{"id":51153,"date":"2024-04-05T08:57:52","date_gmt":"2024-04-05T00:57:52","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=51153"},"modified":"2024-03-26T16:58:24","modified_gmt":"2024-03-26T08:58:24","slug":"%e5%8d%8e%e4%b8%9c%e7%90%86%e5%b7%a5%e5%a4%a7%e5%ad%a6%e7%8e%8b%e6%b5%b7%e4%b8%b0%e8%af%be%e9%a2%98%e7%bb%84jacs%ef%bc%9a%e6%b0%b4-%e6%9d%bf%e9%92%9b%e7%9f%bftio2%e7%95%8c%e9%9d%a2%e5%bc%b1%e6%b0%a2","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/%e5%8d%8e%e4%b8%9c%e7%90%86%e5%b7%a5%e5%a4%a7%e5%ad%a6%e7%8e%8b%e6%b5%b7%e4%b8%b0%e8%af%be%e9%a2%98%e7%bb%84jacs%ef%bc%9a%e6%b0%b4-%e6%9d%bf%e9%92%9b%e7%9f%bftio2%e7%95%8c%e9%9d%a2%e5%bc%b1%e6%b0%a2\/","title":{"rendered":"\u534e\u4e1c\u7406\u5de5\u5927\u5b66\u738b\u6d77\u4e30\u8bfe\u9898\u7ec4JACS\uff1a\u6c34\/\u677f\u949b\u77ffTiO2\u754c\u9762\u5f31\u6c22\u952e\u76f8\u4e92\u4f5c\u7528\u8c03\u63a7\u5149\u50ac\u5316\u6c34\u6c27\u5316\u4e3aH2O2\u7684\u9009\u62e9\u6027"},"content":{"rendered":"<p>\u25b2\u5171\u540c\u7b2c\u4e00\u4f5c\u8005\uff1a\u4efb\u51a0\u534e\u3001\u5468\u654f<\/p>\n<p>\u901a\u8baf\u4f5c\u8005\uff1a\u00a0\u738b\u6d77\u4e30<\/p>\n<p>\u901a\u8baf\u5355\u4f4d\uff1a\u00a0\u534e\u4e1c\u7406\u5de5\u5927\u5b66<\/p>\n<p>\u8bba\u6587DOI\uff1a10.1021\/jacs.3c13402<\/p>\n<p>&nbsp;<\/p>\n<section data-mpa-template=\"t\">\n<section data-mpa-template=\"t\">\n<section>\n<section data-mpa-category=\"\u6a21\u677f\" data-mid=\"\">\n<section data-mid=\"\">\n<section data-mid=\"\"><\/section>\n<section data-mid=\"\">\u00a0<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section><strong>\u5168\u6587\u901f\u89c8<\/strong><\/section>\n<section>\u672c\u6587\u91c7\u7528\u7b2c\u4e00\u6027\u539f\u7406\u5206\u5b50\u52a8\u529b\u5b66\u6a21\u62df\u548c\u5fae\u89c2\u52a8\u529b\u5b66\u5206\u6790\uff0c\u6df1\u5165\u63a2\u8ba8\u4e86\u677f\u949b\u77ff\u76f8TiO<sub>2<\/sub>(210)\uff08b-TiO<sub>2<\/sub>(210)\uff09\u548c\u91d1\u7ea2\u77f3\u76f8TiO<sub>2<\/sub>(110)\uff08r-TiO<sub>2<\/sub>(110)\uff09\u6db2\u56fa\u754c\u9762\u4e0a\u5149\u50ac\u5316\u6c34\u6c27\u5316\u53cd\u5e94\uff08WOR\uff09\u9009\u62e9\u6027\u7684\u673a\u5236\u548c\u51b3\u5b9a\u4e0d\u540c\u6676\u76f8\u8868\u9762\u53cd\u5e94\u9009\u62e9\u6027\u7684\u5173\u952e\u56e0\u7d20\u3002\u7814\u7a76\u7ed3\u679c\u53d1\u73b0\uff0c\u6c34\/b-TiO<sub>2<\/sub>(210)\u754c\u9762\u5bf9\u4e8eH<sub>2<\/sub>O<sub>2<\/sub>\u7684\u9ad8\u9009\u62e9\u6027\u5e76\u975e\u6e90\u4e8eb-TiO<sub>2<\/sub>(210)\u50ac\u5316\u5242\u7684\u672c\u5f81\u6d3b\u6027\uff0c\u800c\u662f\u7531\u4e8e\u8be5\u8868\u9762\u7684\u5c40\u90e8\u9c7c\u9aa8\u5f62\u539f\u5b50\u7ed3\u6784\u8c03\u63a7\u4e86\u5f31\u754c\u9762\u6c22\u952e\u76f8\u4e92\u4f5c\u7528\uff0c\u5728\u8fd1\u5438\u9644\u6c34\u5c42\u5f62\u6210\u4e86\u5c40\u90e8\u4f4e\u6c34\u5bc6\u5ea6\u5fae\u73af\u5883\u3002\u5728\u8fd9\u79cd\u5fae\u73af\u5883\u4e2d\uff0c\u4e0d\u4ec5\u6709\u5229\u4e8e\u76f8\u5bf9\u758f\u6c34\u7684OH<sup>\u2022<\/sup>\u81ea\u7531\u57fa\u5f62\u6210\uff0c\u800c\u4e14\u6709\u52a9\u4e8e\u6291\u5236\u5176\u53bb\u8d28\u5b50\u5316\uff0c\u4ece\u800c\u63d0\u9ad8H<sub>2<\/sub>O<sub>2<\/sub>\u7684\u9009\u62e9\u6027\u3002\u8be5\u7814\u7a76\u5b9a\u91cf\u5730\u8868\u660e\u6db2\/\u56fa\u754c\u9762\u5904\u7684\u5c40\u90e8\u6c22\u952e\u7ed3\u6784\uff08\u6c34\u5bc6\u5ea6\uff09\u5bf9\u8c03\u63a7\u5149\u50ac\u5316\u9009\u62e9\u6027\u7684\u5173\u952e\u4f5c\u7528\uff0c\u4e3a\u8fdb\u4e00\u6b65\u8bbe\u8ba1\u66f4\u9ad8H<sub>2<\/sub>O<sub>2<\/sub>\u9009\u62e9\u6027\u7684\u50ac\u5316\u5242\u63d0\u4f9b\u4e86\u4f9d\u636e\u3002<\/section>\n<section><\/section>\n<section