{"id":51167,"date":"2024-04-07T08:37:30","date_gmt":"2024-04-07T00:37:30","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=51167"},"modified":"2024-03-29T10:39:29","modified_gmt":"2024-03-29T02:39:29","slug":"%e4%b8%8a%e7%a7%91%e5%a4%a7%e6%9d%a8%e6%99%93%e7%91%9c%e8%af%be%e9%a2%98%e7%bb%84acs-catal-%ef%bc%9a%e4%b8%8d%e5%af%b9%e7%a7%b0%e4%ba%b2%e7%94%b5%e8%83%ba%e5%8c%96%e6%9e%84%e5%bb%ba%e4%ba%8c%e8%8a%b3","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/%e4%b8%8a%e7%a7%91%e5%a4%a7%e6%9d%a8%e6%99%93%e7%91%9c%e8%af%be%e9%a2%98%e7%bb%84acs-catal-%ef%bc%9a%e4%b8%8d%e5%af%b9%e7%a7%b0%e4%ba%b2%e7%94%b5%e8%83%ba%e5%8c%96%e6%9e%84%e5%bb%ba%e4%ba%8c%e8%8a%b3\/","title":{"rendered":"\u4e0a\u79d1\u5927\u6768\u6653\u745c\u8bfe\u9898\u7ec4ACS 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class=\"wx_search_keyword_wrap\">HPLC<\/span>\u5206\u79bb\u3002<\/section>\n<section><\/section>\n<section>\u5c3d\u7ba1\u5bf9\u5177\u6709\u5355\u8f74\u7684\u8f74\u624b\u6027\u5316\u5408\u7269\u4e0d\u5bf9\u79f0\u5408\u6210\u53d6\u5f97\u4e86\u663e\u8457\u8fdb\u5c55\uff0c\u4e8c\u82b3\u57fa\u80fa\u9aa8\u67b6\u5728\u5185\u7684\u53cc\u8f74\u624b\u6027\u5206\u5b50\u7684\u4e0d\u5bf9\u79f0\u5408\u6210\u76f4\u5230\u8fd1\u51e0\u5e74\u624d\u88ab\u9646\u7eed\u62a5\u9053\u30022020\u5e74\uff0c\u7f8e\u56fd\u5723\u5730\u4e9a\u54e5\u5dde\u7acb\u5927\u5b66Gustafson\u8bfe\u9898\u7ec4\u62a5\u9053\u4e86\u7b2c\u4e00\u4f8b\u6709\u673a\u50ac\u5316\u7684\u6eb4\u4ee3\u53cd\u5e94\u5408\u6210\u4e86\u4e00\u7cfb\u5217N-\u82b3\u57fa\u918c\u9aa8\u67b6\u7684\u4e8c\u82b3\u57fa\u80fa\u963b\u8f6c\u5f02\u6784\u4f53\uff0c\u968f\u540e\uff0c\u4e0a\u6d77\u4ea4\u901a\u5927\u5b66\u9648\u5fd7\u654f\u8bfe\u9898\u7ec4\u548c\u4e0a\u6d77\u6709\u673a\u6240\u859b\u5c0f\u677e\u8bfe\u9898\u7ec4\u5408\u4f5c\uff0c\u5b9e\u73b0\u4e86N-\u82b3\u57fa\u918c\u9aa8\u67b6\u7684\u4e0d\u5bf9\u79f0\u4eb2\u7535\u786b\u4ee3\u53cd\u5e94\uff0c\u5408\u6210\u4e86\u4e00\u7cfb\u5217\u542b\u786b\u7684\u4e8c\u82b3\u57fa\u80fa\u963b\u8f6c\u5f02\u6784\u4f53\uff08\u56fe1b\uff09\u3002\u6b64\u5916\uff0c\u9752\u5c9b\u5927\u5b66\u5218\u4eba\u8363\u8bfe\u9898\u7ec4\u62a5\u9053\u4e86\u901a\u8fc7\u624b\u6027\u78f7\u9178\u50ac\u5316\u4e32\u8054N-\u82b3\u57fa\u5316\/\u6c27\u5316\u53cd\u5e94\u76f4\u63a5\u6784\u5efaN-\u82b3\u57fa\u918c\u7c7b\