{"id":51539,"date":"2024-05-31T08:19:18","date_gmt":"2024-05-31T00:19:18","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=51539"},"modified":"2024-05-22T10:19:43","modified_gmt":"2024-05-22T02:19:43","slug":"acs-catalysis%ef%bc%9a%e6%b3%a1%e6%b2%abni%e4%b8%8a%e6%b2%89%e7%a7%afcu%ef%bc%8c%e4%bf%83%e8%bf%9b%e5%82%ac%e5%8c%96%e5%89%82%e9%87%8d%e6%9e%84%e6%9d%a5%e5%a2%9e%e5%bc%bapet%e7%94%b5%e5%8c%96","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/acs-catalysis%ef%bc%9a%e6%b3%a1%e6%b2%abni%e4%b8%8a%e6%b2%89%e7%a7%afcu%ef%bc%8c%e4%bf%83%e8%bf%9b%e5%82%ac%e5%8c%96%e5%89%82%e9%87%8d%e6%9e%84%e6%9d%a5%e5%a2%9e%e5%bc%bapet%e7%94%b5%e5%8c%96\/","title":{"rendered":"\u200bACS Catalysis\uff1a\u6ce1\u6cabNi\u4e0a\u6c89\u79efCu\uff0c\u4fc3\u8fdb\u50ac\u5316\u5242\u91cd\u6784\u6765\u589e\u5f3aPET\u7535\u5316\u5b66\u91cd\u6574"},"content":{"rendered":"<section>\u4f5c\u4e3a\u6700\u5e38\u7528\u7684\u5851\u6599\u6750\u6599\u4e4b\u4e00\uff0c\u805a\u5bf9\u82ef\u4e8c\u7532\u9178\u4e59\u4e8c\u9187\u916f(PET)\u6bcf\u5e74\u751f\u4ea7\u8fd17000\u4e07\u5428\uff0c\u7528\u4e8e\u5305\u88c5\u548c\u7eba\u7ec7\u3002\u7136\u800c\uff0c\u7edd\u5927\u591a\u6570\u5e9f\u5f03\u7684PET\u90fd\u88ab\u586b\u57cb\u5904\u7406\uff0c\u8fd9\u4e0d\u4ec5\u5bf9\u73af\u5883\u6709\u5bb3\uff0c\u800c\u4e14\u9020\u6210\u4e86\u5de8\u5927\u7684\u7ecf\u6d4e\u635f\u5931\u3002\u8fd1\u5e74\u6765\uff0c\u7535\u89e3\u6cd5\u4f5c\u4e3a\u4e00\u79cd\u7eff\u8272\u3001\u4f4e\u80fd\u8017\u7684PET\u5851\u6599\u5347\u7ea7\u56de\u6536\u6280\u672f\u800c\u53d7\u5230\u5e7f\u6cdb\u5173\u6ce8\u3002\u5728\u7535\u89e3\u91cd\u6574\u8fc7\u7a0b\u4e2d\uff0cPET\u9996\u5148\u7ecf\u5386\u4e00\u4e2a\u6c34\u89e3\u8fc7\u7a0b\uff0c\u5f62\u6210<span class=\"wx_search_keyword_wrap\">\u5bf9\u82ef\u4e8c\u7532\u9178<\/span>(TPA)\u548c\u4e59\u4e8c\u9187(EG)\u3002\u7531\u4e8eTPA\u5728\u7535\u5316\u5b66\u6761\u4ef6\u4e0b\u76f8\u5f53\u7a33\u5b9a\uff0c\u53ea\u6709EG\u4f1a\u53d1\u751f\u4e59\u4e8c\u9187\u6c27\u5316\u53cd\u5e94(EGOR)\uff0c\u5347\u7ea7\u4e3a\u9ad8\u9644\u52a0\u503c\u4ea7\u54c1\u3002<\/section>\n<p>&nbsp;<\/p>\n<section>\u7136\u800c\uff0cEGOR\u901a\u5e38\u6d89\u53ca\u4e0d\u53ef\u63a7\u5236\u548c\u590d\u6742\u7684\u53cd\u5e94\u9014\u5f84\uff0c\u5bfc\u81f4\u4ea7\u751f\u5404\u79cdC<sub>1<\/sub>\u548cC<sub>2<\/sub>\u4ea7\u7269\u4ea7\u751f\u3002\u7531\u4e8e\u4ea7\u54c1\u5206\u79bb\u9700\u8981\u989d\u5916\u7684\u4e0b\u6e38\u80fd\u91cf\u6295\u5165\uff0c\u4ea7\u54c1\u9009\u62e9\u6027\u5dee\uff0c\u6548\u7387\u4f4e\uff0c\u963b\u788d\u4e86PET\u5347\u7ea7\u5faa\u73af\u7684\u5e7f\u6cdb\u5e94\u7528\u3002\u56e0\u6b64\uff0c\u5f00\u53d1\u9009\u62e9\u6027\u5f3a\u3001\u6548\u7387\u9ad8\u7684PET\u884d\u751f\u9187\u8f6c\u5316\u7535\u50ac\u5316\u5242\u5c06\u6709\u5229\u4e8e\u964d\u4f4e\u4e0b\u6e38\u6210\u672c\u3002<\/section>\n<section><img