data-mpa-template=\"t\">\n<section data-mpa-template=\"t\">\n<section>\n<section data-mpa-category=\"\u6a21\u677f\" data-mid=\"\">\n<section data-mid=\"\">\n<section data-mid=\"\"><\/section>\n<section data-mid=\"\">\u00a0\u00a0<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section><strong>\u80cc\u666f\u4ecb\u7ecd<\/strong><\/section>\n<section>\u5149\u50ac\u5316\u6c34\u6c27\u5316\u53cd\u5e94\uff08WOR\uff09\u901a\u8fc7\u4e24\u7535\u5b50\u9014\u5f84\u4ea7\u751f\u9ad8\u9644\u52a0\u503c\u5316\u5b66\u54c1H<sub>2<\/sub>O<sub>2<\/sub>\u7684\u8fc7\u7a0b\uff082H<sub>2<\/sub>O + 2h<sup>+<\/sup>\u00a0\u2192 H<sub>2<\/sub>O<sub>2<\/sub>\u00a0+ 2H<sup>+<\/sup>\uff09\u53d7\u5230\u8d8a\u6765\u8d8a\u591a\u7684\u5173\u6ce8\u3002\u7136\u800c\uff0c\u5728\u5b9e\u9645\u5e94\u7528\u4e2d\uff0c\u8fd9\u4e00\u8fc7\u7a0b\u9762\u4e34\u4e0e\u56db\u7535\u5b50\u9014\u5f84\u6c27\u6c14\u6790\u51fa\u53cd\u5e94\uff082H<sub>2<\/sub>O + 4h<sup>+<\/sup>\u00a0\u2192 O<sub>2<\/sub>\u00a0+ 4H<sup>+<\/sup>\uff09\u7684\u7ade\u4e89\u3002\u5728\u8fd9\u4e2a\u8fc7\u7a0b\u4e2d\u5b9e\u73b0\u9ad8H<sub>2<\/sub>O<sub>2<\/sub>\u9009\u62e9\u6027\u5df2\u7ecf\u88ab\u8bc1\u660e\u662f\u5177\u6709\u6311\u6218\u6027\u7684\uff0c\u7279\u522b\u662f\u5bf9\u4e8e\u5e7f\u6cdb\u4f7f\u7528\u7684\u91d1\u7ea2\u77f3\u76f8TiO<sub>2<\/sub>\uff08r-TiO<sub>2<\/sub>\uff09\u57fa\u6750\u6599\u3002\u6709\u8da3\u7684\u662f\uff0c\u6700\u8fd1\u7684\u7814\u7a76\u8868\u660e\uff0c\u901a\u8fc7\u7b80\u5355\u7684\u6676\u76f8\u8c03\u63a7\uff0c\u9ad8\u7eaf\u5ea6\u677f\u949b\u77ffTiO<sub>2<\/sub>\uff08b-TiO<sub>2<\/sub>\uff09\u4e0e\u5e38\u89c1\u7684\u91d1\u7ea2\u77f3\u76f8TiO<sub>2<\/sub>\uff08r-TiO<sub>2<\/sub>\uff09\u76f8\u6bd4\u8868\u73b0\u51fa\u663e\u8457\u7684H<sub>2<\/sub>O<sub>2<\/sub>\u9009\u62e9\u6027\u3002\u7136\u800c\uff0c\u8fd9\u4e24\u79cd\u6676\u76f8\u5177\u6709\u76f8\u540c\u7684\u539f\u5b50\u7ec4\u6210\u548c\u76f8\u4f3c\u7684\u539f\u5b50\u914d\u4f4d\u6784\u578b\uff0c\u5b83\u4eec\u53ef\u80fd\u5177\u6709\u76f8\u4f3c\u7684\u672c\u5f81\u50ac\u5316\u6d3b\u6027\u3002\u8fd9\u4fbf\u5f15\u53d1\u4e86\u4e00\u4e2a\u95ee\u9898\uff1a\u5728\u4e0d\u540c\u6676\u76f8\u8868\u9762\u4e0a\uff0c\u51b3\u5b9a\u53cd\u5e94\u9009\u62e9\u6027\u7684\u5173\u952e\u56e0\u7d20\u662f\u4ec0\u4e48\uff1f<\/section>\n<section><\/section>\n<section>\u4ece\u539f\u5b50\u6c34\u5e73\u4e0a\u7406\u89e3\u63a7\u5236WOR\u9009\u62e9\u6027\u7684\u56e0\u7d20\u5bf9\u4e8e\u9610\u660e\u6676\u76f8\u4f9d\u8d56\u6027\u5e76\u63d0\u9ad8H<sub>2<\/sub>O<sub>2<\/sub>\u7684\u9009\u62e9\u6027\u81f3\u5173\u91cd\u8981\u3002\u7136\u800c\uff0c\u63a2\u7a76\u51b3\u5b9a\u4e0d\u540c\u6676\u76f8\u8868\u9762\u53cd\u5e94\u9009\u62e9\u6027\u7684\u5173\u952e\u56e0\u7d20\u4ecd\u5341\u5206\u5177\u6709\u6311\u6218\u6027\uff0c\u8fd9\u4e3b\u8981\u7531\u6db2\u