u963b\u8f6c\u5f02\u6784\u4f53\uff08\u56fe1c\uff09\u3002\u6700\u8fd1\uff0c\u5357\u5f00\u5927\u5b66\u674e\u946b\u8bfe\u9898\u7ec4\u56e2\u961f\u901a\u8fc7N-\u4eb2\u6838\u82b3\u57fa\u5316\u548cC-\u4eb2\u6838\u6eb4\u4ee3\u53cd\u5e94\u5408\u6210\u4e86\u201cNO<sub>2<\/sub>\u2026NH\u201d\u6c22\u952e\u7a33\u5b9a\u7684\u4e8c\u82b3\u57fa\u80fa\u963b\u8f6c\u5f02\u6784\u4f53\uff08\u56fe1d\uff09\u3002\u5c3d\u7ba1\u8fd9\u4e9b\u65b9\u6cd5\u53d6\u5f97\u4e86\u826f\u597d\u7684\u7ed3\u679c\uff0c\u8fd9\u4e9b\u65b9\u6cd5\u5927\u591a\u5c40\u9650\u4e8eN-\u82b3\u57fa\u918c\u9aa8\u67b6\uff0c\u5e76\u4e14\u5747\u901a\u8fc7\u5206\u5b50\u5185\u6c22\u952e\u56fa\u5b9a\u4e00\u6839C-N\u8f74\u6210\u4e94\u5143\u6216\u516d\u5143\u73af\uff0c\u800c\u50ac\u5316\u4e0d\u5bf9\u79f0\u5408\u6210\u975eN-\u82b3\u57fa\u918c\u9aa8\u67b6\u7684\u4e8c\u82b3\u57fa\u80fa\u7c7b\u963b\u8f6c\u5f02\u6784\u4f53\uff0c\u7279\u522b\u662f\u975e\u6c22\u952e\u7a33\u5b9a\u7684\u4f8b\u5b50\uff0c\u8fd8\u672a\u89c1\u62a5\u9053\u3002<\/section>\n<section><\/section>\n<section>\u4e0a\u6d77\u79d1\u6280\u5927\u5b66\u6768\u6653\u745c\u8bfe\u9898\u7ec4\u8fd1\u5e74\u6765\u81f4\u529b\u4e8e\u50ac\u5316\u4e0d\u5bf9\u79f0\u5408\u6210\u65b0\u578b\u624b\u6027\u9aa8\u67b6\u5206\u5b50\uff08\u5e73\u9762\u624b\u6027\u5927\u73af\uff1a<em>Angew. Chem. Int. Ed.<\/em>\u00a02022,\u00a0<em>61<\/em>, e2022010;\u00a0\u8f74\u624b\u6027\u4e8c\u82b3\u57fa\u919a\uff1a<em>Angew. Chem. Int. Ed.\u00a0<\/em>2023,\u00a0<em>62<\/em>, e202300481\uff1b\u87ba\u65cb\u624b\u6027\u6c2e\u6742\u87ba\u70ef\uff1a<em>Angew. Chem. Int. Ed.<\/em>\u00a02023,\u00a0<em>62<\/em>, e202303430\uff09\u3002\u6700\u8fd1\uff0c\u8be5\u8bfe\u9898\u7ec4\u5229\u7528\u8fdb\u4e00\u6b65\u5229\u7528\u624b\u6027\u78f7\u9178\u50ac\u5316\u4e0e\u5076\u6c2e\u4e8c\u7532\u9178\u916f\u7684\u4eb2\u7535\u80fa\u5316\u53cd\u5e94\u5b9e\u73b0\u4e86\u8f74\u624b\u6027\u4e8c\u82b3\u57fa\u80fa\u7684\u76f4\u63a5\u50ac\u5316\u4e0d\u5bf9\u79f0\u5408\u6210\uff0c\u8be5\u65b9\u6cd5\u7a81\u7834\u4e86\u57fa\u4e8e\u918c\u9aa8\u67b6\u4e8c\u82b3\u57fa\u80fa\u7c7b\u963b\u8f6c\u5f02\u6784\u4f53\u7684\u8303\u7574\uff0c\u5b9e\u73b0\u4e86\u9996\u4f8b\u50ac\u5316\u4e0d\u5bf9\u79f0\u5408\u6210\u65e0\u5206\u5b50\u5185\u6c22\u952e\u7a33\u5b9a\u7684\u4e8c\u82b3\u57fa\u80fa\u963b\u8f6c\u5f02\u6784\u4f53\uff08\u56fe1e\uff09\u3002<\/section>\n<section><\/section>\n<p><img