{"id":51502,"date":"2024-05-25T08:35:34","date_gmt":"2024-05-25T00:35:34","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=51502"},"modified":"2024-05-16T10:35:53","modified_gmt":"2024-05-16T02:35:53","slug":"eurjoc%ef%bc%9a%e5%90%a1%e5%92%af%e5%b9%b621-a%e5%bc%82%e5%96%b9%e5%95%89%e8%a1%8d%e7%94%9f%e7%89%a9%e7%9a%84%e7%a1%9d%e5%9f%ba%e5%8c%96%e4%bf%ae%e9%a5%b0","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/eurjoc%ef%bc%9a%e5%90%a1%e5%92%af%e5%b9%b621-a%e5%bc%82%e5%96%b9%e5%95%89%e8%a1%8d%e7%94%9f%e7%89%a9%e7%9a%84%e7%a1%9d%e5%9f%ba%e5%8c%96%e4%bf%ae%e9%a5%b0\/","title":{"rendered":"EurJOC\uff1a\u5421\u54af\u5e76[2,1-a]\u5f02\u55b9\u5549\u884d\u751f\u7269\u7684\u785d\u57fa\u5316\u4fee\u9970"},"content":{"rendered":"<section>\n<section>\n<section>\n<section>\n<section>\u785d\u57fa\u53d6\u4ee3\u7684\u82b3\u70c3\u548c\u6742\u82b3\u70c3\u662f\u591a\u79cd\u751f\u7406\u6d3b\u6027\u5316\u5408\u7269\u3001\u67d3\u6599\u3001\u519c\u836f\u548c\u5176\u4ed6\u529f\u80fd\u5206\u5b50\u7684\u91cd\u8981\u7ed3\u6784\u5355\u5143\u3002\u4e0d\u4ec5\u5982\u6b64\uff0c\u785d\u57fa\u82b3\u70c3\u548c\u785d\u57fa\u6742\u82b3\u70c3\u4e5f\u53ef\u7ecf\u8fd8\u539f\u3001\u5076\u8054\u3001\u53d6\u4ee3\u3001\u52a0\u6210\u7b49\u591a\u6837\u6027\u5316\u5b66\u8f6c\u5316\uff0c\u8fdb\u800c\u6784\u5efa\u9ad8\u5ea6\u5b98\u80fd\u56e2\u5316\u7684\u6709\u673a\u5206\u5b50\u3002\u9274\u4e8e\u785d\u57fa\u82b3\u9999\u5316\u5408\u7269\u7684\u91cd\u8981\u6027\uff0c\u53d1\u5c55\u7eff\u8272\u73af\u4fdd\u7684\u82b3\u70c3\u548c\u6742\u82b3\u70c3\u76f4\u63a5\u785d\u57fa\u5316\u53cd\u5e94\u65b9\u6cd5\u5b66\u548c\u5bfb\u627e\u9ad8\u6548\u4f4e\u6210\u672c\u7684\u785d\u57fa\u5316\u8bd5\u5242\u4e5f\u5f97\u5230\u4e86\u5316\u5b66\u5bb6\u4eec\u7684\u666e\u904d\u91cd\u89c6\u3002\u4e9a\u785d\u9178\u94a0\uff08NaNO<sub>2<\/sub>\uff09\u662f\u4e00\u79cd\u5ec9\u4ef7\u6613\u5f97\u7684\u785d\u57fa\u6e90\uff0c\u8fd1\u6765\u88ab\u6210\u529f\u7528\u4e8e\u915a\u7c7b\u3001\u82b3\u9999\u80fa\u7c7b\u548c\u5432\u54da\u7c7b\u5316\u5408\u7269\u7b49\u7684\u785d\u57fa\u5316\u53cd\u5e94\u3002<\/p>\n<p>\u5421\u54af\u5e76[2,1-a]<span class=\"wx_search_keyword_wrap\">\u5f02\u55b9\u5549<\/span>\u4f5c\u4e3a\u4e00\u79cd\u7ed3\u5408\u4e86\u5421\u54af\u548c\u5f02\u55b9\u5549\u7684\u91cd\u8981\u6bcd\u6838\u7ed3\u6784\u5e38\u89c1\u4e8e\u591a\u79cd\u6d77\u6d0b\u5929\u7136\u4ea7\u7269\u7247\u87ba\u7d20\u5206\u5b50\u548c\u5408\u6210\u6d3b\u6027\u5316\u5408\u7269\u3002\u7136\u800c\uff0c\u4e0d\u540c\u4e8e<span