{"id":51793,"date":"2024-07-05T09:19:25","date_gmt":"2024-07-05T01:19:25","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=51793"},"modified":"2024-06-26T09:19:49","modified_gmt":"2024-06-26T01:19:49","slug":"angew-chem-%ef%bc%9a%e6%9d%82%e5%8e%9f%e5%ad%90%e5%8f%96%e4%bb%a3%e7%ad%96%e7%95%a5hss%e8%ae%be%e8%ae%a1%e5%90%88%e6%88%90%e5%8c%96%e5%ad%a6%e5%8f%af%e5%9b%9e%e6%94%b6%e8%81%9a%e9%85%af%e5%b9%b6","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/angew-chem-%ef%bc%9a%e6%9d%82%e5%8e%9f%e5%ad%90%e5%8f%96%e4%bb%a3%e7%ad%96%e7%95%a5hss%e8%ae%be%e8%ae%a1%e5%90%88%e6%88%90%e5%8c%96%e5%ad%a6%e5%8f%af%e5%9b%9e%e6%94%b6%e8%81%9a%e9%85%af%e5%b9%b6\/","title":{"rendered":"Angew. Chem. \uff1a\u6742\u539f\u5b50\u53d6\u4ee3\u7b56\u7565(HSS)\u8bbe\u8ba1\u5408\u6210\u5316\u5b66\u53ef\u56de\u6536\u805a\u916f\u5e76\u901a\u8fc7\u6e29\u5ea6\u8f6c\u6362\u8c03\u63a7\u5171\u805a\u7269\u5355\u4f53\u5e8f\u5217"},"content":{"rendered":"<section>\n<section>\n<section>\n<section>\n<section>\u4e3a\u4e86\u63a2\u7d22\u51fa\u66f4\u597d\u7684\u89e3\u51b3\u5851\u6599\u5783\u573e\u7684\u65b9\u6cd5\uff0cEugene Y.-X. Chen\u7b49\u4eba\u57282016\u5e74\u9996\u6b21\u63d0\u51fa\u4e86\u5316\u5b66\u56de\u6536\u5230\u5355\u4f53\u7684\u6982\u5ff5\uff0c\u5373\u901a\u8fc7\u5316\u5b66\u7684\u65b9\u5f0f\u5c06\u805a\u5408\u7269\u89e3\u805a\u56de\u539f\u59cb\u5355\u4f53\uff0c\u56de\u6536\u5f97\u5230\u7684\u5355\u4f53\u5728\u7ecf\u8fc7\u7eaf\u5316\u540e\u53ef\u4ee5\u91cd\u65b0\u805a\u5408\u4e3a\u805a\u5408\u7269\uff0c\u5e76\u4e14\u6b64\u805a\u5408\u7269\u4e0e\u539f\u59cb\u5355\u4f53\u5236\u5907\u5f97\u5230\u7684\u805a\u5408\u7269\u76f8\u6bd4\uff0c\u5728\u6027\u80fd\u4e0a\u6ca1\u6709\u635f\u5931\uff0c\u56e0\u6b64\u8fd9\u4e00\u65b9\u6cd5\u6709\u671b\u5f7b\u5e95\u89e3\u51b3\u767d\u8272\u6c61\u67d3\u7684\u95ee\u9898\u3002<\/p>\n<p>\u7136\u800c\uff0c\u76ee\u524d\u5316\u5b66\u53ef\u56de\u6536\u805a\u916f\u5355\u4f53\u8bbe\u8ba1\u4ec5\u6709\u7a20\u73af\/\u6865\u73af\u548c\u53d6\u4ee3\u57fa\u4e24\u79cd\u7b56\u7565\uff0c\u56e0\u6b64\u5f00\u53d1\u65b0\u7684\u5316\u5b66\u53ef\u56de\u6536\u805a\u916f\u5355\u4f53\u7684\u8bbe\u8ba1\u7b56\u7565\u663e\u5f97\u5c24\u4e3a\u91cd\u8981\u3002\u5728\u6b64\u80cc\u666f\u4e0b\uff0c\u82cf\u5dde\u5927\u5b66\u7684\u5f20\u6b63\u5f6a\u6559\u6388\/\u738b\u946b\u526f\u6559\u6388\u4ee5N\u3001S\u3001O\u4e09\u79cd\u6742\u539f\u5b50\u53d6\u4ee3\u00a0<span