decoding=\"async\" title=\"1\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240329\/1711679913604389.png\" alt=\"1\" \/><\/p>\n<section>\u56fe1 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decoding=\"async\" title=\"2\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240329\/1711679922847066.png\" alt=\"2\" \/><\/section>\n<section>\u56fe2 \u8f74\u624b\u6027\u4e8c\u82b3\u57fa\u80fa\u5e95\u7269\u9002\u7528\u6027\u63a2\u7a76<\/section>\n<section><\/section>\n<section>\u4e3a\u4e86\u63a2\u7a76\u53cd\u5e94\u7684\u673a\u7406\u548c\u7acb\u4f53\u9009\u62e9\u6027\uff0c\u4f5c\u8005\u8fdb\u884c\u4e86\u63a7\u5236\u5b9e\u9a8c\u7684\u63a2\u7a76\uff08\u56fe3\uff09\u3002\u7814\u7a76\u53d1\u73b0\u5f53\u628a\u6d53\u5ea6\u4ece0.1M\u964d\u81f30.00625M\u65f6\uff0c\u80cc\u666f\u53cd\u5e94\u80fd\u591f\u88ab\u5927\u5927\u51cf\u5f31\uff08\u56fe3a\uff09\uff0c\u5c06C3\u4f4d\u80fa\u57fa\u53cc\u7532\u57fa\u5316\u540e\u53cd\u5e94\u51e0\u4e4e\u4e0d\u53d1\u751f\uff0c\u8bf4\u660e\u4e86\u8be5\u4f2f\u80fa\u5bf9\u4e8e\u5e95\u7269\u4e0e\u78f7\u9178\u4e4b\u95f4\u5f62\u6210\u6c22\u952e\u7684\u91cd\u8981\u6027\uff08\u56fe3b\uff09\uff0c\u6b64\u5916\uff0c\u5c062\u2019\u4f4d\u7684\u82b3\u57fa\u6539\u4e3a\u7532\u57fa\u540e\u5f97\u5230\u4f4e\u5bf9\u6620\u9009\u62e9\u6027\u4ea7\u7269\uff0c\u4f5c\u8005\u63a8\u6d4b\u53ef\u80fd\u662f\u7531\u4e8e\u7f3a\u5c11\u4e86\u4e0e\u78f7\u9178\u7684\u82b3\u57fa-\u82b3\u57fa\u7684\u76f8\u4e92\u4f5c\u7528\uff08\u56fe3c\uff09\uff0c\u57fa\u4e8e\u4ee5\u4e0a\u7ed3\u679c\uff0c\u4f5c\u8005\u63d0\u51fa\u5982\u56fe3d\u6240\u793a\u7684\u53ef\u80fd\u50ac\u5316\u6a21\u578b\uff0c\u624b\u6027\u78f7\u9178\u53cc\u6c22\u952e\u6d3b\u5316\u4f5c\u7528\u4e8e\u5076\u6c2e\u548c\u5e95\u7269C3\u4f4d\u80fa\u57fa\uff0c\u5b9e\u73b0\u4e86\u4e0d\u5bf9\u79f0\u4eb2\u7535\u80fa\u5316\u53cd\u5e94\u3002<\/section>\n<section><\/section>\n<section><img decoding=\"async\" title=\"3\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240329\/1711679931797680.png\" alt=\"3\" \/><\/section>\n<section>\u56fe3 \u63a7\u5236\u5b9e\u9a8c\u548c\u53cd\u5e94\u8fc7\u6e21\u6001<\/section>\n<section><\/section>\n<section>\u4f5c\u8005\u4e4b\u540e\u5bf9\u6807\u51c6\u4ea7\u7269\u7684<span