{"id":51878,"date":"2024-07-19T08:55:15","date_gmt":"2024-07-19T00:55:15","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=51878"},"modified":"2024-07-10T09:55:39","modified_gmt":"2024-07-10T01:55:39","slug":"%e3%80%90acs-catalysis%e3%80%91%e6%96%b0%e5%9e%8b%e9%94%b0%e5%82%ac%e5%8c%96%e7%9a%84%e5%a4%9a%e9%85%ae%e5%90%88%e6%88%90%e6%96%b9%e6%b3%95%ef%bc%9a%e7%bb%bf%e8%89%b2%e5%8c%96%e5%ad%a6%e7%9a%84","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/%e3%80%90acs-catalysis%e3%80%91%e6%96%b0%e5%9e%8b%e9%94%b0%e5%82%ac%e5%8c%96%e7%9a%84%e5%a4%9a%e9%85%ae%e5%90%88%e6%88%90%e6%96%b9%e6%b3%95%ef%bc%9a%e7%bb%bf%e8%89%b2%e5%8c%96%e5%ad%a6%e7%9a%84\/","title":{"rendered":"\u3010ACS Catalysis\u3011\u65b0\u578b\u9530\u50ac\u5316\u7684\u591a\u916e\u5408\u6210\u65b9\u6cd5\uff1a\u7eff\u8272\u5316\u5b66\u7684\u521b\u65b0\u7a81\u7834"},"content":{"rendered":"<p><img decoding=\"async\" title=\"8\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240706\/1720258776394155.webp\" alt=\"8\" \/><\/p>\n<p>&nbsp;<\/p>\n<section>\u591a\u916e\u662f\u4e00\u7c7b\u9ad8\u6027\u80fd\u70ed\u5851\u6027\u5851\u6599\uff0c\u5e7f\u6cdb\u5e94\u7528\u4e8e\u6c7d\u8f66\u3001\u7535\u5b50\u3001\u7535\u6c14\u548c\u533b\u7597\u7b49\u9886\u57df\u3002\u76f8\u6bd4\u4f20\u7edf\u7684\u805a\u70ef\u70c3\uff0c\u591a\u916e\u56e0\u5176\u4e3b\u94fe\u4e2d\u542b\u6709\u6781\u6027\u7684C=O\u57fa\u56e2\uff0c\u5177\u5907\u4f18\u5f02\u7684\u673a\u68b0\u6027\u80fd\u3001\u7ed3\u6676\u6027\u548c\u4eb2\u6c34\u6027\u3002\u7136\u800c\uff0c\u5c3d\u7ba1\u5176\u6027\u80fd\u5353\u8d8a\uff0c\u591a\u916e\u7c7b\u805a\u5408\u7269\u7684\u7814\u7a76\u76f8\u5bf9\u8f83\u5c11\u3002\u76ee\u524d\uff0c\u5e02\u573a\u4e0a\u5b58\u5728\u4e24\u79cd\u4e3b\u8981\u7684\u591a\u916e\uff1a\u8102\u80aa\u65cf\u591a\u916e\uff08POK\uff09\u548c\u82b3\u9999\u65cf\u591a\u916e\uff08PAEK\uff09\u3002POK\u7531\u4e59\u70ef\u548c\/\u6216\u4e19\u70ef\u4e0e\u4e00\u6c27\u5316\u78b3\u5728\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u4e0b\u5076\u8054\u800c\u6210\uff0c\uff08\u56fe1A\uff09\u800cPAEK\u5219\u7531\u4e8c\u915a\u94a0\u76d0\u548c\u53cc\u916e\u5728\u9ad8\u6e29\u4e0b\u805a\u5408\u800c\u6210\u3002\uff08\u56fe1B\uff09\u5c3d\u7ba1\u8fd9\u4e9b\u591a\u916e\u5177\u5907\u4f18\u5f02\u7684\u6027\u80fd\uff0c\u5982PAEK\u56e0\u5176\u5353\u8d8a\u7684\u673a\u68b0\u6027\u80fd\u548c\u5316\u5b66\u7a33\u5b9a\u6027\u88ab\u5e7f\u6cdb\u5e94\u7528\u4e8e\u822a\u7a7a\u822a\u5929\u3001\u77f3\u6cb9\u94bb\u63a2\u548c\u533b\u7597\u690d\u5165\u7269\u4e2d\uff0c\u4f46\u5176\u52a0\u5de5\u96be\u5ea6\u5927\uff0c\u6210\u672c\u9ad8\u6602\u3002\u56e0\u6b64\uff0c\u5f00\u53d1\u5177\u6709\u66f4\u9ad8\u53ef\u52a0\u5de5\u6027\u548c\u76f8\u4f3c\u6027\u80fd\u7684\u65b0\u578b\u591a\u916e\u6750\u6599\u6210\u4e3a\u8feb\u5207\u9700\u6c42\u3002<\/section>\n<section>\u672c\u7814\u7a76\u805a\u7126\u4e8e\u4e00\u79cd\u65b0\u578b\u591a\u916e\u2014\u2014\u82b3\u70f7\u57fa\u916e\uff08PAAK\uff09\u7684\u5408\u6210\uff0c\u5b83\u7ed3\u5408\u4e86\u8102\u80aa\u65cf\u591a\u916e\u7684\u52a0\u5de5\u7075\u6d3b\u6027\u548c\u82b3\u9999\u65cf\u591a\u916e\u7684\u673a\u68b0\u6027\u80fd\uff0c\u65e8\u5728\u586b\u8865\u8fd9\u4e24\u7c7b\u591a\u916e\u4e4b\u95f4\u7684\u6027\u80fd\u7a7a\u767d\u3002<\/section>\n<p>&nbsp;<\/p>\n<p><img