class=\"wx_search_keyword_wrap\">\u03b4-\u620a\u5185\u916f<\/span>\uff08\u00a0\u03b4-VL\uff09\u73af\u4e0a\u7684\u4e9a\u7532\u57fa\uff0c\u5f97\u5230\u4e86\u4e09\u79cd\u5177\u6709\u4e0d\u540c\u805a\u5408\u4e0a\u9650\u6e29\u5ea6\uff08Tc\uff09\u7684\u73af\u72b6\u5355\u4f53M<sub>1<\/sub>(N), M<sub>2<\/sub>(S), M<sub>3<\/sub>(O)\uff0c\u5e76\u901a\u8fc7\u6709\u673a\u50ac\u5316\u7684\u65b9\u5f0f\u5b9e\u73b0\u4e86\u4e09\u79cd\u5355\u4f53\u7684\u6d3b\u6027\/\u53ef\u63a7\u5f00\u73af\u805a\u5408\u4ee5\u53ca\u5408\u6210\u805a\u5408\u7269\u7684\u89e3\u805a\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<p>&nbsp;<\/p>\n<section>\n<section><\/section>\n<\/section>\n<p>&nbsp;<\/p>\n<section><img decoding=\"async\" title=\"1\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240612\/1718160967530782.webp\" alt=\"1\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u5728\u7b5b\u9009\u51fa\u6700\u4f18\u7684\u805a\u5408\u6761\u4ef6\u540e\uff0c\u4f5c\u8005\u901a\u8fc7\u5b9e\u9a8c\u4e0eDFT\u8ba1\u7b97\u5bf9\u4e09\u79cd\u6742\u539f\u5b50\u53d6\u4ee3\u5355\u4f53\u7684\u5f00\u73af\u70ed\u529b\u5b66\u8fdb\u884c\u4e86\u63a2\u7a76\u3002\u4e0d\u540c\u6742\u539f\u5b50\u53d6\u4ee3\u4e0e\u53ef\u56de\u6536\u6027\u7684\u7cfb\u7edf\u6027\u7814\u7a76\u8868\u660e\uff0c\u5f15\u5165\u6742\u539f\u5b50\u786e\u5b9e\u6539\u53d8\u4e86\u5355\u4f53\u7684\u70ed\u529b\u5b66\uff0c\u5305\u62ec\u0394H<sub>p<\/sub><sup>o<\/sup>\uff0c\u0394S<sub>p<\/sub><sup>o<\/sup>\u548cTc\uff0c\u4ece\u800c\u8c03\u8282\u5355\u4f53\u7684\u805a\u5408\u6027\u548c\u89e3\u805a\u6027\u3002DFT\u8ba1\u7b97\u53d1\u73b0\uff0c\u6742\u539f\u5b50\u7684\u5f15\u5165\u6539\u53d8\u4e86\u5355\u4f53\u7684\u89d2\u5f20\u529b\u4ece\u800c\u8c03\u8282\u4e86\u5355\u4f53\u7684\u73af\u5f20\u529b\uff0c\u4e14\u4e09\u79cd\u5355\u4f53\u89d2\u5f20\u529b\u7684\u987a\u5e8f\u4e3a\uff1aM<sub>2<\/sub>\u00a0&gt;\u00a0M<sub>1<\/sub>&gt;\u00a0M<sub>3<\/sub>\uff0c\u5176\u4e0e\u5b9e\u9a8c\u5f97\u5230\u7684<span class=\"wx_search_keyword_wrap\">\u7113\u53d8<\/span>\u7684\u987a\u5e8f\u4e5f\u662f\u4e00\u81f4\u3002\u968f\u540e\u4f5c\u8005\u5bf9\u4e09\u79cd\u6742\u539f\u5b50\u53d6\u4ee3\u5355\u4f53\u6240\u5236\u5907\u805a\u5408\u7269\u7684\u5316\u5b66\u56de\u6536\u6027\u80fd\u8fdb\u884c\u4e86\u63a2\u7a76\uff0c\u53d1\u73b0M<sub>1<\/sub>\u5355\u4f53\u5236\u5907\u7684\u805a\u5408\u7269P(M<sub>1<\/sub>)\u5728\u542b\u50ac\u5316\u5242\u7684\u6eb6\u6db2\