{"id":51331,"date":"2024-04-28T08:27:57","date_gmt":"2024-04-28T00:27:57","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=51331"},"modified":"2024-04-19T14:30:50","modified_gmt":"2024-04-19T06:30:50","slug":"angew-chem-%ef%bc%9a%e8%87%aa%e7%94%b1%e5%9f%ba-%e6%9e%81%e6%80%a7%e4%ba%a4%e5%8f%89%e7%8e%af%e5%8a%a0%e6%88%90%e5%8f%8d%e5%ba%94%e5%ae%9e%e7%8e%b0%e7%8e%af%e8%83%ba%e7%9a%84%e5%90%88%e6%88%90","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/angew-chem-%ef%bc%9a%e8%87%aa%e7%94%b1%e5%9f%ba-%e6%9e%81%e6%80%a7%e4%ba%a4%e5%8f%89%e7%8e%af%e5%8a%a0%e6%88%90%e5%8f%8d%e5%ba%94%e5%ae%9e%e7%8e%b0%e7%8e%af%e8%83%ba%e7%9a%84%e5%90%88%e6%88%90\/","title":{"rendered":"Angew. Chem. \uff1a\u81ea\u7531\u57fa-\u6781\u6027\u4ea4\u53c9\u73af\u52a0\u6210\u53cd\u5e94\u5b9e\u73b0\u73af\u80fa\u7684\u5408\u6210"},"content":{"rendered":"<section>\n<section>\n<section>\n<section>\n<section>\u4ece\u7b80\u5355\u5e95\u7269\u4e00\u6b65\u5feb\u901f\u6784\u5efa\u5177\u6709\u9ad8\u5e94\u9644\u52a0\u503c\u7684\u73af\u80fa\u7ed3\u6784\uff0c\u662f\u4e00\u79cd\u7406\u60f3\u4e14\u9ad8\u6548\u7684\u5408\u6210\u601d\u8def\u3002\u5c3d\u7ba1\u76ee\u524d\u5df2\u7ecf\u62a5\u9053\u4e86\u5927\u91cf\u5173\u4e8e\u73af\u80fa\u5408\u6210\u7684\u7814\u7a76\uff0c\u4f46\u5f80\u5f80\u4ec5\u5c40\u9650\u4e8e\u5355\u7ec4\u4efd\u6216\u53cc\u7ec4\u5206\u53cd\u5e94\uff0c\u901a\u8fc7\u7b80\u5355\u5e95\u7269\u7684\u591a\u7ec4\u5206\u5408\u6210\u4f9d\u65e7\u975e\u5e38\u56f0\u96be\u3002\u540c\u65f6\uff0c\u5728\u4f20\u7edf\u65b9\u6cd5\u4e2d\uff0c\u901a\u5e38\u96be\u4ee5\u5408\u6210\u03b2\u53d6\u4ee3\u7684\u73af\u72b6\u80fa\uff0c\u4e14\u7531\u4e8e\u4f4d\u963b\u6548\u5e94\uff0c\u03b2, 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decoding=\"async\" title=\"1\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240419\/1713508145235432.webp\" alt=\"1\" \/><\/section>\n<section>\u56fe 1\u00a0RPCC\u7b56\u7565\u5408\u6210\u73af\u80fa\u53cd\u5e94\u8bbe\u8ba1<\/p>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u5728\u6700\u4f18\u6761\u4ef6\u4e0b\uff0c\u4f5c\u8005\u5bf9\u78fa\u9170\u80fa\u3001\u672a\u6d3b\u5316\u70ef\u70c3\u4ee5\u53ca\u6d3b\u5316\u70ef\u70c3\u7684\u9002\u7528\u8303\u56f4\u8fdb\u884c\u4e86\u8003\u5bdf\u3002\u7ed3\u679c\u8868\u660e\uff0c\u53cd\u5e94\u5bf9\u4e8e\u78fa\u9170\u80fa\u3001\u975e\u6d3b\u5316\u70ef\u70c3\u3001\u6d3b\u5316\u70ef\u70c3\u90fd\u6709\u7740\u975e\u5e38\u597d\u7684\u517c\u5bb9\u6027\u3002\u503c\u5f97\u4e00\u63d0\u7684\u662f\uff0c\u901a\u8fc7\u79bb\u53bb\u57fa\u56e2\u4e0e\u70ef\u70c3\u95f4\u78b3\u94fe\u957f\u5ea6\u7684\u53d8\u5316\uff0c\u53ef\u4ee5\u5b9e\u73b0\u4e94\u5143\u3001\u516d\u5143\u3001\u4e03\u5143\u6c2e\u6742\u73af\u7684\u5408\u6210\uff0c\u5e76\u4e14\u8fd8\u53ef\u5408\u6210\u6c2e\u6742\u87ba\u73af\u548c\u6c2e\u6c27\u6742\u73af\u3002\u4ee4\u4eba\u6b23\u559c\u7684\u662f\uff0c<span