{"id":51508,"date":"2024-05-26T08:30:15","date_gmt":"2024-05-26T00:30:15","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=51508"},"modified":"2024-05-17T10:34:54","modified_gmt":"2024-05-17T02:34:54","slug":"%e4%ba%94%e9%82%91%e5%a4%a7%e5%ad%a6%e5%bd%ad%e5%a3%ab%e5%8b%87%e8%af%be%e9%a2%98%e7%bb%84%ef%bc%9abc6f53%e5%82%ac%e5%8c%96%e7%9a%84%e5%8f%8c%e7%8e%af1-1-0%e4%b8%81%e7%83%b7%e5%8f%82%e4%b8%8e","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/%e4%ba%94%e9%82%91%e5%a4%a7%e5%ad%a6%e5%bd%ad%e5%a3%ab%e5%8b%87%e8%af%be%e9%a2%98%e7%bb%84%ef%bc%9abc6f53%e5%82%ac%e5%8c%96%e7%9a%84%e5%8f%8c%e7%8e%af1-1-0%e4%b8%81%e7%83%b7%e5%8f%82%e4%b8%8e\/","title":{"rendered":"\u4e94\u9091\u5927\u5b66\u5f6d\u58eb\u52c7\u8bfe\u9898\u7ec4\uff1aB(C6F5)3\u50ac\u5316\u7684\u53cc\u73af[1.1.0]\u4e01\u70f7\u53c2\u4e0e\u7684\uff08n+3\uff09(n = 5\u548c6)\u73af\u52a0\u6210\u53cd\u5e94"},"content":{"rendered":"<section>\u25b2\u5171\u540c\u7b2c\u4e00\u4f5c\u8005\uff1a\u6768\u4eae\u4eae\u3001\u6c6a\u6d77\u9633<\/section>\n<section>\u901a\u8baf\u4f5c\u8005\uff1a\u5f6d\u58eb\u52c7<\/section>\n<section>\u901a\u8baf\u5355\u4f4d\uff1a\u4e94\u9091\u5927\u5b66<\/section>\n<section>\u8bba\u6587DOI\uff1a10.1021\/acs.orglett.4c01219\u00a0\uff08\u70b9\u51fb\u6587\u672b\u300c\u9605\u8bfb\u539f\u6587\u300d\uff0c\u76f4\u8fbe\u94fe\u63a5\uff09<\/section>\n<section><\/section>\n<section data-mpa-template=\"t\">\n<section data-mpa-template=\"t\">\n<section>\n<section data-mpa-category=\"\u6a21\u677f\" data-mid=\"\">\n<section data-mid=\"\">\n<section data-mid=\"\"><\/section>\n<section data-mid=\"\">\u00a0\u00a0<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section><strong>\u5168\u6587\u901f\u89c8<\/strong><\/section>\n<section>\u8fd1\u65e5\uff0c\u5f6d\u58eb\u52c7\u8bfe\u9898\u7ec4\u5728\u54aa\u5511\u70f7\u53c2\u4e0e\u7684\u73af\u52a0\u6210\u53cd\u5e94\u4e2d\u53c8\u53d6\u5f97\u4e86\u91cd\u5927\u7a81\u7834\uff0c\u5b9e\u73b0\u4e86\u54aa\u5511\u70f7\u4e0e\u53cc\u73af[1.1.0]\u4e01\u70f7\u7684\u5076\u6781\u73af\u52a0\u6210\u53cd\u5e94\uff0c\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u8fd9\u4e5f\u662f\u53cc\u73af[1.1.0]\u4e01\u70f7\u9996\u6b21\u62a5\u9053\u7684\u9ad8\u9636\u5076\u6781\u73af\u52a0\u6210\u53cd\u5e94\u3002<\/section>\n<section><\/section>\n<section data-mpa-template=\"t\">\n<section data-mpa-template=\"t\">\n<section>\n<section data-mpa-category=\"\u6a21\u677f\" data-mid=\"\">\n<section data-mid=\"\">\n<section data-mid=\"\"><\/section>\n<section