{"id":52096,"date":"2024-08-22T08:34:05","date_gmt":"2024-08-22T00:34:05","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=52096"},"modified":"2024-08-13T10:36:48","modified_gmt":"2024-08-13T02:36:48","slug":"%e3%80%90acs-catalysis%e3%80%91%e5%85%89%e5%82%ac%e5%8c%96%e8%be%85%e5%8a%a9%e7%9a%84%e9%93%91%e5%82%ac%e5%8c%96%e4%b8%8d%e5%af%b9%e7%a7%b0%e7%83%af%e4%b8%99%e5%9f%ba%e5%8f%96%e4%bb%a3%e5%8f%8d","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/%e3%80%90acs-catalysis%e3%80%91%e5%85%89%e5%82%ac%e5%8c%96%e8%be%85%e5%8a%a9%e7%9a%84%e9%93%91%e5%82%ac%e5%8c%96%e4%b8%8d%e5%af%b9%e7%a7%b0%e7%83%af%e4%b8%99%e5%9f%ba%e5%8f%96%e4%bb%a3%e5%8f%8d\/","title":{"rendered":"\u3010ACS Catalysis\u3011\u5149\u50ac\u5316\u8f85\u52a9\u7684\u94d1\u50ac\u5316\u4e0d\u5bf9\u79f0\u70ef\u4e19\u57fa\u53d6\u4ee3\u53cd\u5e94\uff1a\u4ece\u57fa\u7840\u7814\u7a76\u5230\u5b9e\u9645\u5e94\u7528"},"content":{"rendered":"<p><img decoding=\"async\" title=\"1\" src=\"https:\/\/10110.seohost.cn\/storage\/10110\/article\/20240813\/1723516550673084.webp\" alt=\"1\" \/><\/p>\n<section>\u4e0d\u5bf9\u79f0\u70ef\u4e19\u57fa\u53d6\u4ee3\u53cd\u5e94\u662f\u4e00\u7c7b\u91cd\u8981\u7684\u6709\u673a\u53cd\u5e94\uff0c\u5176\u80fd\u591f\u9ad8\u6548\u6784\u5efa\u5177\u6709\u9ad8\u5bf9\u6620\u9009\u62e9\u6027\u7684\u78b3-\u78b3\u548c\u78b3-\u6742\u539f\u5b50\u952e\u3002\u5728\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u7684\u4f53\u7cfb\u4e2d\uff0c\u94af\u3001\u94f1\u3001\u94dc\u7b49\u91d1\u5c5e\u5df2\u5e7f\u6cdb\u7528\u4e8e\u8be5\u7c7b\u53cd\u5e94\uff0c\u7136\u800c\uff0c\u94d1\u50ac\u5316\u7684\u4e0d\u5bf9\u79f0\u70ef\u4e19\u57fa\u53d6\u4ee3\u53cd\u5e94\uff08AAS\uff09\u76f8\u5bf9\u8f83\u5c11\uff0c\u4e14\u51e0\u4e4e\u6240\u6709\u62a5\u9053\u7684\u94d1\u50ac\u5316\u00a0AAS\u00a0\u53cd\u5e94\u90fd\u662f\u901a\u8fc7\u53cc\u7535\u5b50\u70ef\u4e19\u57fa\u5316\u9014\u5f84\u8fdb\u884c\u7684\u3002\uff08\u56fe1a\uff09\u94d1\u50ac\u5316\u5242\u5177\u6709\u4f18\u826f\u7684\u5e95\u7269\u517c\u5bb9\u6027\u548c\u5316\u5b66\u9009\u62e9\u6027\uff0c\u662f\u4e00\u79cd\u5177\u6709\u6f5c\u529b\u7684\u50ac\u5316\u5242\u3002\u5728\u6b64\u80cc\u666f\u4e0b\uff0c\u8fd1\u5e74\u6765\u7814\u7a76\u8005\u4eec\u9010\u6e10\u5173\u6ce8\u94d1\u50ac\u5316\u7684\u4e0d\u5bf9\u79f0\u70ef\u4e19\u57fa\u53d6\u4ee3\u53cd\u5e94\u3002\u4f8b\u5982\uff0cHayashi\u3001Evans\u7b49\u4eba\u8fdb\u884c\u4e86\u4e00\u7cfb\u5217\u5f00\u521b\u6027\u7684\u7814\u7a76\uff0c\u5c55\u793a\u4e86\u94d1\u50ac\u5316\u5242\u5728\u5b9e\u73b0\u9ad8\u5bf9\u6620\u9009\u62e9\u6027\u65b9\u9762\u7684\u72ec\u7279\u4f18\u52bf\u3002\u6b64\u5916\uff0c\u5149\u5316\u5b66\u4f5c\u4e3a\u4e00\u9879\u8fc5\u901f\u53d1\u5c55\u7684\u6280\u672f\uff0c\u4e3a\u4f20\u7edf\u7684\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u53cd\u5e94\u5f15\u5165\u4e86\u65b0\u6d3b\u6027\u6a21\u5f0f\uff0c\u7279\u522b\u662f\u5728\u5355\u7535\u5b50\u8f6c\u79fb\u673a\u5236\u4e2d\u7684\u5e94\u7528\u3002\uff08\u56fe1b\uff09\u7136\u800c\uff0c\u5c06\u6d3b\u6027\u81ea\u7531\u57fa\u5f15\u5165\u94d1\u50ac\u5316\u4f53\u7cfb\u4e2d\u4ecd\u662f\u4e00\u9879\u5177\u6709\u6311\u6218\u6027\u7684\u8bfe\u9898\u3002\u7ed3\u5408\u5149\u5316\u5b66\u7684\u5355\u7535\u5b50\u8f6c\u79fb\u80fd\u529b\u4e0e\u94d1\u50ac\u5316\u7684\u4e0d\u5bf9\u79f0\u6027\uff0c\u4f5c\u8005\u8bbe\u60f3\u901a\u8fc7\u5149\u751f\u81ea\u7531\u57fa\u4e0e\u94d1\u50ac\u5316\u5242\u7684\u534f\u540c\u4f5c\u7528\uff0c\u63a2\u7d22\u65b0\u7684\u53cd\u5e94\u6a21\u5f0f\u548c\u5e95\u7269\u9002\u5e94\u6027\uff0c\u4ece\u800c\u62d3\u5bbd\u70ef\u4e19\u57fa\u53d6\u4ee3\u53cd\u5e94\u7684\u5e94\u7528\u8303\u56f4\u3002<\/section>\n<p><img decoding=\"async\" title=\"2\" src=\"https:\/\/10110.seohost.cn\/storage\/10110\/article\/20240813\/1723516560658345.webp\" alt=\"2\" \/><\/p>\n<p>\u56fe\u7247\u6765\u6e90\uff1aACS Catalysis<\/p>\n<section>\u672c\u7814\u7a76\u5f00\u53d1\u4e86\u4e00\u79cd\u53cc\u5149\u50ac\u5316\/\u94d1\u50ac\u5316\u7684\u4e0d\u5bf9\u79f0\u70ef\u4e19\u57fa\u53d6\u4ee3\u53cd\u5e94\uff0c\u5229\u7528\u5149\u751f\u6210\u7684\u70f7\u57fa\u81ea\u7531\u57fa\u4f5c\u4e3a\u53cd\u5e94\u6d3b\u6027\u79cd\u3002\uff08\u56fe1c\uff09\u8fd9\u79cd\u65b9\u6cd5\u4e0d\u4ec5\u53ef\u4ee5\u62d3\u5c55\u4f20\u7edf\u94d1\u50ac\u5316\u53cd\u5e94\u7684\u53cd\u5e94\u6a21\u5f0f\uff0c\u8fd8\u80fd\u63d0\u4f9b\u4e00\u79cd\u5728\u6e29\u548c\u6761\u4ef6\u4e0b\u5b9e\u73b0\u9ad8\u6548\u4ea7\u7269\u5408\u6210\u7684\u7b56\u7565\u3002\u7814\u7a76\u4e2d\uff0c\u4f5c\u8005\u9009\u62e9\u4e864-\u70f7\u57fa-1,4-\u4e8c\u6c22\u5421\u5576\u4f5c\