{"id":51219,"date":"2024-04-15T09:08:12","date_gmt":"2024-04-15T01:08:12","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=51219"},"modified":"2024-04-06T09:09:31","modified_gmt":"2024-04-06T01:09:31","slug":"angew-chem-%ef%bc%9a%e5%ba%94%e7%94%a8%e7%82%94%e4%b8%99%e4%bd%8d%e5%8e%bb%e8%b4%a8%e5%ad%90%e5%8c%96%e7%9a%84%e7%ad%96%e7%95%a5%e5%88%b6%e5%a4%87%e6%89%8b%e6%80%a7%e7%82%94%e4%b8%99%e5%9f%ba","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/angew-chem-%ef%bc%9a%e5%ba%94%e7%94%a8%e7%82%94%e4%b8%99%e4%bd%8d%e5%8e%bb%e8%b4%a8%e5%ad%90%e5%8c%96%e7%9a%84%e7%ad%96%e7%95%a5%e5%88%b6%e5%a4%87%e6%89%8b%e6%80%a7%e7%82%94%e4%b8%99%e5%9f%ba\/","title":{"rendered":"Angew. Chem. \uff1a\u5e94\u7528\u7094\u4e19\u4f4d\u53bb\u8d28\u5b50\u5316\u7684\u7b56\u7565\u5236\u5907\u624b\u6027\u7094\u4e19\u57fa\u7845\u70f7\u548c\u8054\u70ef\u57fa\u7845\u70f7"},"content":{"rendered":"<section>\n<section>\n<section>\n<section>\n<section>\u6709\u673a\u7845\u5316\u5408\u7269\u5c24\u5176\u662f\u7094\u4e19\u57fa\u7845\u70f7\u548c\u8054\u70ef\u57fa\u7845\u70f7\u662f\u4e24\u7c7b\u91cd\u8981\u7684\u5408\u6210\u4e2d\u95f4\u4f53\uff0c\u8fd9\u4e24\u7c7b\u4e2d\u95f4\u4f53\u53ef\u4ee5\u7acb\u4f53\u4e13\u4e00\u5730\u5408\u6210\u4e00\u7cfb\u5217\u5177\u6709\u751f\u7269\u6d3b\u6027\u7684\u624b\u6027\u5316\u5408\u7269\uff0c\u5728\u6709\u673a\u5408\u6210\u4e2d\u4e5f\u6709\u5e7f\u6cdb\u7684\u5e94\u7528\u3002\u4ece\u6613\u83b7\u5f97\u7684\u7094\u70c3\u539f\u6599\u51fa\u53d1\u76f4\u63a5\u5b9e\u73b0C(sp<sup>3<\/sup>)\u2013H \u7845\u57fa\u5316\u662f\u6700\u5feb\u6377\u7684\u5408\u6210\u8fd9\u4e24\u7c7b\u5316\u5408\u7269\u7684\u65b9\u6cd5\uff0c\u7136\u800c\u5728\u4f17\u591a\u5df2\u77e5\u7684C(sp<sup>3<\/sup>)\u2013H \u7845\u57fa\u5316\u7684\u65b9\u6cd5\u4e2d\uff0c\u901a\u7528\u5e76\u4e14\u5177\u6709\u7acb\u4f53\u9009\u62e9\u6027\u7684C(sp<sup>3<\/sup>)\u2013H \u7845\u57fa\u5316\u5374\u4ece\u672a\u88ab\u62a5\u9053\u8fc7\u3002<\/p>\n<p>\u8fd1\u51e0\u5e74\u6765\u738b\u4ea6\u9e23\u6559\u6388\u56e2\u961f\u5728\u5229\u7528\u03c0\u952e\u91d1\u5c5e\u7edc\u5408\u7684\u65b9\u5f0f\u8f85\u52a9\u4e0d\u9971\u548c\u952e\u7684\u03b1-\u4f4d\u53bb\u8d28\u5b50\u5b98\u80fd\u56e2\u5316\u65b9\u5411\u4e0a\u53d6\u5f97\u4e86\u4e00\u5b9a\u7684\u8fdb\u5c55\uff0c\u5728\u524d\u671f\u7814\u7a76\u7684\u57fa\u7840\u4e0a\uff0c\u4ed6\u4eec\u5229\u7528\u8fd9\u4e00\u7b56\u7565\u5b9e\u73b0\u4e86\u7094\u70c3\u7094\u4e19\u4f4d\u7684\u76f4\u63a5\u7845\u57fa\u5316\uff0c\u901a\u8fc7\u8c03\u63a7\u7845\u57fa\u5316\u8bd5\u5242\u6210\u529f\u5730\u540c\u65f6\u5408\u6210\u4e86\u624b\u6027\u7094\u4e19\u57fa\u7845\u70f7\u548c\u8054\u70ef\u57fa\u7845\u70f7\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<p>&nbsp;<\/p>\n<section>\n<section><\/section>\n<\/section>\n<p>&nbsp;<\/p>\n<section><img