{"id":51515,"date":"2024-05-27T08:20:37","date_gmt":"2024-05-27T00:20:37","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=51515"},"modified":"2024-05-18T18:22:45","modified_gmt":"2024-05-18T10:22:45","slug":"eurjoc%ef%bc%9acuiii-cf3%e5%8c%96%e5%90%88%e7%89%a9%e4%b8%8edmso%e5%8d%8f%e5%90%8c%e6%b0%a7%e5%8c%96%e9%86%87%e4%b8%ba%e9%85%ae","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/eurjoc%ef%bc%9acuiii-cf3%e5%8c%96%e5%90%88%e7%89%a9%e4%b8%8edmso%e5%8d%8f%e5%90%8c%e6%b0%a7%e5%8c%96%e9%86%87%e4%b8%ba%e9%85%ae\/","title":{"rendered":"EurJOC\uff1aCu(III)-CF3\u5316\u5408\u7269\u4e0eDMSO\u534f\u540c\u6c27\u5316\u9187\u4e3a\u916e"},"content":{"rendered":"<section>\n<section>\n<section>\n<section>\n<section>\u9ad8\u4ef7\u6001Cu(III)-CF<sub>3<\/sub>\u5316\u5408\u7269\u662f\u94dc\u4fc3\u8fdb\u7684\u4e09\u6c1f\u7532\u57fa\u5316\u53cd\u5e94\u7684\u5173\u952e\u4e2d\u95f4\u4f53\u3002\u8fd1\u5e74\u6765\uff0c\u5173\u4e8eCu(III)-CF<sub>3<\/sub>\u5316\u5408\u7269\u7684\u5408\u6210\u4e0e\u53cd\u5e94\u6d3b\u6027\u7814\u7a76\u7684\u76f8\u5173\u5de5\u4f5c\u5f15\u8d77\u4e86\u8d8a\u6765\u8d8a\u591a\u7684\u5173\u6ce8\u3002\u4e00\u4e9b\u5de5\u4f5c\u9646\u7eed\u62a5\u9053\u4e86\u5b83\u4eec\u7684\u5408\u6210\u5206\u79bb\u65b9\u6cd5\u548c\u660e\u786e\u7684\u7ed3\u6784\u8868\u5f81\uff0c\u8fd9\u4e3a\u540e\u7eed\u7684\u53cd\u5e94\u6d3b\u6027\u7814\u7a76\u63d0\u4f9b\u4e86\u57fa\u7840\u3002\u76ee\u524d\u5df2\u7ecf\u62a5\u9053\u7684\u9ad8\u4ef7\u6001Cu(III)-CF<sub>3<\/sub>\u5316\u5408\u7269\u7684\u53cd\u5e94\u6d3b\u6027\u4e3b\u8981\u5305\u62ec[RCu<sup>\u2162<\/sup>(CF<sub>3<\/sub>)<sub>3<\/sub>]-\u5316\u5408\u7269\u7684\u8fd8\u539f\u6d88\u9664\u3001\u787c\u9178\u548c\u5364\u5316\u7269\u7684\u4e09\u6c1f\u7532\u57fa\u5316\u3001\u70c3\u7c7bC-H\u952e\u7684\u76f4\u63a5\u4e09\u6c1f\u7532\u57fa\u5316\u3001\u4ee5\u53ca\u9ad8\u4ef7\u6001Cu(III)-CF<sub>3<\/sub>\u5316\u5408\u7269\u4e0e\u5404\u79cd\u4eb2\u6838\u8bd5\u5242\u5408\u4f5c\u5b9e\u73b0\u70ef\u70c3\u548c\u7094\u70c3\u7684\u9009\u62e9\u6027\u4e8c\u5b98\u80fd\u5316\u53cd\u5e94\u3002\u9664\u4e86\u4f5c\u4e3a\u4e09\u6c1f\u7532\u57fa\u8bd5\u5242\u4ee5\u5916\uff0c\u6700\u8fd1\u7684\u4e00\u4e9b\u5de5\u4f5c\u62a5\u9053\u4e86Cu(III)-CF<sub>3<\/sub>\u5316\u5408\u7269\u7684\u4e00\u4e9b\u65b0\u53cd\u5e94\u6a21\u5f0f\u3002\u4f8b\u5982\uff0cCu(III)-CF<sub>3<\/sub>\u5316\u5408\u7269\u53ef\u4ee5\u4f5c\u4e3a\u4e00\u79cd\u65b0\u578b\u5076\u8054\u8bd5\u5242\u4ecb\u5bfc\u7fa7\u9178\u548c\u9187\/\u80fa\u7684\u7f29\u5408\u751f\u6210\u916f\u548c\u9170\u80fa\uff1bCu(III)-CF<sub>3<\/sub>\u5316\u5408\u7269\u53ef\u4ee5\u4f5c\u4e3a\u6c27\u5316\u5242\u4fc3\u8fdb\u80fa\u7684N-H\/N-H\u6c27\u5316\u5076\u8054\u751f\u6210\u80bc\uff1bCu(III)-CF<sub>3<\/sub>\u5316\u5408\u7269\u4e0eDMSO\u534f\u540c\u6c27\u5316\u73af\u6c27\u