{"id":51521,"date":"2024-05-28T08:35:33","date_gmt":"2024-05-28T00:35:33","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=51521"},"modified":"2024-05-18T18:37:30","modified_gmt":"2024-05-18T10:37:30","slug":"angew-chem-%ef%bc%9a%e6%b0%a2%e6%b0%94%e8%af%b1%e5%af%bc%e5%bd%a2%e6%88%90pt-alpo33%e5%82%ac%e5%8c%96%e5%89%82%e8%a1%a8%e9%9d%a2%e9%85%b8%e4%bd%8d%e7%82%b9%e6%9c%89%e6%95%88%e4%bf%83%e8%bf%9b","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/angew-chem-%ef%bc%9a%e6%b0%a2%e6%b0%94%e8%af%b1%e5%af%bc%e5%bd%a2%e6%88%90pt-alpo33%e5%82%ac%e5%8c%96%e5%89%82%e8%a1%a8%e9%9d%a2%e9%85%b8%e4%bd%8d%e7%82%b9%e6%9c%89%e6%95%88%e4%bf%83%e8%bf%9b\/","title":{"rendered":"Angew. Chem. \uff1a\u6c22\u6c14\u8bf1\u5bfc\u5f62\u6210Pt\/Al(PO3)3\u50ac\u5316\u5242\u8868\u9762\u9178\u4f4d\u70b9\u6709\u6548\u4fc3\u8fdb\u9187\u548c\u919a\u7684\u6c22\u89e3"},"content":{"rendered":"<section>\n<section>\n<section>\n<section>\n<section>\u5728\u8ffd\u6c42\u5316\u5de5\u4ea7\u4e1a\u7684\u53ef\u6301\u7eed\u53d1\u5c55\u4e2d\uff0c\u5c06\u53ef\u518d\u751f\u751f\u7269\u8d28\uff08\u4f8b\u5982\uff0c\u6728\u8d28\u7ea4\u7ef4\u7d20\uff09\u8f6c\u5316\u4e3a\u4ef7\u503c\u8f83\u9ad8\u7684\u5316\u5b66\u54c1\u548c\u751f\u7269\u71c3\u6599\u5c24\u4e3a\u5173\u952e\uff0c\u5176\u4e2d\u9187\u548c\u919a\u7684\u6c22\u89e3\u53cd\u5e94\u662f\u6838\u5fc3\u6b65\u9aa4\u4e4b\u4e00\u3002<span class=\"wx_search_keyword_wrap\">\u5206\u5b50\u6c22<\/span>\u4f5c\u4e3a\u8fd8\u539f\u5242\u7684\u5e94\u7528\uff0c\u5df2\u88ab\u8bc1\u660e\u662f\u4e00\u79cd\u9ad8\u6548\u7684\u8f6c\u5316\u8def\u5f84\u3002\u5c3d\u7ba1\u76ee\u524d\u5df2\u7ecf\u5f00\u53d1\u4e86\u591a\u79cd\u5f02\u76f8\u50ac\u5316\u5242\uff0c\u8fd9\u4e9b\u50ac\u5316\u4f53\u7cfb\u5f80\u5f80\u9700\u8981\u8f83\u82db\u523b\u7684\u53cd\u5e94\u6761\u4ef6\uff0c\u4ece\u800c\u52a0\u5267\u9650\u5236\u4e86\u5176\u66f4\u5e7f\u6cdb\u7684\u5e94\u7528\u3002<\/p>\n<p>\u8fd1\u65e5\uff0c\u65e5\u672c\u4e1c\u4eac\u5927\u5b66\u7684\u91d1\u96c4\u6770(Xiongjie Jin)\u548c\u91ce\u5d0e\u4eac\u5b50(Kyoko Nozaki)\u6559\u6388\u56e2\u961f\u901a\u8fc7\u5229\u7528\u6c22\u6c14\u8bf1\u5bfcPt\/Al(PO<sub>3<\/sub>)<sub>3<\/sub>\u50ac\u5316\u5242\u8868\u9762\u9178\u4f4d\u70b9\u7684\u5f62\u6210\u5b9e\u73b0\u4e86\u9187\u548c\u919aC-O\u952e\u7684\u9ad8\u6548\u6c22\u89e3\u3002\u8fd9\u662f\u7ee72021\u5e74\u8be5\u56e2\u961f\u6210\u529f\u5f00\u53d1Pt\/Al(PO<sub>3<\/sub>)<sub>3<\/sub>\u50ac\u5316\u5242(<em>Nature Catal.2021,4,312<\/em>)\uff0c\u5e76\u53d1\u73b0\u5176\u80fd\u591f\u4fc3\u8fdb\u6e29\u548c\u6761\u4ef6\u4e0b\u9ad8\u9009\u62e9\u6027\u6c22\u89e3\u915a\u540e\u7684\u53c8\u4e00\u91cd\u5927\u7a81\u7834\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<p>&nbsp;<\/p>\n<section>\n<section><\/section>\n<\/section>\n<p>&nbsp;<\/p>\n<section><img