{"id":52290,"date":"2024-09-13T08:14:10","date_gmt":"2024-09-13T00:14:10","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=52290"},"modified":"2024-09-04T10:17:06","modified_gmt":"2024-09-04T02:17:06","slug":"%e4%b8%ad%e7%a7%91%e9%99%a2%e7%89%a9%e7%90%86%e6%89%80%e5%90%b4%e5%87%a1%e5%9b%a2%e9%98%9f%ef%bc%9a%e4%bd%8e%e5%8e%8b%e5%8a%9b%e6%97%a0%e6%9e%9d%e6%99%b6%e7%a1%ab%e5%8c%96%e7%89%a9%e5%9b%ba%e6%80%81","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/%e4%b8%ad%e7%a7%91%e9%99%a2%e7%89%a9%e7%90%86%e6%89%80%e5%90%b4%e5%87%a1%e5%9b%a2%e9%98%9f%ef%bc%9a%e4%bd%8e%e5%8e%8b%e5%8a%9b%e6%97%a0%e6%9e%9d%e6%99%b6%e7%a1%ab%e5%8c%96%e7%89%a9%e5%9b%ba%e6%80%81\/","title":{"rendered":"\u4e2d\u79d1\u9662\u7269\u7406\u6240\u5434\u51e1\u56e2\u961f\uff1a\u4f4e\u538b\u529b\u65e0\u679d\u6676\u786b\u5316\u7269\u56fa\u6001\u7535\u6c60"},"content":{"rendered":"
\u80cc\u666f\u4ecb\u7ecd<\/strong><\/section>\n
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\u8fd1\u5e74\u6765\uff0c\u4f7f\u7528\u56fa\u6001\u7535\u89e3\u8d28( SEs )\u7684\u56fa\u6001\u9502\u7535\u6c60( SSLBs )\u7531\u4e8e\u5176\u9ad8\u5b89\u5168\u6027\u3001\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u3001\u957f\u5faa\u73af\u5bff\u547d\u3001\u826f\u597d\u7684\u500d\u7387\u6027\u80fd\u548c\u5bbd\u5de5\u4f5c\u6e29\u5ea6\u8303\u56f4\u7b49\u4f18\u70b9\uff0c\u88ab\u5e7f\u6cdb\u8ba4\u4e3a\u662f\u4e0b\u4e00\u4ee3\u50a8\u80fd\u6280\u672f\u7684\u5173\u952e\u3002\u5c3d\u7ba1\u786b\u5316\u7269\u57faSSLBs\u9886\u57df\u8fd1\u5e74\u6765\u53d6\u5f97\u4e86\u8bf8\u591a\u8fdb\u5c55\uff0c\u4f46\u7535\u6781\/\u7535\u89e3\u8d28\u754c\u9762\u8f83\u5dee\u7684\u56fa\u56fa\u63a5\u89e6\u4ee5\u53ca\u8d1f\u6781\u4fa7\u7684\u9502\u679d\u6676\u751f\u957f\u9650\u5236\u4e86\u5176\u6027\u80fd\u7684\u63d0\u5347\u3002\u6b64\u5916\uff0c\u786b\u5316\u7269\u57faSSLBs\u5728\u7535\u6c60\u5de5\u4f5c\u671f\u95f4\u901a\u5e38\u9700\u8981\u8d85\u9ad8\u538b(\u51e0\u5341\u5230\u51e0\u767eMPa)\u6765\u4fdd\u6301\u826f\u597d\u754c\u9762\u63a5\u89e6\uff0c\u8fd9\u79cd\u9ad8\u538b\u529b\u9650\u5236\u4e86\u8be5\u7535\u6c60\u7684\u5b9e\u9645\u5e94\u7528\u3002<\/section>\n
\u4e3a\u6539\u5584Li\/\u786b\u5316\u7269\u754c\u9762\u63a5\u89e6\u4ee5\u53ca\u907f\u514d\u9502\u679d\u6676\u7684\u5f62\u6210\uff0c\u4e00\u79cd\u65b9\u6cd5\u662f\u5f15\u5165\u5177\u6709\u5feb\u901f\u79bb\u5b50\/\u7535\u5b50\u6df7\u5408\u5bfc\u7535\u6027\u80fd\u7684\u6db2\u4f53\u754c\u9762\u5c42\u6216\u8005\u6db2\u6001\u8d1f\u6781\uff0c\u5982\u7194\u878d\u78b1\u91d1\u5c5e\u548c\u6db2\u6001\u5408\u91d1\u3002\u7136\u800c\uff0c\u7194\u878d\u78b1\u91d1\u5c5e\u8d1f\u6781\u9700\u8981\u9ad8\u7684\u64cd\u4f5c\u6e29\u5ea6(> 200\u2103)\uff0c\u800c\u6613\u7194\u6db2\u6001\u5408\u91d1(\u5982\u94a0-\u94be\u5408\u91d1)\u53ef\u80fd\u5728\u5faa\u73af\u8fc7\u7a0b\u4e2d\u4ea7\u751f\u5206\u5c42\u51dd\u56fa\u3002\u53e6\u4e00\u79cd\u5bfc\u7535\u6db2\u4f53\u6750\u6599\u662f\u6db2\u6001\u78b1\u91d1\u5c5e\u82b3\u70c3\u7edc\u5408\u7269\uff0c\u5176\u5177\u6709\u4f4e\u6210\u672c\u3001\u9ad8\u5b89\u5168\u6027\u548c\u9ad8\u79bb\u5b50\/\u7535\u5b50\u5bfc\u7535\u6027\u7684\u4f18\u70b9\uff0c\u5434\u51e1\u56e2\u961f\u5728\u524d\u671f\u5de5\u4f5c\u4e2d\u5df2\u5f00\u53d1\u4e86Li-Bp-DME\u6db2\u6001\u8d1f\u6781\u642d\u914d\u786b\u5316\u7269\u7535\u89e3\u8d28\u7684\u65b0\u578b\u7535\u6c60\u3002\u7136\u800c\u6b64\u7c7b\u6db2\u6001\u8d1f\u6781\u6bd4\u5bb9\u91cf\u8f83\u4f4e\uff0c\u957f\u5faa\u73af\u7a33\u5b9a\u6027\u8f83\u5dee\uff0c\u4e14\u5e94\u7528\u8be5\u8d1f\u6781\u7684\u7535\u6c60\u901a\u5e38\u9700\u8981\u5b9a\u5236\u5316\u7684\u6a21\u5177\uff0c\u964d\u4f4e\u4e86\u7535\u6c60\u7684\u80fd\u91cf\u5bc6\u5ea6\u3002<\/section>\n
