{"id":51614,"date":"2024-06-11T08:18:20","date_gmt":"2024-06-11T00:18:20","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=51614"},"modified":"2024-06-02T20:18:57","modified_gmt":"2024-06-02T12:18:57","slug":"angew-chem-%ef%bc%9acu2mg%e9%87%91%e5%b1%9e%e9%97%b4%e5%8c%96%e5%90%88%e7%89%a9%e9%ab%98%e6%95%88%e7%94%b5%e5%82%ac%e5%8c%96co2%e8%bf%98%e5%8e%9f%e4%b8%ba%e4%b9%99%e9%86%87","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/angew-chem-%ef%bc%9acu2mg%e9%87%91%e5%b1%9e%e9%97%b4%e5%8c%96%e5%90%88%e7%89%a9%e9%ab%98%e6%95%88%e7%94%b5%e5%82%ac%e5%8c%96co2%e8%bf%98%e5%8e%9f%e4%b8%ba%e4%b9%99%e9%86%87\/","title":{"rendered":"Angew. Chem. \uff1aCu2Mg\u91d1\u5c5e\u95f4\u5316\u5408\u7269\u9ad8\u6548\u7535\u50ac\u5316CO2\u8fd8\u539f\u4e3a\u4e59\u9187"},"content":{"rendered":"<section>\n<section>\n<section>\n<section>\n<section>\u7535\u50ac\u5316CO<sub>2<\/sub>\u8fd8\u539f\u6280\u672f\uff0c\u662f\u80fd\u5229\u7528\u6e29\u5ba4\u6c14\u4f53CO<sub>2<\/sub>\u4f5c\u4e3a\u53cd\u5e94\u539f\u6599\u5e76\u5236\u53d6\u9ad8\u9644\u52a0\u503c\u7684\u5316\u5de5\u539f\u6599\u6216\u71c3\u6599\u7684\u6709\u6548\u8def\u9014\u4e4b\u4e00\u3002\u7531\u4e8eCO<sub>2<\/sub>\u8fd8\u539f\u7684\u53cd\u5e94\u8def\u5f84\u590d\u6742\uff0c\u5f53\u524d\u5df2\u62a5\u9053\u7684\u94dc\u57fa\u50ac\u5316\u5242\u5bf9\u4e59\u9187\u4ea7\u7269\u7684\u5206\u7535\u6d41\u5bc6\u5ea6\u4e00\u822c\u4f4e\u4e8e400 mA\u00b7cm<sup>-2<\/sup>\u3002<\/p>\n<p>\u6784\u7b51\u53cc\u91d1\u5c5e\u94dc\u57fa\u6750\u6599\u80fd\u6709\u8f83\u5927\u8303\u56f4\u8c03\u53d8\u50ac\u5316\u5242\u7684\u7535\u5b50\u7ed3\u6784\uff0c\u4ece\u800c\u6539\u53d8\u5bf9\u76ee\u6807\u4ea7\u7269\u7684\u5173\u952e\u4e2d\u95f4\u4f53\u7684\u5438\u9644\u5f3a\u5ea6\uff0c\u662f\u4e00\u79cd\u5e7f\u6cdb\u62a5\u9053\u5e76\u884c\u4e4b\u6709\u6548\u7684\u7b56\u7565\u3002\u7136\u800c\uff0c\u5f53\u524d\u62a5\u9053\u7684\u7b2c\u4e8c\u7ec4\u5206\uff08\u53e6\u5916\u4e00\u79cd\u4e3a\u94dc\uff09\u91d1\u5c5e\u591a\u4e3a\u5bf9CO<sub>2<\/sub>\u8fd8\u539f\u53cd\u5e94\u5177\u6709\u6d3b\u6027\u7684\u91d1\u5c5e\uff0c\u5982Au\u3001Ag\u3001Zn\u3001Sn\u3001Pd\u3001Bi\u7b49\uff0c\u8fd9\u53ea\u80fd\u63d0\u9ad8\u5bf9CO\u3001\u7532\u9178\/\u7532\u9178\u76d0\u6216\u4e59\u70ef\uff0c\u800c\u4e0d\u662f\u4e59\u9187\u4ea7\u7269\u7684\u9009\u62e9\u6027\u3002\u53e6\u5916\uff0c\u7531\u4e8e\u78b1\u91d1\u5c5e\u6216\u78b1\u571f\u91d1\u5c5e\u5728\u6c34\u6216\u7a7a\u6c14\u4e2d\u7684\u9ad8\u5316\u5b66\u53cd\u5e94\u6d3b\u6027\uff0c\u79d1\u7814\u5de5\u4f5c\u8005\u5f88\u5c11\u5173\u6ce8\u5230\u5b83\u4eec\u3002\u5176\u4e2d\uff0c\u91d1\u5c5e\u9541\u5728\u4e00\u822c\u73af\u5883\u4e0b\u5177\u6709\u8f83\u9ad8\u7684\u5316\u5b66\u60f0\u6027\uff1b\u540c\u65f6\uff0c\u5b83\u7684\u9633\u79bb\u5b50\u5177\u6709\u591a\u4ef7\u7279\u6027\u548c\u8f83\u5c0f\u7684\u534a\u5f84\uff0c\u88ab\u62a5\u9053\u80fd\u4e0e*CO<sub>2<\/sub><sup>\u2013<\/sup>\u00a0\u4e2d\u95f4\u4f53\u6709\u8f83\u5f3a\u7684\u77ed\u7a0b\u76f8\u4e92