56fa\u754c\u9762\u4f53\u7cfb\u548c\u6fc0\u53d1\u6001\u5316\u5b66\u7684\u590d\u6742\u6027\u51b3\u5b9a\u3002\u9996\u5148\uff0cWOR\u8fc7\u7a0b\u6d89\u53ca\u8fc7\u6c27\u5316\u7269\u4e2d\u95f4\u4f53\u5f62\u6210\u7684\u591a\u79cd\u7ade\u4e89\u9014\u5f84\u548c\u590d\u6742\u7684\u8fc7\u6c27\u5316\u7269\u8f6c\u5316\u8fc7\u7a0b\u3002\u56e0\u6b64\uff0c\u53cd\u5e94\u7f51\u7edc\u7684\u590d\u6742\u6027\u4f7f\u5f97\u8fa8\u522bH<sub>2<\/sub>O<sub>2<\/sub>\u548cO<sub>2<\/sub>\u6790\u51fa\u7684\u673a\u7406\u548c\u52a8\u529b\u5b66\u975e\u5e38\u56f0\u96be\u3002\u5176\u6b21\uff0c\u660e\u786e\u7684\u6a21\u62df\u6db2\/\u56fa\u754c\u9762\u4e0a\u5149\u8bf1\u5bfc\u81ea\u7531\u57fa\u4e2d\u95f4\u4f53\uff08\u5982OH<sup>\u2022<\/sup>\u3001O<sup>\u2022\u2212<\/sup>\u00a0\u53ca\u8fc7\u6c27\u5316\u7269\u4e2d\u95f4\u4f53\uff09\u53ca\u5176\u5728\u754c\u9762\u5904\u7684\u53cd\u5e94\u5728\u65b9\u6cd5\u4e0a\u4ecd\u7136\u5f88\u56f0\u96be\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u5149\u50ac\u5316WOR\u8fc7\u7a0b\u53d1\u751f\u5728\u56fa\u6db2\u754c\u9762\uff0c\u6eb6\u6db2\u5fae\u73af\u5883\u5982\u4f55\u5f71\u54cd\u8fd9\u4e9b\u81ea\u7531\u57fa\u4e2d\u95f4\u4f53\u53ca\u5176\u53cd\u5e94\u70ed\u529b\u5b66\u548c\u52a8\u529b\u5b66\u5c1a\u4e0d\u786e\u5b9a\u3002\u56e0\u6b64\uff0c\u63a2\u7a76\u754c\u9762\u5fae\u73af\u5883\u5bf9\u5149\u50ac\u5316WOR\u52a8\u529b\u5b66\u7684\u5f71\u54cd\u975e\u5e38\u91cd\u8981\u3002<\/section>\n<section><\/section>\n<section data-mpa-template=\"t\">\n<section data-mpa-template=\"t\">\n<section>\n<section data-mpa-category=\"\u6a21\u677f\" data-mid=\"\">\n<section data-mid=\"\">\n<section data-mid=\"\"><\/section>\n<section data-mid=\"\">\u00a0\u00a0<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section><strong>\u672c\u6587\u4eae\u70b9<\/strong><\/section>\n<section>\uff081\uff09\u672c\u7814\u7a76\u91c7\u7528\u7b2c\u4e00\u6027\u539f\u7406\u5206\u5b50\u52a8\u529b\u5b66\u6a21\u62df\u548c\u5fae\u89c2\u52a8\u529b\u5b66\u5206\u6790\uff0c\u5bf9WOR\u5728\u6c34\/b-TiO<sub>2<\/sub>(210)\u548c\u6c34\/r-TiO<sub>2<\/sub>(110)\u754c\u9762\u4e0a\u7684\u9009\u62e9\u6027\u673a\u7406\u8fdb\u884c\u4e86\u5168\u9762\u7684\u7814\u7a76\uff0c\u5206\u6790\u4e86\u6574\u4f53\u6d3b\u6027\u8d8b\u52bf\uff0c\u5e76\u786e\u5b9a\u4e86\u4e3b\u8981\u7684\u53cd\u5e94\u9014\u5f84\u3001\u5173\u952e\u4e2d\u95f4\u4f53\u7684\u8868\u9762\u8986\u76d6\u5ea6\u4ee5\u53ca\u4e3b\u8981\u7684\u52a8\u529b\u5b66\u969c\u788d\u3002<\/section>\n<section>\uff082\uff09\u8bc1\u660eb-TiO<sub>2<\/sub>(210)\u4e0er-TiO<sub>2<\/sub>(110)\u50ac\u5316\u5242\u5177\u6709\u76f8\u4f3c\u7684OH<sup>\u2022<\/sup>\u81ea\u7531\u57fa\u5f62\u6210\u7684\u672c\u5f81\u6d3b\u6027\u3002<\/section>\n<section>\uff083\uff09\u5b9a\u91cf\u63ed\u793a\u4e86\u6db2\/\u56fa\u754c\u9762\u5904\u7684\u5c40\u90e8\u6c22\u952e\u7ed3\u6784\uff08\u6c34\u5bc6\u5ea6\uff09\u5bf9\u8c03\u63a7\u5149\u50ac\u5316\u9009\u62e9\u6027\u7684\u5173\u952e\u4f5c\u7528\u3002\u6c34\/b-TiO<sub>2<\/sub>(210)\u754c\u9762\u63d0\u9ad8H<sub>2<\/sub>O<sub>2<\/sub>\u9009\u62e9\u6027\u7684\u5173\u952e\u56e0\u7d20\u662f\u754c\u9762\u5f31\u7684\u6c22\u952e\u76f8\u4e92\u4f5c\u7528\uff0c\u4e0d\u4ec5\u6709\u5229\u4e8e\u76f8\u5bf9\u758f\u6c34\u7684OH<sup>\u2022<\/sup>\u81ea\u7531\u57fa\u5f62\u6210\uff0c\u5e76\u4e14\u6709\u52a9\u4e8e\u6291\u5236\u5176\u53bb\u8d28\u5b50\u5316\uff0c\u4ece\u800c\u63d0\u9ad8H<sub>2<\/sub>O<sub>2<\/sub>\u7684\u9009\u62e9\u6027\u3002<\/section>\n<section><\/section>\n<section