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\u00a0\u00a0<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n
\u5de5\u4f5c\u4ecb\u7ecd<\/strong><\/section>\n
\u4e3a\u6b64\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u7269\u7406\u7814\u7a76\u6240\u3001\u4e2d\u79d1\u56fa\u80fd<\/span>\u5434\u51e1\u56e2\u961f\u5f00\u53d1\u4e86\u4e00\u79cd\u65b0\u578b\u5ba4\u6e29\u6db2\u6001\u9502\u8d1f\u6781\u6750\u6599\u9502-\u83f2-\u919a\u7c7b\uff08Li-Phen-Ether\uff09\u3002\u5176\u76f8\u6bd4\u5df2\u62a5\u9053\u7684\u8054\u82ef(Bp)\u548c\u8418(Naph<\/span>)\u4f53\u7cfb\u5177\u6709\u66f4\u9ad8\u7684\u5b89\u5168\u6027\u548c\u5316\u5b66\u7a33\u5b9a\u6027\u3002\u4e3a\u4e86\u5b9e\u73b0\u66f4\u9ad8\u7684\u6bd4\u5bb9\u91cf\u548c\u66f4\u597d\u7684\u957f\u5faa\u73af\u7a33\u5b9a\u6027\uff0c\u8fdb\u4e00\u6b65\u7814\u5236\u4e863D LiSi@Li-Phen-Ether (3D LSLL)\u8d1f\u6781\uff0c\u8fd9\u79cd\u590d\u5408\u9633\u6781\u6bd4\u7eaf\u9502\u548c\u9502\u7845\u5408\u91d1\u66f4\u5b89\u5168\u3002\u57283D LSLL\u4e2d\uff0c\u4eb2\u9502\u7684Li-Phen-Ether\u5145\u5206\u6d78\u6da6LiSi\u5408\u91d1\u7c89\u672b\u5e76\u5f62\u62103D Li+\/e-\u5feb\u901f\u8fc1\u79fb\u8def\u5f84\u3002\u5f97\u76ca\u4e8e\u5145\u5206\u7a33\u5b9a\u7684\u8d1f\u6781\/SE\u754c\u9762\u63a5\u89e6\uff0c\u5bf9\u79f0\u7535\u6c60\u5728\u5ba4\u6e29\u4f4e\u538b\u4e0b\u5b9e\u73b0\u4e86\u9ad8\u4e34\u754c\u7535\u6d41\u5bc6\u5ea6(> 13mA cm-2<\/sup>)\u548c\u957f\u5faa\u73af\u5bff\u547d(> 1000 h\uff0c0.25mA cm-2<\/sup>)\u3002\u6b64\u5916\u5728\u6b63\u6781\u754c\u9762\u5904\u5f15\u5165DOL\u539f\u4f4d\u805a\u5408\u7684\u51dd\u80f6\u754c\u9762\u5c42\uff0c\u7ec4\u88c5\u7684LFP<\/span>\/\u786b\u5316\u7269\u7535\u89e3\u8d28\/3D LSLL\u5168\u7535\u6c60\u53ef\u4ee5\u5728\u6781\u4f4e\u7684\u5916\u90e8\u538b\u529b(0.5 MPa)\u548c\u5ba4\u6e29\u4e0b\u4ee5\u9ad8\u500d\u7387(2C)\u5b9e\u73b0\u8d85\u8fc7300\u6b21\u7684\u7a33\u5b9a\u5faa\u73af\u3002<\/section>\n
\u8be5\u6210\u679c\u4ee5\u201c\u00a0 Low-pressure Dendrite-free Sulfide Solid-state Battery with 3D LiSi@Li-Phen-Ether Anode\u201d<\/strong>\u4e3a\u9898\u53d1\u8868\u5728Energy Storage Materials<\/strong>\u4e0a<\/strong>\uff0c\u7b2c\u4e00\u4f5c\u8005\u4e3a\u4e2d\u56fd\u79d1\u5b66\u9662\u7269\u7406\u7814\u7a76\u6240\u535a\u58eb\u751f\u4f0d\u767b\u65ed\uff0c<\/strong>\u901a\u8baf\u4f5c\u8005\u4e3a\u4e2d\u56fd\u79d1\u5b66\u9662\u7269\u7406\u7814\u7a76\u6240\u5434\u51e1<\/strong>\u7814\u7a76\u5458\u3002<\/section>\n
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\u00a0\u00a0<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n
\u6838\u5fc3\u5185\u5bb9<\/strong><\/section>\n
1.<\/strong>\u65b0\u578b<\/strong>\u6db2\u6001\u9502\u91d1\u5c5e\u82b3\u70c3\u914d\u5408\u7269<\/strong>(Li-Phen-Ether)<\/strong><\/section>\n
\"1\"<\/section>\n
\u56fe1 (a)\u5173\u4e8e\u4f7f\u7528\u6db2\u6001\u78b1\u91d1\u5c5e\u82b3\u70c3\u7edc\u5408\u7269\u6eb6\u6db2\u4f5c\u4e3a\u9633\u6781\u7684\u7535\u6c60\u7684\u6587\u732e\u62a5\u9053\u3002(b )(\u4e0d)\u9971\u548cLi-Bp-DME\/Li-Naph-DME\/Li-Phen-DME\u7684\u79bb\u5b50\/\u7535\u5b50\/\u603b\u7535\u5bfc\u7387\u3002(c)\u5728\u5ba4\u6e29\u4e0b\u9759\u7f6e\u540e\uff0cDME\u5728Li-Bp-DME\/Li-Naph-DME\/Li-Phen-DME\u4e2d\u7684\u4fdd\u7559\u7387\u3002(d)\u5728\u5ba4\u6e29\u4e0b\u9759\u7f6e\u671f\u95f4Li-Bp-DME\/Li-Naph-DME\/Li-Phen-DME\u7684\u603b\u7535\u5bfc\u7387\u53d8\u5316\u3002(e)(\u672a)\u9971\u548c\u7684Li-Phen-DME\/Li-Phen-G2\/Li-Phen-G3\u7684\u79bb\u5b50\/\u7535\u5b50\/\u603b\u7535\u5bfc\u7387\u3002(f)\u4e0d\u540c\u9502\u6d53\u5ea6\u4e0bLi-Phen-G2\u7684\u79bb\u5b50\/\u7535\u5b50\/\u603b\u7535\u5bfc\u7387\u3002<\/section>\n