data-mid=\"\">\u00a0\u00a0<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section><strong>\u80cc\u666f\u4ecb\u7ecd<\/strong><\/section>\n<section>\u6865\u73af\u4f53\u7cfb\u4f5c\u4e3a\u6bcd\u6838\u7ed3\u6784\u5e7f\u6cdb\u5b58\u5728\u4e8e\u5929\u7136\u4ea7\u7269\u3001\u836f\u7269\u5206\u5b50\u4ee5\u53ca\u4e00\u4e9b\u751f\u7269\u6d3b\u6027\u5206\u5b50\u4e2d\uff0c\u56e0\u6b64\uff0c\u5982\u4f55\u4e00\u6b65\u6784\u5efa\u6865\u73af\u9aa8\u67b6\u5bf9\u4e8e\u836f\u7269\u7814\u53d1\u6709\u7740\u6781\u4e3a\u91cd\u8981\u7684\u610f\u4e49\u3002\u53cc\u73af[1.1.0]\u4e01\u70f7(BCB)\u7531\u4e8e\u81ea\u8eab\u72ec\u7279\u7684\u5316\u5b66\u6027\u8d28\uff0c\u53ef\u4ee5\u901a\u8fc7\u80fd\u91cf\u8f6c\u79fb\u3001\u5355\u7535\u5b50\u8f6c\u79fb\u548c\u53cc\u7535\u5b50\u53c2\u4e0e\u7684\u5404\u79cd\u7b56\u7565\u5b9e\u73b0(n+3)\u73af\u52a0\u6210\u53cd\u5e94(\u56fe1A)\u3002<\/section>\n<section><\/section>\n<section>\u7531\u4e8e\u4e2d\u73af\u4f53\u7cfb\u7684\u78b3(\u6742)\u73af\u5316\u5408\u7269\u5177\u6709\u8f83\u5927\u7684\u73af\u5f20\u529b\uff0c\u6240\u4ee5\u5408\u6210\u8be5\u7c7b\u5316\u5408\u7269\u4e5f\u9762\u4e34\u7740\u5de8\u5927\u7684\u6311\u6218\u3002\u6839\u636e\u5f6d\u58eb\u52c7\u8bfe\u9898\u7ec4\u4e4b\u524d\u7684\u7814\u7a76\uff0c\u5df2\u7ecf\u5b9e\u73b0\u4e86\u54aa\u5511\u70f7\u4e0e\u4f9b\u4f53-\u53d7\u4f53\u73af\u4e19\u70f7(<span class=\"wx_search_keyword_wrap\">DAC<\/span>)\u7684(5+3)\u73af\u52a0\u6210\u53cd\u5e94\uff0c\u6210\u529f\u7684\u6784\u5efa\u4e86\u9971\u548c1,4-\u4e8c\u6c2e\u6742\u58ec\u70f7\u5316\u5408\u7269\uff0c\u5e76\u4e14\u5728\u57fa\u4e8e\u8def\u6613\u65af\u9178\u50ac\u5316\u4e0b\u53cc\u73af[1.1.0]\u4e01\u70f7\u4e0e\u4f9b\u4f53-\u53d7\u4f53\u73af\u4e19\u70f7\u7684\u53cd\u5e94\u6d3b\u6027\u7684\u76f8\u4f3c\u6027\uff0c\u8fdb\u4e00\u6b65\u63d0\u51fa\u54aa\u5511\u70f7\u80fd\u591f\u4e0e\u53cc\u73af[1.1.0]\u4e01\u70f7\u53d1\u751f\u5076\u6781\u73af\u5316\u8fdb\u800c\u6784\u5efa\u51fa\u4e2d\u7b49\u6865\u73af\u9aa8\u67b6\u4f53\u7cfb\u7684\u53ef\u80fd\u6027\u3002(\u56fe1B)\u3002<\/section>\n<section><\/section>\n<section><img decoding=\"async\" title=\"1\" src=\"https:\/\/17332.seohost.cn\/storage\/17332\/article\/20240517\/1715913206399956.png\" alt=\"1\" \/>\u56fe1 \u7814\u7a76\u80cc\u666f<\/section>\n<section><\/section>\n<section data-mpa-template=\"t\">\n<section data-mpa-template=\"t\">\n<section>\n<section data-mpa-category=\"\u6a21\u677f\" data-mid=\"\">\n<section data-mid=\"\">\n<section data-mid=\"\"><\/section>\n<section data-mid=\"\">\u00a0\u00a0<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section><strong>\u672c\u6587\u4eae\u70b9<\/strong><\/section>\n<section>\u4f5c\u8005\u901a\u8fc7\u4f7f\u7528\u975e\u91d1\u5c5e\u7684\u8def\u6613\u65af\u9178B(C<sub>6<\/sub>F<sub>5<\/sub>)<sub>3<\/sub>\u4e3a\u50ac\u5316\u5242\uff0c\u514b\u670d\u4e86\u4e2d\u73af\u4f53\u7cfb\u5316\u5408\u7269\u5b58\u5728\u7684\u73af\u5f20\u529b\u95ee\u9898\uff0c\u5b9e\u73b0\u4e86\u54aa\u5511\u70f7\/\u516d\u6c22\u5627\u5576\u4e0e\u53cc\u73af\u4e01\u70f7\u7684\uff085+3\uff09\u548c\uff086+3\uff09\u73af\u5316\u53cd\u5e94\uff0c\u6210\u529f\u7684\u6784\u7b51\u4e86[5.1.1]\u58ec\u70f7\u548c[6.1.1]\u7678\u70f7\u5316\u5408\u7269\u3002<\/section>\n<section><\/section>\n<section