{"id":52058,"date":"2024-08-16T08:09:20","date_gmt":"2024-08-16T00:09:20","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=52058"},"modified":"2024-08-07T10:11:09","modified_gmt":"2024-08-07T02:11:09","slug":"angew-chem-%ef%bc%9a22%e4%ba%94%e5%85%83%e6%89%a9%e7%8e%af%e5%8d%9f%e5%95%892-0-1-1-0%e7%bb%8f%e5%8e%86%e6%b0%a7%e5%8c%96%e5%92%8c%e9%87%91%e5%b1%9e%e5%8c%96%e6%97%b6%e6%98%be%e7%8e%b0%e6%b0%ae","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/angew-chem-%ef%bc%9a22%e4%ba%94%e5%85%83%e6%89%a9%e7%8e%af%e5%8d%9f%e5%95%892-0-1-1-0%e7%bb%8f%e5%8e%86%e6%b0%a7%e5%8c%96%e5%92%8c%e9%87%91%e5%b1%9e%e5%8c%96%e6%97%b6%e6%98%be%e7%8e%b0%e6%b0%ae\/","title":{"rendered":"Angew. Chem. \uff1a[22]\u4e94\u5143\u6269\u73af\u535f\u5549(2.0.1.1.0)\u7ecf\u5386\u6c27\u5316\u548c\u91d1\u5c5e\u5316\u65f6\u663e\u73b0\u6c2e\u7a20\u5408\u3001\u5421\u54af\u91cd\u6392\u548c\u4e8c\u805a\u5316\u53cd\u5e94"},"content":{"rendered":"<section>\n<section>\n<section>\n<section>\n<section>\u4e94\u5143\u6269\u73af\u535f\u5549\u7531\u4e94\u4e2a\u5421\u54af\u5355\u5143\u548c\u82e5\u5e72\u6865\u57fa\u78b3\u539f\u5b50\u8fde\u63a5\u6784\u6210\uff0c\u6839\u636e\u6865\u57fa\u78b3\u539f\u5b50\u6570\u76ee\u53ca\u8fde\u63a5\u65b9\u5f0f\u7684\u4e0d\u540c\uff0c\u5176\u82b3\u9999\u6027\u3001\u5149\u7269\u7406\u6027\u80fd\u53ca\u53cd\u5e94\u6d3b\u6027\u7b49\u6027\u8d28\u53ef\u80fd\u5b58\u5728\u91cd\u5927\u5dee\u5f02\u3002\u5176\u4e2d\u4e94\u5421\u54af\u6269\u73af\u535f\u5549(1.1.1.1.0)\u5373Sapphyrin\u662f\u4e16\u754c\u4e0a\u6700\u65e9\u88ab\u53d1\u73b0\u7684\u6269\u73af\u535f\u5549\uff0c\u5728\u4e0a\u4e16\u7eaa60\u5e74\u4ee3\u7531\u7f8e\u56fd\u5316\u5b66\u5bb6R. B. Woodward\u5728\u5408\u6210\u7ef4\u751f\u7d20B12\u8fc7\u7a0b\u4e2d\u610f\u5916\u5408\u6210\u3002\u4e4b\u540e\u6570\u5341\u5e74\u95f4\u6269\u73af\u535f\u5549\u5316\u5b66\u5f97\u5230\u5feb\u901f\u7684\u53d1\u5c55\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"1\" src=\"https:\/\/10110.seohost.cn\/storage\/10110\/article\/20240807\/1722996624734250.webp\" alt=\"1\" \/><\/section>\n<section>\u56fe1. \u5177\u6709\u4ee3\u8868\u6027\u7684\u4e94\u5143\u6269\u73af\u535f\u5549<\/p>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u6700\u8fd1\uff0c\u6e56\u5357\u5e08\u8303\u5927\u5b66\u5b8b\u5efa\u65b0\u6559\u6388\u56e2\u961f\u62a5\u9053\u4e86\u4e00\u79cd\u9ad8\u6548\u6784\u5efa\u65b0\u578b\u4e94\u5143\u6269\u73af\u535f\u5549(2.0.1.1.0)\u7684\u65b9\u6cd5\u3002\u7814\u7a76\u4eba\u5458\u5229\u7528\u4e8c\u6eb4\u4ee3tripyrrin\u548c\u542b\u6709\u4e59\u70ef\u57fa\u5355\u5143\u7684\u4e8c\u5421\u54af\u5728\u9178\u6027\u6761\u4ef6\u4e0b\u53d1\u751f[3+2]\u5173\u73af\uff0c\u6210\u529f\u5408\u6210\u7cfb\u5217\u4e94\u5143\u6269\u73af\u535f\u5549(2.0.1.1.0) 