5316\u5408\u7269\u751f\u62101,2-\u4e8c\u916e\u3002\u8fd9\u4e9b\u5de5\u4f5c\u663e\u793a\u4e86Cu(III)-CF<sub>3<\/sub>\u5316\u5408\u7269\u4e30\u5bcc\u7684\u53cd\u5e94\u6d3b\u6027\u548c\u5728\u6709\u673a\u5408\u6210\u4e2d\u7684\u5de8\u5927\u6f5c\u529b\uff0c\u56e0\u800c\u53d1\u5c55\u65b0\u7684Cu(III)-CF<sub>3<\/sub>\u5316\u5408\u7269\u7684\u53cd\u5e94\u6d3b\u6027\u5177\u6709\u91cd\u8981\u7684\u7814\u7a76\u4ef7\u503c\u3002<\/p>\n<p>\u6700\u8fd1\uff0c\u6c5f\u5357\u5927\u5b66\u5f20\u677e\u6797\u6559\u6388\u8bfe\u9898\u7ec4\u53d1\u73b0\u5229\u7528\u9ad8\u4ef7\u6001Cu(III)-CF<sub>3<\/sub>\u5316\u5408\u7269\u4e0eDMSO\u534f\u540c\u4f5c\u7528\u7684\u7b56\u7565\uff0c\u53ef\u4ee5\u5b9e\u73b0\u9187\u7684\u6c27\u5316\u53cd\u5e94\u751f\u6210\u916e\uff08\u919b\uff09\u3002\u8be5\u53cd\u5e94\u6d89\u53ca\u5173\u952e\u7684\u786b\u6b63\u4e2d\u95f4\u4f53(sulfonium)\u7684\u751f\u6210\u548c\u8f6c\u5316(Fig. 1)\u3002\u8be5\u53cd\u5e94\u5728\u6c2e\u6c14\u73af\u5883\u4e0b\u8fdb\u884c\uff0c\u6761\u4ef6\u8f83\u4e3a\u6e29\u548c\uff0c\u64cd\u4f5c\u65b9\u4fbf\uff0c\u80fd\u517c\u5bb9\u591a\u79cd\u5b98\u80fd\u56e2\uff0c\u7279\u522b\u662f\u4e00\u4e9b\u8f83\u4e3a\u654f\u611f\u7684\u5b98\u80fd\u56e2(Fig.2)\u3002\u672c\u7814\u7a76\u4e30\u5bcc\u4e86\u9ad8\u4ef7\u6001Cu(III)-CF<sub>3<\/sub>\u5316\u5408\u7269\u7684\u53cd\u5e94\u6d3b\u6027\uff0c\u63d0\u4f9b\u4e86\u4e00\u4e2a\u65b9\u4fbf\u7684\u5f00\u53d1\u786b\u6b63\u4e2d\u95f4\u4f53(sulfonium)\u5316\u5b66\u7684\u5e73\u53f0\uff0c\u6709\u671b\u5728\u66f4\u591a\u7684\u53cd\u5e94\u4e2d\u5f97\u5230\u5e94\u7528\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"1\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240518\/1716027720421512.webp\" alt=\"1\" \/><\/section>\n<section>Fig. 1 \u65b0\u9896\u7684Cu(III)-CF3 compound\/DMSO \u4ecb\u5bfc\u7684\u9187\u7684\u6c27\u5316\u7b56\u7565\u3002<\/p>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u8be5\u53cd\u5e94\u4e2d\uff0c\u5728\u82ef\u73af\u7684\u5bf9\u4f4d\u3001\u95f4\u4f4d\u6216\u90bb\u4f4d\u5747\u53ef\u4ee5\u8010\u53d7\u4e00\u7cfb\u5217\u5b98\u80fd\u56e2\uff0c\u5305\u62ec\u70f7\u57fa\u3001\u82ef\u57fa\u3001\u73af\u4e19\u57fa\u3001\u7532\u6c27\u57fa\u3001\u5364\u7d20\u3001\u4e09\u6c1f\u7532\u57fa\u3001\u6c30\u57fa\u3001\u7532\u57fa\u786b\u5316\u7269\u3001<span class=\"wx_search_keyword_wrap\">\u4e8c\u7532\u6c28\u57fa<\/span>\u3001\u916f\u57fa\u4ee5\u53ca\u6742\u82b3\u57fa(Fig.2)\u3002\u6b64\u5916\uff0c\u672a\u7ecf\u4fdd\u62a4\u7684\u7f9f\u57fa\u4e5f\u540c\u6837\u9002\u7528\u3002\u4f2f\u9187\u7684\u6c27\u5316\u4e5f\u53ef\u4ee5\u751f\u6210\u76f8\u5e94\u7684\u919b\u3002\u5229\u7528\u8be5\u65b9\u6cd5\u53ef\u4ee5\u65b9\u4fbf\u5730\u5408\u6210\u964d\u8840\u8102\u836f\u7269\u975e\u8bfa\u8d1d\u7279(fenofibrate)\uff0c\u8fdb\u4e00\u6b65\u663e\u793a\u4e86\u8be5\u65b9\u6cd5\u7684\u5408\u6210\u4ef7\u503c\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"2\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240518\/1716027730753787.webp\" alt=\"2\" \/><\/section>\n<section>Fig. 