\u7531\u4e8e\u83f2\u7684\u79bb\u57df\u5171\u8f6d\u4f53\u7cfb\uff0cLi-Phen-Ether\u5177\u6709\u4f18\u5f02\u7684\u6df7\u5408\u5bfc\u7535\u6027\u80fd\u3002Fig.1b\u603b\u7ed3\u4e86Li-Bp-DME\/Li-Naph-DME\/Li-Phen-DME\u4f53\u7cfb\u7684\u79bb\u5b50\/\u7535\u5b50\/\u603b\u7535\u5bfc\u7387\u3002\u5176\u4e2dLi2<\/sub>Phen2<\/sub>DME10<\/sub>\u5177\u670911.0 mS cm-1\u7684\u9ad8\u603b\u7535\u5bfc\u7387\uff0c\u4e0eLi2<\/sub>Naph2<\/sub>DME10<\/sub>(12.0 mS cm-1)\u548cLi1.5<\/sub>Bp3<\/sub>DME10<\/sub>\u00a0(12.2 mS cm-1)\u76f8\u5f53\u3002\u5f53\u6db2\u4f53Li\u4e2d\u7684\u9502\u542b\u91cf\u9971\u548c\u65f6\uff0c\u9971\u548cLi-Phen2<\/sub>DME10<\/sub>\u7684\u603b\u7535\u5bfc\u7387\u964d\u4f4e\u52306.6 mS cm-1\u3002\u4e3a\u4e86\u63ed\u793a\u4e0d\u540c\u6db2\u6001Li\u7684\u7a33\u5b9a\u6027\uff0c\u5c06\u5c11\u91cfLi-Bp\/Naph\/Phen-DME\u5728\u5ba4\u6e29\u4e0b\u9759\u7f6e\u6325\u53d1\uff0c\u8bb0\u5f55\u5b83\u4eec\u7684\u8d28\u91cf\u4fdd\u7559\u7387\u3002\u5982\u56fe1c\u6240\u793a\uff0cDME\u5728Li-Bp-DME\u4e2d\u6325\u53d1\u6700\u5feb\uff0c\u5176\u6b21\u662fLi-Naph-DME\u3002\u800c\u5728Li-Phen-DME\u4e2d\uff0cDME\u7684\u6325\u53d1\u901f\u7387\u8f83\u5c0f\u3002\u6b64\u5916\uff0c\u5728\u4e0a\u8ff0\u8fc7\u7a0b\u4e2d\u8fd8\u8bb0\u5f55\u4e86Li-Bp\/Naph\/Phen-DME\u7684\u603b\u7535\u5bfc\u7387\u53d8\u5316(\u56fe1d\u548cS2\u8868)\u3002\u9759\u7f6e1\u5c0f\u65f6\u540e\uff0c\u6240\u6709\u6db2\u6001Li\u53d8\u6210\u9ed1\u8272\u56fa\u4f53\u3002Li-Bp-DME\u7684\u603b\u7535\u5bfc\u7387\u8fc5\u901f\u4e0b\u964d\u81f3\u7ea60.01 mS cm-1\uff0cLi-Naph-DME\u4fdd\u6301\u57280.1 mS cm-1\u3002\u800c\u5bf9\u4e8eLi-Phen-DME\uff0c\u7535\u5bfc\u7387\u572820\u5206\u949f\u5185\u4e0b\u964d\u975e\u5e38\u7f13\u6162\u3002\u5373\u4f7f\u5728\u6e38\u79bbDME\u5b8c\u5168\u6325\u53d1\u540e\uff0cLi-Phen\u4f53\u7cfb\u4ecd\u4fdd\u63010.4 mS cm-1\u7684\u7535\u5bfc\u7387\uff0c\u663e\u8457\u9ad8\u4e8eLi-Naph\u548cLi-Bp\u3002\u7531\u4ee5\u4e0a\u5206\u6790\u53ef\u77e5\uff0cLi-Phen-Ether\u4e0d\u4ec5\u5177\u6709\u9ad8\u7684\u79bb\u5b50\/\u7535\u5b50\u7535\u5bfc\u7387\uff0c\u800c\u4e14\u5177\u6709\u4f18\u5f02\u7684\u957f\u671f\u7a33\u5b9a\u6027\uff0c\u662f\u4e00\u79cd\u5f88\u6709\u524d\u9014\u7684\u65b0\u578b\u9633\u6781\u6750\u6599\u3002<\/section>\n
\u8003\u8651\u5230DME\u7684\u4f4e\u6cb8\u70b9(83\u00b0C)\u548c\u95ea\u70b9(2\u00b0C)\uff0c\u6709\u5fc5\u8981\u5f00\u53d1\u6cb8\u70b9\u548c\u95ea\u70b9\u66f4\u9ad8\u7684\u5176\u4ed6\u6eb6\u5242(\u5982\u4e8c\u7518\u9187\u4e8c\u7532\u919a(G2)\u548c\u4e09\u7518\u9187\u5355\u7532\u919a(G3))\u3002\u56fe1e\u603b\u7ed3\u4e8625\u00b0c\u65f6Li-Phen-DME\/G2\/G3\u7684\u79bb\u5b50\/\u7535\u5b50\/\u603b\u7535\u5bfc\u7387\u3002G2\u548cG3\u7684\u6eb6\u5242\u5316\u80fd\u529b\u6bd4DME\u5f31\uff0c\u56e0\u6b64\uff0c\u5728Li-Phen-G2\/G3\u4e2d\u9502\u9633\u79bb\u5b50\u4e0ePhen\u81ea\u7531\u57fa\u9634\u79bb\u5b50\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u66f4\u5f3a\uff0c\u6574\u4f53\u7535\u5bfc\u7387\u66f4\u4f4e\u3002\u7efc\u5408\u6765\u770b\uff0cLi-Phen-G2\u5177\u6709\u76f8\u5bf9\u8f83\u9ad8\u7684\u7535\u5bfc\u7387(5.4 mS