data-mpa-template=\"t\">\n<section data-mpa-template=\"t\">\n<section>\n<section data-mpa-category=\"\u6a21\u677f\" data-mid=\"\">\n<section data-mid=\"\">\n<section data-mid=\"\"><\/section>\n<section data-mid=\"\">\u00a0\u00a0<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section><strong>\u56fe\u6587\u89e3\u6790<\/strong><\/section>\n<section><img decoding=\"async\" title=\"1\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240314\/1710383999503768.png\" alt=\"1\" \/><\/section>\n<section>\u56fe1| b-TiO<sub>2<\/sub>(210)\u548cr-TiO<sub>2<\/sub>(110)\u7684\u914d\u4f4d\u6784\u578b\u53ca\u5149\u50ac\u5316WOR\u5236H<sub>2<\/sub>O<sub>2<\/sub>\/O<sub>2<\/sub>\u7684\u4e00\u822c\u673a\u7406<\/section>\n<section><\/section>\n<section>\u8981\u70b91\uff1a<\/section>\n<section>\u7531\u4e8eb-TiO<sub>2<\/sub>(210)\u548cr-TiO<sub>2<\/sub>(110)\u4e24\u79cd\u6676\u76f8\u7684\u6784\u578b\u5177\u6709\u76f8\u540c\u7684\u539f\u5b50\u7ec4\u6210\u548c\u76f8\u4f3c\u7684\u539f\u5b50\u914d\u4f4d\u6784\u578b\uff08\u56fe1\uff09\uff0c\u5e76\u5728\u8868\u9762\u66b4\u9732\u51fa\u76f8\u4f3c\u7684\u4e94\u914d\u4f4dTi\u4f4d\u70b9\uff08Ti<sub>5c<\/sub>\uff0cWOR\u7684\u4e00\u4e2a\u5173\u952e\u6d3b\u6027\u4f4d\u70b9\uff09\uff0c\u53ef\u77e5\u8fd9\u4e24\u79cd\u6676\u578b\u53ef\u80fd\u5177\u6709\u76f8\u4f3c\u7684\u672c\u5f81\u50ac\u5316\u6d3b\u6027\u3002\u56fe1\u6982\u8ff0\u4e86\u5149\u50ac\u5316WOR\u53ef\u80fd\u7684\u53cd\u5e94\u8def\u5f84\uff0c\u5927\u81f4\u53ef\u4ee5\u5206\u4e3a\u4e09\u4e2a\u9636\u6bb5\uff1a\u7b2c\u4e00\u9636\u6bb5\uff0cO-H \u952e\u89e3\u79bb\uff1b\u7b2c\u4e8c\u9636\u6bb5\uff0cO-O \u952e\u5f62\u6210\uff1b\u548c\u7b2c\u4e09\u9636\u6bb5\uff0cO<sub>2<\/sub>\/H<sub>2<\/sub>O<sub>2<\/sub>\u00a0\u6790\u51fa\u3002<\/section>\n<section><\/section>\n<section><\/section>\n<section><img decoding=\"async\" title=\"2\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240314\/1710384010513926.jpg\" alt=\"2\" \/><\/section>\n<section>\u56fe2| WOR\u5728\u6c34\/b-TiO<sub>2<\/sub>(210)\u548c\u6c34\/r-TiO<sub>2<\/sub>(110)\u754c\u9762\u7684\u53cd\u5e94\u52a8\u529b\u5b66\u5206\u6790\u53ca\u53cd\u5e94\u673a\u7406<\/section>\n<section><\/section>\n<section><strong>\u8981\u70b92\uff1a<\/strong><\/section>\n<section><\/section>\n<section>\u6839\u636e\u52a8\u529b\u5b66\u7ed3\u679c\uff0c\u5728\u6c34\/b-TiO<sub>2<\/sub>(210)\u754c\u9762\u4e0a\uff0cH<sub>2<\/sub>O<sub>2<\/sub>\u662f\u4e3b\u8981\u4ea7\u7269\uff0c\u5176\u751f\u6210\u901f\u7387\u7ea6\u4e3aO<sub>2<\/sub>\u76843.7\u500d\u3002\u5176\u4e2d\uff0cH<sub>2<\/sub>O<sub>2<\/sub>\u662f\u901a\u8fc7OH<sup>\u2022<\/sup>\/OH<sup>\u2022<\/sup>\u8026\u5408\u9014\u5f84\u4ea7\u751f\u7684\uff0c\u800cO<sub>2<\/sub>\u5219\u662f\u901a\u8fc7\u6c34\/b-TiO<sub>2<\/sub>(210)\u754c\u9762\u7684O<sup>\u2022\u2212<\/sup>\/O<sup>\u2022\u2212<\/sup>\u8026\u5408\u9014\u5f84\u4ea7\u751f\u7684\u3002\u7136\u800c\uff0c