2. \u53cd\u5e94\u9002\u7528\u6027\u8303\u56f4\u7814\u7a76<\/p>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u4e3a\u4e86\u7406\u89e3\u53cd\u5e94\u673a\u7406\uff0c\u4f5c\u8005\u8fdb\u884c\u4e86\u4e00\u7cfb\u5217\u76f8\u5173\u7684\u673a\u7406\u63a2\u7a76\uff0c\u5305\u62ec\u5bf9\u7167\u5b9e\u9a8c\u3001\u81ea\u7531\u57fa\u6355\u83b7\u5b9e\u9a8c\uff0c<sup>19<\/sup>F NMR\u548cHRMS\u68c0\u6d4b\u4e2d\u95f4\u4f53\u7684\u5b9e\u9a8c\u3002\u63d0\u51fa\u4e86\u4e00\u4e2a\u6d89\u53ca\u786b\u6b63\u4e2d\u95f4\u4f53(sulfonium)\u7684\u673a\u7406(Fig. 3). Cu(III)-CF<sub>3<\/sub>\u5316\u5408\u7269\u9996\u5148\u5bf9DMSO\u8fdb\u884c\u4eb2\u7535\u4e09\u6c1f\u7532\u57fa\u5316\uff0c\u751f\u6210\u4e86[Me<sub>2<\/sub>S-OCF<sub>3<\/sub>]<sup>+<\/sup>\u00a0[Cu(I)(CF<sub>3<\/sub>)<sub>2<\/sub>]<sup>&#8211;<\/sup>\u4e2d\u95f4\u4f53A\u3002A\u4e0e\u9187\u5e95\u7269\u53d1\u751f\u786b\u6b63\u4e2d\u5fc3\u4e0a\u7684\u70f7\u6c27\u57fa\u56e2\u53d6\u4ee3\uff0c\u751f\u6210\u65b0\u7684\u786b\u6b63\u4e2d\u95f4\u4f53B\u3002<sup>19<\/sup>F NMR\u548c\u9ad8\u5206\u8fa8\u8d28\u8c31\u7684\u68c0\u6d4b\u7ed3\u679c\u90fd\u9a8c\u8bc1\u4e86\u8fd9\u4e24\u4e2a\u5173\u952e\u4e2d\u95f4\u4f53\u7684\u751f\u6210\u3002\u4e2d\u95f4\u4f53B\u5728\u78b1\u7684\u4f5c\u7528\u4e0b\u53d1\u751fE2\u6d88\u9664\uff0c\u5f97\u5230\u7fb0\u57fa\u4ea7\u7269\u3002\u8be5\u673a\u7406\u540c\u65f6\u80fd\u89e3\u91ca\u53cd\u5e94\u4e2d\u89c2\u5bdf\u5230\u7684\u4e00\u4e9b\u526f\u4ea7\u7269\uff0c\u5982\u9187\u8131\u6c34\u4ea7\u7269\u70ef\u70c3\u4ee5\u53ca\u78b3\u9178\u916f\u7684\u751f\u6210\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"5\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240518\/1716027742617670.webp\" alt=\"5\" \/>\u200b<\/section>\n<section>Fig. 3. \u63d0\u51fa\u7684sulfonium\u53cd\u5e94\u673a\u7406\u4ee5\u89e3\u91ca\u4ea7\u7269\u548c\u526f\u4ea7\u7269\u7684\u751f\u6210\u3002<\/p>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u603b\u4e4b\uff0c\u8be5\u7814\u7a76\u53d1\u5c55\u4e86\u4e00\u79cd\u9ad8\u4ef7\u6001Cu(III)-CF<sub>3<\/sub>\u5316\u5408\u7269\u534f\u540cDMSO\u4ecb\u5bfc\u7684\u6c27\u5316\u7c7b\u578b\u7684\u65b0\u53cd\u5e94\u6a21\u5f0f\uff0c\u5b9e\u73b0\u4e86\u9187\u6c27\u5316\u751f\u6210\u916e\uff08\u919b\uff09\u5316\u5408\u7269\u7684\u53cd\u5e94\u3002\u8be5\u65b9\u6cd5\u6761\u4ef6\u6e29\u548c\uff0c\u5e95\u7269\u8303\u56f4\u5e7f\u6cdb\uff0c\u80fd\u517c\u5bb9\u591a\u79cd\u5b98\u80fd\u56e2\u3002\u540c\u65f6\u836f\u7269\u5206\u5b50\u7684\u5408\u6210\u53ca\u590d\u6742\u5206\u5b50\u7684\u540e\u671f\u5b98\u80fd\u5316\u663e\u793a\u4e86\u8be5\u