decoding=\"async\" title=\"1\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240325\/1711332668983729.webp\" alt=\"1\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u5728\u6700\u4f18\u6761\u4ef6\u4e0b\uff0c\u4f5c\u8005\u5bf9\u7094\u70c3\u548c\u7845\u57fa\u5316\u8bd5\u5242\u7684\u9002\u7528\u8303\u56f4\u8fdb\u884c\u4e86\u8003\u5bdf\uff0c\u7ed3\u679c\u8868\u660e\uff0c\u4e0d\u8bba\u4f7f\u7528\u5546\u4e1a\u53ef\u5f97\u7684\u8fd8\u662f\u539f\u4f4d\u751f\u6210\u7684\u7845\u57fa\u5316\u8bd5\u5242\uff0c\u53cd\u5e94\u5bf9\u82b3\u57fa\u70f7\u57fa\u3001\u4e8c\u70f7\u57fa\u53d6\u4ee3\u7684\u7094\u70c3\uff0c\u4ee5\u53ca1,3-\u70ef<span class=\"wx_search_keyword_wrap\">\u7094\u7c7b<\/span>\u7684\u5e95\u7269\u90fd\u80fd\u5f97\u5230\u826f\u597d\u7684\u7ed3\u679c\uff0c\u5e76\u4e14\u5bf9\u5e38\u89c1\u7684\u6742\u73af\u6709\u5f88\u597d\u7684\u517c\u5bb9\u6027\uff0c\u5747\u80fd\u591f\u4ee5\u9ad8\u5bf9\u6620\u9009\u62e9\u6027\u5f97\u5230\u7094\u4e19\u57fa\u7845\u70f7\u4ea7\u7269\u3002\u901a\u8fc7\u8c03\u8282\u7845\u57fa\u5316\u8bd5\u5242\u7684\u79bb\u53bb\u57fa\u56e2\uff0c\u4f5c\u8005\u80fd\u591f\u4ee5\u826f\u597d\u7684\u533a\u57df\u9009\u62e9\u6027\u548c\u5bf9\u6620\u9009\u62e9\u6027\u5f97\u5230\u8054\u70ef\u57fa\u7845\u70f7\u4ea7\u7269\uff0c\u8fd9\u7c7b\u53cd\u5e94\u4e5f\u6709\u8f83\u5e7f\u7684\u5e95\u7269\u8303\u56f4\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"2\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240325\/1711332682555254.webp\" alt=\"2\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u4f5c\u8005\u901a\u8fc7\u4e00\u7cfb\u5217\u673a\u7406\u5b9e\u9a8c\u7814\u7a76\u4e86\u53cd\u5e94\u5bf9\u4e8e\u4e0d\u540c\u4f4d\u963b\u7845\u57fa\u5316\u8bd5\u5242\u7684\u52a8\u529b\u5b66<span class=\"wx_search_keyword_wrap\">\u540c\u4f4d\u7d20\u6548\u5e94<\/span>\u00a0(KIE)\uff0c\u63a2\u7a76\u4e86\u5728\u4e0d\u540c\u7684\u5236\u5907\u6761\u4ef6\u4e0b\u7531\u4e8e\u53cc\u914d\u4f53\u94f1\u4e2d\u95f4\u4f53\u7684\u7a33\u5b9a\u6027\u5f15\u8d77\u7684\u7279\u6b8a\u7684\u975e\u7ebf\u6027\u6548\u5e94 (non-linear effect)\uff0c\u660e\u786e\u4e86\u53cd\u5e94\u4e2d\u5404\u79cd\u539f\u6599\u7684\u7ea7\u6570\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"3\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240325\/1711332697466500.webp\" alt=\"3\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u901a\u8fc7\u548c\u5218\u9e4f\u6559\u6388\u8bfe\u9898\u7ec4\u5408\u4f5c\uff0c\u8fdb\u4e00\u6b65\u5229\u7528\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba (DFT) \u8ba1\u7b97\u7814\u7a76\u4e86\u53cd\u5e94\u7684\u6574\u4f53\u8fc7\u7a0b\uff0c\u5e76\u4e14\u5bf9\u53cd\u5e94\u7684\u7ea7\u6570\u548c\u7acb\u4f53\u9009\u62e9\u6027\u505a\u51fa\u4e86\u89e3\u91ca\u3002<\/p>\n<p>\u8be5\u5de5\u4f5c\u4e2d\uff0c\u738b\u4ea6\u9e23\u6559\u6388\u56e2\u961f\u53d1\u5c55\u4e86\u94f1\u50ac\u5316\u7684\u4e0d\u5bf9\u79f0\u7094\u4e19\u4f4d\u5b98\u80fd\u56e2\u5316\uff0c\u5728\u6e29\u548c\u7684\u6761\u4ef6\u4e0b\u5b9e\u73b0\u4e86\u624b\u6027\u7094\u4e19\u57fa\u7845\u70f7\u548c\u8054\u70ef\u57fa\u7845\u70f7\u7684\u5408\u6210\uff0c\u8fd9\u4e5f\u662f\u9996\u4f8b\u5206\u5b50\u95f4\u4e0d\u5bf9\u79f0C(sp<sup>3<\/sup>)\u2013H \u7845\u57fa\u5316\u7684\u62a5\u9053\u3002\u8be5\u53cd\u5e94\u5728\u7094\u4e19\u4f4d\u6210\u529f\u5730\u5f15\u5165\u4e86\u7845\u539f\u5b50\uff0c\u5bf9\u5c06\u6765\u5728\u5206\u5b50\u4e2d\u5f15\u5165\u66f4\u591a\u79cd\u7c7b\u7684\u542b\u6742\u539f\u5b50\u5b98\u80fd\u56e2\u5177\u6709\u6307\u5bfc\u610f\u4e49\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section><strong>\u8bba<\/strong><strong>\u6587\u4fe1\u606f<\/strong><\/p>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section><\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>Enantioselective and Regiodivergent Synthesis of Propargyl- and Allenylsilanes through Catalytic Propargylic C\u2212H Deprotonation<\/p>\n<p><span class=\"wx_search_keyword_wrap\">Jin Zhu<\/span>,\u00a0Hengye Xiang,\u00a0Hai Chang,\u00a0James C. Corcoran,\u00a0Ruiqi Ding,\u00a0Yue Xia,\u00a0Prof.\u2005Dr. Peng Liu,\u00a0Prof.\u2005Dr. Yi-Ming Wang<\/p>\n<p>\u6587\u7ae0\u7684\u7b2c\u4e00\u4f5c\u8005\u662f\u5339\u5179\u5821\u5927\u5b66\u535a\u58eb\u751f\u6731\u9526 (\u73b0\u4e3a\u9ebb\u7701\u7406\u5de5\u5b66\u9662\u535a\u58eb\u540e)\uff0c\u901a\u8baf\u4f5c\u8005\u662f\u5339\u5179\u5821\u5927\u5b66\u7684\u5218\u9e4f\u6559\u6388\u548c\u738b\u4ea6\u9e23\u6559\u6388\u3002<\/p>\n<p><em>Angewandte Chemie International Edition<\/em><\/p>\n<p>DOI:\u00a010.1002\/anie.202318040<\/p>\n<\/section>\n<\/section>\n<\/section>\n","protected":false},"excerpt":{"rendered":"<p>\u6709\u673a\u7845\u5316\u5408\u7269\u5c24\u5176\u662f\u7094\u4e19\u57fa\u7845\u70f7\u548c\u8054\u70ef\u57fa\u7845\u70f7\u662f\u4e24\u7c7b\u91cd\u8981\u7684\u5408\u6210\u4e2d\u95f4\u4f53\uff0c\u8fd9\u4e24\u7c7b\u4e2d\u95f4\u4f53\u53ef\u4ee5\u7acb\u4f53\u4e13\u4e00\u5730\u5408\u6210\u4e00\u7cfb\u5217\u5177\u6709\u751f\u7269\u6d3b [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-51219","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51219","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=51219"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51219\/revisions"}],"predecessor-version":[{"id":51220,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51219\/revisions\/51220"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=51219"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=51219"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=51219"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}