\u5728\u6c34\/r-TiO<sub>2<\/sub>(110)\u754c\u9762\uff0cO<sub>2<\/sub>\u662f\u4e3b\u8981\u4ea7\u7269\uff0c\u4e3b\u8981\u901a\u8fc7O<sup>\u2022\u2212<\/sup>\/O<sup>\u2022\u2212<\/sup>\u8026\u5408\u9014\u5f84\u5f62\u6210\uff0c\u5360100%\uff0cH<sub>2<\/sub>O<sub>2<\/sub>\u7684\u751f\u6210\u51e0\u4e4e\u53ef\u4ee5\u5ffd\u7565\u4e0d\u8ba1\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0cOH<sup>\u2022<\/sup>\u8986\u76d6\u5ea6\u5728\u6c34\/b-TiO<sub>2<\/sub>(210)\u754c\u9762\u5904\u6bd4\u6c34\/r-TiO<sub>2<\/sub>(110)\u754c\u9762\u7ea6\u9ad8\u4e09\u4e2a\u6570\u91cf\u7ea7\u3002<\/section>\n<section>\u5f53\u53cd\u5e94\u5728\u6c34\/b-TiO<sub>2<\/sub>(210)\u754c\u9762\u5904\u8fbe\u5230\u5e73\u8861\u65f6\uff0cH<sub>2<\/sub>O<sub>2<\/sub>\u548cO<sub>2<\/sub>\u7684\u751f\u6210\u901f\u7387\u53ef\u5199\u6210\uff1a<\/section>\n<section><\/section>\n<section><img decoding=\"async\" title=\"3\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240314\/1710384017322769.png\" alt=\"3\" \/><\/section>\n<section><\/section>\n<section>\u5176\u4e2dk<sub>6+<\/sub>\u00a0\u548ck<sub>7+<\/sub>\u00a0\u5206\u522b\u5bf9\u5e94\u4e8e\u6b65\u9aa46\uff08OH<sup>\u2022<\/sup>\/OH<sup>\u2022<\/sup>\u8026\u5408\uff09\u548c\u6b65\u9aa47\uff08O<sup>\u2022\u2212<\/sup>\/O<sup>\u2022\u2212\u00a0<\/sup>\u8026\u5408\uff09\u7684\u6b63\u53cd\u5e94\u901f\u7387\u5e38\u6570\uff0c\u5b83\u4eec\u7531\u53cd\u5e94\u80fd\u5792\u51b3\u5b9a\u3002\u03b8(OH<sup>\u2022<\/sup>)\u548c\u00a0\u03b8(O<sup>\u2022\u2212<\/sup>)\u5206\u522b\u8868\u793aOH<sup>\u2022<\/sup>\u548cO<sup>\u2022\u2212<\/sup>\u4e2d\u95f4\u4f53\u7684\u8986\u76d6\u5ea6\u3002\u6839\u636e\u8be5\u65b9\u7a0b\u5f0f\uff0c\u63a7\u5236WOR\u9009\u62e9\u6027\u7684\u4e3b\u8981\u969c\u788d\u53ef\u5206\u4e3a\u4e24\u4e2a\u56e0\u7d20\uff1a\uff08i\uff09\u03b8(OH<sup>\u2022<\/sup>)\u548c\u03b8(O<sup>\u2022\u2212<\/sup>)\u7684\u503c\uff0c\u4ee5\u53ca\uff08ii\uff09OH<sup>\u2022<\/sup>\/OH<sup>\u2022<\/sup>\u8026\u5408\u548cO<sup>\u2022\u2212<\/sup>\/O<sup>\u2022\u2212\u00a0<\/sup>\u8026\u5408\u7684\u80fd\u5792\u3002\u00a0<\/section>\n<section><\/section>\n<section><\/section>\n<section><img decoding=\"async\" title=\"4\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240314\/1710384024441532.jpg\" alt=\"4\" \/><\/section>\n<section>\u56fe3| \u6db2\/\u56fa\u754c\u9762\u4e0aOH<sup>\u2022<\/sup>\u81ea\u7531\u57fa\u7684\u5f62\u6210<\/section>\n<section><\/section>\n<section><strong>\u8981\u70b93\uff1a<\/strong><\/section>\n<section>\u6db2\u56fa\u754c\u9762\u4e0aOH<sup>\u2022<\/sup>\u7684HTC\u503c\uff08\u7a7a\u7a74\u6355\u83b7\u80fd\u529b\uff09\u6bd4\u6c14\/\u50ac\u5316\u5242\u754c\u9762\u4e0a\u7684HTC\u503c\u653e\u70ed\u66f4\u5c11\uff08\u56fe3b\uff09\uff0c\u8fd9\u8868\u660e\u6eb6\u5242\u5316\u6548\u5e94\u51cf\u5f31\u4e86OH<sup>\u2022<\/sup>\u7684\u5f62\u6210\u3002\u6b64\u5916\uff0c\u6c34\/b-TiO<sub>2<\/sub>(210)\u754c\u9762\u7684HTC\u503c\u6bd4\u6c34\/r-TiO<sub>2<\/sub>(110)\u754c\u9762\u7684HTC\u503c\u66f4\u8d1f\uff0c\u8bf4\u660e\u6eb6\u6db2\u5bf9b-TiO<sub>2<\/sub>(210)\u8868\u9762\u7684\u524a\u5f31\u4f5c\u7528\u6ca1\u6709\u6c34\/r-TiO<sub>2<\/sub>(110)\u754c\u9762\u660e\u663e\u3002\u8fdb\u4e00\u6b65