class=\"wx_search_keyword_wrap\">\u7acb\u4f53\u6784\u578b<\/span>\u7a33\u5b9a\u6027\u505a\u4e86\u8be6\u7ec6\u7684\u7814\u7a76\uff0c\u6807\u51c6\u4ea7\u72693a\u5728\u7532\u82ef\u8fdb\u884c\u4e86\u70ed\u529b\u5b66\u7a33\u5b9a\u6027\u6d4b\u8bd5\uff08\u56fe4a\uff09\uff0c\u6d4b\u5f97\u7684\u6d88\u65cb\u80fd\u5792\u9ad8\u8fbe30.4 kcal\/mol\uff0c\u8fbe\u5230\u4e863\u7c7b\u963b\u8f6c\u5f02\u6784\u4f53\u7684\u6807\u51c6\uff0c\u6b64\u5916\u5728\u6781\u6027\u6eb6\u5242\u5982\u4e59\u8148\u548c\u5f02\u4e19\u9187\u4e2d\u6d4b\u5f97\u7684\u6d88\u65cb\u80fd\u5792\u5e76\u6ca1\u6709\u660e\u663e\u4e0b\u964d\uff0c\u8bf4\u660e\u5206\u5b50\u5185\u6c22\u952e\u5bf9\u8be5\u7c7b\u4e8c\u82b3\u57fa\u80fa\u963b\u8f6c\u5f02\u6784\u4f53\u6784\u578b\u7684\u7a33\u5b9a\u4f5c\u7528\u6781\u5c0f\uff0c\u5176\u6d88\u65cb\u8fc7\u7a0b\u53ef\u80fd\u7ecf\u5386\u4e86\u53cc\u8f74\u534f\u540c\u8f6c\u52a8\u7684\u8fc7\u7a0b\u3002\u5bf9\u6b64\uff0c\u4f5c\u8005\u8fdb\u884c\u4e86\u6d88\u65cb\u673a\u7406\u7684DFT\u8ba1\u7b97\uff08\u56fe4b-c\uff09\uff0c\u8ba1\u7b97\u8868\u660e\uff0c(S<sub>a<\/sub>,\u00a0<em>ci<\/em>s)-3a\u8fd9\u4e00\u53ef\u80fd\u5177\u6709\u5206\u5b50\u5185\u6c22\u952e\u7684\u6784\u578b\u53ea\u4e0e(S<sub>a<\/sub>, trans)-3a\u76f8\u5dee0.99 kcal\/mol\uff0c\u6d88\u65cb\u8fc7\u7a0b\u7ecf\u5386\u53cc\u8f74\u987a\u65cb\u5f97\u5230\u5782\u76f4\u6784\u8c61\u7684\u8fc7\u6e21\u6001TS-1\uff0c\u800c\u540e\u4e24\u6839C-N\u8f74\u901a\u8fc7\u5bf9\u65cb\u8fd0\u52a8\u4f7f(S<sub>a<\/sub>,\u00a0<em>ci<\/em>s)-3a\u751f\u6210\u5176\u5bf9\u6620\u5f02\u6784\u4f53(<em>R<sub>a<\/sub><\/em>,\u00a0<em>cis<\/em>)-3a\uff0c\u8ba1\u7b97\u5f97\u5230\u7684\u6d88\u65cb\u80fd\u5792\u4e3a31.45kcal\/mol\uff0c\u4e0e\u5b9e\u9a8c\u7ed3\u679c\u543b\u5408\uff0c\u8fdb\u4e00\u6b65\u8bf4\u660e\u4e86\u6f5c\u5728\u7684\u5206\u5b50\u5185\u6c22\u952e\u4f5c\u7528\u4e0d\u8db3\u4ee5\u7a33\u5b9a\u8be5\u4e8c\u82b3\u57fa\u80fa\u4e2d\u7684\u4e00\u6839C-N\u8f74\u4f7f\u5176\u4e0e\u5176\u4e2d\u4e00\u8fb9\u82b3\u57fa\u5171\u5e73\u9762\u3002<\/section>\n<section><\/section>\n<section><img