{"id":51398,"date":"2024-05-09T08:31:40","date_gmt":"2024-05-09T00:31:40","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=51398"},"modified":"2024-04-30T10:32:05","modified_gmt":"2024-04-30T02:32:05","slug":"acs-catalysis%ef%bc%9a%e7%94%b5%e5%8a%bf%e5%92%8c%e6%b4%bb%e6%80%a7%e4%bd%8d%e7%8e%af%e5%a2%83%e5%af%b9%e5%8d%95%e9%93%81%e5%8e%9f%e5%ad%90%e5%82%ac%e5%8c%96%e7%94%b5%e5%8c%96%e5%ad%a6co2%e8%bf%98","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/acs-catalysis%ef%bc%9a%e7%94%b5%e5%8a%bf%e5%92%8c%e6%b4%bb%e6%80%a7%e4%bd%8d%e7%8e%af%e5%a2%83%e5%af%b9%e5%8d%95%e9%93%81%e5%8e%9f%e5%ad%90%e5%82%ac%e5%8c%96%e7%94%b5%e5%8c%96%e5%ad%a6co2%e8%bf%98\/","title":{"rendered":"ACS Catalysis\uff1a\u7535\u52bf\u548c\u6d3b\u6027\u4f4d\u73af\u5883\u5bf9\u5355\u94c1\u539f\u5b50\u50ac\u5316\u7535\u5316\u5b66CO2\u8fd8\u539f\u7684\u5f71\u54cd"},"content":{"rendered":"
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\"1\"<\/section>\n
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\"2\"<\/section>\n
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\"3\"<\/section>\n
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\"4\"<\/section>\n
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\"9\"<\/section>\n
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\u5982\u56fe5\u6240\u793a\uff0cFeN4<\/sub>+V\u7684CO2<\/sub>RR\u8d77\u59cb\u7535\u4f4d\u4e3a-0.56 V vs RHE\uff0c\u4e0e\u7eafFeN4<\/sub>\u7c7b\u4f3c\uff08-0.51 V vs RHE\uff09\u3002\u5728FeN4<\/sub>+2N\u4e0a\u7684\u4f4e\u8fc7\u7535\u4f4d\uff08\u8d77\u59cb\u7535\u4f4d0.01V vs RHE\uff09\u4e0b\uff0cCO2<\/sub>RR\u4e3b\u8981\u53d7\u5230CO2<\/sub>\u5438\u9644\u7684\u9650\u5236\u3002FeN4<\/sub>+V\u548cFeN4<\/sub>+2N\u4e0aHER\u7684\u8d77\u59cb\u7535\u4f4d\u5206\u522b\u4e3a-0.91\u548c-0.34V\u3002\u4f5c\u8005\u901a\u8fc7\u4f7f\u7528UL<\/sub>\uff08CO2<\/sub>RR\uff09\u2013UL<\/sub>\uff08HER\uff09\u4f5c\u4e3a\u63cf\u8ff0\u7b26\u6765\u786e\u5b9a\u7535\u50ac\u5316\u5242\u7684\u9009\u62e9\u6027<\/span>\uff0c\u5e76\u4e14\u53d1\u73b0FeN4<\/sub>+V\u548cFeN4<\/sub>+2N\u90fd\u6bd4\u7eafFeN4<\/sub>\u66f4\u5177\u9009\u62e9\u6027\uff0cCO2<\/sub>RR\u548cHER\u4e4b\u95f4\u7684\u8d77\u59cb\u7535\u52bf\u5dee\u4e3a0.35 V\u3002\u56e0\u6b64\uff0c\u4e0e\u7eafFeN4<\/sub>\u76f8\u6bd4\uff0cFeN4<\/sub>+V\u548cFeN4<\/sub>+2N\u5177\u6709\u66f4\u5bbd\u7684\u9ad8FE\u64cd\u4f5c\u7535\u52bf\u7a97\u53e3\u3002<\/section>\n
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\u6587\u732e\u4fe1\u606f<\/strong><\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n
Jincheng Lei et.al Impact of Potential and Active-Site Environment on Single-Iron-Atom-Catalyzed Electrochemical CO2<\/sub>\u00a0Reduction from Accurate Quantum Many-Body Simulations ACS Catalysis 2024<\/section>\n
https:\/\/doi.org\/10.1021\/acscatal.3c05999<\/section>\n","protected":false},"excerpt":{"rendered":"

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