\u7684\u6c34\u5438\u9644\u7279\u6027\u548c\u76f8\u5e94\u7684\u6c34\u7f51\u7edc\u5206\u5e03\u7684\u5206\u6790\u8868\u660e\uff0cb-TiO<sub>2<\/sub>(210)\u8868\u9762\u7531\u4e8e\u5f3a\u7684\u6c34\u5438\u9644\u80fd\uff08\u56fe3f\uff09\u548c\u72ec\u7279\u7684\u5438\u9644\u65b9\u5411\uff08\u56fe3c-e\uff09\uff0c\u964d\u4f4e\u4e86\u5438\u9644\u5c42\u4e0e\u8fd1\u5438\u9644\u5c42\u6c34\u4e4b\u95f4\u7684\u6c22\u952e\u76f8\u4e92\u4f5c\u7528\uff0c\u5bfc\u81f4\u754c\u9762\u5904\u6c34\u5bc6\u5ea6\u51cf\u5c0f\u3002\u56e0\u6b64\uff0c\u5728\u6c34\/b-TiO<sub>2<\/sub>(210)\u754c\u9762\u4e0a\u5f62\u6210\u7684\u76f8\u5bf9\u758f\u6c34\u6027\u7684OH<sup>\u2022<\/sup>\u53d7\u6eb6\u5242\u5316\u6548\u5e94\u7684\u5f71\u54cd\u8f83\u5c0f\uff0c\u8fd9\u5c31\u89e3\u91ca\u4e86\u4e3a\u4ec0\u4e48\u5728\u6c34\/b-TiO<sub>2<\/sub>(210)\u754c\u9762\u4e0a\u7684\u03b8(OH<sup>\u2022<\/sup>)\u6bd4\u4e0a\u6c34\/r-TiO<sub>2<\/sub>(110)\u754c\u9762\u7684\u5927\u3002<\/section>\n<section><\/section>\n<section><img decoding=\"async\" title=\"5\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240314\/1710384032426655.jpg\" alt=\"5\" \/><\/section>\n<section>\u56fe4| \u6c34\u5206\u5b50\u5728b-TiO<sub>2<\/sub>(210)\u754c\u9762\u5904\u7684\u7edf\u8ba1\u5206\u5e03\u6982\u7387<\/section>\n<section><\/section>\n<section>\u6b64\u5de5\u4f5c\u4eceAIMD\u6a21\u62df\u7684\u5e73\u8861\u6784\u578b\u4e2d\u5171\u9009\u53d6\u9009\u53d6500\u6b65\u5177\u6709\u4ee3\u8868\u6027\u7684\u7ed3\u6784\uff0c\u8ba1\u7b97\u6c34\u5206\u5e03\u6982\u7387\u3002\u901a\u8fc7\u6bd4\u8f83\u76f8\u540c\u5438\u9644\u4f4d\u70b9\u7684\u6c34\u5206\u5b50\u5438\u9644\u65b9\u5411\u8bc1\u5b9e\u4e86\u6c34\u5206\u5b50\u7684\u5438\u9644\u65b9\u5411\u662f\u5f71\u54cd\u6c34\u6c22\u952e\u7f51\u7edc\u5206\u5e03\u7684\u4e00\u4e2a\u91cd\u8981\u56e0\u7d20\u3002\u5982\u56fe4\u6240\u793a\uff0c\u6c34\u5206\u5b50\u7684\u201cH-parallel\u201d\u6784\u578b\u660e\u663e\u964d\u4f4e\u4e86\u5438\u9644\u5c42\u4e0e\u8fd1\u5438\u9644\u5c42\u6c34\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\uff0c\u5bfc\u81f4\u6c22\u952e\u76f8\u4e92\u4f5c\u7528\u51cf\u5f31\uff0c\u5728b-TiO<sub>2<\/sub>(210)\u8868\u9762\u6c34\u5206\u5b50\u5438\u9644\u5c42\u4e0e\u8fd1\u5438\u9644\u5c42\u4e4b\u95f4\u5f62\u6210\u4e86\u4e00\u4e2a\u7a7a\u8154\uff0c\u8fd9\u4e2a\u7a7a\u8154\u53ef\u4ee5\u5bb9\u7eb3\u5e76\u7a33\u5b9a\u76f8\u5bf9\u758f\u6c34\u6027\u7684OH<sup>\u2022<\/sup>\u81ea\u7531\u57fa\u3002\u4e0e\u4e4b\u76f8\u53cd\u7684\uff0c\u201cH-up\u201d\u6784\u578b\u5bfc\u81f4\u4e86\u8fd1\u5438\u9644\u5c42\u66f4\u52a0\u9760\u8fd1\u5438\u9644\u5c42\uff0c\u4f7f\u5f97\u5438\u9644\u7684\u6c34\u5206\u5b50\u4e0e\u8fd1\u5438\u9644\u5c42\u4e2d\u6c34\u5206\u5b50\u95f4\u7684\u6c22\u952e\u76f8\u4e92\u4f5c\u7528\u589e\u52a0\uff08\u9ec4\u8272\u9ad8\u4eae\u90e8\u5206\uff09\u3002<\/section>\n<section><\/section>\n<section><img decoding=\"async\" title=\"6\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240314\/1710384040797741.jpg\" alt=\"6\" \/><\/section>\n<section>\u56fe5| \u6db2\/\u56fa\u754c\u9762\u4e0aOH<sup>\u2022<\/sup>\u7684\u53bb\u8d28\u5b50\u5316<\/section>\n<section><\/section>\n<section><strong>\u8981\u70b94\uff1a<\/strong><\/section>\n<section>OH<sup>\u2022<\/sup>\u53bb\u8d28\u5b50\u5316\uff08OH<sup>\u2022<\/sup>\u00a0\u2192 