{"id":51596,"date":"2024-06-08T08:01:55","date_gmt":"2024-06-08T00:01:55","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=51596"},"modified":"2024-05-30T10:02:23","modified_gmt":"2024-05-30T02:02:23","slug":"angew-chem-%ef%bc%9a%e5%8a%9f%e8%83%bd%e5%8c%96%e8%8f%b2%e9%85%b0%e4%ba%9a%e8%83%ba%e5%9f%ban%e5%9e%8b%e8%81%9a%e5%90%88%e7%89%a9%e5%8d%8a%e5%af%bc%e4%bd%93%e6%9d%90%e6%96%99%e5%9c%a8%e8%96%84","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/angew-chem-%ef%bc%9a%e5%8a%9f%e8%83%bd%e5%8c%96%e8%8f%b2%e9%85%b0%e4%ba%9a%e8%83%ba%e5%9f%ban%e5%9e%8b%e8%81%9a%e5%90%88%e7%89%a9%e5%8d%8a%e5%af%bc%e4%bd%93%e6%9d%90%e6%96%99%e5%9c%a8%e8%96%84\/","title":{"rendered":"Angew. Chem. \uff1a\u529f\u80fd\u5316\u83f2\u9170\u4e9a\u80fa\u57fan\u578b\u805a\u5408\u7269\u534a\u5bfc\u4f53\u6750\u6599\u5728\u8584\u819c\u6676\u4f53\u7ba1\u4e2d\u7684\u5e94\u7528"},"content":{"rendered":"<section>\n<section>\n<section>\n<section>\n<section>\u805a\u5408\u7269\u534a\u5bfc\u4f53\u5177\u6709\u8d28\u8f7b\u3001\u67d4\u6027\u548c\u53ef\u6eb6\u6db2\u52a0\u5de5\u7b49\u4f18\u70b9\uff0c\u53d7\u5230\u4e86\u5e7f\u6cdb\u5173\u6ce8\u3002\u4f46\u4e0ep\u578b\u805a\u5408\u7269\u534a\u5bfc\u4f53\u6750\u6599\u76f8\u6bd4\uff0c\u76ee\u524dn\u578b\u805a\u5408\u7269\u534a\u5bfc\u4f53\u6750\u6599\u7684\u53d1\u5c55\u76f8\u5bf9\u6ede\u540e\uff0c\u5176\u4e2d\u5f3a\u7f3a\u7535\u5b50\u57fa\u5143\u7684\u79cd\u7c7b\u76f8\u5bf9\u532e\u4e4f\u662f\u4e3b\u8981\u539f\u56e0\u4e4b\u4e00\u3002\u56e0\u6b64\u5f00\u53d1\u65b0\u578b\u7684\u7f3a\u7535\u5b50\u57fa\u5143\u5177\u6709\u91cd\u8981\u610f\u4e49\uff0c\u6709\u5229\u4e8e\u4fc3\u8fdbn\u578b\u805a\u5408\u7269\u534a\u5bfc\u4f53\u53d1\u5c55\u4ee5\u53ca\u76f8\u5e94\u7535\u5b50\u5668\u4ef6\u7684\u5e94\u7528\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<p>&nbsp;<\/p>\n<section>\n<section><\/section>\n<\/section>\n<p>&nbsp;<\/p>\n<section><img decoding=\"async\" title=\"1\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240422\/1713754591679599.webp\" alt=\"1\" \/><\/section>\n<section>\u56fe 1. \uff08a\uff09\u529f\u80fd\u5316\u83f2\u9170\u4e9a\u80fa\u57fa\u53d7\u4f53\u57fa\u5143\u7684\u8bbe\u8ba1\u601d\u8def\uff1b\uff08b\uff09\u57fa\u4e8e\u7406\u8bba\u8ba1\u7b97\u7684LUMO\u80fd\u7ea7\u3002<\/p>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u8fd1\u65e5\uff0c\u5357\u65b9\u79d1\u6280\u5927\u5b66\u90ed\u65ed\u5c97\u6559\u6388\u8bfe\u9898\u7ec4\u548c\u6d77\u5357\u5927\u5b66\u6750\u6599\u5b66\u9662\u9648\u5fd7\u624d\u526f\u6559\u6388\u5408\u4f5c\uff0c\u91c7\u7528\u83f2\u7a20\u73af\u57fa\u5143\uff08PhA\uff09\u4e3a\u6838\u5fc3\uff0c\u901a\u8fc7\u9170\u4e9a\u80fa\u57fa\uff0c\u7fb0\u57fa\u6216\u6c30\u57fa\u53cc\u529f\u80fd\u5316\u7684\u7b56\u7565\uff0c\u8bbe\u8ba1\u3001\u5408\u6210\u4e86\u65b0\u578b\u7684\u53d7\u4f53\u57fa\u5143CPOI\u548cCPCNI\uff0c\u5176\u8bbe\u8ba1\u7b56\u7565\u5982\u56fe1\u6240\u793a\u3002\u4e0e\u4f20\u7edf\u7684\u5355\u9170\u4e9a\u80fa\u529f\u80fd\u5316\u7684\u53d7\u4f53\u57fa\u5143\u76f8\u6bd4\uff0c\u8fdb\u4e00\u6b65\u7fb0\u57fa\u6216\u6c30\u57fa\u529f\u80fd\u5316\uff0c\u53ef\u4ee5\u5b9e\u73b0\u66f4\u5f3a\u7684\u62c9\u7535\u5b50\u80fd\u529b\uff0c\u5176\u4e2d