decoding=\"async\" title=\"4\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240329\/1711679940178090.png\" alt=\"4\" \/><\/section>\n<section>\u56fe4\u6784\u578b\u7a33\u5b9a\u6027\u548c\u6d88\u65cb\u673a\u7406\u7684\u8ba1\u7b97<\/section>\n<section><\/section>\n<section>\u4e3a\u4e86\u8bc1\u660e\u8be5\u65b9\u6cd5\u7684\u5b9e\u7528\u6027\uff0c\u4f5c\u8005\u5bf9\u624b\u6027\u4ea7\u7269\u8fdb\u884c\u4e86\u884d\u751f\u5316\u63a2\u7a76\uff08\u56fe5\uff09\u3002\u4f5c\u8005\u9996\u5148\u901a\u8fc7\u4e0d\u540c\u7684\u5364\u4ee3\u8bd5\u5242\u5b9e\u73b0\u4e86\u4ea7\u7269C4\u4f4d\u7684\u4eb2\u7535\u5364\u4ee3\u53cd\u5e94\uff08\u56fe5a\uff09\uff0c\u6b64\u5916\uff0c\u901a\u8fc7\u5bf9\u6807\u51c6\u4ea7\u7269\u4f2f\u80fa\u8fdb\u884c\u4fdd\u62a4\u540e\uff0c\u53ef\u4ee5\u901a\u8fc7\u4e0d\u540c\u7684\u6c22\u5316\u6761\u4ef6\u5f97\u5230\u5e26\u6709\u4e0d\u540c\u5b98\u80fd\u56e2\u7684\u8fd8\u539f\u4ea7\u7269\uff0c\u5982\u5e26\u4fdd\u62a4\u57fa\u7684\u80fa\u57fa\uff0c\u80bc\u57fa\u3001\u5076\u6c2e\u4ee5\u53ca\u5e26\u6709\u82ef\u5e76\u54aa\u5511\u916e\u9aa8\u67b6\u7684C-N\u8f74\u963b\u8f6c\u5f02\u6784\u4f53\u3002\u7531\u4e8e\u53d6\u4ee3\u57fa\u4f4d\u963b\u7684\u51cf\u5c0f\u5bfc\u81f4\u4ea7\u7269\u6d88\u65cb\u80fd\u5792\u8fdb\u4e00\u6b65\u964d\u4f4e\uff0c\u800c\u5177\u6709\u5206\u5b50\u5185\u6c22\u952e\u7684\u5206\u5b5013a\u5219\u5177\u6709\u660e\u663e\u66f4\u9ad8\u7684\u6d88\u65cb\u80fd\u5792\uff0c\u518d\u6b21\u8bc1\u660e\u4e86\u5728\u8be5\u7c7b\u4e8c\u82b3\u57fa\u80fa\u963b\u8f6c\u5f02\u6784\u4f53\u4e2d\u4f4d\u963b\u6548\u5e94\u8d77\u4e86\u4e3b\u8981\u7a33\u5b9a\u6784\u578b\u7684\u4f5c\u7528\u3002<\/section>\n<section><\/section>\n<section><img decoding=\"async\" title=\"6\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240329\/1711679950248913.png\" alt=\"6\" \/>\u200b<\/section>\n<section>\u56fe5 \u624b\u6027\u4ea7\u7269\u7684\u884d\u751f\u5316<\/section>\n<section><\/section>\n<section>\u7efc\u4e0a\u6240\u8ff0\uff0c\u6768\u6653\u745c\u8bfe\u9898\u7ec4\u5229\u7528\u624b\u6027\u78f7\u9178\u50ac\u5316\u7684\u4eb2\u7535\u80fa\u5316\u53cd\u5e94\u5b9e\u73b0\u4e86\u4e8c\u82b3\u57fa\u80fa\u7c7b\u963b\u8f6c\u5f02\u6784\u4f53\u7684\u4e0d\u5bf9\u79f0\u5408\u6210\u3002\u4ee5\u826f\u597d\u7684\u4ea7\u7387\u548c\u9ad8\u5bf9\u6620\u9009\u62e9\u6027\u5f97\u5230\u4e86\u4e00\u7cfb\u5217\u5177\u6709\u5927\u4f4d\u963b\u7684\u975eN-\u82b3\u57fa\u918c\u9aa8\u67b6\u7684\u4e8c\u82b3\u57fa\u80fa\u7c7b\u963b\u8f6c\u5f02\u6784\u4f53\uff0c\u901a\u8fc7\u5b9e\u9a8c\u548c\u8ba1\u7b97\u7cfb\u7edf\u5730\u8bf4\u660e\u4e86\u8be5\u7c7b\u5316\u5408\u7269\u901a\u8fc7\u4e24\u6839C-N\u8f74\u534f\u540c\u8f6c\u52a8\u7684\u6d88\u65cb\u673a\u5236\u3002\u4e30\u5bcc\u7684\u4ea7\u7269\u884d\u751f\u5316\u5b9e\u9a8c\u8bc1\u660e\u4e86\u8be5\u65b9\u6cd5\u7684\u5e94\u7528\u6f5c\u529b\u3002<\/section>\n<section><\/section>\n<section>\u8be5\u7814\u7a76\u6210\u679c\u8fd1\u671f\u53d1\u8868\u5728\u56fd\u9645\u5b66\u672f\u671f\u520a<em>ACS