65b9\u6cd5\u7684\u5408\u6210\u4ef7\u503c\u3002\u673a\u7406\u8bc1\u636e\u652f\u6301\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u6d89\u53ca\u5173\u952e\u7684\u786b\u6b63\u4e2d\u95f4\u4f53\u3002\u8be5\u5de5\u4f5c\u662f\u5bf9\u9ad8\u4ef7\u6001Cu(\u2162)-CF<sub>3<\/sub>\u5316\u5408\u7269\u65b0\u53cd\u5e94\u7c7b\u578b\u7684\u63a2\u7a76\uff0c\u8fdb\u4e00\u6b65\u4e30\u5bcc\u5176\u53cd\u5e94\u6d3b\u6027\uff0c\u62d3\u5c55\u4e86\u5176\u5408\u6210\u548c\u5e94\u7528\u4ef7\u503c\u3002\u8be5Cu(III)-CF<sub>3<\/sub>\u5316\u5408\u7269\/DMSO\u534f\u540c\u7b56\u7565\uff0c\u6709\u671b\u5e94\u7528\u4e8e\u5176\u4ed6\u53cd\u5e94\u4e2d\uff0c\u53d1\u5c55\u51fa\u6709\u4ef7\u503c\u7684\u65b0\u53cd\u5e94\u3002\u540e\u7eed\u76f8\u5173\u7814\u7a76\u6b63\u5728\u8fdb\u884c\u4e2d\uff0c\u5e76\u53d6\u5f97\u4e86\u521d\u6b65\u6210\u529f\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section><strong>\u8bba<\/strong><strong>\u6587\u4fe1\u606f<\/strong><\/p>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section><\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>Cu(III)-CF<sub>3<\/sub>\u00a0Compound-Activated DMSO: An Efficient Oxidizing Reagent to Convert Alcohols to Ketones<\/p>\n<p>Yi-Feng Hou,\u00a0Song-Lin Zhang<\/p>\n<p>\u672c\u8bba\u6587\u7684\u7b2c\u4e00\u4f5c\u8005\u662f\u6c5f\u5357\u5927\u5b662021\u7ea7\u7855\u58eb\u7814\u7a76\u751f\u4faf\u827a\u950b\u540c\u5b66\uff0c\u8d1f\u8d23\u5168\u90e8\u7684\u5b9e\u9a8c\u5de5\u4f5c\u548c\u6570\u636e\u5206\u6790\uff0c\u901a\u8baf\u4f5c\u8005\u662f\u5f20\u677e\u6797\u6559\u6388\uff0c\u6307\u5bfc\u8be5\u8bfe\u9898\u7684\u8bbe\u8ba1\uff0c\u534f\u52a9\u5b8c\u6210\u6570\u636e\u5206\u6790\uff0c\u4ee5\u53ca\u8d1f\u8d23\u8bba\u6587\u7684\u64b0\u5199\u548c\u6295\u7a3f\u53d1\u8868\u3002<\/p>\n<p><em>European Journal of Organic Chemistry\u00a0<\/em><\/p>\n<p>DOI:\u00a010.1002\/ejoc.202400097<\/p>\n<\/section>\n<\/section>\n<\/section>\n","protected":false},"excerpt":{"rendered":"<p>\u9ad8\u4ef7\u6001Cu(III)-CF3\u5316\u5408\u7269\u662f\u94dc\u4fc3\u8fdb\u7684\u4e09\u6c1f\u7532\u57fa\u5316\u53cd\u5e94\u7684\u5173\u952e\u4e2d\u95f4\u4f53\u3002\u8fd1\u5e74\u6765\uff0c\u5173\u4e8eCu(III)-CF3\u5316\u5408 [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-51515","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51515","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=51515"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51515\/revisions"}],"predecessor-version":[{"id":51516,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51515\/revisions\/51516"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=51515"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=51515"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=51515"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}