{"id":51718,"date":"2024-06-27T08:24:10","date_gmt":"2024-06-27T00:24:10","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=51718"},"modified":"2024-06-18T10:26:55","modified_gmt":"2024-06-18T02:26:55","slug":"angew-chem-%ef%bc%9a%e6%b0%a2%e9%94%ae%e7%bd%91%e7%bb%9c%e8%af%b1%e5%af%bc%e6%89%8b%e6%80%a7%e4%b8%80%e7%bb%b4%e6%9c%89%e6%9c%ba%e6%97%a0%e6%9c%ba%e6%9d%82%e5%8c%96%e9%94%b0%e6%b0%af%e5%8c%96","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/angew-chem-%ef%bc%9a%e6%b0%a2%e9%94%ae%e7%bd%91%e7%bb%9c%e8%af%b1%e5%af%bc%e6%89%8b%e6%80%a7%e4%b8%80%e7%bb%b4%e6%9c%89%e6%9c%ba%e6%97%a0%e6%9c%ba%e6%9d%82%e5%8c%96%e9%94%b0%e6%b0%af%e5%8c%96\/","title":{"rendered":"Angew. Chem. \uff1a\u6c22\u952e\u7f51\u7edc\u8bf1\u5bfc\u624b\u6027\u4e00\u7ef4\u6709\u673a\u65e0\u673a\u6742\u5316\u9530\u6c2f\u5316\u7269\u4ea7\u751f\u9ad8\u6548\u5706\u504f\u632f\u53d1\u5149"},"content":{"rendered":"
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\u5706\u504f\u632f\u53d1\u5149(Circularly polarized luminescence, CPL)\u6750\u6599\u5728\u4e09\u7ef4\u5149\u5b66\u663e\u793a\u3001\u5149\u5b50\u5b66\u52a0\u5bc6\u4f20\u8f93\u548c\u4fe1\u606f\u5b58\u50a8\u3001X\u5c04\u7ebf\u6210\u50cf\u548c\u5149\u5b66\u4f20\u611f\u5668\u7b49\u591a\u4e2a\u5149\u7535\u9886\u57df\u90fd\u5177\u6709\u5e7f\u6cdb\u7684\u5e94\u7528\u3002\u5728\u4f17\u591a\u6750\u6599\u91cc\u5177\u6709\u4f18\u5f02\u53d1\u5149\u6027\u8d28\u4ee5\u53ca\u72ec\u7279\u624b\u6027\u7ed3\u6784\u7684\u6709\u673a-\u65e0\u673a\u6742\u5316\u91d1\u5c5e\u5364\u5316\u7269\u6709\u671b\u6210\u4e3a\u4e00\u7c7b\u65b0\u578b\u7684CPL\u529f\u80fd\u6750\u6599\u76ee\u524d\uff0c\u8fd9\u4e00\u70ed\u95e8\u7814\u7a76\u9886\u57df\u7684\u9996\u8981\u6311\u6218\u662f\u540c\u65f6\u5b9e\u73b0\u9ad8\u5149\u81f4\u53d1\u5149\u91cf\u5b50\u4ea7\u7387\uff08PLQY\uff09\u3001\u9ad8\u6297\u70ed\u6dec\u706d\u548c\u5927\u7684\u53d1\u5149\u4e0d\u5bf9\u79f0\u56e0\u5b50(glum<\/sub>)\u7ed3\u6784\u786e\u5b9a\u7684CPL\u6750\u6599\u5408\u6210\u3002\u56e0\u6b64\uff0c\u5982\u4f55\u5236\u5907\u5177\u6709\u4f18\u5f02CPL\u6027\u80fd\u7684\u6742\u5316\u9530\u57fa\u5364\u5316\u7269\u5355\u6676\uff0c\u5e76\u63ed\u793a\u5149\u5b66\u6d3b\u6027\u7684\u6765\u6e90\uff0c\u4ecd\u7136\u662f\u4e00\u4e2a\u4e9f\u5f85\u89e3\u51b3\u7684\u96be\u9898\u3002<\/p>\n