cm-1)\u3001\u9ad8\u6cb8\u70b9\/\u95ea\u70b9\u548c\u4f4e\u6325\u53d1\u6027\uff0c\u4f7f\u5176\u6210\u4e3a\u4e00\u79cd\u5b89\u5168\u4e14\u957f\u671f\u7a33\u5b9a\u7684\u9633\u6781\u6750\u6599\u3002\u57fa\u4e8eLi-Phen-G2\u7cfb\u7edf\uff0c\u5177\u6709\u4e0d\u540cLi\u6d53\u5ea6\u7684Li-Phen-G2\u7684\u79bb\u5b50\/\u7535\u5b50\/\u603b\u7535\u5bfc\u7387\u603b\u7ed3\u5728\u8868S4\u548c\u56fe1f\u4e2d\u3002\u6709\u8da3\u7684\u662f\uff0c\u5bf9\u4e8eLi-Phen-Ether\u4f53\u7cfb\uff0c\u5f53Li\u6d53\u5ea6\u8f83\u4f4e\u65f6(\u53731M-2M\uff0c\u5bf9\u5e94Li1.5<\/sub>Phen3<\/sub>G210<\/sub>\u548cLi3<\/sub>Phen3<\/sub>G210<\/sub>)\uff0c\u6db2\u6001\u9502\u79bb\u5b50\u7535\u5bfc\u7387\u8fdc\u4f4e\u4e8e\u7535\u5b50\u7535\u5bfc\u7387\u3002\u7136\u800c\uff0c\u5f53Li\u9971\u548c\u65f6\uff0c\u79bb\u5b50\u7535\u5bfc\u7387\u5360\u4e3b\u5bfc\u5730\u4f4d(\u56fe1f)\u3002\u8fd9\u4e00\u73b0\u8c61\u4e0d\u540c\u4e8eLi-Bp-Ether\u4f53\u7cfb\uff0c\u5728\u8be5\u4f53\u7cfb\u4e2d\uff0c\u5373\u4f7fLi\u9971\u548c\uff0c\u7535\u5b50\u7535\u5bfc\u7387\u4e5f\u603b\u662f\u9ad8\u4e8e\u79bb\u5b50\u7535\u5bfc\u7387\u3002<\/section>\n
<\/section>\n
\"2\"<\/section>\n
\u56fe2. (a) 30\u00b0C \u65f6 Li-Bp-G2\/ LPSCl \/Li-Bp-G2 \u7ebd\u6263\u7535\u6c60\u7684\u6052\u7535\u6d41\u653e\u7535\/\u5145\u7535\u7535\u538b\u66f2\u7ebf\u3002(b) 30\u00b0C \u65f6 Li-Naph-G2\/ LPSCl \/Li-Naph-G2 \u7ebd\u6263\u7535\u6c60\u7684\u6052\u7535\u6d41\u653e\u7535\/\u5145\u7535\u7535\u538b\u66f2\u7ebf\u3002(c) 30\u00b0C \u65f6 Li-Phen-G2\/ LPSCl \/Li-Phen-G2 \u7ebd\u6263\u7535\u6c60\u7684\u6052\u7535\u6d41\u653e\u7535\/\u5145\u7535\u7535\u538b\u66f2\u7ebf\u3002(d)\u81ea\u5236Li-Phen-G2 \/ LPSCl \/Li-Phen -G2 \u7535\u6c60\u7684\u6052\u7535\u6d41\u653e\u7535\/\u5145\u7535\u7535\u538b\u66f2\u7ebf 30\u00b0C \u65f6\u4e0d\u9508\u94a2\u96c6\u6d41\u4f53\u3002(e) 30\u00b0C \u65f6 Li\/Li-Phen-G2\/ LPSCl \/Li-Phen-G2 \u81ea\u5236\u7535\u6c60\u7684\u6052\u7535\u6d41\u653e\u7535\/\u5145\u7535\u7535\u538b\u66f2\u7ebf\u3002(f) 30\u00b0C \u65f6 Ln\/Li-Phen-G2\/ LPSCl \/Li-Phen-G2 \u81ea\u5236\u7535\u6c60\u7684\u6052\u7535\u6d41\u653e\u7535\/\u5145\u7535\u7535\u538b\u66f2\u7ebf.<\/section>\n
<\/section>\n
\u56fe2a,2b,2c\u5c55\u793a\u4e86\u5177\u6709\u5404\u79cd\u6db2\u6001Li\u9633\u6781\u548cPEO\u4fdd\u62a4\u7684LPSCl\u7684\u5bf9\u79f0\u7535\u6c60\u7684\u6027\u80fd\u3002\u8fd9\u4e9b\u7535\u6c60\u5728\u7ebd\u6263\u7535\u6c60\u4e2d\u8fdb\u884c\u6d4b\u8bd5\uff0c\u5176\u4e2d30 \u03bcL\u6db2\u6001\u9502\u50a8\u5b58\u5728LPSCl\u4e24\u4fa7\u7684\u591a\u5b54\u6ce1\u6cab\u954d\u4e2d\u3002\u6db2\u6001\u9502\u9633\u6781\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u987a\u5e8f\u4e3aLi-Phen-G2 (260\u5c0f\u65f6)> Li-Naph-G2 (150\u5c0f\u65f6)> Li-Bp-G2 (100\u5c0f\u65f6)\u3002\u6b64\u5916\u57fa\u4e8e\u81ea\u5236\u7684\u7535\u6c60\u6a21\u5177\uff08\u6bcf\u4fa7\u5177\u67095 mL\u6db2\u6001Li\uff09\uff0cLi-Phen-G2\/LPSCl\/Li-Phen-G2\u5bf9\u79f0\u7535\u6c60\u5b9e\u73b0\u4e861200 h\u7684\u957f\u7a33\u5b9a\u5faa\u73af\u3002\u7136\u800c\uff0c\u6db2\u6001Li\u9633\u6781\u7684\u5e94\u7528\u4ecd\u7136\u53d7\u5230\u4e24\u4e2a\u95ee\u9898\u7684\u56f0\u6270:1)\u6db2\u4f53Li\u9633\u6781\u7684\u7406\u8bba\u6bd4\u5bb9\u91cf\u4f4e\uff08\u226470 mAh\/g\uff09\u30022)\u57fa\u4e8e\u6db2\u6001\u9502\u9633\u6781\u7684\u7535\u6c60\u901a\u5e38\u9700\u8981\u5b9a\u5236\u8bbe\u8ba1\uff0c\u4f8b\u5982\u5706\u67f1\u5f62\u7535\u6c60\u548c\u73bb\u7483\u69fd\u7535\u6c60\uff0c\u5bfc\u81f4\u7535\u6c60\u7ed3\u6784\u590d\u6742\u5ea6\u9ad8\uff0c\u80fd\u91cf\u5bc6\u5ea6\u4f4e\u3002\u56e0\u6b64\uff0c\u5728\u6db2\u6001\u9502\u4e2d\u5f15\u5165\u5176\u4ed6\u9502\u6e90\u662f\u4e00\u6761\u5f88\u6709\u524d\u9014\u7684\u9014\u5f84\uff0c\u53ef\u4ee5\u51cf\u5c11\u6db2\u6001\u9502\u7684\u7528\u91cf\uff0c\u63d0\u9ad8\u6bd4\u5bb9\u91cf\u548c\u5faa\u73af\u5bff\u547d\u3002<\/section>\n
<\/section>\n
2.<\/strong>\u00a0\u00a0\u4e09\u7ef4<\/strong>LiSi @<\/strong>\u6db2\u6001\u9502\u8d1f\u6781<\/strong><\/section>\n
\"3\"<\/section>\n