class=\"wx_search_keyword_wrap\">\u585e\u6765\u6614\u5e03<\/span>\u3001\u753e\u4f53\u7b49\u5929\u7136\u4ea7\u7269\u5728\u6b64\u53cd\u5e94\u4f53\u7cfb\u4e2d\u4f9d\u7136\u6709\u7740\u8f83\u9ad8\u7684\u6536\u7387\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"2\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240419\/1713508162884418.webp\" alt=\"2\" \/><\/section>\n<section>\u56fe 2\u00a0\u4e8c\u53d6\u4ee3\u73af\u80fa\u5e95\u7269\u62d3\u5c55<\/p>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u4f5c\u8005\u5728\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u53d1\u73b0\uff0c\u5c06\u50ac\u5316\u91cf\u7684\u786b\u915a\u66ff\u4ee3\u6d3b\u5316\u70ef\u70c3\uff0c\u53ef\u4ee5\u5b9e\u73b0\u03b2\u5355\u53d6\u4ee3\u70ef\u70c3\u7684\u5408\u6210\uff0c\u5e76\u4e14\u53cd\u5e94\u4ecd\u7136\u5177\u6709\u6781\u597d\u7684\u517c\u5bb9\u6027\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"3\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240419\/1713508183243610.webp\" alt=\"3\" \/><\/section>\n<section>\u56fe 3\u00a0\u5355\u53d6\u4ee3\u73af\u80fa\u7684\u5e95\u7269\u62d3\u5c55<\/p>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u4e3a\u4e86\u8bc1\u660e\u53cd\u5e94\u7684\u5b9e\u7528\u6027\uff0c\u4f5c\u8005\u8fdb\u884c\u4e86\u514b\u7ea7\u53cd\u5e94\uff0c\u5f53\u53cd\u5e94\u4ee55 mmol\u89c4\u6a21\u8fdb\u884c\u65f6\uff0c\u53ef\u4ee5\u4ee584%\u7684\u6536\u7387\u5f97\u52301.55 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4\u00a0\u514b\u7ea7\u53cd\u5e94\u53ca\u673a\u7406\u7814\u7a76<\/p>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u9ec4\u7115\u660e\u8bfe\u9898\u7ec4\u5f00\u53d1\u4e86\u4e00\u79cd\u81ea\u7531\u57fa-\u6781\u6027\u4ea4\u53c9\u73af\u52a0\u6210\u65b0\u65b9\u6cd5\uff0c\u7528\u4e8e\u5728\u6e29\u548c\u7684\u5149\u6c27\u5316\u8fd8\u539f\u6761\u4ef6\u4e0b\u4ece\u4f2f\u78fa\u9170\u80fa\u3001\u672a\u6d3b\u5316\u7684\u70ef\u70c3\u548c\u6d3b\u5316\u7684\u70ef\u70c3\u5408\u6210\u73af\u80fa\uff0c\u53cd\u5e94\u6709\u7740\u51fa\u8272\u7684\u517c\u5bb9\u6027\u3002\u6b64\u5916\uff0c\u8fd8\u53ef\u4ee5\u4f7f\u7528\u4f2f\u78fa\u9170\u80fa\u3001\u672a\u6d3b\u5316\u7684\u70ef\u70c3\u548c\u50ac\u5316\u91cf\u7684\u82b3\u57fa\u786b\u9187\u6765\u751f\u6210\u03b2-\u5355\u53d6\u4ee3\u73af\u80fa\u3002\u503c\u5f97\u4e00\u63d0\u7684\u662f\uff0c\u8be5\u5de5\u4f5c\u7a81\u7834\u6027\