data-mpa-template=\"t\">\n<section data-mpa-template=\"t\">\n<section>\n<section data-mpa-category=\"\u6a21\u677f\" data-mid=\"\">\n<section data-mid=\"\">\n<section data-mid=\"\"><\/section>\n<section data-mid=\"\">\u00a0\u00a0<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section><strong>\u56fe\u6587\u89e3\u6790<\/strong><\/section>\n<section>\u4f5c\u8005\u9996\u5148\u4ee5\u53cc\u73af[1.1.0]\u4e01\u70f7<strong>1a<\/strong>\u548c\u54aa\u5511\u70f7<strong>2a<\/strong>\u4f5c\u4e3a\u6a21\u677f\u5e95\u7269\u5bf9\u53cd\u5e94\u6761\u4ef6\u8fdb\u884c\u4e86\u4f18\u5316\uff0c\u5728\u6700\u4f18\u7684\u53cd\u5e94\u6761\u4ef6\u4e0b\uff0c\u4ee581%\u7684\u5206\u79bb\u6536\u7387\uff0c\u751f\u6210\u4ea7\u7269<strong>4aa<\/strong>\uff08\u88681\uff09\u3002<\/section>\n<section><\/section>\n<section><img decoding=\"async\" title=\"2\" src=\"https:\/\/17332.seohost.cn\/storage\/17332\/article\/20240517\/1715913216704939.png\" alt=\"2\" \/><\/section>\n<section>\u88681 \u6761\u4ef6\u7b5b\u9009<\/section>\n<section><img decoding=\"async\" title=\"3\" src=\"https:\/\/17332.seohost.cn\/storage\/17332\/article\/20240517\/1715913223344442.png\" alt=\"3\" \/><\/section>\n<section><em><sup>a<\/sup><\/em>Reaction conditions:<strong>1a<\/strong>(0.15 mmol),<strong>2a<\/strong>(0.1 mmol), catalyst (20 mol%), solvent (1.0 mL), rt, 2 h.<em><sup>b<\/sup><\/em>Isolated yields.<em><sup>c<\/sup><\/em>At 40<sup>o<\/sup>C.<em><sup>d<\/sup><\/em>At 0<sup>o<\/sup>C for 12 h.<em><sup>e<\/sup><\/em>CH<sub>2<\/sub>Cl<sub>2<\/sub>(2.0 mL).<\/section>\n<section><\/section>\n<section>\u5728\u4e0a\u8ff0\u7684\u6700\u4f73\u53cd\u5e94\u6761\u4ef6\u4e0b\uff0c\u4f5c\u8005\u5bf9\u4e00\u7cfb\u5217BCB\u5e95\u7269\u7684\u5e94\u7528\u8303\u56f4\u8fdb\u884c\u4e86\u6df1\u5165\u7814\u7a76\u3002\u5f53\u82b3\u916e\u82b3\u73af\u4e0a\u5177\u6709\u7ed9\u7535\u5b50\u6216\u5438\u7535\u5b50\u53d6\u4ee3\u57fa\u3001\u6742\u73af\u53d6\u4ee3\u57fa\u65f6\uff0c\u5747\u80fd\u4ee5\u4e2d\u7b49\u81f3\u826f\u597d\u7684\u6536\u7387\u5f97\u5230\u76ee\u6807\u4ea7\u7269\u3002\u6b64\u5916\uff0c\u8102\u80aa\u916e\u5305\u62ec\u94fe\u72b6\u8102\u80aa\u70c3\u3001\u73af\u70f7\u70c3\u3001\u70ef\u70c3\u548c\u7094\u70c3\u90fd\u5c55\u73b0\u51fa\u826f\u597d\u7684\u5e95\u7269\u9002\u7528\u6027\uff0c\u5c06BCB\u66ff\u6362\u4e3a1,3-\u4e8c\u53d6\u4ee3BCB\u65f6\uff0c\u4f9d\u7136\u80fd\u591f\u4ee5\u826f\u597d\u7684\u6536\u7387\u83b7\u5f97\u76ee\u6807\u4ea7\u7269(\u56fe2)\u3002<\/section>\n<section><\/section>\n<section><img