decoding=\"async\" title=\"1\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240413\/1713010278591199.webp\" alt=\"1\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u5b9e\u73b0\u6e29\u548c\u6761\u4ef6\u4e0b\u9ad8\u6548\u6c22\u89e3\u9187\u548c\u919a\u7684\u5173\u952e\u5728\u4e8e\u6709\u6548\u6d3b\u5316C-O\u952e\uff0c\u4ece\u800c\u4fc3\u4f7f\u5176\u6613\u4e8e\u65ad\u88c2\u3002\u78f7\u9178\u957f\u671f\u4ee5\u6765\u4e00\u76f4\u88ab\u7528\u4f5c\u5747\u76f8Br\u00f8nsted<span class=\"wx_search_keyword_wrap\">\u9178\u50ac\u5316\u5242<\/span>\uff0c\u7528\u4e8e\u9187\u548c\u919a\u7684\u8f6c\u5316\uff0c\u8fd9\u5f97\u76ca\u4e8e\u5176\u6d3b\u5316C-O\u952e\u7684\u80fd\u529b\u3002\u968f\u540e\u53d1\u73b0\u91d1\u5c5e\u6c27\u5316\u7269\u8d1f\u8f7d\u78f7\u9178\u4ea6\u53ef\u5b9e\u73b0C-O\u952e\u7684\u6709\u6548\u6d3b\u5316\u3002\u9274\u4e8e\u6b64\uff0c\u4f5c\u8005\u5229\u7528Al(PO<sub>3<\/sub>)<sub>3<\/sub>\u4f5c\u4e3aPt\u7eb3\u7c73\u7c92\u5b50\u7684\u8f7d\u4f53\uff0c\u5e76\u901a\u8fc7Pt\u6d3b\u5316\u5206\u5b50\u6c22\u5f62\u6210\u8868\u9762Br\u00f8nsted\u9178(\u78f7\u9178)\u4f4d\u70b9\uff0c\u6210\u529f\u5b9e\u73b0\u4e86\u6e29\u548c\u6761\u4ef6\u4e0b\u9187\u548c\u919aC-O\u952e\u7684\u9ad8\u6548\u6d3b\u5316\u4e0e\u6c22\u89e3\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"2\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240413\/1713010290934450.webp\" alt=\"2\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u4f5c\u8005\u901a\u8fc7\u5bf9\u7167\u5b9e\u9a8c\u53d1\u73b0\uff0c\u91d1\u5c5e\u6c27\u5316\u7269\u5982\u6c27\u5316\u94dd\uff0c\u4e8c\u6c27\u5316\u949b\uff0c\u4e8c\u6c27\u5316\u94c8\u8d1f\u8f7d\u7684Pt\u50ac\u5316\u5242\u65e0\u6cd5\u4fc3\u8fdb\u9187\u7684\u6c22\u89e3\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0cPt\/Al(PO<sub>3<\/sub>)<sub>3<\/sub>\u663e\u793a\u51fa\u4e86\u4f18\u5f02\u7684\u50ac\u5316\u6027\u80fd\uff0c\u4ee5\u9ad8\u6536\u7387\u5f97\u5230\u76f8\u5e94\u7684\u70f7\u70c3\u3002\u56e0\u6b64\uff0c\u5229\u7528\u78f7\u9178\u76d0\u8f7d\u4f53\u662f\u6210\u529f\u5b9e\u73b0C-O\u952e\u9ad8\u6548\u6c22\u89e3\u7684\u5173\u952e\u3002\u7814\u7a76\u53d1\u73b0\uff0c\u5229\u7528\u6b64\u50ac\u5316\u5242\u53ef\u5728\u6e29\u548c\u6761\u4ef6\u4e0b(110 \u00b0C\uff0c1\u5927\u6c14\u538b\u6c22\u6c14)\u5c06\u751f\u7269\u67f4\u6cb9\u524d\u4f53\u8f6c\u5316\u4e3a\u76f8\u5e94\u7684\u78b3\u6c22\u71c3\u6599\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"3\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240413\/1713010300109657.webp\" alt=\"3\" \/><\/section>\n<p>&nbsp;<\/p>\n<p>&nbsp;<\/p>\n<section>\n<section>\n<section>\n<section>\n<section>\u901a\u8fc7\u6269\u6563\u53cd\u5c04\u7ea2\u5916<span