{"id":51854,"date":"2024-07-15T08:16:39","date_gmt":"2024-07-15T00:16:39","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=51854"},"modified":"2024-07-06T17:17:03","modified_gmt":"2024-07-06T09:17:03","slug":"kaust-%e7%89%a9%e6%9e%84%e6%89%80jacs-%e5%bc%95%e5%85%a5ni%e5%8e%9f%e5%ad%90%ef%bc%8c%e4%bf%83%e8%bf%9bin2o3ni%e9%80%89%e6%8b%a9%e6%80%a7%e5%85%89%e7%83%ad%e5%82%ac%e5%8c%96co2%e8%bd%ac","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/kaust-%e7%89%a9%e6%9e%84%e6%89%80jacs-%e5%bc%95%e5%85%a5ni%e5%8e%9f%e5%ad%90%ef%bc%8c%e4%bf%83%e8%bf%9bin2o3ni%e9%80%89%e6%8b%a9%e6%80%a7%e5%85%89%e7%83%ad%e5%82%ac%e5%8c%96co2%e8%bd%ac\/","title":{"rendered":"\u200bKAUST\/\u7269\u6784\u6240JACS: 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src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240703\/1719970652436242.webp\" alt=\"1\" \/><\/section>\n<section><img decoding=\"async\" title=\"2\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240703\/1719970661368748.webp\" alt=\"2\" \/><\/section>\n<section>\u5177\u6709\u660e\u786e\u6d3b\u6027\u4e2d\u5fc3\u7684\u5355\u539f\u5b50\u50ac\u5316\u5242\u4e3a\u5728\u539f\u5b50\u5c3a\u5ea6\u4e0a\u63a2\u7d22\u7cbe\u786e\u7684\u7ed3\u6784-\u6d3b\u6027\u5173\u7cfb\u63d0\u4f9b\u4e86\u4e00\u4e2a\u7406\u60f3\u7684\u5e73\u53f0\u3002\u8fd1\u65e5\uff0c<strong>\u963f\u535c\u675c\u62c9\u56fd\u738b\u79d1\u6280\u5927\u5b66\u5f20\u534e\u5f6c<\/strong>\u3001<strong>Jorge Gascon<\/strong>\u548c<strong>\u4e2d\u56fd\u79d1\u5b66\u9662\u798f\u5efa\u7269\u6784\u6240\u674e\u5de7\u7ea2<\/strong>\u7b49\u5c06\u5747\u5300\u5206\u6563\u7684\u5355\u539f\u5b50Ni\u4e2d\u5fc3\u951a\u5b9a\u5728In<sub>2<\/sub>O<sub>3<\/sub>\u8868\u9762\u4e0a(In<sub>2<\/sub>O<sub>3<\/sub>@Ni)\uff0c\u8be5\u50ac\u5316\u5242\u5177\u6709\u660e\u786e\u7684\u914d\u4f4d\u7ed3\u6784\uff0c\u7528\u4e8e\u9ad8\u9009\u62e9\u6027\u50ac\u5316CO<sub>2<\/sub>\u52a0\u6c22\u5236CH<sub>4<\/sub>\u3002\u5b9e\u9a8c\u7ed3\u679c\u8868\u660e\uff0cIn<sub>2<\/sub>O<sub>3<\/sub>@Ni\u50ac\u5316\u5242\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u50ac\u5316\u6d3b\u6027\uff0c\u5176\u5728\u6a21\u62df\u5149\u70ed\u6761\u4ef6\u4e0b\u50ac\u5316CO<sub>2<\/sub>\u52a0\u6c22\u751f\u6210CH<sub>4<\/sub>\u7684\u9009\u62e9\u6027\u9ad8\u8fbe99%\uff0c\u52a0\u6c22\u901f\u7387\u8fbe\u52301043 \u03bcmol g<sup>\u22121<\/sup>\u00a0h<sup>\u22121<\/sup>\uff0c\u8fd9\u79cdCH<sub>4<\/sub>\u7684\u751f\u4ea7\u901f\u7387\u662f\u5149\u50ac\u5316\u7684200\u500d\u548c\u70ed\u50ac\u5316\u76846\u500d\u3002\u6b64\u5916\uff0c\u5728\u8fde\u7eed\u8fdb\u884c\u5149\u70ed\u50ac\u5316\u53cd\u5e9480\u5c0f\u65f6\u540e\uff0c\u8be5\u50ac\u5316\u5242\u4ecd\u8868\u73b0\u51fa\u826f\u597d\u7684\u6d3b\u6027\uff0c\u4e14\u53cd\u5e94\u540e\u6837\u54c1\u8868\u9762\u6ca1\u6709Ni\u805a\u96c6\u5f15\u8d77\u7684\u56e2\u7c07\u6216\u9897\u7c92\u3002<\/section>\n<section><img