u4e2d\uff0c\u6216\u9ad8\u6e29\u771f\u7a7a\u6761\u4ef6\u4e0b\u5747\u80fd\u5b8c\u5168\u89e3\u805a\u56de\u539f\u59cb\u5355\u4f53\uff0c\u4e14\u6ca1\u6709\u6742\u8d28\u7684\u751f\u6210\u3002\u6b64\u5916\uff0c\u9ad8\u6e29\u771f\u7a7a\u6761\u4ef6\u4e0b\u89e3\u805a\u5f97\u5230\u7684\u56de\u6536\u5355\u4f53\u65e0\u9700\u8fdb\u4e00\u6b65\u7eaf\u5316\uff0c\u4fbf\u80fd\u7528\u4e8e\u4e0b\u4e00\u6b65\u7684\u805a\u5408\u53cd\u5e94\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"2\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240612\/1718160975809452.webp\" alt=\"2\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u5728\u7cfb\u7edf\u5730\u63a2\u7a76\u4e86\u4e09\u79cd\u6742\u539f\u5b50\u53d6\u4ee3\u5355\u4f53\u7684\u805a\u5408\u884c\u4e3a\u548c\u5bf9\u5e94\u7684\u5747\u805a\u7269\u6027\u80fd\u540e\uff0c\u4f5c\u8005\u4e5f\u91c7\u7528\u4e00\u9505\u4e00\u6b65\u6295\u6599\u6cd5\u5c06\u4e09\u79cd\u5355\u4f53\u4e24\u4e24\u5171\u805a\uff0c\u5bf9\u4e09\u79cd\u5355\u4f53\u4e24\u4e24\u95f4\u7684\u5171\u805a\u884c\u4e3a\u8fdb\u884c\u4e86\u63a2\u7a76\u3002\u7531\u4e8e\u4e09\u79cd\u6742\u539f\u5b50\u53d6\u4ee3\u5355\u4f53\u7684\u6d3b\u5316\u80fd\uff08E<sub>a<\/sub>\uff09\u4e0d\u540c\uff08M<sub>1<\/sub>\u00a0= 30.3 kJ\/mol, M<sub>2<\/sub>\u00a0= 42.5 kJ\/mol, M<sub>3<\/sub>\u00a0= 27.8 kJ\/mol\uff09\uff0c\u5bfc\u81f4\u4e86\u4e0d\u540c\u5355\u4f53\u5728\u5171\u805a\u65f6\u7684\u7ade\u805a\u7387\u968f\u6e29\u5ea6\u7684\u6539\u53d8\u800c\u6539\u53d8\u3002\u6d3b\u5316\u80fd\u6700\u5927\u7684M<sub>2<\/sub>\u5355\u4f53\uff0c\u5728\u4e0e\u6d3b\u5316\u80fd\u8f83\u5c0f\u7684M<sub>1<\/sub>\u6216M<sub>3<\/sub>\u5355\u4f53\u8fdb\u884c\u5171\u805a\u65f6\uff0c\u968f\u7740\u805a\u5408\u6e29\u5ea6\u7684\u964d\u4f4e\uff0cM<sub>2<\/sub>\u5355\u4f53\u5411\u805a\u5408\u7269\u94fe\u4e0a\u7684\u589e\u957f\u9010\u6e10\u88ab\u6291\u5236\uff0c\u4ece\u800c\u5b9e\u73b0\u5171\u805a\u7269\u5355\u4f53\u5e8f\u5217\u7531\u65e0\u89c4\u5411\u5d4c\u6bb5\u7684\u8f6c\u53d8\u3002\u800c\u6d3b\u5316\u80fd\u76f8\u5dee\u8f83\u5c0f\u7684M<sub>1<\/sub>\u548cM<sub>3<\/sub>\u5355\u4f53\u8fdb\u884c\u5171\u805a\u65f6\uff0c\u4e0d\u7ba1\u6e29\u5ea6\u5982\u4f55\u6539\u53d8\uff0c\u4e24\u79cd\u5355\u4f53\u7ade\u805a\u7387\u59cb\u7ec8\u63a5\u8fd1\uff0c\u6240\u5f97\u5230\u7684\u5747\u4e3a\u65e0\u89c4\u5171\u805a\u7269\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"6\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