\u56fe3.(a) LiSi\u5408\u91d1\u7684XRD\u56fe\u6848\u3002(b)Phen\u3001LiSi\u548cLiSi@Li-Phen-DME\u7684XRD\u56fe\u3002(c)Li\u91d1\u5c5e\u3001Li-Phen\u548cLi@Li-Phen-DME\u7684XRD\u56fe\u3002(d) 3D LiSi @\u6db2\u6001Li\u9633\u6781\u5236\u5907\u793a\u610f\u56fe\u3002(e)LiSi\u6db2\u4f53Li\u548cLiSi\u4e0e\u84b8\u998f\u6c34\u7684\u53cd\u5e94\u3002(f)\u5177\u6709\u4e0d\u540c\u9633\u6781\u7684\u9502\u5bf9\u79f0\u7535\u6c60\u7684\u5854\u83f2\u5c14\u66f2\u7ebf\u3002<\/section>\n
<\/section>\n
\u901a\u8fc7\u7eb3\u7c73\u7845\u7c89\u548c\u91d1\u5c5e\u9502\u7684\u70ed\u70e7\u7ed3\u5236\u5907\u4e86\u9502\u7845\u5408\u91d1\u7c89\u3002\u901a\u8fc7X\u5c04\u7ebf\u884d\u5c04(XRD)\u56fe(\u56fe3a)\uff0c\u5236\u5907\u7684LiSi\u6837\u54c1\u4e2d\u7684\u4e3b\u8981\u6210\u5206\u662fLi13Si4\u3002\u5c06LiSi\u7c89\u672b\u6d78\u5165\u9971\u548cLi-Phen-DME\u4e2d5\u5929\uff0c\u7136\u540e\u53d6\u51fa\u5e72\u71e5\u3002\u56fe3b\u4e2d\u793a\u51fa\u4e86\u6d78\u6e0d\u524d\u540e\u7684XRD\u56fe\uff0c\u5176\u63ed\u793a\u4e86LiSi\u5408\u91d1\u4fdd\u6301\u4e86\u7a33\u5b9a\u7684\u7ec4\u6210\u548c\u5f62\u6001\uff0c\u4ec5\u6709\u5c11\u91cf\u5e72\u71e5\u7684Phen\u9644\u7740\u5728LiSi\u8868\u9762\u3002\u7c7b\u4f3c\u5b9e\u9a8c\u4e5f\u5728\u9502\u91d1\u5c5e\u4e0a\u8fdb\u884c\u3002\u5982\u56fe3c\u6240\u793a\uff0c\u5728\u6d78\u5165\u9971\u548cLi-Phen-DME\u540e\uff0c\u9502\u7247\u7684\u8868\u9762\u9644\u7740\u4e00\u5c42\u9ed1\u8272\u56fa\u4f53\u6750\u6599\u3002\u901a\u8fc7XRD\u5206\u6790\uff0c\u9ed1\u8272\u7269\u8d28\u7684\u7ed3\u6784\u4e0e\u901a\u8fc7\u5e72\u71e5\u9971\u548cLi-Phen-DME\u83b7\u5f97\u7684\u5e72\u71e5Li-Phen\u76f8\u540c\u3002\u91d1\u5c5e\u9502\u7247\u548cLiSi\u7c89\u672b\u5bf9\u6db2\u6001\u9502\u7684\u5dee\u5f02\u4e3b\u8981\u6e90\u4e8e\u53cd\u5e94\u6d3b\u6027\u548c\u5c3a\u5bf8\u6548\u5e94\u3002\u7531\u4e8e\u9502\u91d1\u5c5e\u4e0e\u6db2\u6001\u9502\u6eb6\u6db2\u4e4b\u95f4\u7684\u9ad8\u53cd\u5e94\u6027\uff0c\u9502\u91d1\u5c5e\u8868\u9762\u9644\u8fd1\u7684\u6db2\u6001\u9502\u6eb6\u6db2\u4e2d\u7684\u9502\u6d53\u5ea6\u504f\u9ad8\u3002\u5f53\u6db2\u4f53Li\u5b8c\u5168\u9971\u548c\u65f6\uff0c \u00a0[(Li+<\/sup>)2<\/sub>\u00b7(Phen2\u2212<\/sup>)\u00b7(Ether)x<\/sub>]\u6676\u4f53\u503e\u5411\u4e8e\u6c89\u6dc0\u5728Li\u91d1\u5c5e\u8868\u9762\u4e0a,\u5f62\u6210\u949d\u5316\u5c42\u3002\u5bf9\u4e8e\u9502\u7845\u5408\u91d1\uff0c\u5b83\u4e0e\u6db2\u6001\u9502\u53cd\u5e94\u6027\u6bd4\u9502\u91d1\u5c5e\u4f4e\u5f97\u591a\u3002\u5982\u56feS3\u6240\u793a\uff0c\u5728\u5c06LiSi\u6d78\u5165Phen-DME\u6eb6\u6db2\u4e2d2\u5c0f\u65f6\u540e\uff0cSi\u7684XRD\u4fe1\u53f7\u7a0d\u5fae\u589e\u5f3a\uff0c\u8fd9\u8868\u660e\u53ea\u6709\u5f88\u5c11\u7684LiSi\u7c89\u672b\u4e0ePhen-DME\u53cd\u5e94\u3002\u6b64\u5916\uff0cLiSi\u7c89\u672b\u975e\u5e38\u5c0f(1-10\u5fae\u7c73),\u5e76\u4e14\u5b83\u4eec\u4e0e\u6db2\u6001Li\u5177\u6709\u5747\u5300\u4e14\u5145\u5206\u7684\u63a5\u89e6\u3002\u56e0\u6b64\uff0c\u5728\u7ec6\u9897\u7c92LiSi\u8868\u9762\u96be\u4ee5\u751f\u6210\u949d\u5316\u5c42\u3002LiSi@Liquid Li (LSLL)\u9633\u6781\u901a\u8fc7\u5c06\u5c11\u91cf\u6db2\u6001Li\u6e17\u900f\u5230LiSi\u7c89\u672b\u4e2d\u6765\u5236\u5907\uff0c\u5c06\u8be5\u7c89\u672b\u538b\u5236\u5728\u591a\u5b54\u96c6\u6d41\u4f53(\u4f8b\u5982\u6ce1\u6cab\u954d)\u4e2d\uff0c\u7531\u6b64\u5f62\u6210\u4e09\u7ef4(3d)\u56fa\u6db2\u5747\u5300\u6df7\u5408\u7ed3\u6784(\u56fe3D)\u3002LSLL\u9633\u6781\u5177\u6709\u9ad8\u5b89\u5168\u6027\u3001\u5145\u5206\u7684\u754c\u9762\u63a5\u89e6\u548c\u6291\u5236\u9502\u679d\u6676\u6210\u6838\/\u751f\u957f\u7684\u4f18\u70b9\u3002\u4ece\u5b89\u5168\u89d2\u5ea6\u6765\u770b\uff0c\u6db2\u6001\u9502\u4e0e\u6c34\u7684\u53cd\u5e94\u6027\u6bd4LiSi\/\u9502\u91d1\u5c5e\u7684\u53cd\u5e94\u6027\u6e29\u548c\u5f97\u591a(\u56fe3e)\u3002\u6b64\u5916\uff0c\u7ec4\u88c5\u5bf9\u79f0\u7535\u6c60\u4ee5\u6d4b\u8bd5\u5176Tafel\u66f2\u7ebf\uff0c\u5982\u56fe3f\u6240\u793a\uff0c\u5177\u6709LiSi@\u6db2\u4f53Li\u9633\u6781\u7684\u7535\u6c60\u663e\u793a\u51fa\u9ad8\u4e8eLi\u9633\u6781\u548cLiSi\u9633\u6781\u7684\u4ea4\u6362\u7535\u6d41\u5bc6\u5ea6\u3002<\/section>\n
