\u6001\u81ea\u7531\u57fa\u6d4b\u8bd5\u7ed3\u679c\u5f97\u77e5\uff0c\u53cc\u7a7a\u4f4dCdS\/BiOCl\u5149\u50ac\u5316\u5242\u7684\u8f7d\u6d41\u5b50\u8f6c\u79fb\u8def\u5f84\u5c5e\u4e8e\u5178\u578b\u7684S-scheme\u5f02\u8d28\u7ed3\u3002\u6b64\u5916\uff0c\u5dee\u5206\u7535\u8377\u7ed3\u679c\u8fdb\u4e00\u6b65\u8bc1\u5b9e\u4e86\u53cc\u7a7a\u4f4d\u7684\u5f15\u5165\u80fd\u591f\u660e\u663e\u5730\u4fc3\u8fdbCdS\u548cBiOCl\u4e24\u76f8\u754c\u9762\u95f4\u7684\u7535\u5b50\u8f6c\u79fb\uff0c\u8fd9\u5bf9\u4e8e\u5149\u751f\u8f7d\u6d41\u5b50\u7684\u8fd0\u8f93\u8d77\u7740\u6781\u5176\u91cd\u8981\u7684\u4f5c\u7528\u3002<\/section>\n<section><\/section>\n<section><strong>4.5\u3001CO<sub>2<\/sub>\u5149\u8fd8\u539f\u673a\u7406\u5206\u6790<\/strong><\/section>\n<section><img decoding=\"async\" title=\"7\" src=\"https:\/\/10110.seohost.cn\/storage\/10110\/article\/20240912\/1726106720614681.png\" alt=\"7\" \/>\u200bFigure 5. E<sub>ads<\/sub>\u00a0of the intermediate products on the photocatalyst surface: (a) B\/SV-C, (b) OV-B\/C and (c) OV-B\/SV-C; (d) Gibbs free energy calculations of as-prepared samples; (e) Schematic illustration of dual-defective OV-B\/SV-C for promoting the photoreduction of CO<sub>2<\/sub>\u00a0to CO<\/section>\n<section><\/section>\n<section>\u5229\u7528\u7b2c\u4e00\u6027\u539f\u7406\u8ba1\u7b97\u4e86\u5149\u50ac\u5316\u5242\u4e0e\u5404\u4e2d\u95f4\u4ea7\u7269\u7684\u5438\u9644\u80fd\uff08E<sub>ads<\/sub>\uff09\u3002\u7ed3\u679c\u8868\u660e\uff0c\u53cc\u7a7a\u4f4d\u7684\u5f15\u5165\u4e0d\u4ec5\u6709\u5229\u4e8eCO<sub>2<\/sub>\u5206\u5b50\u7684\u5438\u9644\uff0c\u800c\u4e14\u4ea7\u7269\uff08CO\uff09\u66f4\u6613\u9003\u9038\u51fa\u53bb\uff0c\u8fd9\u4e5f\u662f\u9ad8\u9009\u62e9\u6027\u751f\u6210CO\u7684\u4e3b\u8981\u539f\u56e0\u3002\u6b64\u5916\uff0c\u901a\u8fc7\u7b2c\u4e00\u6027\u539f\u7406\u8ba1\u7b97\u8fdb\u4e00\u6b65\u63a2\u7a76\u4e86\u5728\u5149\u50ac\u5316CO<sub>2<\/sub>\u8fd8\u539f\u8fc7\u7a0b\u4e2d\uff0c\u6837\u54c1\u751f\u6210\u5404\u4e2d\u95f4\u4ea7\u7269\u65f6\u6240\u9700\u7684Gibbs\u81ea\u7531\u80fd\u53d8\uff08\u25b3G\uff09\u3002\u7ed3\u679c\u53d1\u73b0\uff0c\u53cc\u7f3a\u9677\u7684\u5f15\u5165\u4e0d\u4ec5\u53ef\u4ee5\u663e\u8457\u589e\u5f3a\u5149\u50ac\u5316\u5242\u7684\u53cd\u5e94\u6d3b\u6027\uff0c\u4fc3\u8fdb\u5bf9CO<sub>2<\/sub>\u5206\u5b50\u7684\u5438\u9644\uff0c\u800c\u4e14\u8fd8\u80fd\u7a33\u5b9a\u5728\u5149\u50ac\u5316CO<sub>2<\/sub>\u8fd8\u539f\u8fc7\u7a0b\u4e2d\u4ea7\u751f\u7684\u548c\u4e2d\u95f4\u4ea7\u7269\uff0c\u8fd9\u6709\u5229\u4e8e\u5149\u50ac\u5316\u5242\u9ad8\u6548\u5730\u5c06CO<sub>2<\/sub>\u8fd8\u539f\u4e3aCO\u3002\u4e14\u8fd8\u539f\u4ea7\u7269\uff08CO\uff09\u5728\u5149\u50ac\u5316\u5242\u8868\u9762\u7684\u8131\u9644\u8fc7\u7a0b\u5c5e\u4e8e\u81ea\u53d1\u8fdb\u884c\u7684\u653e\u70ed\u53cd\u5e94\u3002\u5176\u4e2d\uff0cCO\u5728\u53cc\u7a7a\u4f4dCdS\/BiOCl\u5149\u50ac\u5316\u5242\u4e0a\u7684\u8131\u9644\u8fc7\u7a0b\u6240\u9700\u8981\u7684\u6700\u5c0f\uff0c\u8fd9\u8bf4\u660eCO\u5728\u53cc\u7a7a\u4f4dCdS\/BiOCl\u5149\u50ac\u5316\u5242\u8868\u9762\u6781\u6613\u9003\u9038\u51fa\u53bb\uff0c\u56e0\u6b64\uff0c\u53cc\u7a7a\u4f4dCdS\/BiOCl\u5149\u50ac\u5316\u5242\u5448\u73b0\u51fa\u8f83\u9ad8\u7684CO\u9009\u62e9\u6027\u3002<\/section>\n<section><\/section>\n<section