{"id":52034,"date":"2024-08-12T08:34:13","date_gmt":"2024-08-12T00:34:13","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=52034"},"modified":"2024-08-03T22:36:40","modified_gmt":"2024-08-03T14:36:40","slug":"%e3%80%90jacs%e3%80%91%e6%96%b0%e5%9e%8b%e9%93%91%e5%82%ac%e5%8c%96%e7%83%af%e7%83%83%e5%8d%95%e7%a2%b3%e6%8f%92%e5%85%a5%e5%8f%8d%e5%ba%94%e7%9a%84%e5%bc%80%e5%88%9b%e6%80%a7%e7%a0%94%e7%a9%b6","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/%e3%80%90jacs%e3%80%91%e6%96%b0%e5%9e%8b%e9%93%91%e5%82%ac%e5%8c%96%e7%83%af%e7%83%83%e5%8d%95%e7%a2%b3%e6%8f%92%e5%85%a5%e5%8f%8d%e5%ba%94%e7%9a%84%e5%bc%80%e5%88%9b%e6%80%a7%e7%a0%94%e7%a9%b6\/","title":{"rendered":"\u3010JACS\u3011\u65b0\u578b\u94d1\u50ac\u5316\u70ef\u70c3\u5355\u78b3\u63d2\u5165\u53cd\u5e94\u7684\u5f00\u521b\u6027\u7814\u7a76"},"content":{"rendered":"

\"1\"<\/p>\n

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\u7136\u800c\uff0c\u5c3d\u7ba1\u8fd9\u4e9b\u53cd\u5e94\u7684\u7814\u7a76\u53d6\u5f97\u4e86\u4e00\u4e9b\u8fdb\u5c55\uff0c\u4f46\u5bf9\u4e8e\u6d89\u53ca\u5728C(sp2<\/sup>)\u2212C(sp2<\/sup>)\u952e\u4e2d\u8fdb\u884c\u4e0d\u5bf9\u79f0\u624b\u6027\u78b3\u63d2\u5165\u7684\u9aa8\u67b6\u7f16\u8f91\u53cd\u5e94\uff0c\u5c24\u5176\u662f\u901a\u8fc7\u94d1-\u5361\u5bbe\u5316\u5408\u7269\u5b9e\u73b0\u7684\u53cd\u5e94\uff0c\u63a2\u7d22\u4ecd\u7136\u6709\u9650\u3002\u968f\u7740\u79d1\u5b66\u5bb6\u4eec\u5bf9\u6709\u673a\u5206\u5b50\u4e2d\u78b3-\u78b3\u548c\u78b3-\u6742\u539f\u5b50\u952e\u9aa8\u67b6\u7f16\u8f91\u7684\u5174\u8da3\u56de\u6f6e\uff0c\u5f00\u53d1\u65b0\u7684\u53cd\u5e94\u548c\u7b56\u7565\u53d8\u5f97\u6108\u53d1\u91cd\u8981\u3002\u8fd9\u4e9b\u53cd\u5e94\u80fd\u591f\u4e3a\u5df2\u6709\u7684\u9006\u5408\u6210\u903b\u8f91\u63d0\u4f9b\u65b0\u7684\u89e3\u79bb\u65b9\u6cd5\u3002\u901a\u8fc7\u5355\u78b3\u63d2\u5165\u5b9e\u73b0\u5bf9\u73af\u72b6\u548c\u975e\u73af\u72b6\u5206\u5b50\uff0c\u5305\u62ec\u70ef\u70c3\u3001\u5432\u54da\u3001\u82b3\u70c3\u6216\u831a\u6ee1\u7684\u9aa8\u67b6\u7f16\u8f91\uff0c\u9010\u6e10\u6210\u4e3a\u53ef\u80fd\uff0c\u4f46\u5728\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u5f15\u5165\u4e0d\u5bf9\u79f0\u8bf1\u5bfc\u7684\u65b9\u6cd5\u4ecd\u5f85\u7a81\u7834\u3002<\/section>\n

\"2\"<\/p>\n

\u56fe\u7247\u6765\u6e90\uff1aJACS<\/p>\n

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\"\u56fe\u7247\"<\/p>\n

\u56fe\u7247\u6765\u6e90\uff1aJACS<\/p>\n

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\u6807\u9898\uff1aRh-Catalyzed Enantioselective Single-Carbon Insertion of Alkenes<\/p>\n

\u4f5c\u8005\uff1aWei Jie, TeoJosep Esteve Guasch, Liyin Jiang, Bowen Li, and Marcos G. Suero*<\/p>\n

\u94fe\u63a5\uff1ahttps:\/\/doi.org\/10.1021\/jacs.4c06158<\/p>\n","protected":false},"excerpt":{"rendered":"

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