\"4\"<\/section>\n
\u56fe4.(a)3D LSLL\/LPS cl\/3D LSLL\u7ebd\u6263\u7535\u6c60\u5728\u5ba4\u6e29\u4e0b\u7535\u6d41\u5bc6\u5ea6\u4e3a0.25mA cm-2\u65f6\u7684\u6052\u7535\u6d41\u653e\u7535\/\u5145\u7535\u7535\u538b\u66f2\u7ebf\uff0c(b)3D LSLL\/LPS cl\/3D LSLL\u7ebd\u6263\u7535\u6c60\u572830 RT\u4e0b\u7535\u6d41\u5bc6\u5ea6\u4e3a1.3mA cm-2\u65f6\u7684\u6052\u7535\u6d41\u653e\u7535\/\u5145\u7535\u7535\u538b\u66f2\u7ebf\uff0c(c)3D LSLL\/LPS cl\/3D LSLL\u5bf9\u79f0\u7535\u6c60\u7684CCD\u6d4b\u91cf\uff0c\u6bcf\u4e2a\u5468\u671f\u7684\u65f6\u95f4\u56fa\u5b9a\u4e3a1\u5c0f\u65f6\uff0c(d)Li\/LPSCl\/Li\u5bf9\u79f0\u7684CCD\u6d4b\u91cf(e)\u5177\u67090.25 mAh cm\u56fa\u5b9a\u5bb9\u91cf\u7684LiSi\/LPSCl\/LiSi\u5bf9\u79f0\u7535\u6c60\u7684CCD\u6d4b\u91cf\u3002(f)\u5177\u67090.25 mAh cm\u56fa\u5b9a\u5bb9\u91cf\u76843D LSLL\/LPSCl\/3D LSLL\u5bf9\u79f0\u7535\u6c60\u7684CCD\u6d4b\u91cf\u3002(g)\u5177\u6709LiSi\u5408\u91d1\u9633\u6781\u548c3D LSLL\u9633\u6781\u7684\u7535\u6c60\u4e2d\u9502\u7535\u9540\u884c\u4e3a\u7684\u793a\u610f\u56fe\u3002(h)\u5177\u67093D LSLL\u9633\u6781\u548cGPE\u754c\u9762\u5c42\u7684\u4f4e\u538bSSB\u7684\u793a\u610f\u56fe\u3002<\/section>\n
LSLL\u9633\u6781\u7684\u6027\u80fd\u901a\u8fc7\u7ebd\u6263\u5bf9\u79f0\u7535\u6c60\u8fdb\u884c\u8bc4\u4f30\u3002\u5728\u8fd9\u79cd\u7535\u6c60\u4e2d\uff0cLSLL\u9633\u6781\u753115 \u03bcL Li-Phen-Ether\u548c8 mg LiSi\u7c89\u672b\u7ec4\u6210\u3002\u6db2\u6001\u9502\u7684\u7528\u91cf\u4f4e\u4e8e\u5176\u5b83\u4efb\u4f55\u4f7f\u7528\u6db2\u6001\u78b1\u91d1\u5c5e\u82b3\u70c3\u590d\u5408\u9633\u6781\u7684\u62a5\u9053\u3002\u6b64\u5916\uff0c\u8ba1\u7b97\u51faLSLL\u8d1f\u6781\u7684\u8d2e\u9502\u5bb9\u91cf\u8d85\u8fc7600 mAh\u00b7g-1<\/sup>\uff0c\u6709\u671b\u6210\u4e3a\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7535\u6c60\u7684\u66ff\u4ee3\u8d1f\u6781\u6750\u6599\u3002\u56fe4a\u663e\u793a\u4e86LiSi @ Li-Phen-G2\/LPS cl\/LiSi @ Li-Phen-G2\u7535\u6c60\u57280.25mA cm2\u56fa\u5b9a\u7535\u6d41\u548c0.125 mAh cm\u9762\u79ef\u5bb9\u91cf\u4e0b\u7684\u7535\u538b\u66f2\u7ebf\u3002\u8be5\u7535\u6c60\u5728\u5ba4\u6e29\u4e0b\u8868\u73b0\u51fa\u7ea690 mV\u7684\u4f4e\u521d\u59cb\u8fc7\u7535\u4f4d\uff0c\u80fd\u591f\u7a33\u5b9a\u5faa\u73af1000\u591a\u5c0f\u65f6\u3002\u6b64\u5916,\u7535\u6c60\u5373\u4f7f\u57281.3mA cm\u20132<\/sup>\u7684\u9ad8\u7535\u6d41\u5bc6\u5ea6\u4e0b\u4e5f\u80fd\u4fdd\u6301\u51fa\u8272\u7684\u7a33\u5b9a\u6027\uff0c\u6301\u7eed700 h\u7684\u5faa\u73af\u8fc7\u7535\u4f4d\u4fdd\u6301\u5728200 mV\uff0c\u5982\u56fe4b\u6240\u793a\u3002\u5728\u5faa\u73af\u4e4b\u540e\uff0c\u901a\u8fc7XRD\u5206\u6790\u53ef\u4ee5\u660e\u663e\u89c2\u5bdf\u5230Li13Si4\u76f8\uff0c\u6ca1\u6709\u4efb\u4f55\u5176\u4ed6\u526f\u53cd\u5e94\u4ea7\u7269(\u56feS7)\uff0c\u8fd9\u8868\u660e\u5728\u7535\u5316\u5b66\u8fc7\u7a0b\u4e2d\u6db2\u6001Li\u548cLiSi\u5408\u91d1\u4e4b\u95f4\u7684\u9ad8\u7a33\u5b9a\u6027\u3002\u56fe4c\u663e\u793a\u4e863D LSLL\/LPSCl\/3D LSLL\u5bf9\u79f0\u7535\u6c60\u7684CCD\u6d4b\u91cf\uff0c\u6bcf\u4e2a\u5468\u671f\u7684\u65f6\u95f4\u56fa\u5b9a\u4e3a1\u5c0f\u65f6\uff0c\u5373\u4f7f\u57286 