{"id":51670,"date":"2024-06-19T08:10:38","date_gmt":"2024-06-19T00:10:38","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=51670"},"modified":"2024-06-10T10:12:22","modified_gmt":"2024-06-10T02:12:22","slug":"angew-chem-%ef%bc%9a%e5%9f%ba%e4%ba%8e%e7%a9%ba%e9%97%b4%e7%94%b5%e8%8d%b7%e8%bd%ac%e7%a7%bb%e4%bf%83%e8%bf%9b%e7%b3%bb%e9%97%b4%e7%aa%9c%e8%b6%8a%e7%9a%84%e6%96%b0%e5%9e%8b%e5%85%89%e5%82%ac","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/angew-chem-%ef%bc%9a%e5%9f%ba%e4%ba%8e%e7%a9%ba%e9%97%b4%e7%94%b5%e8%8d%b7%e8%bd%ac%e7%a7%bb%e4%bf%83%e8%bf%9b%e7%b3%bb%e9%97%b4%e7%aa%9c%e8%b6%8a%e7%9a%84%e6%96%b0%e5%9e%8b%e5%85%89%e5%82%ac\/","title":{"rendered":"Angew. Chem. \uff1a\u57fa\u4e8e\u7a7a\u95f4\u7535\u8377\u8f6c\u79fb\u4fc3\u8fdb\u7cfb\u95f4\u7a9c\u8d8a\u7684\u65b0\u578b\u5149\u50ac\u5316\u5242\u9a71\u52a8\u9ad8\u6548\u3001\u5feb\u901f\u5149\u805a\u5408"},"content":{"rendered":"<section>\n<section>\n<section>\n<section>\n<section>\u6709\u673a\u5149\u6c27\u5316\u8fd8\u539f\u50ac\u5316\u805a\u5408\u57283D\/4D\u6253\u5370\u3001\u5149\u523b\u7b49\u9886\u57df\u5177\u6709\u91cd\u8981\u5e94\u7528\u4ef7\u503c\uff0c\u53d7\u5230\u4e86\u5b66\u672f\u754c\u4e0e\u5de5\u4e1a\u754c\u7684\u5e7f\u6cdb\u5173\u6ce8\u3002\u4f46\u76ee\u524d\u5927\u591a\u6570\u5149\u805a\u5408\u4f53\u7cfb\u9700\u6dfb\u52a0\u989d\u5916\u7684\u7535\u5b50\u4f9b\u4f53\u5e76\u4e14\u5b58\u5728\u805a\u5408\u65f6\u95f4\u957f\u3001\u6fc0\u53d1\u5149\u529f\u7387\u9ad8\u7b49\u96be\u9898\uff0c\u56e0\u6b64\uff0c\u5728\u5149\u805a\u5408\u9886\u57df\u9ad8\u6548\u5149\u50ac\u5316\u5242\u7684\u7cbe\u51c6\u8bbe\u8ba1\u4f9d\u7136\u5b58\u5728\u8f83\u5927\u6311\u6218\u3002<\/p>\n<p>\u8fd1\u671f\uff0c\u5e7f\u4e1c\u5de5\u4e1a\u5927\u5b66\u7c4d\u5c11\u654f\u6559\u6388\u4e0e\u5927\u8fde\u7406\u5de5\u5927\u5b66\u8d75\u5efa\u7ae0\u6559\u6388\u5408\u4f5c\uff0c\u63d0\u51fa\u4e00\u79cd\u901a\u8fc7\u7a7a\u95f4\u7535\u8377\u8f6c\u79fb\u673a\u5236\u6784\u5efa\u5149\u50ac\u5316\u5242\u7b56\u7565\uff0c\u8be5\u50ac\u5316\u5242\u5177\u6709\u8f83\u5f3a\u7ed9\u7535\u5b50\u80fd\u529b\u4ee5\u53ca\u8f83\u957f\u7684\u6fc0\u53d1\u6001\u5bff\u547d\uff0c\u5b9e\u73b0\u4e86\u4e19\u70ef\u9178\u916f\u7c7b\u9ad8\u6548\u3001\u5feb\u901f\u5149\u805a\u5408\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"1\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240610\/1717985494269989.webp\" alt=\"1\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u672c\u7814\u7a76\u4ee5\u5494\u5511\u4e3a\u7535\u5b50\u7ed9\u4f53\uff0c\u8418\u9170\u4e9a\u80fa\u4e3a\u7535\u5b50\u53d7\u4f53\uff0c\u82ef\u73af\u4e3a\u6865\u8fde\u57fa\u56e2\uff0c\u901a\u8fc7Suzuki\u5076\u8054\u53cd\u5e94\u5236\u5f97\u7535\u5b50\u7ed9\u4f53\u4e0e\u53d7\u4f53\u57fa\u56e2\u4e