decoding=\"async\" title=\"1\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240414\/1713061112866763.jpg\" alt=\"1\" \/><\/section>\n<section><img decoding=\"async\" title=\"2\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240414\/1713061122139594.jpg\" alt=\"2\" \/><\/section>\n<section>\u8fd1\u65e5\uff0c<strong>\u5723\u5730\u4e9a\u54e5\u5dde\u7acb\u5927\u5b66\u987e\u7ade<\/strong>\u8bfe\u9898\u7ec4\u5c06Cu\u7535\u5316\u5b66\u6c89\u79ef\u5728\u6ce1\u6cabNi\u4e0a(NiCu\/NF)\u7528\u4e8e\u7684EG\u548cPET\u5851\u6599\u7684\u589e\u503c\u5316\u3002\u539f\u4f4d\u548c\u5f02\u4f4d\u8868\u5f81\u7ed3\u679c\u663e\u793a\uff0cCu<sup>0<\/sup>\/CuO\u6838\u58f3\u6c89\u79ef\u5728NF\u4e0a\uff0c\u5728\u91cd\u6784\u8fc7\u7a0b\u4e2d\uff0cCu\u548cNi\u7269\u79cd\u88ab\u91cd\u6784\u4e3aCu(OH)<sub>2<\/sub>\/CuOOH\u548cNiOOH\u6d3b\u6027\u7269\u79cd\u3002\u540c\u65f6\uff0c\u6c89\u79ef\u7684Cu\u7269\u79cd\u6709\u5229\u4e8e\u50ac\u5316\u5242\u52a8\u6001\u6f14\u5316\u5f62\u6210Ni<sup>3+<\/sup>\u6d3b\u6027\u7269\u79cd\uff0c\u4fc3\u8fdb\u66f4\u5feb\u7684\u754c\u9762\u7535\u5b50\u8f6c\u79fb\uff0c\u589e\u52a0\u7535\u5316\u5b66\u6d3b\u6027\u9762\u79ef\uff0c\u8fd9\u4e9b\u90fd\u534f\u540c\u63d0\u9ad8\u4e86<span class=\"wx_search_keyword_wrap\">NiCu<\/span>\/NF\u7684EGOR\u6027\u80fd\u3002<\/section>\n<section>\u6b64\u5916\uff0c\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba(DFT)\u8ba1\u7b97\u8868\u660e\uff0cNiCu\/NF (0.51 eV)\u4e0aEGOR\u901f\u7387\u63a7\u5236\u6b65\u9aa4(RDS)\u7684\u80fd\u5792\u76f8\u5bf9\u4e8e\u6ce1\u6cabNi(1.41 eV)\u663e\u8457\u964d\u4f4e\uff0c\u5e76\u4e14Cu\u7684\u5b58\u5728\u4f7f*COOHCH<sub>2<\/sub>OH\u5230*CH<sub>2<\/sub>OH+HCOOH\u6b65\u9aa4\u7684\u80fd\u5792\u964d\u4f4e\uff0c\u4ece\u800c\u4fc3\u8fdb\u4e86C-C\u952e\u7684\u65ad\u88c2\u3002<\/section>\n<section><img decoding=\"async\" title=\"3\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240414\/1713061131925051.jpg\" alt=\"3\" \/><\/section>\n<section><img decoding=\"async\" title=\"5\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240414\/1713061143544278.jpg\" alt=\"5\" \/><\/section>\n<section>\u7535\u5316\u5b66\u6027\u80fd\u6d4b\u8bd5\u7ed3\u679c\u663e\u793a\uff0c\u6700\u4f18\u7684NiCu<sub>60s<\/sub>\/NF\u50ac\u5316\u5242\u7684\u7532\u9178\u76d0\u6cd5\u62c9\u7b2c\u6548\u7387\u548c\u4ea7\u7387\u5206\u522b\u4e3a95.8 %\u548c0.70 mmol cm<sup>\u22122<\/sup>\u00a0h<sup>\u22121<\/sup>\u3002\u7814\u7a76\u4eba\u5458\u8fd8\u9a8c\u8bc1\u4e86\u8be5\u7535\u50ac\u5316\u4f53\u7cfb\u7684\u5b9e\u9645\u5e94\u7528\uff1a\u91c7\u7528\u5546\u7528PET\u7c89\u672b\u4f5c\u4e3a\u539f\u6599\uff0cPET\u7c89\u672b\u6c34\u89e3\u4ea7\u7269\u4e3b\u8981\u4e3a\u7532\u9178\u76d0(FE&gt; 80%)\uff1b\u53e6\u5916\uff0c\u5e02\u552ePET\u6c34\u74f6\u6c34\u89e3\u6db2\u7ecf\u8fc7\u7b80\u5355\u7684\u9178\u5316\u548c\u5206\u79bb\u8fc7\u7a0b\uff0c\u4ec5\u97001\u5c0f\u65f6\u5373\u53ef\u518d\u751f\u51fa\u7eafTPA\uff0c\u5c55\u793a\u4e86\u7535\u91cd\u6574\u65b9\u6cd5\u5728\u5b9e\u9645\u751f\u6d3b\u4e2d\u7684\u6f5c\u5728\u5b9e\u9645\u5e94\u7528\u4ef7\u503c\u3002<\/section>\n<section>\u603b\u7684\u6765\u8bf4\uff0c\u8be5\u9879\u5de5\u4f5c\u901a\u8fc7\u5bf9\u50ac\u5316\u5242\u7684\u52a8\u6001\u6f14\u53d8\u3001\u771f\u5b9e\u6d3b\u6027\u4e2d\u5fc3\u548c\u53cd\u5e94\u673a\u7406\u7684\u63a2\u7d22\uff0c\u4e3a\u7406\u89e3\u548c\u8bbe\u8ba1\u9ad8\u6027\u80fd\u7535\u50ac\u5316\u5242\u4ee5\u5b9e\u73b0\u66f4\u9ad8\u6548\u3001\u66f4\u6709\u9009\u62e9\u6027\u7684\u5851\u6599\u5347\u7ea7\u63d0\u4f9b\u4e86\u7406\u8bba\u4f9d\u636e\u3002<\/section>\n<section>Cu promoted the dynamic evolution of Ni-based catalysts for polyethylene terephthalate plastic upcycling. ACS Catalysis, 2024. DOI: 10.1021\/acscatal.3c05509<\/section>\n","protected":false},"excerpt":{"rendered":"<p>\u4f5c\u4e3a\u6700\u5e38\u7528\u7684\u5851\u6599\u6750\u6599\u4e4b\u4e00\uff0c\u805a\u5bf9\u82ef\u4e8c\u7532\u9178\u4e59\u4e8c\u9187\u916f(PET)\u6bcf\u5e74\u751f\u4ea7\u8fd17000\u4e07\u5428\uff0c\u7528\u4e8e\u5305\u88c5\u548c\u7eba\u7ec7\u3002\u7136\u800c\uff0c\u7edd\u5927\u591a\u6570 [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-51539","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51539","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=51539"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51539\/revisions"}],"predecessor-version":[{"id":51540,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51539\/revisions\/51540"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=51539"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=51539"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=51539"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}