mA\/cm2\u7684\u9ad8\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u4e5f\u6ca1\u6709\u89c2\u5bdf\u5230\u77ed\u8def\u3002\u56fe4d\u3001e\u548cf\u5206\u522b\u663e\u793a\u4e86\u5177\u6709\u7eafLi\u3001LiSi\u5408\u91d1\u548c3D LSLL\u9633\u6781\u7684\u5bf9\u79f0\u7535\u6c60\u7684CCD\uff0c\u91c7\u75280.25 mAh\/cm2\u7684\u6052\u5b9a\u5bb9\u91cf\u6d4b\u8bd5\u65b9\u6cd5\u3002\u5177\u67093D LSLL\u9633\u6781\u7684\u7535\u6c60\u5177\u6709\u8d85\u8fc713mA\/cm2\u7684\u6700\u9ad8CCD\uff0c\u800c\u5177\u6709Li\u548cLiSi\u9633\u6781\u7684CCD\u4ec5\u5206\u522b\u8fbe\u52301.5\u548c6.3 mA\/cm2\u3002<\/section>\n
<\/section>\n
3.<\/strong>\u00a0\u00a0\u4f4e\u5916\u538b\u4e0b\u7684<\/strong>SSLBs<\/strong><\/section>\n
\"5\"<\/section>\n
\u56fe5.(a)DOL\u539f\u4f4d\u805a\u5408\u8fc7\u7a0b\u7684\u3002(b)\u4f7f\u7528\u4e0d\u540c\u7c7b\u578b\u7684GPE\u754c\u9762\u5c42\u7684LFP@GPE\/LSPCl\/3D LSLL\u7ebd\u6263\u7535\u6c60\u4ee50.3C\u7684\u901f\u7387\u8fdb\u884c\u7535\u6c60\u5faa\u73af\u3002(c)\u7b2c1\u6b21\u5faa\u73af\u548c\u7b2c100\u6b21\u5faa\u73af\u540e\u5168\u7535\u6c60EIS\u8868\u5f81\u3002(d)\u5168\u7535\u6c60\u5145\u653e\u7535\u500d\u7387\u6027\u80fd\u3002(e)\u4e0d\u540c\u6e29\u5ea6\u4e0b\u5168\u7535\u6c60\u5faa\u73af\u3002(f)\u8f6f\u5305\u7535\u6c60\u5faa\u73af\u3002<\/section>\n
<\/section>\n
\u4f17\u6240\u5468\u77e5\u5bf9\u4e8e\u786b\u5316\u7269\u578bSSLBs\uff0c\u5728\u7535\u6c60\u8fd0\u884c\u671f\u95f4\u9ad8\u5916\u538b(\u901a\u5e38\u51e0\u5341\u5230\u51e0\u767eMPa)\u5bf9\u4e8e\u4fc3\u8fdb\u754c\u9762\u63a5\u89e6\u662f\u5fc5\u4e0d\u53ef\u5c11\u7684\u3002\u7136\u800c\uff0c\u9ad8\u538b\u4e0d\u5229\u4e8e\u5b9e\u9645\u5e94\u7528\u3002\u5229\u7528\u7d27\u5bc6\u7684\u56fa-\u6db2\u754c\u9762\u63a5\u89e6\uff0c3D LSLL\u9633\u6781\u53ef\u4ee5\u5728<1 MPa\u7684\u4f4e\u5916\u538b\u4e0b\u5de5\u4f5c\u3002\u4e3a\u4e86\u5236\u9020\u53ef\u4ee5\u5728\u4f4e\u5916\u538b\u4e0b\u5de5\u4f5c\u7684\u5168\u7535\u6c60\uff0c\u5e94\u8be5\u6539\u8fdb\u9634\u6781\/\u786b\u5316\u7269SE\u754c\u9762\u3002\u4e3a\u6b64\u5728\u9634\u6781\u8868\u9762\u5f15\u5165\u4e86\u4e00\u79cd\u539f\u4f4d\u805a\u5408\u7684\u919a\u57fa\u51dd\u80f6\u805a\u5408\u7269\u7535\u89e3\u8d28(GPE)\uff0cGPE\u5c06\u5dee\u7684\u65e0\u673a\u56fa\u4f53-\u56fa\u4f53\u63a5\u89e6\u6539\u53d8\u4e3a\u8f6f\u63a5\u89e6(\u56fe4h)\u3002\u539f\u4f4d\u805a\u5408\u65b9\u5f0f\u4e3a\u5229\u7528\u9ad8\u6d53\u5ea6LiFSI<\/span>\u5f15\u53d11\uff0c3-\u4e8c\u6c27\u620a\u73af(DOL)\u7684DOL\u5f00\u73af\u805a\u5408\uff08\u56fe5a\uff09\u3002\u8be5\u539f\u4f4d\u805a\u5408\u5177\u6709\u64cd\u4f5c\u7b80\u5355\u3001\u51dd\u80f6\u5316\u65f6\u95f4\u77ed\u3001\u65e0\u6742\u8d28\/\u5f15\u53d1\u5242\u3001\u6e29\u5ea6\u4f4e\u7b49\u4f18\u70b9\u3002\u4e0e\u5728\u9634\u6781\u754c\u9762\u5904\u6ca1\u6709GPE\u5c42\u7684\u7535\u6c60\u76f8\u6bd4\uff0cLFP-LSLL\u7535\u6c60\u7684\u5bb9\u91cf\u6027\u80fd\u548c\u5faa\u73af\u7a33\u5b9a\u6027\u5f97\u5230\u6539\u5584(\u56fe5b)\u3002\u4e3a\u4e86\u8fdb\u4e00\u6b65\u63d0\u9ad8GPE\u7684\u79bb\u5b50\u7535\u5bfc\u7387\uff0c\u5f15\u5165DME\u8d77\u5230\u589e\u5851\u5242\u7684\u4f5c\u7528\u5e76\u9632\u6b62DOL\u7684\u8fc7\u5ea6\u805a\u96c6\uff0c\u540c\u65f6\u52a0\u5165\u5c11\u91cfFEC\u4fdd\u6301\u51dd\u80f6\u7684\u7ed3\u6784\u7a33\u5b9a\u6027\u4ee5\u53ca\u63d0\u9ad8\u5bf9\u6b63\u6781\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u6027(DOL-DME-FEC\u7684\u4f53\u79ef\u6bd4\u4e3a3:1:0.4)\u3002\u5177\u6709\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\u7684\u51dd\u80f6\u5c42\uff082.1 mS\/cm\uff09\u663e\u8457\u63d0\u9ad8\u4e86\u5faa\u73af\u6027\u80fd(\u56fe5b)\u3002\u5168\u7535\u6c600.3 C\u65f6\u7684\u653e\u7535\u5bb9\u91cf\u9ad8\u8fbe159.5 