4b\u95f4\u5448\u9762\u5bf9\u9762\u6784\u578b\u7684NI-1\u3001NI-2\u5206\u5b50\uff0c\u5e76\u901a\u8fc7\u7406\u8bba\u8ba1\u7b97\u8bc1\u5b9e\u4e86\u7535\u5b50\u7ed9\u4f53\u4e0e\u53d7\u4f53\u4e4b\u95f4\u53ef\u901a\u8fc7\u7a7a\u95f4\u8f6c\u79fb\u7535\u5b50\u6709\u6548\u4fc3\u8fdb\u4e86\u5355\u91cd\u6fc0\u53d1\u6001\u4e0e\u4e09\u91cd\u6fc0\u53d1\u6001\u4e4b\u95f4\u7cfb\u95f4\u7a9c\u8dc3\uff0c\u4e0e\u5bf9\u6bd4\u5206\u5b50NI-3\u3001NI-4\u76f8\u6bd4\uff0c\u83b7\u5f97\u4e86\u66f4\u6709\u6548\u7684\u4e09\u91cd\u6001\u6548\u7387\uff08\u03a6<sub>\u0394<\/sub>\u00a0= 54.3%\uff09\u4ee5\u53ca\u66f4\u957f\u7684\u4e09\u91cd\u6fc0\u53d1\u6001\u5bff\u547d\uff08t<sub>T<\/sub>\u00a0= 62\u03bcs\uff09\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"2\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240610\/1717985504786010.webp\" alt=\"2\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u8bba\u6587\u901a\u8fc7\u8d85\u5feb\u5149\u8c31\uff0c\u5bf9\u6240\u5408\u6210\u5149\u654f\u5242\u7684\u5149\u7269\u7406\u8fc7\u7a0b\u4e0e\u6fc0\u53d1\u6001\u6027\u8d28\u8fdb\u884c\u4e86\u8be6\u7ec6\u7814\u7a76\uff0c\u5176\u4e2d\uff0c\u98de\u79d2\u77ac\u6001\u5438\u6536\u5149\u8c31\u8868\u660eNI-1\u4e0eNI-2\u7684\u7a7a\u95f4\u7535\u8377\u8f6c\u79fb\u8fc7\u7a0b\u5c0f\u4e8e1 ps\uff0c\u5176\u7cfb\u95f4\u7a9c\u8d8a\u673a\u5236\u53ef\u5f52\u5c5e\u4e8e\u81ea\u65cb\u8f68\u9053\u7535\u5b50\u8f6c\u79fb\u4fc3\u8fdb\u7cfb\u95f4\u7a9c\u8d8a\u3002\u7eb3\u79d2\u77ac\u6001\u5438\u6536\u5149\u8c31\u6d4b\u8bd5\u4e86NI-1\u4e0eNI-2\u7684\u4e09\u91cd\u6fc0\u53d1\u6fc0\u53d1\u6001\u5bff\u547d\u5206\u522b\u4e3a62 ms\u4e0e35 ms\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"8\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240610\/1717985514989274.webp\" alt=\"8\" \/>\u200b<\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u8bba\u6587\u8fdb\u4e00\u6b65\u5bf9NI-1\u5206\u5b50\u7684\u7535\u5316\u5b66\u6027\u80fd\u8fdb\u884c\u4e86\u6d4b\u8bd5\uff0c\u7814\u7a76\u8868\u660eNI-1\u5206\u5b50\u5177\u6709\u8f83\u5f3a\u7684\u6fc0\u53d1\u6001\u8fd8\u539f\u80fd\u529b\uff08\u5355\u91cd\u6001: E<sub>1\/2<\/sub>\u00a0(PC<sup>+1<\/sup>\/*PC) = -1.93 eV, \u4e09\u91cd\u6001: E<sub>1\/2<\/sub>\u00a0(PC<sup>+1<\/sup>\/*PC) = -0.84 eV\uff09\uff0c\u7ed3\u5408\u5176\u8f83\u9ad8\u7684\u4e09\u91cd\u6fc0\u53d1\u6001\u6548\u7387\u3001\u8f83\u957f\u7684\u6fc0\u53d1\u6001\u5bff\u547d\u7b49\u4f18\u70b9\uff0c\u5c06\u8be5\u5206\u5b50\u4f5c\u4e3a\u5149\u50ac\u5316\u5242\u7528\u4e8e\u4e19\u70ef\u9178\u6811\u8102\u5149\u805a\u5408\u3002\u8be5\u5149\u805a\u5408\u4f53\u7cfb\u65e0\u9700\u6dfb\u52a0\u7535\u5b50\u7ed9\u4f53\u5728\u4f4e\u6fc0\u53d1\u5149\u529f\u7387\uff0810 mW cm<sup>-2<\/sup>\uff09\u3001\u4f4e\u50ac\u5316\u5242\u8d1f\u8f7d\u91cf\uff080.05 