\u8fd1\u65e5\uff0c\u5e7f\u897f\u5927\u5b66\u5e9e\u8d77\u6559\u6388\u548c\u6c55\u5934\u5927\u5b66\u7f57\u5f6c\u5f6c\u526f\u6559\u6388\u5408\u4f5c\uff0c\u4f7f\u7528\u624b\u6027\u6709\u673a\u80fa\u5206\u5b50\u8bf1\u5bfc\u5408\u6210\u7b56\u7565\uff0c\u901a\u8fc7\u7b80\u5355\u7684\u53cd\u6eb6\u5242<\/span>\u7ed3\u6676\u6cd5\uff0c\u83b7\u5f97\u4e86\u4e24\u5bf9\u624b\u6027\u6742\u5316\u9530\u57fa\u5364\u5316\u7269\u5355\u6676\uff0cR\/S-(3-methyl piperidine)MnCl3<\/sub>\u00a0(R\/S-1)\u548cR\/S-(3-hydroxy piperidine)MnCl3<\/sub>\u00a0(R\/S-2)\uff0c\u5b83\u4eec\u7ed3\u6676\u4e8e\u975e\u4e2d\u5fc3\u5bf9\u79f0\u7a7a\u95f4\u7fa4P21<\/sub>21<\/sub>21<\/sub>\u3002\u8fd9\u4e9b\u5355\u6676\u663e\u793a\u51fa\u5f3a\u70c8\u7684\u7ea2\u8272\u53d1\u5c04\uff0c\u4f18\u5f02\u7684\u70ed\u7a33\u5b9a\u6027\uff0c\u800c\u4e14\u8fd8\u663e\u793a\u51fa\u5706\u504f\u632f\u53d1\u5149\u3002\u4e0eR\/S-1\u76f8\u6bd4\uff0cR\/S-2\u5355\u6676\u5177\u6709100%\u5149\u81f4\u53d1\u5149\u91cf\u5b50\u4ea7\u7387\uff08PLQY\uff09\u548c\u9ad8\u6297\u70ed\u6dec\u706d\u80fd\u529b\uff0c\u4e0d\u5bf9\u79f0\u56e0\u5b50 (glum<\/sub>) \u4e3a2.5\u00d710\u22123<\/sup>\uff0c\u8fd9\u5f52\u56e0\u4e8eR\/S-(3-\u7f9f\u57fa\u54cc\u5576)\u9633\u79bb\u5b50\u4e0e[MnCl6<\/sub>]4-<\/sup>\u94fe\u4e4b\u95f4\u7684\u6c22\u952e\u7f51\u7edc\u589e\u5f3a\u4e86\u6676\u4f53\u521a\u6027\u3002\u5706\u504f\u632f\u53d1\u5149\u6d3b\u6027\u6e90\u81ea\u4e8e\u4e0eR\/S-(3-\u7f9f\u57fa\u54cc\u5576) \u53d1\u751f\u7684\u4e0d\u5bf9\u79f0\u7684 [MnCl6<\/sub>]4-<\/sup>\u00a0\u53d1\u5149\u56e2\u7684N-H\u00b7\u00b7\u00b7Cl \u6c22\u952e\u4f5c\u7528\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n

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\"1\"<\/section>\n
\u56fe1\u3001\u4e00\u7ef4\u6742\u5316\u9530\u6676\u4f53\u7ed3\u6784\u56fe\u3002(a, c) R\/S-1\u548cR\/S-2\u7684\u5806\u79ef\u6846\u67b6\uff0c\u63d2\u56fe\u4e3a\u624b\u6027\u9633\u79bb\u5b50\u7684\u5206\u5b50\u7ed3\u6784\u5f0f\u3002(b, d) R-1\u548cR-2\u4e2d\u6c22\u952e\u7684\u793a\u610f\u56fe\u3002<\/p>\n<\/section>\n
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\u901a\u8fc7\u6676\u4f53\u7ed3\u6784\u5206\u6790\u8868\u660e\uff0c\u8fd9\u4e9b\u5bf9\u6620\u4f53\u5206\u522b\u5448\u73b0\u51fa\u4e0d\u53ef\u53e0\u52a0\u7684\u955c\u50cf\u51e0\u4f55\u6784\u578b\u3002\u6240\u6709\u5355\u6676\u90fd\u663e\u793a\u51fa\u4e00\u7ef4\u5171\u9762[MnCl6<\/sub>]4-<\/sup>\u516b\u9762\u4f53\u3002\u4e0eR\/S-1\u76f8\u6bd4\uff0cR\/S-2\u5355\u6676\u9664\u4e86N-H\u00b7\u00b7\u00b7Cl \u6c22\u952e\u5916\uff0c\u76f8\u90bb\u624b\u6027\u6709\u673a\u9633\u79bb\u5b50\u4e4b\u95f4\u8fd8\u5f62\u6210\u4e86\u4e24\u79cd\u65b0\u7684\u6c22\u952e\uff0c\u5176\u957f\u5ea6\u5206\u522b\u4e3a2.84 \u00c5\u548c2.24 \u00c5\u7684O-H\u00b7\u00b7\u00b7O\u548cN-H\u00b7\u00b7\u00b7O\u6c22\u952e\uff0c\u8fd9\u5c06\u5bf9\u5176\u6027\u8d28\u4ea7\u751f\u5f71\u54cd\u3002\u5149\u8c31\u5206\u6790\u8868\u660e\uff0c\u5728 373 