class=\"wx_search_keyword_wrap\">\u5085\u91cc\u53f6\u53d8\u6362<\/span>\u5149\u8c31\uff08DRIFTS\uff09\u5206\u6790\uff0c\u8fdb\u4e00\u6b65\u9a8c\u8bc1\u4e86\u6c22\u6c14\u8bf1\u5bfc\u8868\u9762Br\u00f8nsted\u9178\u4f4d\u70b9\u7684\u5f62\u6210\u3002\u6c22\u6c14\u5904\u7406\u8fc7\u7684Pt\/Al(PO<sub>3<\/sub>)<sub>3<\/sub>\u663e\u793a\u51fa\u5f52\u56e0\u4e8eO-H\u952e\u62c9\u4f38\u632f\u52a8\u7684\u5bbd\u7ea2\u5916\u5e26\uff0c\u8868\u660e\u6c22\u6c14\u8bf1\u5bfc\u5f62\u6210\u8868\u9762\u7f9f\u57fa\u56e2\u3002\u6b64\u5916\uff0c\u4f7f\u7528\u5421\u5576\u4f5c\u4e3a\u63a2\u9488\u5206\u5b50\u7684DRIFTS\u5206\u6790\u8868\u660e\uff0c\u6c22\u6c14\u8bf1\u5bfc\u5f62\u6210\u7684\u7f9f\u57fa\u53ef\u5f52\u7ed3\u4e8e\u8868\u9762Br\u00f8nsted\u9178\u4f4d\u70b9\uff08\u53cd\u5e94\u673a\u7406\u89c1\u4e0b\u56fe\uff09\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"8\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240413\/1713010313113667.webp\" alt=\"8\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u5728\u8be5\u5de5\u4f5c\u4e2d\uff0c\u4f5c\u8005\u63ed\u793a\u8868\u9762Br\u00f8nsted\u9178\u4f4d\u70b9\u5728Pt\/Al(PO<sub>3<\/sub>)<sub>3<\/sub>\u50ac\u5316\u9187\u4e0e\u919a\u6c22\u89e3\u7684\u91cd\u8981\u6027\uff0c\u5e76\u6210\u529f\u5b9e\u73b0\u4e86\u6e29\u548c\u6761\u4ef6\u4e0b\u5e7f\u6cdb\u9187\u548c\u919a\u7684\u6c22\u89e3\uff0c\u663e\u793a\u51fa\u8be5\u50ac\u5316\u4f53\u7cfb\u5728\u9ad8\u6548\u8282\u80fd\u751f\u7269\u8d28\u8f6c\u5316\u6216\u7cbe\u7ec6\u6709\u673a\u5408\u6210\u4e2d\u7684\u6f5c\u5728\u5e94\u7528\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section><strong>\u8bba<\/strong><strong>\u6587\u4fe1\u606f<\/strong><\/p>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section><\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>Hydrogen-Induced Formation of Surface Acid Sites on Pt\/Al(PO<sub>3<\/sub>)<sub>3<\/sub>\u00a0Enables Remarkably Efficient Hydrogenolysis of C\u2212O Bonds in Alcohols and Ethers<\/p>\n<p>Kento Oshida,\u00a0Kang Yuan,\u00a0Dr. Yukari Yamazaki,\u00a0Rio Tsukimura,\u00a0Hidenori Nishio,\u00a0Katsutoshi Nomoto,\u00a0Prof. Hiroki Miura,\u00a0Prof. Tetsuya Shishido,\u00a0Prof. Xiongjie Jin,\u00a0Prof. Kyoko Nozaki<\/p>\n<p><em>Angewandte Chemie International Edition<\/em><\/p>\n<p>DOI:\u00a010.1002\/anie.202403092<\/p>\n<\/section>\n<\/section>\n<\/section>\n","protected":false},"excerpt":{"rendered":"<p>\u5728\u8ffd\u6c42\u5316\u5de5\u4ea7\u4e1a\u7684\u53ef\u6301\u7eed\u53d1\u5c55\u4e2d\uff0c\u5c06\u53ef\u518d\u751f\u751f\u7269\u8d28\uff08\u4f8b\u5982\uff0c\u6728\u8d28\u7ea4\u7ef4\u7d20\uff09\u8f6c\u5316\u4e3a\u4ef7\u503c\u8f83\u9ad8\u7684\u5316\u5b66\u54c1\u548c\u751f\u7269\u71c3\u6599\u5c24\u4e3a\u5173\u952e\uff0c\u5176\u4e2d [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-51521","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51521","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=51521"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51521\/revisions"}],"predecessor-version":[{"id":51522,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51521\/revisions\/51522"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=51521"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=51521"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=51521"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}