mol%\uff09\u7684\u6761\u4ef6\u4e0b\uff0c60 s\u5185\u53ef\u5b9e\u73b0\u9ad8\u8fbe90%\u7684\u805a\u5408\u6548\u7387\uff0c\u7814\u7a76\u53d1\u73b0\u8be5\u4f53\u7cfb\u5149\u805a\u5408\u6548\u7387\u4e0e\u50ac\u5316\u5242\u7684<span class=\"wx_search_keyword_wrap\">\u4e09\u91cd\u6001<\/span>\u6548\u7387\u5448\u6b63\u76f8\u5173\u3002\u4e3a\u4fc3\u8fdb\u5176\u5e94\u7528\uff0c\u8fdb\u4e00\u6b65\u5c06\u8be5\u805a\u5408\u4f53\u7cfb\u7528\u4e8e\u5149\u523b\u7814\u7a76\uff0c\u57288 mW cm<sup>-2<\/sup>\u7684\u7d2b\u5916\u5149\u6761\u4ef6\u4e0b\u66dd\u5149100 s\u540e\uff0c\u83b7\u5f97\u7684\u56fe\u6848\u5206\u8fa8\u7387\u53ef\u8fbe10 mm\u3002\u8be5\u5de5\u4f5c\u4e3a\u65b0\u578b\u9ad8\u6548\u5149\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u4ee5\u53ca\u5149\u805a\u5408\u4f53\u7cfb\u7684\u6784\u5efa\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u601d\u8def\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section><strong>\u8bba<\/strong><strong>\u6587\u4fe1\u606f<\/strong><\/p>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section><\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>Novel Photocatalyst Based on Through-Space Charge Transfer Induced Intersystem Crossing Enables Rapid and Efficient Polymerization Under Low-Power Excitation Light<\/p>\n<p>Hui Liang, Xue Zhang, Manlin Lu,\u00a0<span class=\"wx_search_keyword_wrap\">Xi Chen<\/span>, Weiqiang Li, Shangru Li, Ming-De Li,\u00a0 Jianzhang Zhao,* Yanping Huo, Shaomin Ji*<\/p>\n<p>\u6587\u7ae0\u7684\u7b2c\u4e00\u4f5c\u8005\u4e3a\u5e7f\u4e1c\u5de5\u4e1a\u5927\u5b66\u7684\u535a\u58eb\u540e\u6881\u8f89\u3002<\/p>\n<p><em>Angewandte Chemie International Edition<\/em><\/p>\n<p>DOI:\u00a010.1002\/anie.202402774<\/p>\n<\/section>\n<\/section>\n<\/section>\n","protected":false},"excerpt":{"rendered":"<p>\u6709\u673a\u5149\u6c27\u5316\u8fd8\u539f\u50ac\u5316\u805a\u5408\u57283D\/4D\u6253\u5370\u3001\u5149\u523b\u7b49\u9886\u57df\u5177\u6709\u91cd\u8981\u5e94\u7528\u4ef7\u503c\uff0c\u53d7\u5230\u4e86\u5b66\u672f\u754c\u4e0e\u5de5\u4e1a\u754c\u7684\u5e7f\u6cdb\u5173\u6ce8\u3002\u4f46\u76ee\u524d\u5927\u591a [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-51670","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51670","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=51670"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51670\/revisions"}],"predecessor-version":[{"id":51671,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51670\/revisions\/51671"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=51670"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=51670"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=51670"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}