{"id":52142,"date":"2024-08-23T08:12:57","date_gmt":"2024-08-23T00:12:57","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=52142"},"modified":"2024-08-14T10:15:18","modified_gmt":"2024-08-14T02:15:18","slug":"%e5%a4%aa%e5%8e%9f%e7%90%86%e5%b7%a5acs-catal-znzrox-zsm-5%e4%b8%ad%e5%bc%95%e5%85%a5al2o3%ef%bc%8c%e4%bf%83%e8%bf%9b%e8%8b%af%e4%b8%8eco2-h2%e7%83%b7%e5%9f%ba%e5%8c%96%e5%8f%8d%e5%ba%94","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/%e5%a4%aa%e5%8e%9f%e7%90%86%e5%b7%a5acs-catal-znzrox-zsm-5%e4%b8%ad%e5%bc%95%e5%85%a5al2o3%ef%bc%8c%e4%bf%83%e8%bf%9b%e8%8b%af%e4%b8%8eco2-h2%e7%83%b7%e5%9f%ba%e5%8c%96%e5%8f%8d%e5%ba%94\/","title":{"rendered":"\u200b\u592a\u539f\u7406\u5de5ACS Catal.: ZnZrOx-ZSM-5\u4e2d\u5f15\u5165Al2O3\uff0c\u4fc3\u8fdb\u82ef\u4e0eCO2\/H2\u70f7\u57fa\u5316\u53cd\u5e94"},"content":{"rendered":"<section>\u82ef\u4e0eCO<sub>2<\/sub>\/H<sub>2<\/sub>\u70f7\u57fa\u5316\u5408\u6210\u7532\u82ef\u548c\u4e8c\u7532\u82ef\uff0c\u5bf9\u51cf\u5c11\u78b3\u6392\u653e\u3001\u63d0\u9ad8\u8f7b\u82b3\u70c3\u5411\u589e\u503c\u5316\u5b66\u54c1\u7684\u8f6c\u5316\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002\u7136\u800c\uff0cCO<sub>2<\/sub>\u52a0\u6c22\u5f62\u6210\u7684\u70f7\u57fa\u5316\u8bd5\u5242\u8868\u73b0\u51fa\u8f83\u5f31\u7684\u70f7\u57fa\u5316\u6d3b\u6027\u548c\u4e25\u91cd\u7684\u81ea\u53cd\u5e94\uff0c\u5bfc\u81f4\u70f7\u57fa\u5316\u6548\u7387\u4f4e\u3002<\/section>\n<section>\u4e3a\u89e3\u51b3\u8fd9\u4e00\u95ee\u9898\uff0c<strong>\u592a\u539f\u7406\u5de5\u5927\u5b66\u674e\u5fe0<\/strong>\u548c<strong>\u4ed8\u5ef7\u4fca<\/strong>\u7b49\u5728ZnZrO<sub>x<\/sub>-ZSM-5\u4f53\u7cfb\u4e2d\u5f15\u5165Al<sub>2<\/sub>O<sub>3<\/sub>\uff0c\u8bbe\u8ba1\u4e86ZnZrO<sub>x<\/sub>(ZZO)\u50ac\u5316CO<sub>2<\/sub>\u52a0\u6c22\u3001Al<sub>2<\/sub>O<sub>3<\/sub>\u50ac\u5316\u7532\u9187\u8131\u6c34\u3001Z5\u5206\u5b50\u7b5b\u50ac\u5316\u4e8c\u7532\u919a\u4e0e\u82ef\u70f7\u57fa\u5316\u7684\u4e09\u5143\u590d\u5408\u50ac\u5316\u4f53\u7cfb\uff0c\u5b9e\u73b0\u4e86\u82ef\u4e0eCO<sub>2<\/sub>\/H<sub>2<\/sub>\u7684\u9ad8\u6548\u70f7\u57fa\u5316\u53cd\u5e94\u3002<\/section>\n<section><img decoding=\"async\" title=\"1\" src=\"https:\/\/10110.seohost.cn\/storage\/10110\/article\/20240814\/1723601649579780.webp\" alt=\"1\" \/><\/section>\n<section><img