decoding=\"async\" title=\"4\" src=\"https:\/\/17332.seohost.cn\/storage\/17332\/article\/20240517\/1715913234795855.png\" alt=\"4\" \/>\u56fe2 (5+3)\u5e95\u7269\u62d3\u5c55<\/section>\n<section><\/section>\n<section>\u968f\u540e\u4f5c\u8005\u8003\u5bdf\u4e86\u54aa\u5511\u70f7\u6c2e\u539f\u5b50\u4e0a\u4e0d\u540c\u53d6\u4ee3\u57fa\u5bf9\u4e8e\u8be5\u53cd\u5e94\u7684\u5f71\u54cd\uff0c\u65e0\u8bba\u662f\u70f7\u57fa\u54aa\u5511\u70f7\u8fd8\u662f\u82b3\u57fa\u54aa\u5511\u70f7\uff0c\u5e95\u7269\u5747\u80fd\u591f\u987a\u5229\u8f6c\u5316\uff0c\u5f97\u5230\u76f8\u5e94\u7684\u6865\u73af\u5316\u5408\u7269\u3002\u7d27\u63a5\u7740\u4f5c\u8005\u4e5f\u5408\u6210\u4e86\u4e00\u4e9b\u975e\u5bf9\u79f0\u7684\u54aa\u5511\u70f7\u8fdb\u800c\u8003\u5bdf\u4e86\u7535\u5b50\u6548\u5e94\u548c\u4f4d\u963b\u6548\u5e94\u5bf9\u533a\u57df\u9009\u62e9\u6027\u7684\u5f71\u54cd(\u56fe3)\u3002<\/section>\n<section><\/section>\n<section><img decoding=\"async\" title=\"5\" src=\"https:\/\/17332.seohost.cn\/storage\/17332\/article\/20240517\/1715913242819371.png\" alt=\"5\" \/>\u56fe3 (5+3)\u5e95\u7269\u62d3\u5c55<\/section>\n<section><\/section>\n<section>\u6839\u636e\u5f6d\u58eb\u52c7\u8bfe\u9898\u7ec4\u4e4b\u524d\u7684\u7814\u7a76\u7ed3\u679c\uff0c\u54aa\u5511\u70f7\u7684\u540c\u7cfb\u7269\u516d\u6c22\u5627\u5576\u53ef\u4ee5\u4f5c\u4e3a1,6-\u5076\u6781\u524d\u4f53\u3002\u4f5c\u8005\u5728\u6807\u51c6\u6761\u4ef6\u4e0b\u5bf9\u53cd\u5e94\u8fdb\u884c\u4e86\u5c1d\u8bd5\uff0c\u5e78\u8fd0\u7684\u662f\uff0c\u4e0a\u8ff0\u50ac\u5316\u6761\u4ef6\u540c\u6837\u9002\u7528\u4e8e\u8be5(6+3)\u73af\u5316\u8fc7\u7a0b(\u56fe4)\u3002<\/section>\n<section><\/section>\n<section><img decoding=\"async\" title=\"6\" src=\"https:\/\/17332.seohost.cn\/storage\/17332\/article\/20240517\/1715913252492958.png\" alt=\"6\" \/>\u56fe4\u00a0 (6+3)\u5e95\u7269\u62d3\u5c55<\/section>\n<section><\/section>\n<section>\u968f\u540e\uff0c\u4f5c\u8005\u8fdb\u884c\u4e86\u6beb\u6469\u5c14\u7ea7\u653e\u5927\u53cd\u5e94\u4ee5\u53ca\u4ea7\u7269\u7684\u591a\u6837\u6027\u8f6c\u5316\uff0c\u572810 mmol\u7684\u53cd\u5e94\u89c4\u6a21\u4e0b\uff0c\u6807\u51c6\u6761\u4ef6\u4e0b\u4f9d\u7136\u80fd\u4ee577%\u7684\u6536\u7387\u83b7\u5f97\u76ee\u6807\u4ea7\u7269\uff0c\u4ea7\u7269<strong>4aa<\/strong>\u7684\u7fb0\u57fa\u53ef\u4ee5\u9ad8\u6548\u7684\u53d1\u751f\u7f29\u5408\u53cd\u5e94\u3001\u683c\u6c0f\u53cd\u5e94\u3001<span