7a-d\uff08\u56fe2\uff09\u3002\u901a\u8fc7\u5bf9\u6bd47a-d\u7684\u6838\u78c1\u5171\u632f\u6c22\u8c31\uff0c\u7d2b\u5916\u53ef\u89c1\u5438\u6536\u5149\u8c31\u4ee5\u53ca\u7406\u8bba\u8ba1\u7b97\u7ed3\u679c\uff0c\u53d1\u73b0<span class=\"wx_search_keyword_wrap\">\u4e59\u70ef\u57fa<\/span>\u4e3a\u6865\u8fde\u57fa\u56e2\u76847a\u5177\u6709\u5f3a\u768422\u03c0\u7535\u5b50\u4f11\u514b\u5c14\u82b3\u9999\u6027\uff0c7c\u6b21\u4e4b\uff0c\u800c7b\u548c7d\u5219\u4e3a\u975e\u82b3\u9999\u6027\u5316\u5408\u7269\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"2\" src=\"https:\/\/10110.seohost.cn\/storage\/10110\/article\/20240807\/1722996633492871.webp\" alt=\"2\" \/><\/section>\n<section>\u56fe2. \u5408\u6210\u4e94\u5143\u6269\u73af\u535f\u5549(2.0.1.1.0) 7a-d<\/p>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u7814\u7a76\u4eba\u5458\u5bf9\u4e94\u5143\u6269\u73af\u535f\u5549(2.0.1.1.0) 7a\u8fdb\u884c\u6c27\u5316\uff0c\u8bd5\u56fe\u83b7\u5f9720p\u7535\u5b50\u53cd\u82b3\u9999\u6027\u7684\u4e94\u5143\u6269\u73af\u535f\u5549(2.0.1.1.0)\u3002\u7136\u800c7a\u7ecf\u6c27\u5316\u53cd\u5e94\u5e76\u6ca1\u83b7\u5f97\u53cd\u82b3\u9999\u6027\u7684\u4ea7\u7269\uff0c\u800c\u662f\u83b7\u5f97\u6c2e\u7a20\u5408\u4e94\u5143\u6269\u73af\u535f\u5549 8 \u4ee5\u53ca\u5421\u54af\u91cd\u6392\u7684\u6c2e\u7a20\u5408\u4e94\u5143\u6269\u73af\u535f\u5549 9\u3002X\u5c04\u7ebf\u5355\u6676\u884d\u5c04\u5206\u6790\u8868\u660e\u5316\u5408\u72698\u548c9\u7684\u5171\u9762\u6027\u826f\u597d\uff0c\u4e14\u5b83\u4eec\u9aa8\u67b6\u4e2d\u5421\u54af\u5355\u5143E\u5747\u4e0e\u76f8\u90bb\u7684\u5421\u54af\u5355\u5143D\u53d1\u751f\u7a20\u5408\uff1b\u5176\u4e2d\u5316\u5408\u72699\u4e2d\u5421\u54af\u5355\u5143\u8fd8D\u53d1\u751f\u4e86\u91cd\u6392\u3002\u6838\u78c1\u5171\u632f\u6c22\u8c31\u548c\u7406\u8bba\u8ba1\u7b97\u8868\u660e\uff0c\u5316\u5408\u72698\u548c9\u7684\u5747\u4e3a22p\u7535\u5b50\u4f11\u514b\u5c14\u82b3\u9999\u6027\u3002\u800c\u5f53\u535f\u5549\u7a20\u5408\u7684\u4e94\u5143\u6269\u73af\u535f\u5549(2.0.1.1.0) 