decoding=\"async\" title=\"9\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240706\/1720258776885183.webp\" alt=\"9\" \/><\/p>\n<p>\u56fe\u7247\u6765\u6e90\uff1aACS Catalysis<\/p>\n<p>&nbsp;<\/p>\n<section>\u672c\u7814\u7a76\u4e3b\u8981\u5f00\u53d1\u4e86\u4e00\u79cd\u5229\u7528\u9530\u94b3\u5b50\u914d\u5408\u7269\u50ac\u5316\uff0c\u901a\u8fc7\u6c22\u501f\u7528\u673a\u5236\u5408\u6210\u82b3\u70f7\u57fa\u916e\uff08PAAK\uff09\u7684\u65b9\u6cd5\u3002\uff08\u56feD\uff09\u6c22\u501f\u7528\u673a\u5236\u662f\u4e00\u79cd\u7eff\u8272\u5316\u5b66\u65b9\u6cd5\uff0c\u901a\u8fc7\u9187\u7684\u8131\u6c22\u751f\u6210\u919b\uff0c\u518d\u901a\u8fc7\u919b\u4e0e\u53cc\u916e\u7684\u7f29\u5408\u751f\u6210\u67e5\u5c14\u916e\u884d\u751f\u7269\uff0c\u6700\u540e\u6c22\u5316\u751f\u6210\u591a\u916e\u3002\u7814\u7a76\u9996\u5148\u901a\u8fc7\u6a21\u578b\u53cd\u5e94\u9a8c\u8bc1\u8be5\u65b9\u6cd5\u7684\u53ef\u884c\u6027\uff0c\u4f7f\u7528\u4e59\u9170\u82ef\u548c\u5bf9\u82ef\u4e8c\u7532\u9187\u5728\u9530\u50ac\u5316\u5242\u548c\u78b3\u9178\u94ef\u7684\u4f5c\u7528\u4e0b\u5728\u7532\u82ef\u4e2d\u53cd\u5e94\uff0c\u751f\u6210\u9884\u671f\u7684\u53cc\u916e\u3002\u968f\u540e\uff0c\u7814\u7a76\u8fdb\u4e00\u6b65\u4f18\u5316\u53cd\u5e94\u6761\u4ef6\uff0c\u5305\u62ec\u50ac\u5316\u5242\u7528\u91cf\u3001\u5e95\u7269\u6d53\u5ea6\u3001\u53cd\u5e94\u65f6\u95f4\u548c\u6e29\u5ea6\u7b49\uff0c\u6700\u7ec8\u786e\u5b9a\u4e86\u6700\u4f73\u53cd\u5e94\u6761\u4ef6\u3002\u6700\u540e\uff0c\u7814\u7a76\u6269\u5c55\u4e86\u5e95\u7269\u8303\u56f4\uff0c\u9a8c\u8bc1\u4e86\u8be5\u65b9\u6cd5\u5bf9\u4e0d\u540c\u53cc\u916e\u548c\u4e8c\u9187\u7684\u9002\u7528\u6027\uff0c\u5e76\u901a\u8fc7\u7ea2\u5916\u5149\u8c31\u3001\u56fa\u6001\u6838\u78c1\u5171\u632f\u548c\u70ed\u91cd\u5206\u6790\u7b49\u6280\u672f\u5bf9\u751f\u6210\u7684\u591a\u916e\u8fdb\u884c\u8868\u5f81\uff0c\u786e\u8ba4\u5176\u7ed3\u6784\u548c\u6027\u80fd\u3002<\/section>\n<section>\u672c\u7814\u7a76\u5f00\u53d1\u4e86\u4e00\u79cd\u65b0\u9896\u7684\u9530\u50ac\u5316\u5408\u6210\u82b3\u70f7\u57fa\u916e\u7684\u65b9\u6cd5\uff0c\u4e0d\u4ec5\u4e30\u5bcc\u4e86\u591a\u916e\u7684\u79cd\u7c7b\uff0c\u8fd8\u4e3a\u7eff\u8272\u5316\u5b66\u7684\u7814\u7a76\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\u3002\u9996\u5148\uff0c\u8be5\u65b9\u6cd5\u91c7\u7528\u4e86\u6c22\u501f\u7528\u673a\u5236\uff0c\u5b9e\u73b0\u4e86\u9ad8\u539f\u5b50\u7ecf\u6d4e\u6027\u7684\u53cd\u5e94\u8def\u5f84\uff0c\u51cf\u5c11\u4e86\u526f