\u4f5c\u7528\u548c\u66f4\u5bb9\u6613\u7684\u6d3b\u5316\u6c34\u7684\u80fd\u529b\u3002\u6b64\u5916\uff0c\u4e0e\u78b3\u914d\u4f4d\u7684\u9541\u5355\u539f\u5b50\u50ac\u5316\u5242\u53ef\u4ee5\u901a\u8fc7\u8c03\u6574p-band\u4f4d\u7f6e\uff0c\u6765\u63d0\u9ad8\u5bf9\u542b\u6c27\u7269\u79cd\u7684\u7ed3\u5408\u5f3a\u5ea6\u3002\u56e0\u6b64\uff0c\u8bbe\u8ba1\u5408\u6210\u9541\u548c\u94dc\u7684\u5408\u91d1\u50ac\u5316\u5242\u53ef\u80fd\u589e\u5f3aCO<sub>2<\/sub>\u8fd8\u539f\u4e2d\u4e59\u9187\u7684\u542b\u6c27\u4e2d\u95f4\u4f53\u7684\u5438\u9644\u5f3a\u5ea6\u6765\u63d0\u9ad8\u4e59\u9187\u4ea7\u7269\u7684\u9009\u62e9\u6027\u548c\u6d3b\u6027\u3002<\/p>\n<p>\u8fd1\u65e5\uff0c\u590d\u65e6\u5927\u5b66\u7684\u90d1\u803f\u950b\u6559\u6388\u3001\u5546\u4e18\u5e08\u8303\u5b66\u9662\u7684\u7f57\u5e72\u535a\u58eb\u548c\u4e1c\u534e\u5927\u5b66\u7684\u51b5\u654f\u7814\u7a76\u5458\u5408\u4f5c\uff0c\u901a\u8fc7\u4ee5\u5fae\u7c73\u7ea7\u7684\u5546\u4e1a\u94dc\u7c89\u548c\u9541\u7c89\u4e3a\u539f\u6599\uff0c\u76f4\u63a5\u4e00\u6b65\u5408\u6210\u4e86\u5177\u6709\u9ad8\u5bc6\u5ea6\u6709\u5e8fCu<sub>3<\/sub>-Mg\u4f4d\u70b9\u7684(111)\u9762\u66b4\u9732\u7684\u7eb3\u7c73Cu<sub>2<\/sub>Mg<span class=\"wx_search_keyword_wrap\">\u91d1\u5c5e\u95f4\u5316\u5408\u7269<\/span>(\u8bb0\u4e3aCu<sub>2<\/sub>Mg(111))\uff0c\u80fd\u9ad8\u6548\u5730\u5c06CO<sub>2<\/sub>\u7535\u8fd8\u539f\u4e3a\u4e59\u9187\u4ea7\u7269\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<p>&nbsp;<\/p>\n<section>\n<section><\/section>\n<\/section>\n<p>&nbsp;<\/p>\n<section><img decoding=\"async\" title=\"1\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240422\/1713755244306663.webp\" alt=\"1\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u5728|j<sub>total<\/sub>| \u4e3a600\u00a0mA\u00b7cm<sup>-2<\/sup>\u7684\u5927\u7535\u6d41\u5bc6\u5ea6\u7535\u89e3\u65f6\uff0cCu<sub>2<\/sub>Mg(111)\u50ac\u5316\u5242\u5bf9\u4e59\u9187\u4ea7\u7269\u8868\u73b0\u51fa\u4e86\u4f18\u5f02\u7684\u6cd5\u62c9\u7b2c\u6548\u7387\uff0c\u9ad8\u8fbe76.2\u00a0\u00b1 4.8%\uff0c\u5206\u7535\u6d41\u5bc6\u5ea6\u6700\u9ad8\u4e3a720\u00a0\u00b1 34\u00a0mA\u00b7cm<sup>-2<\/sup>\uff0c\u662fCO<sub>2<\/sub>\u7535\u8fd8\u539f\u5236\u53d6\u4e59\u9187\u7684\u6700\u4f73\u7ed3\u679c\u4e4b\u4e00\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"2\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240422\/1713755267707095.webp\" alt=\"2\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u5bc6\u5ea6\u51fd\u6570\u7406\u8bba\u8ba1\u7b97\u548c\u539f\u4f4d\u62c9\u66fc\u5149\u8c31\u8868\u660e\uff0cCu<sub>2<\/sub>Mg(111)\u9762\u4e0a\u7684Cu<sub>3<\/sub>-Mg\u4f4d\u70b9\uff0c\u7535\u5b50\u4eceMg\u8f6c\u79fb\u5230Cu\uff0c\u4ece\u800c\u5f62\u6210\u00a0Cu<sub>3<\/sub><sup>\u1e9f-<\/sup>-Mg<sup>\u1e9f+<\/sup>\u3002\u8be5\u6d3b\u6027\u4f4d\u70b9\u80fd\u63d0\u9ad8*CO\u7684\u8868\u9762\u8986\u76d6\u7387\uff0c\u964d\u4f4e*CO\u2013CO\u5076\u8054\u80fd\u5792\uff0c\u5e76\u7a33\u5b9a\