Catalysis<\/em>\u4e0a\u3002\u6768\u6653\u745c\u8bfe\u9898\u7ec422\u7ea7\u535a\u58eb\u7814\u7a76\u751f\u53f6\u5b50\u65e6\u4e3a\u672c\u6587\u7b2c\u4e00\u4f5c\u8005\uff0c\u4e0a\u6d77\u79d1\u6280\u5927\u5b66\u4e3a\u672c\u8bba\u6587\u7b2c\u4e00\u5b8c\u6210\u5355\u4f4d\uff0c\u6768\u6653\u745c\u6559\u6388\u4e3a\u672c\u6587\u901a\u8baf\u4f5c\u8005\u3002\u4ee5\u4e0a\u5de5\u4f5c\u90fd\u5f97\u5230\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u59d4\u548c\u4e0a\u6d77\u79d1\u6280\u5927\u5b66\u542f\u52a8\u8d44\u91d1\u7684\u652f\u6301\u3002<\/section>\n<section><\/section>\n<section><strong>\u8bba\u6587\u94fe\u63a5<\/strong><\/section>\n<section>Atroposelective Synthesis of Diarylamines via Organocatalyzed Electrophilic Amination,\u00a0Zidan Ye, Wansen Xie, Donglei Wang, Hua Liu, and Xiaoyu Yang*<\/section>\n<section><em>ACS Catal.<\/em>\u00a02024,\u00a0<em>14<\/em>, 4958-4967,<\/section>\n<section>https:\/\/doi.org\/10.1021\/acscatal.4c00414<\/section>\n","protected":false},"excerpt":{"rendered":"<p>\u963b\u8f6c\u5f02\u6784\u4f53\u662f\u7531\u4e8e\u5927\u4f4d\u963b\u53d6\u4ee3\u57fa\u5bfc\u81f4\u5355\u952e\u65cb\u8f6c\u53d7\u963b\u800c\u4ea7\u751f\u7684\u4e00\u7c7b\u72ec\u7279\u7684\u624b\u6027\u5206\u5b50\u3002\u8fd1\u5e74\u6765\uff0c\u8f74\u624b\u6027\u963b\u8f6c\u5f02\u6784\u4f53\u5f97\u5230\u4e86\u5e7f\u6cdb\u7684\u5e94 [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-51167","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51167","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=51167"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51167\/revisions"}],"predecessor-version":[{"id":51168,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51167\/revisions\/51168"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=51167"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=51167"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=51167"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}