12\u7ecfMnO<sub>2<\/sub>\u6c27\u5316\u540e\uff0c\u7814\u7a76\u8005\u5e76\u6ca1\u5206\u79bb\u5f97\u5230\u7684\u6c2e\u7a20\u5408\u4ea7\u7269\uff0c\u800c\u662f\u83b7\u5f97\u03b2-\u03b2\u76f4\u63a5\u76f8\u8fde\u7684\u4e8c\u805a\u4f5313\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"3\" src=\"https:\/\/10110.seohost.cn\/storage\/10110\/article\/20240807\/1722996641640649.webp\" alt=\"3\" \/><\/section>\n<section>\u56fe3. \u5408\u6210\u6c2e\u7a20\u5408Pentaphyrin 8\uff0c\u5421\u54af\u91cd\u6392\u7684\u6c2e\u7a20\u5408Pentaphyrin 9\u548c\u535f\u5549\u7a20\u5408Pentaphyrin(2.0.1.1.0)\u4e8c\u805a\u4f5313<\/p>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u968f\u540e\u7814\u7a76\u4eba\u5458\u63a2\u7a76\u4e86\u5316\u5408\u72698\u548c9\u7684\u914d\u4f4d\u5316\u5b66\u6027\u8d28\u30028\u548c9\u5728\u4e8c\u6c2f\u7532\u70f7\/\u7532\u9187\u6eb6\u6db2\u4e2d\u4e0eAgOAc\u8fdb\u884c\u914d\u4f4d\uff0c\u53ef\u9ad8\u4ea7\u7387\u83b7\u5f97\u76f8\u5e94\u6c2e\u7a20\u5408\u4e94\u5143\u6269\u73af\u535f\u5549<span class=\"wx_search_keyword_wrap\">Pd<\/span><sup><span class=\"wx_search_keyword_wrap\">II<\/span><\/sup>\u914d\u5408\u72698Pd\u548c9Pd\uff08\u56fe4\uff09\u3002\u800c\u5f53\u7814\u7a76\u4eba\u5458\u91c7\u7528CuCl<sub>2<\/sub>\u6216CuCl\u4e0e\u5316\u5408\u72698\u548c9\u8fdb\u884c\u91d1\u5c5e\u914d\u4f4d\uff0c\u5206\u522b\u83b7\u5f97\u4e86\u9762\u5bf9\u9762<span class=\"wx_search_keyword_wrap\">Cu<\/span><sup><span class=\"wx_search_keyword_wrap\">II<\/span><\/sup>\u914d\u5408\u7269\u4e8c\u805a\u4f53(8Cu)<sub>2<\/sub>\u548c\u7ebf\u5f62CuII\u914d\u5408\u7269\u4e8c\u805a\u4f53(9Cu)<sub>2<\/sub>\u3002\u4e0a\u8ff0\u4e24\u79cd\u6c2e\u7a20\u5408\u4e94\u5143\u6269\u73af\u535f\u5549\u4e8c\u805a\u4f53\u7684Cu<sup>II<\/sup>\u914d\u5408\u7269\u53ef\u80fd\u662f\u901a\u8fc7\u81ea\u7531\u57fa\u4e0e\u81ea\u7531\u57fa\u5076\u8054\u5f62\u6210\u7684\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"6\" src=\"https:\/\/10110.seohost.cn\/storage\/10110\/article\/20240807\/1722996652416000.webp\" alt=\"6\" \/>\u200b<\/section>\n<section>\u56fe4. 8\u548c9\u7684\u91d1\u5c5e\u5316\u53cd\u5e94<\/p>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u7efc\u4e0a\u6240\u8ff0\uff0c\u8be5\u5de5\u4f5c\u91c7\u7528\u5168\u65b0\u7b56\u7565\u8bbe\u8ba1\u5408\u6210\u7cfb\u5217\u4e94\u5143\u6269\u73af\u535f\u5549(2.0.1.1.0) 7a-d\uff0c\u5176\u4e2d\u4e94\u5143\u6269\u73af\u535f\u5549(2.0.1.1.0) 