data-mpa-template=\"t\">\n<section data-mpa-template=\"t\">\n<section>\n<section data-mpa-category=\"\u6a21\u677f\" data-mid=\"\">\n<section data-mid=\"\">\n<section data-mid=\"\"><\/section>\n<section data-mid=\"\">\u00a0\u00a0<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section><strong>\u603b\u7ed3\u4e0e\u5c55\u671b<\/strong><\/section>\n<section>\u672c\u7814\u7a76\u6210\u529f\u8bbe\u8ba1\u4e86S-scheme\u53cc\u7a7a\u4f4dCdS\/BiOCl\u5149\u50ac\u5316\u5242\uff0c\u901a\u8fc7\u5f15\u5165\u6c27\u7a7a\u4f4d\u548c\u786b\u7a7a\u4f4d\u663e\u8457\u63d0\u5347\u4e86\u5149\u50ac\u5316\u5242\u7684\u7535\u8377\u5206\u79bb\u6548\u7387\u548c\u8868\u9762\u53cd\u5e94\u6d3b\u6027\u3002\u5b9e\u9a8c\u7ed3\u679c\u8868\u660e\uff0c\u8be5\u50ac\u5316\u5242\u5728\u5149\u50ac\u5316CO<sub>2<\/sub>\u8fd8\u539f\u8fc7\u7a0b\u4e2d\u5c55\u73b0\u51fa\u4f18\u5f02\u7684CO\u6790\u51fa\u7387\u548c\u9ad8\u9009\u62e9\u6027\u3002\u8fd9\u4e00\u6210\u679c\u4e0d\u4ec5\u9a8c\u8bc1\u4e86\u53cc\u7a7a\u4f4dS-scheme\u5f02\u8d28\u7ed3\u6784\u5728\u5149\u50ac\u5316\u9886\u57df\u7684\u6f5c\u529b\uff0c\u4e5f\u4e3a\u672a\u6765\u9ad8\u6548\u5149\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\u3002<\/section>\n<section><\/section>\n<section>\u5c55\u671b\u672a\u6765\uff0c\u6211\u4eec\u5c06\u8fdb\u4e00\u6b65\u4f18\u5316\u53cc\u7a7a\u4f4dS-scheme CdS\/BiOCl\u5149\u50ac\u5316\u5242\u7684\u5236\u5907\u5de5\u827a\uff0c\u63a2\u7d22\u66f4\u591a\u79cd\u7c7b\u7684\u7a7a\u4f4d\u548c\u5f02\u8d28\u7ed3\u6784\u7ec4\u5408\uff0c\u4ee5\u671f\u5b9e\u73b0\u66f4\u9ad8\u7684\u5149\u50ac\u5316\u6548\u7387\u548c\u66f4\u5e7f\u6cdb\u7684\u5e94\u7528\u8303\u56f4\u3002\u540c\u65f6\uff0c\u6211\u4eec\u4e5f\u5c06\u6df1\u5165\u7814\u7a76\u5149\u50ac\u5316CO<sub>2<\/sub>\u8fd8\u539f\u7684\u673a\u7406\uff0c\u4e3a\u5f00\u53d1\u66f4\u52a0\u9ad8\u6548\u3001\u7a33\u5b9a\u7684\u5149\u50ac\u5316\u5242\u63d0\u4f9b\u7406\u8bba\u652f\u6301\u3002<\/section>\n","protected":false},"excerpt":{"rendered":"<p>\u25b2\u7b2c\u4e00\u4f5c\u8005\uff1a\u8c2d\u5ddd \u5171\u540c\u901a\u8baf\u4f5c\u8005\uff1a\u827e\u793c\u8389\u3001\u738b\u9c81\u9999 \u901a\u8baf\u5355\u4f4d\uff1a\u65b0\u7586\u5927\u5b66\u00a0 \u8bba\u6587DOI\uff1a10.1039\/d4ta04 [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14,3],"tags":[],"class_list":["post-52343","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu","category-hangyezixun"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/52343","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=52343"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/52343\/revisions"}],"predecessor-version":[{"id":52344,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/52343\/revisions\/52344"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=52343"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=52343"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=52343"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}