CPCNI\u7684\u7406\u8bba\u8ba1\u7b97LUMO\u80fd\u7ea7\u6df1\u81f3-3.52 eV\uff0c\u7f3a\u7535\u5b50\u6027\u80fd\u529b\u5f3a\u4e8e\u7ecf\u5178\u7684\u5f3a\u53d7\u4f53\u7ed3\u6784\u57fa\u5143NDI\uff08-3.41 eV\uff09\u548cPDI\uff08-3.46 eV\uff09\u3002\u7535\u5316\u5b66\u6d4b\u8bd5\u7ed3\u679c\u8fdb\u4e00\u6b65\u8bc1\u660e\u4e86\u4e0a\u8ff0\u7ed3\u8bba\uff0cCPCNI\u7684\u5b9e\u9a8c\u6d4b\u8bd5LUMO\u80fd\u7ea7\u53ef\u4ee5\u6df1\u81f3-3.84 eV\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"2\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240422\/1713754603212832.webp\" alt=\"2\" \/><\/section>\n<section>\u56fe 2. \uff08a\uff09DIPCPOI\u548c\uff08b\uff09DIPCPCNI\u7684\u5355\u6676\u7ed3\u6784\u548c\u5806\u79ef\u6a21\u5f0f\u3002<\/p>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u4e3a\u7814\u7a76\u4e24\u79cd\u53d7\u4f53\u57fa\u5143\u5206\u5b50\u9aa8\u67b6\u7684\u51e0\u4f55\u6784\u578b\uff0c\u4f5c\u8005\u6210\u529f\u57f9\u517b\u5e76\u89e3\u6790\u4e86\u5b83\u4eec\u7684\u884d\u751f\u7269DIPCPOI\u548cDIPCPCNI\u7684\u5355\u6676\u7ed3\u6784\u3002\u5982\u56fe2\u6240\u793a\uff0c\u4e24\u79cd\u53d7\u4f53\u57fa\u5143\u7684\u5206\u5b50\u9aa8\u67b6\u90fd\u8868\u73b0\u51fa\u4e86\u9ad8\u5ea6\u7684\u5e73\u9762\u6027\uff0c\u76f8\u90bb\u5206\u5b50\u4e4b\u95f4\u4e5f\u5806\u79ef\u7d27\u5bc6\uff0c\u8fd9\u6709\u5229\u4e8e\u63d0\u9ad8\u76f8\u5e94\u805a\u5408\u7269\u534a\u5bfc\u4f53\u6750\u6599\u4e3b\u94fe\u7684\u5e73\u9762\u6027\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"3\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240422\/1713754618341500.webp\" alt=\"3\" \/><\/section>\n<section>\u56fe 3. \u00a0\u529f\u80fd\u5316\u83f2\u9170\u4e9a\u80fa\u57fan\u578b\u9ad8\u5206\u5b50\u534a\u5bfc\u4f53\u7684\u5408\u6210\u8def\u7ebf\u3002<\/p>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u57fa\u4e8e\u4e0a\u8ff0\u53d7\u4f53\u6784\u5efa\u57fa\u5143\u4f18\u5f02\u7684\u6eb6\u89e3\u6027\u3001\u9ad8\u5ea6\u7684\u5e73\u9762\u6027\u548c\u5f3a\u7684\u7f3a\u7535\u5b50\u6027\uff0c\u4f5c\u8005\u5c06\u5b83\u4eec\u5e94\u7528\u4e8e\u4e86n\u578b\u805a\u5408\u7269\u534a\u5bfc\u4f53\u7684\u5f00\u53d1\uff0c\u5408\u6210\u4e86 PCPOI-Tz\u548cPCPCNI-Tz\uff08\u56fe3\uff09\u3002\u5f97\u76ca\u4e8e\u9170\u4e9a\u80fa\u57fa\u3001\u6c30\u57fa\u7684\u534f\u540c\u62c9\u7535\u5b50\u6548\u5e94\uff0cPCPCNI-Tz\u7684LUMO\u80fd\u7ea7\u53ef\u4ee5\u6df1\u81f3-3.83 eV\uff0c\u5728\u6709\u673a\u573a\u6548\u5e94\u6676\u4f53\u7ba1\u4e2d\u8868\u73b0\u51fan\u578b\u4f20\u8f93\u6027\u80fd\uff0c\u8fc1\u79fb\u7387\u4e3a0.014 cm<sup>2<\/sup>\u00a0V<sup>-1<\/sup>\u00a0s<sup>-1<\/sup>\uff1b\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u5f97\u76ca\u4e8e\u5176\u8f83\u6df1\u7684LUMO\u80fd\u7ea7\uff0c\u6676\u4f53\u7ba1\u5668\u4ef6\u7684\u9608\u503c\u7535\u538b\u53ef\u4ee5\u4f4e\u81f319 