O<sup>\u2022\u2212<\/sup>\u00a0+ H<sup>+<\/sup>(sol)\uff09\u662f\u51b3\u5b9a\u03b8(OH<sup>\u2022<\/sup>)\u4e0e\u03b8(O<sup>\u2022\u2212<\/sup>)\u6bd4\u4f8b\u7684\u91cd\u8981\u8fc7\u7a0b\u3002\u52a8\u529b\u5b66\u5206\u6790\u8868\u660e\uff0c\u03b8(OH<sup>\u2022<\/sup>)\u3001\u03b8(O<sup>\u2022\u2212<\/sup>)\u548cH<sub>2<\/sub>O<sub>2<\/sub>\u7684\u9009\u62e9\u6027\u663e\u8457\u53d7\u5230OH<sup>\u2022<\/sup>\u53bb\u8d28\u5b50\u5316\u80fd\u5792\u7684\u5f71\u54cd\uff08\u56fe5a-c\uff09\u3002\u5728\u6c34\u73af\u5883\u4e2d\uff0cO-Ti\u952e\u5f3a\u4ee5\u53caOH<sup>\u2022<\/sup>\u7684H\u539f\u5b50\u548c\u8fd1\u5438\u9644\u5c42\u6c34\u5206\u5b50\u7684O\u539f\u5b50\u95f4\u7684\u6c22\u952e\u5f3a\u5ea6\u5c06\u5171\u540c\u5f71\u54cdO-H\u952e\u7684\u65ad\u88c2\uff08\u89c1\u56fe5d\u63d2\u56fe\uff09\u3002\u7136\u800c\uff0c\u7531\u4e8eO-Ti\u952e\u5f3a\u5ea6\u5728\u4e09\u4e2a\u4f4d\u70b9\u4e0a\u7684\u53d8\u5316\u5f88\u5c0f\uff08\u56fe5d\uff09\uff0c\u8fd9\u610f\u5473\u7740\u5176\u5f71\u54cd\u7a0b\u5ea6\u8fdc\u5c0f\u4e8e\u6c22\u952e\u5f3a\u5ea6\u3002\u968f\u7740\u6c22\u952e\u5f3a\u5ea6\u6309\u7167Ti<sub>5c<\/sub>\u00a0&gt; Ti<sub>5c<\/sub><sup>B<\/sup>\u00a0&gt; Ti<sub>5c<\/sub><sup>G<\/sup>\u7684\u987a\u5e8f\u9012\u51cf\uff0c\u76f8\u5e94\u7684O-H\u952e\u65ad\u88c2\u80fd\u5792\u4e5f\u968f\u4e4b\u589e\u52a0\u3002\u91cd\u8981\u7684\u662f\uff0cOH<sup>\u2022<\/sup>\u7684\u53bb\u8d28\u5b50\u5316\u80fd\u5792\u4e0e\u4e24\u4e2a\u754c\u9762\u4e0a\u7684\u6c22\u952e\u5f3a\u5ea6\u5448\u826f\u597d\u7684\u7ebf\u6027\u5173\u7cfb\u3002\u56e0\u6b64\uff0c\u6c34\/b-TiO<sub>2<\/sub>(210)\u754c\u9762\u4e0aOH<sup>\u2022<\/sup>\u548c\u8fd1\u5438\u9644\u5c42\u6c34\u4e4b\u95f4\u7684\u5f31\u6c22\u952e\u76f8\u4e92\u4f5c\u7528\u5728OH<sup>\u2022<\/sup>\u7684\u53bb\u8d28\u5b50\u5316\u8fc7\u7a0b\u4e2d\u8d77\u7740\u91cd\u8981\u7684\u949d\u5316\u4f5c\u7528\u3002<\/section>\n<section><\/section>\n<section><img decoding=\"async\" title=\"7\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240314\/1710384050515305.jpg\" alt=\"7\" \/><\/section>\n<section>\u56fe6| \u6c34\/TiO<sub>2<\/sub>\u754c\u9762\u4e0a\u7684O-O\u8026\u5408<\/section>\n<section><\/section>\n<section><strong>\u8981\u70b95\uff1a<\/strong><\/section>\n<section>\u4e0eO-O\u8026\u5408\u76f8\u5173\u7684\u80fd\u5792\u662f\u5f71\u54cdH<sub>2<\/sub>O<sub>2<\/sub>\u9009\u62e9\u6027\u7684\u53e6\u4e00\u4e2a\u5173\u952e\u56e0\u7d20\u3002\u5728\u6c34\/b-TiO<sub>2<\/sub>(210)\u754c\u9762\u5904\uff0c\u7531\u4e8e\u6c22\u952e\u4f5c\u7528\uff0cOH<sup>\u2022<\/sup>\/OH<sup>\u2022<\/sup>\u8026\u5408\u80fd\u5792\u4ece0.71 eV\u663e\u8457\u964d\u4f4e\u52300.38 