240612\/1718160986237748.webp\" alt=\"6\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u6700\u540e\uff0c\u5411\u73af\u916f\u5355\u4f53\u4e2d\u5f15\u5165\u6742\u539f\u5b50\u4e0d\u4ec5\u5728\u70ed\u529b\u5b66\u4e0a\u8c03\u63a7\u4e86\u5355\u4f53\u7684\u5316\u5b66\u53ef\u56de\u6536\u6027\u80fd\uff0c\u8fd8\u5728\u52a8\u529b\u5b66\u4e0a\u6539\u53d8\u4e86\u5355\u4f53\u7684\u6d3b\u5316\u80fd\uff0c\u4f7f\u6d3b\u5316\u80fd\u76f8\u5dee\u8f83\u5927\u7684\u5355\u4f53\u80fd\u591f\u901a\u8fc7\u7b80\u5355\u7684\u6e29\u5ea6\u8f6c\u6362\u5b9e\u73b0\u5bf9\u5171\u805a\u7269\u5355\u4f53\u5e8f\u5217\u7684\u8c03\u8282\u3002\u8be5\u5de5\u4f5c\u4e3a\u5316\u5b66\u53ef\u56de\u6536\u805a\u916f<span class=\"wx_search_keyword_wrap\">\u5747\u805a\u7269<\/span>\u548c\u5171\u805a\u7269\u7684\u5408\u6210\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u7684\u7b56\u7565\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section><strong>\u8bba<\/strong><strong>\u6587\u4fe1\u606f<\/strong><\/p>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section><\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>Heteroatom Substitution Strategy Modulates Thermodynamics Towards Chemically Recyclable Polyesters and Monomeric Unit Sequence by Temperature Switching<\/p>\n<p>Da Zhang,\u00a0Xin Wang,\u00a0Zhengbiao Zhang,\u00a0Nikos Hadjichristidis<\/p>\n<p><em>Angewandte Chemie International Edition<\/em><\/p>\n<p>DOI:\u00a010.1002\/anie.202402233<\/p>\n<\/section>\n<\/section>\n<\/section>\n","protected":false},"excerpt":{"rendered":"<p>\u4e3a\u4e86\u63a2\u7d22\u51fa\u66f4\u597d\u7684\u89e3\u51b3\u5851\u6599\u5783\u573e\u7684\u65b9\u6cd5\uff0cEugene Y.-X. Chen\u7b49\u4eba\u57282016\u5e74\u9996\u6b21\u63d0\u51fa\u4e86\u5316\u5b66\u56de\u6536\u5230\u5355\u4f53 [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-51793","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51793","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=51793"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51793\/revisions"}],"predecessor-version":[{"id":51794,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51793\/revisions\/51794"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=51793"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=51793"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=51793"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}