decoding=\"async\" title=\"2\" src=\"https:\/\/10110.seohost.cn\/storage\/10110\/article\/20240814\/1723601669589026.webp\" alt=\"2\" \/><\/section>\n<section>\u5b9e\u9a8c\u7ed3\u679c\u8868\u660e\uff0c\u6700\u4f18\u7684ZZO-0.3Al<sub>2<\/sub>O<sub>3<\/sub>\/Z5\u50ac\u5316\u5242\u7684\u7532\u82ef\u548c\u4e8c\u7532\u82ef\u6df7\u5408\u9009\u62e9\u6027\u9ad8\u8fbe97%\uff0c\u82ef\u8f6c\u5316\u7387\u4e3a9.7%\uff0c\u7532\u82ef\u7684\u65f6\u7a7a\u6536\u7387(STY)\u9ad8\u8fbe111.7 g<sub>zeolite<\/sub><sup>-1<\/sup>\u00a0h<sup>-1<\/sup>\u3002\u540c\u65f6\uff0cAl<sub>2<\/sub>O<sub>3<\/sub>\u50ac\u5316CO<sub>2<\/sub>\u52a0\u6c22\u53cd\u5e94\u7ed3\u679c\u8868\u660e\uff0c\u50ac\u5316\u5242\u7684\u9ad8\u70f7\u57fa\u5316\u6027\u80fd\u53ef\u4ee5\u901a\u8fc7\u5f15\u5165Al<sub>2<\/sub>O<sub>3<\/sub>\u6765\u5b9e\u73b0\u3002<\/section>\n<section>\u5177\u4f53\u800c\u8a00\uff0cAl<sub>2<\/sub>O<sub>3<\/sub>\u53ef\u4ee5\u901a\u8fc7\u7532\u9187\u4ea7\u7269\u5728Lewis\u9178\u4e2d\u5fc3\u7684\u5931\u6c34\u53cd\u5e94\u52a0\u901fCO<sub>2<\/sub>\u52a0\u6c22\u4e3a\u7532\u9187\u3002\u5e76\u4e14\uff0c\u8be5\u8def\u7ebf\u8fd8\u4e3a\u82ef\u70f7\u57fa\u5316\u63d0\u4f9b\u4e86\u66f4\u591a\u7684\u9ad8\u6d3b\u6027\u70f7\u57fa\u5316\u8bd5\u5242\uff0c\u51cf\u5c11\u4e86\u7532\u9187\u4e0eC<sub>1<\/sub>-C<sub>5<\/sub>\u70c3\u7684\u81ea\u53cd\u5e94\u3002<\/section>\n<section><img decoding=\"async\" title=\"3\" src=\"https:\/\/10110.seohost.cn\/storage\/10110\/article\/20240814\/1723601680362715.webp\" alt=\"3\" \/><\/section>\n<section><img decoding=\"async\" title=\"4\" src=\"https:\/\/10110.seohost.cn\/storage\/10110\/article\/20240814\/1723601690201493.webp\" alt=\"4\" \/><\/section>\n<section><img decoding=\"async\" title=\"0\" src=\"https:\/\/10110.seohost.cn\/storage\/10110\/article\/20240814\/1723601700104432.webp\" alt=\"0\" \/>\u200b<\/section>\n<section>\u66f4\u91cd\u8981\u7684\u662f\uff0cAl<sub>2<\/sub>O<sub>3<\/sub>\u8868\u9762\u7684\u4e0d\u9971\u548c\u914d\u4f4d\u4fc3\u8fdb\u4e86H<sub>2<\/sub>\u89e3\u79bb\u4e3aH\u539f\u5b50\uff0c\u8fd9\u79cd\u89e3\u79bb\u4f7f\u5f97H\u8f6c\u79fb\u5230\u76f8\u90bb\u7684\u6c27\u7a7a\u4f4d\uff0c\u4ece\u800c\u4fc3\u8fdb\u5438\u9644\u7684\u78b3\u9178\u76d0\u7269\u79cd\u52a0\u6c22\u5f62\u6210\u7532\u9178\u548c\u7532\u6c27\u57fa\u4e2d\u95f4\u4f53\u3002\u6b64\u5916\uff0cAl<sub>2<\/sub>O<sub>3<\/sub>\u7684\u5f15\u5165\u589e\u5f3a\u4e86\u4e2d\u95f4\u4f53\u7532\u9187\u7684\u5438\u9644\u4f5c\u7528\uff0c\u4e3a