7a\u8868\u73b0\u51fa\u72ec\u7279\u7684\u53cd\u5e94\u6d3b\u6027\uff0c\u5728\u6c27\u5316\u6761\u4ef6\u4e0b\u5b9e\u73b0\u4e86\u5421\u54af\u5355\u5143\u7ffb\u8f6c\u548c\u91cd\u6392\uff0c\u751f\u6210\u4e24\u79cd\u4e0d\u540c\u7684\u6c2e\u7a20\u5408\u4e94\u5143\u6269\u73af\u535f\u55498\u548c9\u3002\u66f4\u4e3a\u6709\u8da3\u7684\u662f\uff0c8\u548c9\u4e0e\u94dc\u79bb\u5b50\u8fdb\u884c\u914d\u4f4d\u8fc7\u7a0b\u8fd8\u80fd\u53d1\u751f\u4e8c\u805a\u5316\u53cd\u5e94\u751f\u6210\u4e8c\u805a\u4f53Cu<sup>II<\/sup>\u914d\u5408\u7269\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section><strong>\u8bba<\/strong><strong>\u6587\u4fe1\u606f<\/strong><\/p>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section><\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>[22]Pentaphyrins(2.0.1.1.0) Displaying N-Fusion, Pyrrole-Rearrangement, and Dimerization Reactions Upon Oxidation and Metalation<\/p>\n<p>Jinchao Chen,\u00a0Le Liu,\u00a0Dr. Yutao Rao,\u00a0Dr. Ling Xu,\u00a0Prof.\u2005Dr. Mingbo Zhou,\u00a0Dr. Bangshao Yin,\u00a0Prof.\u2005Dr. Soji Shimizu,\u00a0Dr. Daiki Shimizu,\u00a0Dr. Atsuhiro Osuka,\u00a0Prof.\u2005Dr. Jianxin Song<\/p>\n<p>\u672c\u6587\u7b2c\u4e00\u4f5c\u8005\u4e3a\u6e56\u5357\u5e08\u8303\u5927\u5b66\u7855\u58eb\u7814\u7a76\u751f\u9648\u9526\u8d85\uff0c\u901a\u8baf\u4f5c\u8005\u4e3a\u6e56\u5357\u5e08\u8303\u5927\u5b66\u9976\u7389\u6ed4\u8bb2\u5e08\uff0cAtsuhiro Osuka\u6559\u6388\u548c\u5b8b\u5efa\u65b0\u6559\u6388\u3002<\/p>\n<p><em>Angewandte Chemie International Edition<\/em><\/p>\n<p>DOI:\u00a010.1002\/anie.202407340<\/p>\n<\/section>\n<\/section>\n<\/section>\n","protected":false},"excerpt":{"rendered":"<p>\u4e94\u5143\u6269\u73af\u535f\u5549\u7531\u4e94\u4e2a\u5421\u54af\u5355\u5143\u548c\u82e5\u5e72\u6865\u57fa\u78b3\u539f\u5b50\u8fde\u63a5\u6784\u6210\uff0c\u6839\u636e\u6865\u57fa\u78b3\u539f\u5b50\u6570\u76ee\u53ca\u8fde\u63a5\u65b9\u5f0f\u7684\u4e0d\u540c\uff0c\u5176\u82b3\u9999\u6027\u3001\u5149\u7269\u7406\u6027\u80fd\u53ca [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-52058","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/52058","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=52058"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/52058\/revisions"}],"predecessor-version":[{"id":52059,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/52058\/revisions\/52059"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=52058"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=52058"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=52058"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}