u4e3a\u81ea\u7531\u57fa\u524d\u4f53\uff0c\u5e76\u91c7\u75284CzIPN\u4f5c\u4e3a\u5149\u654f\u5242\uff0c\u5728427nmLED\u5149\u7167\u4e0b\uff0c\u901a\u8fc7\u5149\u50ac\u5316\u8fd8\u539f\u03c0-\u70ef\u4e19\u57fa\u94d1(III)\u7edc\u5408\u7269\u751f\u6210\u03c0-\u70ef\u4e19\u57fa\u94d1(II)\u7edc\u5408\u7269\u3002\u968f\u540e\uff0c\u70f7\u57fa\u81ea\u7531\u57fa\u4e0e\u751f\u6210\u7684\u94d1(II)\u7edc\u5408\u7269\u7ed3\u5408\uff0c\u8fdb\u884c\u8fd8\u539f\u6027\u6d88\u9664\uff0c\u6700\u7ec8\u5f97\u5230\u76ee\u6807\u70ef\u4e19\u57fa\u53d6\u4ee3\u4ea7\u7269\u3002\u901a\u8fc7\u7cfb\u7edf\u7684\u53cd\u5e94\u6761\u4ef6\u4f18\u5316\uff0c\u4f5c\u8005\u786e\u5b9a\u4e86\u6700\u4f73\u53cd\u5e94\u6761\u4ef6\uff0c\u5e76\u5bf9\u4e00\u7cfb\u5217\u4e8c\u6c22\u5421\u5576\u548c\u70ef\u4e19\u57fa\u4e59\u9178\u916f\u5e95\u7269\u8fdb\u884c\u4e86\u8003\u5bdf\u3002\u7ed3\u679c\u8868\u660e\uff0c\u7814\u7a76\u6240\u5f00\u53d1\u7684\u50ac\u5316\u4f53\u7cfb\u5728\u591a\u79cd\u5e95\u7269\u4e2d\u8868\u73b0\u51fa\u826f\u597d\u7684\u53cd\u5e94\u6d3b\u6027\u548c\u9009\u62e9\u6027\uff0c\u80fd\u591f\u572848-80%\u7684\u6536\u7387\u4e0b\u83b7\u5f9780-98%\u7684\u5bf9\u6620\u9009\u62e9\u6027\u3002<\/section>\n<p><img decoding=\"async\" title=\"4\" src=\"https:\/\/10110.seohost.cn\/storage\/10110\/article\/20240813\/1723516573948741.webp\" alt=\"4\" \/>\u200b<\/p>\n<p>\u56fe\u7247\u6765\u6e90\uff1aACS Catalysis<\/p>\n<section>\u672c\u7814\u7a76\u5f00\u521b\u6027\u5730\u5c06\u5149\u5316\u5b66\u5f15\u5165\u94d1\u50ac\u5316\u7684\u4e0d\u5bf9\u79f0\u70ef\u4e19\u57fa\u53d6\u4ee3\u53cd\u5e94\u4e2d\uff0c\u5c55\u793a\u4e86\u5149\u751f\u81ea\u7531\u57fa\u4e0e\u94d1\u50ac\u5316\u4f53\u7cfb\u7ed3\u5408\u7684\u5de8\u5927\u6f5c\u529b\u3002\u8fd9\u4e00\u65b9\u6cd5\u901a\u8fc7\u5f15\u5165\u5149\u751f\u81ea\u7531\u57fa\uff0c\u62d3\u5bbd\u4e86\u94d1\u50ac\u5316\u53cd\u5e94\u7684\u53cd\u5e94\u6a21\u5f0f\uff0c\u63d0\u4f9b\u4e86\u4e00\u79cd\u5728\u6e29\u548c\u6761\u4ef6\u4e0b\u5b9e\u73b0\u9ad8\u6548\u70ef\u4e19\u57fa\u53d6\u4ee3\u7684\u7b56\u7565\u3002\u8be5\u65b9\u6cd5\u4e0d\u4ec5\u4e30\u5bcc\u4e86\u94d1\u50ac\u5316\u53cd\u5e94\u7684\u5e95\u7269\u9002\u5e94\u6027\uff0c\u8fd8\u4e3a\u6709\u673a\u5408\u6210\u4e2d\u7684\u5bf9\u6620\u9009\u62e9\u6027\u63a7\u5236\u63d0\u4f9b\u4e86