V\u3002<\/p>\n<p>\u8be5\u5de5\u4f5c\u4e2d\uff0c\u90ed\u65ed\u5c97\u6559\u6388\u548c\u9648\u5fd7\u624d\u526f\u6559\u6388\u7b49\u901a\u8fc7\u9170\u4e9a\u80fa\u57fa\u7ed3\u5408\u7fb0\u57fa\u6216\u6c30\u57fa\u53cc\u529f\u80fd\u5316\u83f2\u57fa\u5143\u7684\u7b56\u7565\uff0c\u6784\u7b51\u4e86\u4e24\u79cd\u5177\u6709\u4f18\u5f02\u6eb6\u89e3\u6027\u3001\u9ad8\u5ea6\u5e73\u9762\u6027\u548c\u5f3a\u7f3a\u7535\u5b50\u6027\u7684\u53d7\u4f53\u6784\u7b51\u57fa\u5143CPOI\u548cCPCNI\uff0c\u5e76\u57fa\u4e8e\u5b83\u4eec\u5f00\u53d1\u4e86\u65b0\u578b\u7684n\u578b\u805a\u5408\u7269\u534a\u5bfc\u4f53\u6750\u6599\u3002\u8be5\u5de5\u4f5c\u4e0d\u4ec5\u4e30\u5bcc\u4e86\u5f3a\u53d7\u4f53\u57fa\u5143\u7684\u79cd\u7c7b\uff0c\u4e5f\u63d0\u4f9b\u4e86\u201c\u53cc\u529f\u80fd\u5316\u201d\u7a20\u73af\u57fa\u5143\u5f00\u53d1\u65b0\u578b\u5f3a\u53d7\u4f53\u57fa\u5143\u7684\u8bbe\u8ba1\u7b56\u7565\uff0c\u4e3a\u540e\u7eed\u5de5\u4f5c\u63d0\u4f9b\u4e86\u53ef\u501f\u9274\u7684\u91cd\u8981\u7ecf\u9a8c\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section><strong>\u8bba<\/strong><strong>\u6587\u4fe1\u606f<\/strong><\/p>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section><\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>Functionalized Phenanthrene Imide-Based Polymers for n-Type Organic Thin-Film Transistors<\/p>\n<p>Jie Yang, Dr. Jianfeng Li, Xiage Zhang, Wanli Yang, Sang Young Jeong, Enmin Huang, Dr. Bin Liu, Prof. Han Young Woo, Dr. Zhicai Chen and Prof. Xugang Guo<\/p>\n<p>\u6587\u7ae0\u7b2c\u4e00\u4f5c\u8005\u662f\u5357\u65b9\u79d1\u6280\u5927\u5b66\u535a\u58eb\u7814\u7a76\u751f\u6768\u6770\u548c\u9ad8\u7ea7\u7814\u7a76\u5b66\u8005\u674e\u5efa\u950b\u3002\u901a\u8baf\u4f5c\u8005\u4e3a\u5357\u65b9\u79d1\u6280\u5927\u5b66\u90ed\u65ed\u5c97\u6559\u6388\u548c\u6d77\u5357\u5927\u5b66\u9648\u5fd7\u624d\u526f\u6559\u6388\u3002<\/p>\n<p><em>Angewandte Chemie International Edition<\/em><\/p>\n<p>DOI:\u00a010.1002\/anie.202319627<\/p>\n<\/section>\n<\/section>\n<\/section>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u805a\u5408\u7269\u534a\u5bfc\u4f53\u5177\u6709\u8d28\u8f7b\u3001\u67d4\u6027\u548c\u53ef\u6eb6\u6db2\u52a0\u5de5\u7b49\u4f18\u70b9\uff0c\u53d7\u5230\u4e86\u5e7f\u6cdb\u5173\u6ce8\u3002\u4f46\u4e0ep\u578b\u805a\u5408\u7269\u534a\u5bfc\u4f53\u6750\u6599\u76f8\u6bd4\uff0c\u76ee\u524dn\u578b\u805a\u5408\u7269\u534a\u5bfc [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-51596","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51596","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=51596"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51596\/revisions"}],"predecessor-version":[{"id":51597,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51596\/revisions\/51597"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=51596"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=51596"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=51596"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}