class=\"wx_search_keyword_wrap\">Wittig\u53cd\u5e94<\/span>\u4ee5\u53ca\u6c22\u5316\u53cd\u5e94\uff0c\u4e14\u6865\u73af\u9aa8\u67b6\u5e76\u672a\u53d7\u5230\u5f71\u54cd\u3002\u6700\u540e\u901a\u8fc7\u4f7f\u7528\u6c2f\u7532\u9178\u6c2f\u4e59\u916f\u7ecf\u8fc7\u4e24\u6b65\u4e00\u9505\u6cd5\u4ee5\u5b9a\u91cf\u7684\u6536\u7387\u5f97\u5230\u9009\u62e9\u6027\u82c4\u57fa\u8131\u9664\u7684\u4ea7\u7269\uff0c\u8fdb\u800c\u80fd\u591f\u9009\u62e9\u6027\u7684\u5728\u6865\u73af\u6c2e\u539f\u5b50\u4e0a\u5f15\u5165\u836f\u6548\u5206\u5b50\uff0c\u5c55\u793a\u4e86\u5176\u5728\u5408\u6210\u4e2d\u7684\u6f5c\u5728\u5e94\u7528\u6027(\u56fe5)\u3002<\/section>\n<section><\/section>\n<section><img decoding=\"async\" title=\"7\" src=\"https:\/\/17332.seohost.cn\/storage\/17332\/article\/20240517\/1715913265852885.png\" alt=\"7\" \/>\u56fe5\u8f6c\u5316\u5e94\u7528<\/section>\n<section><\/section>\n<section>\u6700\u540e\uff0c\u4f5c\u8005\u901a\u8fc7\u8bbe\u8ba1\u5bf9\u7167\u8bd5\u9a8c\uff0c\u8bc1\u660e\u8be5\u53cd\u5e94\u662f\u901a\u8fc7\u8def\u6613\u65af\u9178B(C<sub>6<\/sub>F<sub>5<\/sub>)<sub>3<\/sub>\u5bf9BCB\u8fdb\u884c\u6d3b\u5316\u8fdb\u800c\u53d7\u5230\u54aa\u5511\u70f7\u7684\u4eb2\u6838\u8fdb\u653b\u800c\u53d1\u751f\u73af\u5316\u7684\u53cd\u5e94\u8def\u5f84\u83b7\u5f97\u76ee\u6807\u5206\u5b50\uff0c\u800c\u975e\u6b64\u524d\u7531Leitch\u3001Studer\u4ee5\u53caGlorius\u6240\u62a5\u9053\u7684BCB\u5f00\u73af\u751f\u6210\u5076\u6781\u5b50\u518d\u53bb\u8fdb\u653b\u53e6\u4e00\u5e95\u7269\u7684\u65b9\u5f0f\u3002\u6839\u636e\u5b9e\u9a8c\u7ed3\u679c\uff0c\u4f5c\u8005\u63d0\u51fa\u4e86\u53ef\u80fd\u7684\u53cd\u5e94\u673a\u5236(\u56fe6)\u3002<\/section>\n<section><\/section>\n<section><img decoding=\"async\" title=\"8\" src=\"https:\/\/17332.seohost.cn\/storage\/17332\/article\/20240517\/1715913276381876.png\" alt=\"8\" \/>\u200b\u56fe6 \u5bf9\u7167\u8bd5\u9a8c\u53ca\u53ef\u80fd\u7684\u673a\u5236<\/section>\n<section><\/section>\n<section data-mpa-template=\"t\">\n<section data-mpa-template=\"t\">\n<section>\n<section data-mpa-category=\"\u6a21\u677f\" data-mid=\"\">\n<section data-mid=\"\">\n<section data-mid=\"\"><\/section>\n<section data-mid=\"\">\u00a0\u00a0<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section><strong>\u603b\u7ed3\u4e0e\u5c55\u671b<\/strong><\/section>\n<section>\u5f6d\u58eb\u52c7\u8bfe\u9898\u7ec4\u62a5\u9053\u4e86\u5728\u6e29\u548c\u7684\u6761\u4ef6\u4e0b\u4ee5\u975e\u91d1\u5c5e\u8def\u6613\u65af\u9178B(C<sub>6<\/sub>F<sub>5<\/sub>)<sub>3<\/sub>\u4e3a\u50ac\u5316\u5242\uff0c\u5b9e\u73b0\u4e86\u54aa\u5511\u70f7\u4e0e\u53cc\u73af[1.1.0]\u4e01\u70f7\u7684(5+3)\u5076\u6781\u73af\u52a0\u6210\u53cd\u5e94\uff0c\u53cd\u5e94\u5177\u6709\u4f18\u826f\u7684\u5e95\u7269\u666e\u9002\u6027\u3002\u8fdb\u4e00\u6b65\u5730\u5728\u8be5\u6761\u4ef6\u4e0b\u5b9e\u73b0\u4e86\u516d\u6c22\u5627