nm\u7684\u6fc0\u53d1\u4e0b\uff0c\u8fd9\u4e9b\u6676\u4f53\u5448\u73b0\u51fa\u660e\u4eae\u7684\u7ea2\u8272\u53d1\u5c04\uff0cR\/S-1\u548cR\/S-2\u7684PLQY\u5206\u522b\u7ea6\u4e3a60%\u548c100%\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0cR\/S-2\u6676\u4f53\u5177\u6709\u63a5\u8fd1100%\u7684PLQY\u503c\uff0c\u662f\u76ee\u524d\u62a5\u9053\u7684\u4e00\u7ef4\u6742\u5316\u9530\u57fa\u5364\u5316\u7269\u7684\u6700\u9ad8\u503c\u3002\u5706\u4e8c\u8272\u8c31\uff08CD\uff09\u4fe1\u53f7\u8868\u660e\u624b\u6027\u6210\u529f\u5730\u4ece\u6709\u673a\u9633\u79bb\u5b50\u8f6c\u79fb\u5230[MnCl6<\/sub>]4-<\/sup>\u65e0\u673a\u94fe\u4e0a\u3002\u5706\u504f\u632f\u5149\u7684\u5404\u5411\u5f02\u6027\u56e0\u5b50\u7528\u4e0d\u5bf9\u79f0\u56e0\u5b50(glum<\/sub>)\u6765\u91cf\u5316\uff0cR\/S-2\u6676\u4f53\u7684\u6700\u5927glum<\/sub>\u503c\u4e3a2.5\u00d710-3<\/sup>\uff0c\u8868\u660e\u8fd9\u4e9b\u624b\u6027\u6742\u5316\u9530\u6c2f\u5316\u7269\u4e3a\u5706\u504f\u632f\u53d1\u5149\u6d3b\u6027\u6750\u6599\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n
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\"2\"<\/section>\n
\u56fe2\u3001 R\/S-1\u548c R\/S-2\u5355\u6676\u7684\u5149\u5b66\u6027\u8d28\u3002(a) R-1\u548cR-2\u5355\u6676\u7684\u6fc0\u53d1\u5149\u8c31\u548c\u53d1\u5c04\u5149\u8c31\u3002(b) R\/S-2 \u7684\u5706\u4e8c\u8272\u8c31\u548c\u5438\u6536\u5149\u8c31\u3002\uff08c-d\uff09R\/S-1\u548cR\/S-2\u5355\u6676\u5728\u5ba4\u6e29\u4e0b\u7684CPL\u5149\u8c31\u3002<\/p>\n<\/section>\n
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\u56e2\u961f\u8fdb\u4e00\u6b65\u4f7f\u7528\u4e0e\u6e29\u5ea6\u76f8\u5173\u7684\u7a33\u6001\u548c\u77ac\u6001\u5149\u8c31\u7814\u7a76\u4e86\u5b83\u4eec\u7684\u5149\u7269\u7406\u6027\u8d28\u3002\u7ed3\u679c\u663e\u793a\uff0c\u572880 K-300 K\u6e29\u5ea6\u8303\u56f4\u5185\uff0c R\/S-2\u5355\u6676\u7684\u53d1\u5c04\u5cf0\u548c\u8367\u5149\u5bff\u547d\u51e0\u4e4e\u4fdd\u6301\u4e0d\u53d8\uff0c\u800cR\/S-1\u5219\u663e\u793a\u51fa\u660e\u663e\u7684\u53d1\u5c04\u5f3a\u5ea6\u548c\u8367\u5149\u5bff\u547d\u53d8\u5316\u3002\u8fd9\u79cd\u5dee\u5f02\u5f52\u56e0\u4e8eR\/S-2\u4e2d\u6c22\u952e\u7f51\u7edc\u5f62\u6210\u7684\u8f83\u5f3a\u7684\u521a\u6027\u73af\u5883\u3002\u6b64\u5916\uff0c\u8fd9\u4e9b\u6750\u6599\u8fd8\u8868\u73b0\u51fa\u826f\u597d\u7684\u70ed\u7a33\u5b9a\u6027\uff0c\u5728420 K\u65f6\u80fd\u591f\u4fdd\u6301\u521d\u59cb\u5f3a\u5ea6\u768483.2%\u00a0(R-1<\/span>)\u548c85.9%\u00a0(R-2)\u3002\u8fdb\u4e00\u6b65\u7684\u7535\u5b50\u987a\u78c1\u5171\u632f\u5149\u8c31\uff08EPR\uff09\u548c\u78c1\u6ede\u56de\u7ebf\u5206\u6790\u8bc1\u5b9e\u4e86\u7ea2\u8272\u53d1\u5149\u6765\u6e90\u4e8eMn2+<\/sup>\u7684d-d\u8dc3\u8fc1\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n