u4e59\u9187\u7684\u5173\u952e\u4e2d\u95f4\u4f53*CHCHOH\uff0c\u4ece\u800c\u4fc3\u8fdbC<sub>2+<\/sub>\u4ea7\u7269\u4e2d\u7684\u4e59\u9187\u751f\u6210\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"0\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240422\/1713755286808204.webp\" alt=\"0\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u8be5\u5de5\u4f5c\u521b\u65b0\u6027\u5730\u5c06\u78b1\u571f\u91d1\u5c5e\u5f15\u5165\u91d1\u5c5e\u94dc\u4e2d\uff0c\u5e76\u5f62\u6210\u7eb3\u7c73\u7ea7\u522b\u7684\u91d1\u5c5e\u95f4\u5316\u5408\u7269\uff0c\u4e3a\u9ad8\u6548\u5c06CO<sub>2<\/sub>\u8fd8\u539f\u5236\u53d6\u4e59\u9187\u4ea7\u7269\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u7684\u50ac\u5316\u5242\u8bbe\u8ba1\u601d\u8def\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section><strong>\u8bba<\/strong><strong>\u6587\u4fe1\u606f<\/strong><\/p>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section><\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>(111) Facet-oriented Cu<sub>2<\/sub>Mg Intermetallic Compound with Cu<sub>3<\/sub>-Mg Sites for CO<sub>2<\/sub>\u00a0Electroreduction to Ethanol with Industrial Current Density<\/p>\n<p>Dr. Chen Peng,\u00a0Jiaxing Ma,\u00a0Dr. Gan Luo,\u00a0Shuai Yan,\u00a0Junbo Zhang,\u00a0Yangshen Chen,\u00a0Dr. Ning Chen,\u00a0Dr. Zhiqiang Wang,\u00a0Prof. Wei Wei,\u00a0Prof. Tsun-Kong Sham,\u00a0Prof. Yao Zheng,\u00a0Prof. Min Kuang,\u00a0Prof. Gengfeng Zheng<\/p>\n<p>\u6587\u7ae0\u7684\u5171\u540c\u7b2c\u4e00\u4f5c\u8005\u662f\u590d\u65e6\u5927\u5b66\u5148\u8fdb\u6750\u6599\u5b9e\u9a8c\u5ba42018\u7ea7\u76f4\u535a\u751f\u5f6d\u9648\uff0823\u5e74\u535a\u58eb\u6bd5\u4e1a\uff0c\u73b0\u4e3a\u963f\u5fb7\u83b1\u5fb7\u5927\u5b66\u535a\u58eb\u540e\uff09\u548c\u590d\u65e6\u5927\u5b66\u5316\u5b66\u7cfb2021\u7ea7\u672c\u79d1\u751f\u9a6c\u5bb6\u5174\u3002<\/p>\n<p><em>Angewandte Chemie International Edition<\/em><\/p>\n<p>DOI:\u00a010.1002\/anie.202316907<\/p>\n<\/section>\n<\/section>\n<\/section>\n","protected":false},"excerpt":{"rendered":"<p>\u7535\u50ac\u5316CO2\u8fd8\u539f\u6280\u672f\uff0c\u662f\u80fd\u5229\u7528\u6e29\u5ba4\u6c14\u4f53CO2\u4f5c\u4e3a\u53cd\u5e94\u539f\u6599\u5e76\u5236\u53d6\u9ad8\u9644\u52a0\u503c\u7684\u5316\u5de5\u539f\u6599\u6216\u71c3\u6599\u7684\u6709\u6548\u8def\u9014\u4e4b\u4e00\u3002\u7531\u4e8eCO [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-51614","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51614","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=51614"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51614\/revisions"}],"predecessor-version":[{"id":51615,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51614\/revisions\/51615"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=51614"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=51614"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=51614"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}