class=\"wx_search_keyword_wrap\">\u5432\u54da<\/span>\u3001\u5421\u54af\u3001\u5f02\u55b9\u5549\u548c\u55b9\u5549\u7b49\u4f18\u52bf\u6bcd\u6838\u7684\u5316\u5b66\u53cd\u5e94\u63a2\u7a76\uff0c\u5421\u54af\u5e76[2,1-a]\u5f02\u55b9\u5549\u884d\u751f\u7269\u7684\u8fdb\u4e00\u6b65\u4fee\u9970\u5c1a\u65e0\u6df1\u5165\u63a2\u7d22\u3002\u4e3a\u63ed\u793a\u8be5\u7c7b\u6742\u73af\u5316\u5408\u7269\u7684\u53cd\u5e94\u5316\u5b66\u3001\u540c\u65f6\u63d0\u4f9b\u53ef\u4ee5\u5728\u591a\u4e2a\u7814\u7a76\u9886\u57df\u6709\u5e94\u7528\u6f5c\u529b\u7684\u4fee\u9970\u884d\u751f\u7269\uff0c\u5bf9\u5421\u54af\u5e76[2,1-a]\u5f02\u55b9\u5549\u591a\u6837\u5316\u4fee\u9970\u7814\u7a76\u6781\u5177\u4ef7\u503c\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<p>&nbsp;<\/p>\n<p>&nbsp;<\/p>\n<section>\n<section><\/section>\n<\/section>\n<p>&nbsp;<\/p>\n<p>&nbsp;<\/p>\n<section><img decoding=\"async\" title=\"1\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240413\/1713010158114662.webp\" alt=\"1\" \/><\/section>\n<section>Scheme 1.<\/p>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u91cd\u5e86\u6587\u7406\u5b66\u9662\u5d14\u6d77\u78ca\u8bfe\u9898\u7ec4\u548c\u91cd\u5e86\u79d1\u6280\u5927\u5b66\u88f4\u53d4\u5bb8\u8bfe\u9898\u7ec4\u5408\u4f5c\uff0c\u5728\u5df2\u5b8c\u6210\u785d\u9178\u94c8\u94f5\u3001\u785d\u9178\u94dc\u548c\u785d\u9178\u94c1\u4ecb\u5bfc\u7684\u785d\u57fa\u5316\u53cd\u5e94\u57fa\u7840\u4e0a\u7ee7\u7eed\u53d1\u6398\u4e86\u4e9a\u785d\u9178\u94a0\/<span class=\"wx_search_keyword_wrap\">\u516d\u6c1f\u5f02\u4e19\u9187<\/span>\uff08NaNO<sub>2<\/sub>\/HFIP\uff09\u4f5c\u4e3a\u4e00\u79cd\u6e29\u548c\u7684\u785d\u57fa\u5316\u4f53\u7cfb\u3002\u8be5\u53cd\u5e94\u4f53\u7cfb\u53ef\u4ee5\u5728\u73af\u5883\u6e29\u5ea6\u4e0b\u5bf9\u4e00\u7cfb\u5217\u5421\u54af\u5e76[2,1-a]\u5f02\u55b9\u5549\u884d\u751f\u7269\u8fdb\u884c\u785d\u57fa\u5316\u4fee\u9970\uff0c\u4ee5\u4e2d\u7b49\u5230\u8f83\u597d\u7684\u6536\u7387\u5f97\u5230\u6240\u6c42\u4ea7\u7269\u3002\u7ecf\u7b80\u5355\u7684\u8fd8\u539f\u548c\u9170\u5316\u53cd\u5e94\u53ef\u4ee5\u5f97\u5230\u666e\u901a\u65b9\u6cd5\u96be\u4ee5\u6784\u5efa\u7684\u542b\u4f2f\u80fa\u57fa\u56e2\u548c\u9170\u80fa\u57fa\u56e2\u7684\u5421\u54af\u5e76[2,1-a]\u5f02\u55b9\u5549\u884d\u751f\u7269\u3002\u4f46\u662f\uff0c\u8be5\u4f53\u7cfb\u5bf9\u5176\u4ed6\u5bcc\u7535\u5b50\u6742\u82b3\u70c3\u7684\u785d\u57fa\u5316\u4fee\u9970\u4ecd\u6709\u7f3a\u9677\uff1a\u5f53\u8be5\u65b9\u6cd5\u62d3\u5c55\u81f3\u5432\u54da\u7c7b\u5e95\u7269\u65f6\uff0c\u53ea\u5f97\u5230\u8f83\u4f4e\u6536\u7387\u3002\u57fa\u4e8e\u5df2\u6709\u6587\u732e\u62a5\u9053\u548c\u673a\u7406\u5b9e\u9a8c\uff0c\u4f5c\u8005\u8ba4\u4e3a<span