\u82ef\u70f7\u57fa\u5316\u53cd\u5e94\u63d0\u4f9b\u4e86\u66f4\u591a\u7684\u70f7\u57fa\u8bd5\u5242\u3002\u5c24\u5176\u662f\uff0cAl<sub>2<\/sub>O<sub>3<\/sub>\u4e0eZ5\u5206\u5b50\u7b5b\u4e4b\u95f4\u7684\u5bc6\u5207\u63a5\u8fd1\uff0c\u4f7f\u5f97\u82ef\u4e0e\u4e8c\u7532\u919a\u7684\u70f7\u57fa\u5316\u53cd\u5e94\u6548\u7387\u63d0\u9ad8\uff0c\u4e0e\u5176\u4ed6\u6574\u5408\u65b9\u5f0f\u76f8\u6bd4\uff0c\u63d0\u9ad8\u4e86\u82ef\u4e0eCO<sub>2<\/sub>\/H<sub>2<\/sub>\u70f7\u57fa\u5316\u53cd\u5e94\u7684\u8f6c\u5316\u7387\u3002<\/section>\n<section>\u6b64\u5916\uff0c\u6cb8\u77f3\u5916\u90e8\u7684\u7532\u9187\u8131\u6c34\u53cd\u5e94\u51cf\u5c11\u4e86\u6c34\u548c\u82ef\u5728\u6cb8\u77f3\u901a\u9053\u9178\u6027\u4e2d\u5fc3\u4e0a\u5438\u9644\u7684\u7ade\u4e89\uff0c\u4ece\u800c\u589e\u52a0\u4e86\u82ef\u7684\u8f6c\u5316\u7387\uff0c\u63d0\u9ad8\u4e86\u50ac\u5316\u5242\u7684\u7a33\u5b9a\u6027\u3002\u7efc\u4e0a\uff0c\u8be5\u9879\u7814\u7a76\u4e3a\u8bbe\u8ba1\u9ad8\u6548\u3001\u7a33\u5b9a\u7684CO<sub>2<\/sub>\u52a0\u6c22\u4e0e\u82ef\u70f7\u57fa\u5316\u53cd\u5e94\u5408\u6210\u9ad8\u9644\u52a0\u503c\u82b3\u70c3\u7684\u591a\u7ec4\u5206\u50ac\u5316\u4f53\u7cfb\u63d0\u4f9b\u4e86\u601d\u8def\u3002<\/section>\n<section>Boosting benzene alkylation conversion with CO<sub>2<\/sub>\/H<sub>2<\/sub>\u00a0via a triple composite catalyst. ACS Catalysis, 2024.<strong>\u00a0<\/strong>DOI: 10.1021\/acscatal.4c02253<\/section>\n","protected":false},"excerpt":{"rendered":"<p>\u82ef\u4e0eCO2\/H2\u70f7\u57fa\u5316\u5408\u6210\u7532\u82ef\u548c\u4e8c\u7532\u82ef\uff0c\u5bf9\u51cf\u5c11\u78b3\u6392\u653e\u3001\u63d0\u9ad8\u8f7b\u82b3\u70c3\u5411\u589e\u503c\u5316\u5b66\u54c1\u7684\u8f6c\u5316\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002\u7136\u800c\uff0cCO2\u52a0 [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-52142","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/52142","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=52142"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/52142\/revisions"}],"predecessor-version":[{"id":52143,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/52142\/revisions\/52143"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=52142"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=52142"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=52142"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}