u5730\u9996\u6b21\u5c06\u4f2f\u78fa\u9170\u80fa\u540c\u65f6\u4f5c\u4e3a\u6c2e\u4e2d\u5fc3\u81ea\u7531\u57fa\u524d\u4f53\u548c\u4eb2\u6838\u8bd5\u5242\u3002\u540c\u65f6\uff0c\u672c\u5de5\u4f5c\u63d0\u51fa\u7684RPCC\u5408\u6210\u65b9\u6cd5\u53ef\u4ee5\u6210\u4e3a\u6742\u73af\u5408\u6210\u7684\u901a\u7528\u7b56\u7565\uff0c\u5e76\u4e14\u4f2f\u78fa\u9170\u80fa\u4f5c\u4e3a\u53cc\u529f\u80fd\u8bd5\u5242\u6709\u7740\u8fdb\u4e00\u6b65\u7684\u53d1\u5c55\u6f5c\u529b\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section><strong>\u8bba<\/strong><strong>\u6587\u4fe1\u606f<\/strong><\/p>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section><\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>Cyclic Amine Synthesis via Catalytic Radical-Polar Crossover Cycloadditions<\/p>\n<p>Ying Zhang, Shu-Sheng Chen, Kai-Dian Li and Huan-Ming Huang*<\/p>\n<p>\u4e0a\u6d77\u79d1\u6280\u5927\u5b66\u7814\u7a76\u751f<span class=\"wx_search_keyword_wrap\">\u5f20\u83b9<\/span>\u4e3a\u8be5\u8bba\u6587\u7684\u7b2c\u4e00\u4f5c\u8005\uff0c\u9ec4\u7115\u660e\u6559\u6388\u4e3a\u552f\u4e00\u901a\u8baf\u4f5c\u8005\uff0c\u4e0a\u6d77\u79d1\u6280\u5927\u5b66\u4e3a\u552f\u4e00\u901a\u8baf\u5355\u4f4d\u3002\u8be5\u7814\u7a76\u5de5\u4f5c\u5f97\u5230\u4e86<span class=\"wx_search_keyword_wrap\">\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u59d4<\/span>\u3001\u4e0a\u6d77\u79d1\u6280\u5927\u5b66\u542f\u52a8\u91d1\u7b49\u9879\u76ee\u7684\u8d44\u52a9\u3002<\/p>\n<p><em>Angewandte Chemie International Edition<\/em><\/p>\n<p>DOI:\u00a010.1002\/anie.202401671<\/p>\n<\/section>\n<\/section>\n<\/section>\n","protected":false},"excerpt":{"rendered":"<p>\u4ece\u7b80\u5355\u5e95\u7269\u4e00\u6b65\u5feb\u901f\u6784\u5efa\u5177\u6709\u9ad8\u5e94\u9644\u52a0\u503c\u7684\u73af\u80fa\u7ed3\u6784\uff0c\u662f\u4e00\u79cd\u7406\u60f3\u4e14\u9ad8\u6548\u7684\u5408\u6210\u601d\u8def\u3002\u5c3d\u7ba1\u76ee\u524d\u5df2\u7ecf\u62a5\u9053\u4e86\u5927\u91cf\u5173\u4e8e\u73af\u80fa\u5408\u6210 [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-51331","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51331","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=51331"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51331\/revisions"}],"predecessor-version":[{"id":51332,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51331\/revisions\/51332"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=51331"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=51331"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=51331"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}