{"id":51278,"date":"2024-04-20T08:33:55","date_gmt":"2024-04-20T00:33:55","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=51278"},"modified":"2024-04-11T10:34:16","modified_gmt":"2024-04-11T02:34:16","slug":"angew-chem-%ef%bc%9a%e9%80%89%e6%8b%a9%e6%80%a7c-o%e9%94%ae%e8%8a%b3%e5%9f%ba%e5%8c%96%e5%8f%8d%e5%ba%94%e6%9e%84%e5%bb%ba%e7%a2%b3%e6%b0%ae%e8%bd%b4%e6%89%8b%e6%80%a7","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/angew-chem-%ef%bc%9a%e9%80%89%e6%8b%a9%e6%80%a7c-o%e9%94%ae%e8%8a%b3%e5%9f%ba%e5%8c%96%e5%8f%8d%e5%ba%94%e6%9e%84%e5%bb%ba%e7%a2%b3%e6%b0%ae%e8%bd%b4%e6%89%8b%e6%80%a7\/","title":{"rendered":"Angew. 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decoding=\"async\" title=\"1\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240411\/1712802807667849.webp\" alt=\"1\" \/><\/section>\n<section>\u56fe1 \u9009\u62e9\u6027C\u2013O\u952e\u82b3\u57fa\u5316\u53cd\u5e94\u6784\u5efa\u78b3\u6c2e\u8f74\u624b\u6027<\/p>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u901a\u8fc7\u53cd\u5e94\u6761\u4ef6\u4f18\u5316\uff0c\u4f5c\u8005\u53d1\u73b0\u542b\u53cc\u5641\u5511\u5549\u7684\u81a6\u914d\u4f53\u80fd\u663e\u8457\u63d0\u9ad8\u50ac\u5316\u7684\u6d3b\u6027\u548c\u7acb\u4f53\u9009\u62e9\u6027\u63a7\u5236\uff08\u56fe2\uff09\u3002\u6e29\u548c\u7684\u6709\u673a\u950c\u8bd5\u5242\u4f7f\u53cd\u5e94\u5bf9\u5404\u7c7b\u5b98\u80fd\u56e2\u90fd\u80fd\u5f88\u597d\u5730\u517c\u5bb9\uff0c\u9ad8\u7acb\u4f53\u9009\u62e9\u6027\u5f97\u5230\u5b98\u80fd\u56e2\u591a\u6837\u76841,3-\u5f02\u55b9\u5549\u4e8c\u916e\u5316\u5408\u7269\u3002\u5e76\u4e14\uff0c\u8be5\u53cd\u5e94\u540c\u6837\u9002\u7528\u4e8e\u5421\u54af\u5e76<span class=\"wx_search_keyword_wrap\">\u5421\u5576\u916e<\/span>\u5316\u5408\u7269\u7684\u9ad8\u7acb\u4f53\u9009\u62e9\u6027\u6784\u5efa\u3002\u6b64\u5916\uff0c\u4ea7\u7269\u4e2d\u7684\u6d3b\u6027\u4e9a\u7532\u57fa\u7ed3\u6784\u4f7f\u5176\u6210\u4e3a\u975e\u5e38\u6709\u4ef7\u503c\u7684\u4e2d\u95f4\u4f53\uff0c\u901a\u8fc7\u7b80\u5355\u7684\u884d\u751f\u5316\u53cd\u5e94\u53ef\u4ee5\u65b9\u4fbf\u5730\u5408\u6210\u5176\u4ed6\u5404\u7c7b\u6709\u4ef7\u503c\u7684\u78b3\u6c2e\u8f74\u624b\u6027\u4ea7\u7269\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"2\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240411\/1712802816529822.webp\" alt=\"2\" \/><\/section>\n<section>\u56fe2 \u5e95\u7269\u62d3\u5c55\u548c\u884d\u751f\u5316<\/p>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u6700\u540e\uff0c\u4f5c\u8005\u901a\u8fc7\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u8fdb\u4e00\u6b65\u7814\u7a76\u4e86\u53cd\u5e94\u7684\u533a\u57df\u9009\u62e9\u6027\u548c\u7acb\u4f53\u9009\u62e9\u6027\u63a7\u5236\u673a\u5236\uff08\u56fe3\uff09\u3002C\u2013O\u952e\u4e0e\u91d1\u5c5e\u954d\u6c27\u5316\u52a0\u6210\u7684\u8fc7\u6e21\u6001\u80fd\u91cf\u8ba1\u7b97\u8868\u660e\uff0c\u5207\u65ad\u70ef\u57faC\u2013O\u952e\u6240\u9700\u8981\u7684\u80fd\u91cf\u8fdc\u8fdc\u5927\u4e8e\u82b3\u57faC\u2013O\u952e\uff0c\u8fd9\u662f\u56e0\u4e3a\u5e95\u7269\u7684\u6700\u4f4e\u672a\u5360\u8f68\u9053\uff08LUMO\uff09\u4e2d\uff0cC<sub>4<\/sub>=C<sub>6<\/sub>\u952e\u7684\u5bc6\u5ea6\u660e\u663e\u5927\u4e8eC<sub>1<\/sub>=C<sub>5<\/sub>\uff0c\u56e0\u800c\u82b3\u57faC\u2013O\u952e\u66f4\u5bb9\u6613\u4e0e\u96f6\u4ef7