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\"3\"\u56fe3 PPV-Cu\u7f51\u7edc\u5149\u7535\u50ac\u5316NO3<\/sub>–<\/sup>\u8fd8\u539f\u5230NH3<\/sub><\/section>\n
\u00a0<\/sub><\/section>\n
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<\/section>\n
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\u8be5\u5de5\u4f5c\u6210\u529f\u6784\u5efa\u4e86\u57fa\u4e8ePPV\u7684\u5149\u7535\u5171\u8f6d\u805a\u5408\u7269\u7f51\u7edcPPV-Cu\uff0c\u9ad8\u6548\u5730\u5c06NO3<\/sub>–<\/sup>\u8fd8\u539f\u4e3aNH3<\/sub>\u3002\u9996\u5148\uff0c\u901a\u8fc7\u5728\u5171\u4ef7\u7f51\u7edc\u4e2d\u5316\u5b66\u4ea4\u8054\u6c27\u5316\u7684PPV\u94fe\uff0c\u5229\u7528\u5171\u4ef7\u7f51\u7edc\u4e2d\u7684\u79bb\u5b50\u76f8\u4e92\u4f5c\u7528\u5408\u6210\u4e86\u9ad8\u673a\u68b0\u5f3a\u5ea6\u7684PPV\u5149\u7535\u5171\u8f6d\u805a\u5408\u7269\u7f51\u7edc\u3002\u968f\u540e\u8d1f\u8f7d\u7684Cu\u50ac\u5316\u5242\u53ef\u4ee5\u901a\u8fc7\u8d85\u731d\u706dPPV*\u7684\u8367\u5149\uff0c\u8fdb\u800c\u9ad8\u6548\u5730\u5c06\u6fc0\u5b50\u89e3\u79bb\u6210\u81ea\u7531\u7535\u8377\u8f7d\u6d41\u5b50\uff0c\u4fc3\u8fdbNO3<\/sub>–<\/sup>\u8fd8\u539f\u3002PPV-Cu\u7f51\u7edc\u5728\u4e00\u4e2a\u6807\u51c6\u592a\u9633\u5149\u4e0b\u5149\u7535\u6d41\u5bc6\u5ea6\u4e3a8.5 mA cm-2<\/sup>\uff0c\u6cd5\u62c9\u7b2c\u6548\u7387\uff08FE(NH3<\/sub>)\uff09\u9ad8\u8fbe95%\uff0c\u5916\u91cf\u5b50\u6548\u7387\u4e3a13%\uff0c\u5176\u5353\u8d8a\u7684\u5149\u7535\u50ac\u5316\u6027\u80fd\u6e90\u4e8e\u5171\u4ef7\u7f51\u7edc\u4e2d\u81ea\u7531\u7535\u8377\u8f7d\u6d41\u5b50\u7684\u5feb\u901f\u4ea7\u751f\u548c\u4f20\u8f93\u3002\u901a\u8fc7\u7a33\u6001\u8367\u5149\u5149\u8c31\u548c\u7eb3\u79d2\u77ac\u6001\u5438\u6536\u5149\u8c31\uff0c\u4f5c\u8005\u8bc1\u660e\u4e86\u5149\u751f\u8f7d\u6d41\u5b50\u80fd\u591f\u5747\u5300\u5feb\u901f\u7684\u6269\u6563\u5230\u6574\u4e2a\u5171\u4ef7\u7f51\u7edc\u4e2d\uff0c\u4ece\u800c\u589e\u5f3aPPV-Cu\u7684\u5149\u7535\u50ac\u5316\u80fd\u529b\u3002\u901a\u8fc7\u539f\u4f4d\u626b\u63cf\u7535\u5316\u5b66\u663e\u5fae\u955c\uff0c\u4f5c\u8005\u8bc1\u660e\u4e86Cu\u50ac\u5316\u5242\u5728\u6574\u4e2a\u5171\u4ef7\u7f51\u7edc\u4e0a\u7684\u5747\u5300\u5206\u5e03\uff0c\u8fdb\u4e00\u6b65\u63d0\u5347\u4e86PPV-Cu\u7684\u5149\u7535\u50ac\u5316\u6027\u80fd\u3002\u57fa\u4e8e\u9ad8\u6548\u7684PPV-Cu\u7f51\u7edc\uff0c\u4f5c\u8005\u5c06\u5176\u4e0eBiVO4<\/sub>-RuO2<\/sub>\u5149\u9633\u6781\u4e32\u8054\u3002\u8be5\u4f53\u7cfb\u7684\u5149\u7535\u6d41\u548c\u4ea7\u7269\u4ea7\u7387\u662f\u5355\u7ed3BiVO4<\/sub>-RuO2<\/sub>\u7684\u5341\u500d\uff0c\u80fd\u591f\u53ef\u4ee5\u5c06NO3<\/sub>–<\/sup>\u6301\u7eed\u8f6c\u5316\u4e3aNH3<\/sub>\u4e14\u4ea7\u751fO2<\/sub>\uff0c\u6cd5\u62c9\u7b2c\u6548\u7387\u503c\u9ad8\u8fbe95%-98%\u3002\u8be5\u7814\u7a76\u9996\u6b21\u8868\u660e\uff0c\u9ad8\u6548\u7684\u5149\u751f\u8f7d\u6d41\u5b50\u5206\u79bb\u7684\u5171\u8f6d\u805a\u5408\u7269\u7f51\u7edc\u53ef\u4ee5\u4fc3\u8fdb\u5149\u9a71\u52a8NO3<\/sub>–<\/sup>\u8fd8\u539f\u3002\u8fd9\u4e3a\u57fa\u4e8e\u805a\u5408\u7269\u7684\u9ad8\u6548\u548c\u5927\u89c4\u6a21 PEC \u6750\u6599\u5149\u7535\u6781\u7684\u5e94\u7528\u5e26\u6765\u4e86\u5e0c\u671b\u3002<\/section>\n
<\/section>\n
\u8bfe\u9898\u7ec4\u4e3b\u9875: http:\/\/shan-group.net\/<\/section>\n
<\/section>\n
\u6587\u732e\u4fe1\u606f\uff1a<\/section>\n
Manipulating Photoconduction in Supramolecular Networks for Solar-Driven Nitrate Conversion to Ammonia and Oxygen<\/section>\n
Feiyang Hong, Xinhao Su, Yanjie Fang, Xinjia He, and Bing Shan*<\/section>\n
\u8bba\u6587\u94fe\u63a5\uff1a<\/section>\n
https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.4c09052<\/section>\n","protected":false},"excerpt":{"rendered":"

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