mAh\/g\uff0c\u7b2c100\u6b21\u5faa\u73af\u540e\u7684\u53ef\u9006\u653e\u7535\u5bb9\u91cf\u9ad8\u8fbe152.5 mAh\/g\u3002\u5982EIS\u6d4b\u91cf(\u56fe5c)\u6240\u793a\uff0c\u603b\u963b\u6297\u4ec5\u4ece110\u03a9(\u9996\u5708)\u589e\u52a0\u5230127\u03a9(\u7b2c100\u5708)\u3002LFP@GPE\/LSPCl\/3D LSLL\u7684\u500d\u7387\u6027\u80fd\u5982\u56fe5d\u6240\u793a\u3002\u6b64\u5916\u8be5\u7535\u6c60\u8fd8\u5177\u6709\u5bbd\u7684\u5de5\u4f5c\u6e29\u5ea6\u8303\u56f4(0\u00b0C\u201355\u00b0C)(\u56fe5e)\u3002\u4ee5\u4e0a\u7535\u6c60\u90fd\u5728\u7ebd\u6263\u7535\u6c60\u4e2d\u7ec4\u88c5\uff0c\u6b64\u5916\u8fd8\u57280.1 MPa\u7684\u66f4\u4f4e\u5916\u538b\u4e0b\u8bbe\u8ba1\u4e86\u8f6f\u5305\u7535\u6c60(\u56fe5f)\u3002\u539f\u578b\u8f6f\u5305\u7535\u6c60\u7684\u5c3a\u5bf8\u4e3a7.5\u6beb\u7c73*7.5\u6beb\u7c73*3.14\uff0c\u5bb9\u91cf\u4e3a2mAh\u3002\u5728\u5ba4\u6e290.3 C\u4e0b50\u6b21\u5faa\u73af\u540e\u670982%\u7684\u9ad8\u5bb9\u91cf\u4fdd\u6301\u7387\u3002\u5373\u4f7f\u6ca1\u6709\u4efb\u4f55\u5916\u754c\u538b\u529b\uff0c\u7535\u6c60\u4ecd\u7136\u53ef\u4ee5\u6b63\u5e38\u5de5\u4f5c\u70b9\u4eaeLED\u706f\u6ce1\u3002<\/section>\n
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\"6\"\u200b<\/section>\n
\u56fe6. \uff08a) LFP@GPE\/LSPCl\/3D LSLL\u3001LFP@GPE\/LSPCl\/Li\u548cLFP@GPE\/LSPCl\/LiSi\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd\u3002(b)\u8be5\u5de5\u4f5c\u4e0e\u5df2\u62a5\u9053\u7684\u4f4e\u538b\u786b\u5316\u7269SEs<\/span>\u9502\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd\u7684\u6bd4\u8f83\u3002(c)TiS2@GPE\/LSPCl\/3D LSLL\u7535\u6c60\u57280.3 C\u5faa\u73af\u671f\u95f4\u7684\u5145\u653e\u7535\u66f2\u7ebf\u3002(d)LCO@GPE\/LSPCl\/3D LSLL\u7535\u6c60\u57280.3 C\u5faa\u73af\u671f\u95f4\u7684\u5145\u653e\u7535\u66f2\u7ebf\u3002<\/section>\n
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\u672c\u5de5\u4f5c\u5c55\u793a\u4e86\u4e00\u79cd\u89e3\u51b3\u786b\u5316\u7269\u57faSSBs\u4e2d\u754c\u9762\u63a5\u89e6\u548cLi\u679d\u6676\u95ee\u9898\u7684\u521b\u65b0\u65b9\u6cd5\u3002\u9996\u5148\uff0c\u7cfb\u7edf\u7814\u7a76\u4e86Li-Phen-Ether\u7684\u7535\u5316\u5b66\u6027\u8d28\u53ca\u5176\u4e0e\u5df2\u62a5\u9053\u7684Li-Bp-Ether\/Li-Naph-Ether\u7684\u533a\u522b\u3002\u7ed3\u679c\u8868\u660e\uff0cLi-Phen-Ether\u5177\u6709\u540c\u6837\u9ad8\u7684\u7535\u5bfc\u7387\u548c\u66f4\u597d\u7684\u5316\u5b66\u7a33\u5b9a\u6027\u3002\u4ee5Li-Phen-Ether\u4e3a\u57fa\u7840\uff0c\u7814\u5236\u4e863D LiSi@Li-Phen-Ether\u7684\u9633\u6781\u3002\u5f97\u76ca\u4e8e\u5145\u5206\u548c\u7a33\u5b9a\u7684\u8d1f\u6781\/\u786b\u5316\u7269\u7535\u89e3\u8d28\u63a5\u89e6\uff0c\u5bf9\u79f0\u7535\u6c60\u5728\u5ba4\u6e29\u4e0b\u5b9e\u73b0\u4e86\u957f\u5faa\u73af\u5bff\u547d(> 1000 h\uff0c0.25mA cm-2<\/sup>)\u548c\u9ad8\u4e34\u754c\u7535\u6d41\u5bc6\u5ea6(> 13 mA cm-2<\/sup>)\u3002\u6b64\u5916\uff0c\u5728\u9634\u6781\u8868\u9762\u5f15\u5165\u4e86\u5177\u6709\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387(2 mS cm-1<\/sup>)\u7684\u51dd\u80f6\u805a\u5408\u7269\u7535\u89e3\u8d28\u5c42\u3002\u5168\u7535\u6c60\u53ef\u4ee5\u5728\u4f4e\u5916\u538b\uff080.5 MPa\uff09\u548c\u5bbd\u6e29\u5ea6\u8303\u56f4(0-55\u2103)\u5185\u6b63\u5e38\u5de5\u4f5c\u3002\u8fd9\u7c7b\u7535\u6c60\u7ed3\u6784\u53ef\u80fd\u4e3a\u4f4e\u5916\u538b\u3001\u4f4e\u6210\u672c\u548c\u65e0\u679d\u6676\u7684\u56fa\u6001\u7535\u6c60\u7814\u53d1\u63d0\u4f9b\u65b0\u7684\u601d\u8def\u3002<\/section>\n
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\u4f5c\u8005\u4ecb\u7ecd<\/strong><\/section>\n
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