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\"3\"<\/section>\n
\u56fe3\u3001\u00a0(a) R-1\uff08\u4e0a\uff09\u548c R-2\uff08\u4e0b\uff09\u5355\u6676\u968f\u6e29\u5ea6\u53d8\u5316\uff0880-300 K\uff09\u7684\u8367\u5149\u5149\u8c31\u7b49\u7ebf\u56fe\u3002(b) R-1\u548cR-2\u5355\u6676\u7684\u6fc0\u5b50\u7ed3\u5408\u80fd (Eb) \u503c\u3002(c) R-2 \u7684\u968f\u6e29\u5ea6\u53d8\u5316\u7684\u8367\u5149\u5bff\u547d\u8870\u51cf\u66f2\u7ebf\u56fe\u548c\u5355\u6307\u6570\u62df\u5408\u7ed3\u679c\uff08d\uff09\u3002\uff08e\uff0977 K \u65f6R-1\uff08\u4e0a\uff09\u548cR-2\uff08\u4e0b\uff09\u5355\u6676\u4f53\u7684 EPR \u5149\u8c31\u3002(f) 273 K \u65f6R-1 \u548cR-2\u7684\u78c1\u6ede\u56de\u7ebf\u3002<\/p>\n<\/section>\n
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\u7814\u7a76\u56e2\u961f\u6df1\u5165\u63a2\u8ba8\u4e86R\/S-2\u5355\u6676\u5177\u6709\u63a5\u8fd1100% PLQY\u7684\u539f\u56e0\u3002\u4e0eR\/S-1\u76f8\u6bd4\uff0cR\/S-2\u5355\u6676\u4e2d\u76f8\u90bb\u7684 R\/S-(3-hydroxy piperidine)\u9633\u79bb\u5b50\u95f4\u8ddd\u8f83\u77ed\uff0c\u6709\u5229\u4e8e\u6c22\u952e\u7f51\u7edc\u7684\u5f62\u6210\u3002\u76f8\u90bb\u6709\u673a\u79bb\u5b50\u4e4b\u95f4\u6700\u77ed\u7684 O-O \u95f4\u8ddd\u4e3a 3.65 \u00c5\uff0cN-O \u95f4\u8ddd\u4e3a 3.02 \u00c5\uff0c\u4fbf\u4e8e\u5f62\u6210\u6c22\u952e\u7f51\u7edc\u3002\u6c22\u952e\u7f51\u7edc\u4f7f\u5f97R\/S-2\u5177\u6709\u8f83\u5f3a\u521a\u6027\u73af\u5883\uff0c\u5e76\u4e14\u5927\u5927\u6291\u5236\u4e86\u975e\u8f90\u5c04\u8870\u51cf\uff0c\u4ece\u800c\u5c55\u73b0\u51fa\u63a5\u8fd1100%\u7684PLQY\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0cR\/S-1\u4e2d\u7684R\/S-(3-methyl piperidine) \u9633\u79bb\u5b50\u4e4b\u95f4\u7684\u5f31\u76f8\u4e92\u4f5c\u7528\u5bfc\u81f4\u6fc0\u5b50\u901a\u8fc7\u975e\u8f90\u5c04\u9014\u5f84\u8017\u6563\uff0c\u56e0\u6b64\u8868\u73b0\u51fa\u8f83\u4f4e\u7684PLQY\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n
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\"0\"<\/section>\n
\u56fe4\u3001R-2\u5355\u6676\u4e2d\u7684\u6c22\u952e\u76f8\u4e92\u4f5c\u7528\u53ca\u5f62\u6210\u7684\u521a\u6027\u6676\u4f53\u7ed3\u6784\u793a\u610f\u56fe\u3002<\/p>\n<\/section>\n
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\u6b64\u5916\uff0c\u57fa\u4e8eR\/S-2\u6676\u4f53\u4f18\u5f02\u7684\u6027\u8d28\uff0c\u7814\u7a76\u56e2\u961f\u8fd8\u5c55\u73b0\u4e86\u8be5\u6750\u6599\u5728\u5706\u504f\u632f\u53d1\u5149LED\u548cX-\u5c04\u7ebf\u6210\u50cf\u65b9\u9762\u7684\u5e94\u7528\u6f5c\u529b\u3002\u8fd9\u9879\u5de5\u4f5c\u4e3a\u57fa\u4e8e Mn (II) \u7684\u591a\u529f\u80fd\u624b\u6027\u6742\u5316\u5364\u5316\u7269\u6750\u6599\u7684\u7ed3\u6784\u8bbe\u8ba1\u3001\u6676\u4f53\u751f\u957f\u548c\u5149\u7535\u5e94\u7528\u63d0\u4f9b\u4e86\u91cd\u8981\u7684\u6307\u5bfc\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n