\u65b0\u9014\u5f84\u3002\u901a\u8fc7\u8fdb\u4e00\u6b65\u7684\u5e95\u7269\u6269\u5c55\u548c\u53cd\u5e94\u6761\u4ef6\u4f18\u5316\uff0c\u8fd9\u4e00\u7b56\u7565\u6709\u671b\u5728\u836f\u7269\u5408\u6210\u3001\u5929\u7136\u4ea7\u7269\u5408\u6210\u7b49\u9886\u57df\u4e2d\u5f97\u5230\u5e7f\u6cdb\u5e94\u7528\u3002\u6b64\u5916\uff0c\u672c\u7814\u7a76\u7684\u6210\u529f\u5b9e\u65bd\u4e5f\u4e3a\u5176\u4ed6\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u7684\u4e0d\u5bf9\u79f0\u53cd\u5e94\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\u548c\u65b9\u6cd5\uff0c\u63a8\u52a8\u4e86\u4e0d\u5bf9\u79f0\u50ac\u5316\u9886\u57df\u7684\u53d1\u5c55\u3002\u672a\u6765\u7684\u7814\u7a76\u5c06\u81f4\u529b\u4e8e\u63a2\u7d22\u66f4\u591a\u7c7b\u578b\u7684\u81ea\u7531\u57fa\u524d\u4f53\uff0c\u4ee5\u8fdb\u4e00\u6b65\u62d3\u5bbd\u6b64\u7c7b\u53cd\u5e94\u7684\u5e94\u7528\u8303\u56f4\uff0c\u5e76\u63d0\u9ad8\u5176\u5728\u5de5\u4e1a\u751f\u4ea7\u4e2d\u7684\u5b9e\u7528\u6027\u3002<\/section>\n<p>\u6807\u9898\uff1aRh-Catalyzed Asymmetric Allylic Substitution with Photo-Generated Alkyl Radical Species<\/p>\n<p>\u4f5c\u8005\uff1aRui-Xiang Wang, Pusu Yang, Yuan-Zheng Cheng*, and Shu-Li You*<\/p>\n<p>\u94fe\u63a5\uff1ahttps:\/\/doi.org\/10.1021\/acscatal.4c03683<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e0d\u5bf9\u79f0\u70ef\u4e19\u57fa\u53d6\u4ee3\u53cd\u5e94\u662f\u4e00\u7c7b\u91cd\u8981\u7684\u6709\u673a\u53cd\u5e94\uff0c\u5176\u80fd\u591f\u9ad8\u6548\u6784\u5efa\u5177\u6709\u9ad8\u5bf9\u6620\u9009\u62e9\u6027\u7684\u78b3-\u78b3\u548c\u78b3-\u6742\u539f\u5b50\u952e\u3002\u5728\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316 [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-52096","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/52096","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=52096"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/52096\/revisions"}],"predecessor-version":[{"id":52097,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/52096\/revisions\/52097"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=52096"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=52096"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=52096"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}