\u4ea7\u7269\u7684\u751f\u6210\uff0c\u7b26\u5408\u7eff\u8272\u5316\u5b66\u7684\u539f\u5219\u3002\u5176\u6b21\uff0c\u901a\u8fc7\u4f18\u5316\u53cd\u5e94\u6761\u4ef6\u548c\u6269\u5c55\u5e95\u7269\u8303\u56f4\uff0c\u7814\u7a76\u9a8c\u8bc1\u4e86\u8be5\u65b9\u6cd5\u7684\u666e\u9002\u6027\u548c\u9ad8\u6548\u6027\uff0c\u4e3a\u5de5\u4e1a\u751f\u4ea7\u63d0\u4f9b\u4e86\u53ef\u80fd\u3002\u6b64\u5916\uff0c\u901a\u8fc7\u5bf9\u5408\u6210\u7684\u591a\u916e\u8fdb\u884c\u8be6\u7ec6\u7684\u6027\u80fd\u8868\u5f81\uff0c\u7814\u7a76\u8bc1\u660e\u8fd9\u4e9b\u65b0\u578b\u591a\u916e\u5177\u5907\u4f18\u5f02\u7684\u673a\u68b0\u6027\u80fd\u548c\u70ed\u7a33\u5b9a\u6027\uff0c\u663e\u793a\u51fa\u826f\u597d\u7684\u5e94\u7528\u524d\u666f\u3002<\/section>\n<section>\u7279\u522b\u503c\u5f97\u4e00\u63d0\u7684\u662f\uff0c\u8be5\u65b9\u6cd5\u8fd8\u5c55\u793a\u4e86\u5229\u7528\u5e9f\u5851\u6599\uff08\u5982\u805a\u5bf9\u82ef\u4e8c\u7532\u9178\u4e59\u4e8c\u9187\u916f\uff0cPET\uff09\u5236\u5907\u591a\u916e\u7684\u6f5c\u529b\u3002\u901a\u8fc7\u5c06PET\u5e9f\u6599\u6c22\u89e3\u4e3a\u5bf9\u82ef\u4e8c\u7532\u9187\uff0c\u518d\u4e0e\u53cc\u916e\u5728\u9530\u50ac\u5316\u5242\u4f5c\u7528\u4e0b\u53cd\u5e94\uff0c\u6210\u529f\u5408\u6210\u4e86\u534a\u53ef\u518d\u751f\u7684\u591a\u916e\u3002\u8fd9\u4e00\u7ed3\u679c\u4e0d\u4ec5\u4e3a\u5e9f\u5851\u6599\u7684\u9ad8\u503c\u5316\u5229\u7528\u63d0\u4f9b\u4e86\u65b0\u7684\u9014\u5f84\uff0c\u4e5f\u4e3a\u53ef\u518d\u751f\u6750\u6599\u7684\u5f00\u53d1\u548c\u5e94\u7528\u5960\u5b9a\u4e86\u57fa\u7840\u3002<\/section>\n<p>&nbsp;<\/p>\n<p>\u6807\u9898\uff1aManganese-Catalyzed Synthesis of Polyketones Using Hydrogen-Borrowing Approach<\/p>\n<p>\u4f5c\u8005\uff1aPavel S. Kulyabin, Oxana V. Magdysyuk, Aaron B. Naden, Daniel M. Dawson, Ketan Pancholi, Matthew Walker, Massimo Vassalli, and Amit Kumar*<\/p>\n<p>\u94fe\u63a5\uff1ahttps:\/\/doi.org\/10.1021\/acscatal.4c03019<\/p>\n","protected":false},"excerpt":{"rendered":"<p>&nbsp; \u591a\u916e\u662f\u4e00\u7c7b\u9ad8\u6027\u80fd\u70ed\u5851\u6027\u5851\u6599\uff0c\u5e7f\u6cdb\u5e94\u7528\u4e8e\u6c7d\u8f66\u3001\u7535\u5b50\u3001\u7535\u6c14\u548c\u533b\u7597\u7b49\u9886\u57df\u3002\u76f8\u6bd4\u4f20\u7edf\u7684\u805a\u70ef\u70c3\uff0c\u591a\u916e\u56e0\u5176\u4e3b [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-51878","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51878","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=51878"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51878\/revisions"}],"predecessor-version":[{"id":51879,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51878\/revisions\/51879"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=51878"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=51878"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=51878"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}