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\"00\"\u200b<\/section>\n
\u56fe5\u3001R-2\u6676\u4f53\u5728X\u5c04\u7ebf\u95ea\u70c1\u4f53\u4e2d\u7684\u6027\u80fd\u3002\uff08a\uff09R-2\u6676\u4f53\u7684X\u5c04\u7ebf\u8f90\u5c04\u53d1\u5149\uff08RL\uff09\u5149\u8c31\u3002\uff08b\uff09\u57280.21-0.93 mGy\u00b7s\u20131\u8303\u56f4\u5185\uff0c\u4e0d\u540cX\u5c04\u7ebf\u5242\u91cf\u4e0bR-2\u6837\u54c1\u7684RL\u5149\u8c31\u3002\uff08\u63d2\u56fe\uff09\u663e\u793a\u4e86R-2\u7684\u4fe1\u566a\u6bd4\u968f\u5242\u91cf\u7387\u53d8\u5316\u7684\u60c5\u51b5\u3002\uff08c\uff09\u81ea\u5236X\u5c04\u7ebf\u6210\u50cf\u7cfb\u7edf\u793a\u610f\u56fe\u3002\uff08d\uff09R-2\u95ea\u70c1\u5c4f\u548cX\u5c04\u7ebf\u56fe\u50cf\u7684\u7167\u7247\u3002<\/p>\n<\/section>\n
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\u8bba<\/strong>\u6587\u4fe1\u606f<\/strong><\/p>\n<\/section>\n<\/section>\n
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Circularly Polarized Luminescence Induced by Hydrogen-Bonding Networks in a One-Dimensional Hybrid Manganese(II) Chloride<\/p>\n

Jing Li, Qiulian Luo, Jianwu Wei, Liya Zhou, Peican Chen, Binbin Luo, Yibo Chen, Qi Pang, Jin Zhong Zhang<\/p>\n

\u8bba\u6587\u7684\u7b2c\u4e00\u4f5c\u8005\u662f\u5e7f\u897f\u5927\u5b66\u5316\u5b66\u5316\u5de5\u5b66\u9662\u535a\u58eb\u751f\u674e\u9756\uff0c\u901a\u8baf\u4f5c\u8005\u662f\u5e7f\u897f\u5927\u5b66\u5316\u5b66\u5316\u5de5\u5b66\u9662\u5e9e\u8d77\u6559\u6388\u548c\u6c55\u5934\u5927\u5b66\u7f57\u5f6c\u5f6c\u526f\u6559\u6388\u3002<\/p>\n

Angewandte Chemie International Edition<\/em><\/p>\n

DOI:\u00a010.1002\/anie.202405310<\/p>\n<\/section>\n<\/section>\n<\/section>\n","protected":false},"excerpt":{"rendered":"

\u5706\u504f\u632f\u53d1\u5149(Circularly polarized luminescence, CPL)\u6750\u6599\u5728\u4e09\u7ef4\u5149\u5b66\u663e\u793a\u3001 […]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-51718","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51718","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=51718"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51718\/revisions"}],"predecessor-version":[{"id":51719,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51718\/revisions\/51719"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=51718"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=51718"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=51718"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}