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data-mid=\"\">\u00a0\u00a0<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section><strong>\u603b\u7ed3\u4e0e\u5c55\u671b<\/strong><\/section>\n<section>\u672c\u5de5\u4f5c\u5c55\u793a\u4e86\u4e00\u79cd\u6709\u8da3\u7684\u754c\u9762\u5316\u5b66\uff0c\u5e76\u63d0\u4f9b\u4e86\u5bf9\u6c34\/b-TiO<sub>2<\/sub>(210)\u548c\u6c34\/r-TiO<sub>2<\/sub>(110)\u754c\u9762\u4e0a\u6c34\u6c27\u5316\u53cd\u5e94\u9009\u62e9\u6027\u7684\u5168\u9762\u7406\u89e3\u3002\u7814\u7a76\u7ed3\u679c\u8868\u660e\uff0c\u5728\u6c34\/b-TiO<sub>2<\/sub>(210)\u754c\u9762\u5904OH<sup>\u2022<\/sup>\u81ea\u7531\u57fa\u8986\u76d6\u5ea6\u8f83\u9ad8\uff0c\u5e76\u4e14\u8be5\u754c\u9762\u6c22\u952e\u6709\u5229\u4e8eOH<sup>\u2022<\/sup>\/OH<sup>\u2022<\/sup>\u8026\u5408\uff0c\u56e0\u6b64\u5728\u5149\u50ac\u5316\u8fc7\u7a0b\u4e2dH<sub>2<\/sub>O<sub>2<\/sub>\u7684\u9009\u62e9\u6027\u8f83\u9ad8\u3002\u76f8\u53cd\uff0c\u4e0e\u6c34\/b-TiO<sub>2<\/sub>(210)\u754c\u9762\u76f8\u6bd4\uff0c\u6c34\/r-TiO<sub>2<\/sub>(110)\u754c\u9762\u7684OH<sup>\u2022<\/sup>\u8986\u76d6\u5ea6\u660e\u663e\u8f83\u4f4e\uff0c\u5176\u6c22\u952e\u7684\u65b9\u5411\u963b\u788d\u4e86\u8be5\u754c\u9762\u4e0a\u7684O-O\u8026\u5408\uff0c\u5bfc\u81f4\u8be5\u754c\u9762\u51e0\u4e4e\u4e0d\u4ea7\u751fH<sub>2<\/sub>O<sub>2<\/sub>\u3002\u8fd9\u79cd\u72ec\u7279\u7684\u9009\u62e9\u6027\u884c\u4e3a\u662f\u7531b-TiO<sub>2<\/sub>(210)\u8868\u9762\u4e0a\u7c7b\u4f3c\u9c7c\u9aa8\u5f62\u7684\u5c40\u90e8\u539f\u5b50\u7ed3\u6784\u8c03\u63a7\u7684\u5f31\u6c22\u952e\u76f8\u4e92\u4f5c\u7528\u51b3\u5b9a\u7684\uff0c\u53ef\u5f52\u7eb3\u4e3a\u4ee5\u4e0b\u51e0\u70b9\uff1a<\/section>\n<section><\/section>\n<section>\uff081\uff09\u5728\u6c34\/b-TiO<sub>2<\/sub>(210)\u754c\u9762\u4e0a\uff0c\u8f83\u5f3a\u7684\u6c34\u5438\u9644\u80fd\u548c\u72ec\u7279\u7684\u5438\u9644\u53d6\u5411\u524a\u5f31\u4e86\u5438\u9644\u5c42\u6c34\u4e0e\u8fd1\u5438\u9644\u5c42\u6c34\u4e4b\u95f4\u7684\u5c40\u90e8\u6c22\u952e\u76f8\u4e92\u4f5c\u7528\uff0c\u4ece\u800c\u5728b-TiO<sub>2<\/sub>(210)\u8868\u9762\u5f62\u6210\u8f83\u4f4e\u7684\u6c34\u5bc6\u5ea6\u5fae\u73af\u5883\u3002<\/section>\n<section><\/section>\n<section>\uff082\uff09\u6c34\/b-TiO<sub>2<\/sub>(210)\u754c\u9762\u4e0a\u7684\u5f31\u6c22\u952e\u76f8\u4e92\u4f5c\u7528\u589e\u5f3a\u4e86\u76f8\u5bf9\u758f\u6c34\u6027OH<sup>\u2022<\/sup>\u81ea\u7531\u57fa\u7684\u5f62\u6210\uff0c\u5e76\u963b\u788d\u4e86OH<sup>\u2022<\/sup>\u7684\u53bb\u8d28\u5b50\u5316\uff0c\u4ece\u800c\u63d0\u9ad8\u4e86\u8868\u9762\u4e0aOH<sup>\u2022<\/sup>\u7684\u8986\u76d6\u5ea6\u3002<\/section>\n<section><\/section>\n<section>\uff083\uff09\u6c34\/b-TiO<sub>2<\/sub>(210)\u754c\u9762\u7684\u6c22\u952e\u7f51\u7edc\u6709\u5229\u4e8eOH<sup>\u2022<\/sup>\/OH<sup>\u2022<\/sup>\u8026\u5408\uff0c\u4fc3\u8fdb\u4e86H<sub>2<\/sub>O<sub>2<\/sub>\u7684\u751f\u6210\u3002<\/section>\n<section>\u8fd9\u9879\u5de5\u4f5c\u7a81\u51fa\u4e86\u5149\u50ac\u5316\u8fc7\u7a0b\u4e2d\u6db2\u56fa\u754c\u9762\u7684\u7ed3\u6784-\u9009\u62e9\u6027\u5173\u7cfb\uff0c\u5b9a\u91cf\u5730\u8868\u660e\u6db2\/\u56fa\u754c\u9762\u5904\u7684\u5c40\u90e8\u6c22\u952e\u7ed3\u6784\uff08\u6c34\u5bc6\u5ea6\uff09\u5bf9\u8c03\u63a7\u5149\u50ac\u5316\u9009\u62e9\u6027\u7684\u5173\u952e\u4f5c\u7528\uff0c\u4e3a\u8fdb\u4e00\u6b65\u8bbe\u8ba1\u66f4\u9ad8H<sub>2<\/sub>O<sub>2<\/sub>\u9009\u62e9\u6027\u7684\u50ac\u5316\u5242\u63d0\u4f9b\u4e86\u6307\u5bfc\u3002<\/section>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u25b2\u5171\u540c\u7b2c\u4e00\u4f5c\u8005\uff1a\u4efb\u51a0\u534e\u3001\u5468\u654f 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