\u954d\u6c27\u5316\u52a0\u6210\u3002\u6b64\u5916\uff0c\u8fc7\u6e21\u60013\u548c4\u4e2d\uff0cC1\u2013N2\u2013C3\u2013C4\u7684\u4e8c\u9762\u89d241\u00b0\u548c45\u00b0\uff0c\u8fdc\u5927\u4e8e\u8fc7\u6e21\u60011\u548c2\u768434\u00b0\uff0c\u8fd9\u610f\u5473\u7740\u70ef\u57faC\u2013O\u952e\u7684\u63d2\u5165\u4f1a\u5bfc\u81f4\u5e95\u7269\u53d1\u751f\u4e25\u91cd\u7684\u626d\u66f2\uff0c\u4ece\u800c\u5bfc\u81f4\u66f4\u9ad8\u7684\u80fd\u5792\u3002\u5bf9\u4e8e\u7acb\u4f53\u9009\u62e9\u6027\u63a7\u5236\uff0c\u975e\u5171\u4ef7\u76f8\u4e92\u4f5c\u7528\uff08NCI\uff09\u5206\u6790\u8868\u660e\uff0c\u8fc7\u6e21\u60011\u4e2d\u7684C\u2013H\u2026O\u6c22\u952e\u548cC\u2013H\u2026\u03c0\u76f8\u4e92\u4f5c\u7528\u66f4\u5f3a\uff0c\u56e0\u6b64\uff0c\u914d\u4f53\u548c\u5e95\u7269\u4e4b\u95f4\u66f4\u5f3a\u7684\u76f8\u4e92\u4f5c\u7528\u5e94\u8be5\u662fC\u2013O\u952e\u5bf9\u6620\u9009\u62e9\u6027\u5207\u65ad\u7684\u4e3b\u8981\u539f\u56e0\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"9\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240411\/1712802826940766.webp\" alt=\"9\" \/>\u200b<\/section>\n<section>\u56fe3 \u7406\u8bba\u8ba1\u7b97<\/p>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u603b\u4e4b\uff0c\u9093\u745e\u663e\u8bfe\u9898\u7ec4\u548c\u987e\u632f\u534e\u8bfe\u9898\u7ec4\u6210\u529f\u5b9e\u73b0\u4e86\u954d\u50ac\u5316\u533a\u57df\u9009\u62e9\u6027\u548c\u5bf9\u6620\u9009\u62e9\u6027C\u2013O\u952e\u6d3b\u5316\/\u5f00\u73af\u53cd\u5e94\uff0c\u6784\u5efaC\u2013N\u8f74\u624b\u60271,3-\u5f02\u55b9\u5549\u4e8c\u916e\u5206\u5b50\uff0c\u4e3a\u5408\u6210C\u2013N\u963b\u65cb\u5f02\u6784\u4f53\u63d0\u4f9b\u4e86\u65b0\u7684\u7b56\u7565\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section><strong>\u8bba<\/strong><strong>\u6587\u4fe1\u606f<\/strong><\/p>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section><\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>Regio- and Atroposelective Ring-Opening of 1H-Benzo[4,5]oxazolopyridinones<\/p>\n<p>Dr. Ruixian Deng,\u00a0Puyang Dong,\u00a0Jimeng Ge,\u00a0Dr. Wenjing Zhang,\u00a0Dr. Xiaoping Xue,\u00a0Dr. Longhui Duan,\u00a0Dr. Linlin Shi,\u00a0Prof.\u2005Dr. Zhenhua Gu<\/p>\n<p><em>Angewandte Chemie International Edition<\/em><\/p>\n<p>DOI:\u00a010.1002\/anie.202402231<\/p>\n<\/section>\n<\/section>\n<\/section>\n","protected":false},"excerpt":{"rendered":"<p>\u5229\u7528\u6765\u6e90\u4e30\u5bcc\u4e14\u5ec9\u4ef7\u7684\u919a\u7c7b\u5316\u5408\u7269\uff0c\u6784\u5efa\u624b\u6027\u529f\u80fd\u5206\u5b50\uff0c\u662f\u5408\u6210\u5316\u5b66\u91cd\u8981\u7684\u7814\u7a76\u65b9\u5411\u30022020\u5e74\uff0c\u66f9\u5fd7\u8d85\u8bfe\u9898\u7ec4\u9996\u6b21\u5b9e\u73b0\u4e86 [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-51278","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51278","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=51278"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51278\/revisions"}],"predecessor-version":[{"id":51279,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51278\/revisions\/51279"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=51278"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=51278"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=51278"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}