decoding=\"async\" title=\"3\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240703\/1719970670336316.webp\" alt=\"3\" \/><\/section>\n<section><img decoding=\"async\" title=\"8\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240703\/1719970681881247.webp\" alt=\"8\" \/><\/section>\n<section>CO-TPD\u548c\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba(DFT)\u8ba1\u7b97\u7ed3\u679c\u663e\u793a\uff0c\u5728In<sub>2<\/sub>O<sub>3<\/sub>@Ni\u50ac\u5316\u5242\u4e2d\u5f15\u5165Ni\u539f\u5b50\u6709\u52a9\u4e8e\u5149\u751f\u7535\u5b50\u5411CO<sub>2<\/sub>\u7684\u8f6c\u79fb\uff1b\u540c\u65f6\uff0cNi\u7684\u5f15\u5165\u589e\u5f3a\u4e86\u5bf9CO*\u7684\u5438\u9644\u548c\u964d\u4f4e\u4e86COH*\u4e2d\u95f4\u4f53\u7684\u5f62\u6210\u80fd\u5792\uff1b\u6b64\u5916\uff0cIn<sub>2<\/sub>O<sub>3<\/sub>@Ni\u50ac\u5316\u5242\u53ef\u4ee5\u52a0\u901fH<sub>2<\/sub>\u89e3\u79bb\u751f\u6210H\uff0c\u4e3aCO<sub>2<\/sub>\u52a0\u6c22\u63d0\u4f9b\u66f4\u591a\u7684\u8d28\u5b50\uff0c\u4ece\u800c\u63d0\u9ad8CO<sub>2<\/sub>-CH<sub>4<\/sub>\u7684\u9009\u62e9\u6027\u3002<\/section>\n<section>\u603b\u7684\u6765\u8bf4\uff0c\u8be5\u9879\u5de5\u4f5c\u8bc1\u5b9e\u4e86\u5355\u539f\u5b50\u50ac\u5316\u5242\u6709\u52a9\u4e8e\u63ed\u793a\u7ed3\u6784-\u6d3b\u6027\u5173\u7cfb\uff0c\u5e76\u4e14\u8be5\u7814\u7a76\u62a5\u9053\u7684\u7b56\u7565\u53ef\u4ee5\u6307\u5bfc\u65b0\u578b\u5355\u539f\u5b50\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u548c\u5f00\u53d1\uff0c\u5e94\u7528\u4e8e\u7eff\u8272\u80fd\u6e90\u548c\u73af\u5883\u9886\u57df\u3002<\/section>\n<section>Isolated Ni atoms enable near-unity CH<sub>4<\/sub>\u00a0selectivity for photothermal CO<sub>2<\/sub>\u00a0hydrogenation.<strong>\u00a0<\/strong>Journal of the American Chemical Society, 2024.<strong>\u00a0<\/strong>DOI: 10.1021\/jacs.4c05873<\/section>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u5149\u70edCO2\u7532\u70f7\u5316\u662f\u5b9e\u73b0\u51c0\u96f6\u6392\u653e\u76ee\u6807\u7684\u4e00\u4e2a\u91cd\u8981\u7814\u7a76\u9014\u5f84\uff0c\u5728\u5236\u5b9a\u78b3\u4e2d\u548c\u3001\u6c22\u5229\u7528\u3001\u78b3\u5faa\u73af\u548c\u5316\u5b66\u80fd\u50a8\u5b58\u7b56\u7565\u65b9\u9762\u53d1\u6325\u7740\u5173 [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-51854","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51854","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=51854"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51854\/revisions"}],"predecessor-version":[{"id":51855,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51854\/revisions\/51855"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=51854"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=51854"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=51854"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}