\u5576\u4e0e\u53cc\u73af[1.1.0]\u4e01\u70f7\u7684(6+3)\u5076\u6781\u73af\u52a0\u6210\u53cd\u5e94\uff0c\u5f97\u5230\u4e86\u4e00\u7cfb\u52172,6-\u4e8c\u6c2e\u53cc\u73af[6.1.1]\u7678\u70f7\u5316\u5408\u7269\u3002\u636e\u6211\u4eec\u6240\u77e5\uff0c\u8fd9\u662f\u53cc\u73af[1.1.0]\u4e01\u70f7\u53c2\u4e0e\u7684\u9996\u6b21\u9ad8\u9636\u5076\u6781\u73af\u52a0\u53cd\u5e94\uff0c\u4e3a\u4ee5\u540e\u57fa\u4e8e\u53cc\u73af[1.1.0]\u4e01\u70f7\u53c2\u4e0e\u9ad8\u9636\u5076\u6781\u73af\u52a0\u6210\u53cd\u5e94\u6253\u4e0b\u4e86\u57fa\u7840\u3002<\/section>\n<section><\/section>\n<section data-mpa-template=\"t\">\n<section data-mpa-template=\"t\">\n<section>\n<section data-mpa-category=\"\u6a21\u677f\" data-mid=\"\">\n<section data-mid=\"\">\n<section data-mid=\"\"><\/section>\n<section data-mid=\"\">\u00a0\u00a0<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section><strong>\u8bfe\u9898\u7ec4\u4ecb\u7ecd<\/strong><\/section>\n<section>\u4e94\u9091\u5927\u5b66\u836f\u5b66\u4e0e\u98df\u54c1\u5de5\u7a0b\u5b66\u9662\u5f6d\u58eb\u52c7\u8bfe\u9898\u7ec4\u6210\u7acb\u4e8e2017\u5e74\uff0c\u7814\u7a76\u65b9\u5411\u4e3a\u91d1\u5c5e\u6709\u673a\u5316\u5b66\uff0c\u4e0d\u5bf9\u79f0\u5408\u6210\u3002\u73b0\u5df2\u5728<em>ACS Catal., Org. Lett., J. Org. Chem.<\/em>\u7b49\u671f\u520a\u53d1\u8868\u76f8\u5173\u5b66\u672f\u8bba\u658730\u4f59\u7bc7\uff0c\u4e3b\u6301\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\uff0c\u5e7f\u4e1c\u7701\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u3001\u5e7f\u4e1c\u7701\u6559\u80b2\u5385\u3001\u4e94\u9091\u5927\u5b66\u9ad8\u5c42\u6b21\u4eba\u624d\u9879\u76ee5\u9879\u3002<\/section>\n<section><\/section>\n<section>\u8be6\u89c1\u8bfe\u9898\u7ec4\u4e3b\u9875\uff1a<\/section>\n<section>https:\/\/www.x-mol.com\/groups\/peng_shiyong<\/section>\n","protected":false},"excerpt":{"rendered":"<p>\u25b2\u5171\u540c\u7b2c\u4e00\u4f5c\u8005\uff1a\u6768\u4eae\u4eae\u3001\u6c6a\u6d77\u9633 \u901a\u8baf\u4f5c\u8005\uff1a\u5f6d\u58eb\u52c7 \u901a\u8baf\u5355\u4f4d\uff1a\u4e94\u9091\u5927\u5b66 \u8bba\u6587DOI\uff1a10.1021\/acs.or [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-51508","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51508","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=51508"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51508\/revisions"}],"predecessor-version":[{"id":51509,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51508\/revisions\/51509"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=51508"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=51508"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=51508"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}