class=\"wx_search_keyword_wrap\">\u4e8c\u6c27\u5316\u6c2e<\/span>\u7684\u539f\u4f4d\u4ea7\u751f\u662f\u8be5\u53cd\u5e94\u7684\u5173\u952e\u6240\u5728\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"6\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240413\/1713010158869658.webp\" alt=\"6\" \/><\/section>\n<section>Scheme 2.<\/p>\n<\/section>\n<section>\n<section>\n<section>\n<section><strong>\u8bba<\/strong><strong>\u6587\u4fe1\u606f<\/strong><\/p>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section><\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>Nitration of Pyrrolo[2,1\u2010a]isoquinolines with NaNO<sub>2<\/sub>\/HFIP<\/p>\n<p>Xiang Huang, Yun-Meng Li, Jing Zhou, Yu-Yi Pan, Wei Li, Xin Yu, Xiao-Hui Chen, Shu-Chen Pei, Hai-Lei Cui<\/p>\n<p>\u8bba\u6587\u5171\u540c\u7b2c\u4e00\u4f5c\u8005\u4e3a\u91cd\u5e86\u79d1\u6280\u5927\u5b66\u7814\u7a76\u751f\u9ec4\u6e58\u548c\u91cd\u5e86\u6587\u7406\u5b66\u9662\u5927\u4e09\u672c\u79d1\u751f\u674e\u4e91\u68a6<\/p>\n<p><em>European Journal of Organic Chemistry<\/em><\/p>\n<p>DOI: 10.1002\/ejoc.202400116<\/p>\n<\/section>\n<\/section>\n<\/section>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u785d\u57fa\u53d6\u4ee3\u7684\u82b3\u70c3\u548c\u6742\u82b3\u70c3\u662f\u591a\u79cd\u751f\u7406\u6d3b\u6027\u5316\u5408\u7269\u3001\u67d3\u6599\u3001\u519c\u836f\u548c\u5176\u4ed6\u529f\u80fd\u5206\u5b50\u7684\u91cd\u8981\u7ed3\u6784\u5355\u5143\u3002\u4e0d\u4ec5\u5982\u6b64\uff0c\u785d\u57fa\u82b3\u70c3\u548c\u785d\u57fa\u6742 [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-51502","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51502","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=51502"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51502\/revisions"}],"predecessor-version":[{"id":51503,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51502\/revisions\/51503"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=51502"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=51502"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=51502"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}