{"id":51138,"date":"2024-04-03T08:37:45","date_gmt":"2024-04-03T00:37:45","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=51138"},"modified":"2024-03-24T09:38:40","modified_gmt":"2024-03-24T01:38:40","slug":"%e4%b8%ad%e5%9b%bd%e8%8d%af%e7%a7%91%e5%a4%a7%e5%ad%a6%e7%aa%a6%e6%99%93%e5%b7%8d%e8%af%be%e9%a2%98%e7%bb%84%ef%bc%9a%e8%81%94%e8%8a%b3%e5%9f%ba%e5%8d%8a%e7%a1%bc%e9%85%b8%e9%85%af%e9%80%9a%e8%bf%87","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/%e4%b8%ad%e5%9b%bd%e8%8d%af%e7%a7%91%e5%a4%a7%e5%ad%a6%e7%aa%a6%e6%99%93%e5%b7%8d%e8%af%be%e9%a2%98%e7%bb%84%ef%bc%9a%e8%81%94%e8%8a%b3%e5%9f%ba%e5%8d%8a%e7%a1%bc%e9%85%b8%e9%85%af%e9%80%9a%e8%bf%87\/","title":{"rendered":"\u4e2d\u56fd\u836f\u79d1\u5927\u5b66\u7aa6\u6653\u5dcd\u8bfe\u9898\u7ec4\uff1a\u8054\u82b3\u57fa\u534a\u787c\u9178\u916f\u901a\u8fc7\u52a8\u6001\u52a8\u529b\u5b66\u9009\u62e9\u6027Suzuki-Miyaura\u4ea4\u53c9\u5076\u8054\u5408\u6210\u8054\u82b3\u57fa\u963b\u8f6c\u5f02\u6784\u4f53"},"content":{"rendered":"<p>\u671f\u520a\u540d\uff1aJACS<\/p>\n<p>DOI\uff1a10.1021\/jacs.3c14450<\/p>\n<p>&nbsp;<\/p>\n<section>\u8054\u82b3\u57fa\u963b\u8f6c\u5f02\u6784\u4f53\u4e0d\u4ec5\u5e7f\u6cdb\u5b58\u5728\u4e8e\u5929\u7136\u5316\u5408\u7269\u4e2d\uff0c\u800c\u4e14\u5e7f\u6cdb\u5b58\u5728\u4e8e\u5408\u6210\u529f\u80fd\u5206\u5b50\u548c\u65b0\u6750\u6599\u4e2d\u3002\u6b64\u5916\uff0c\u8054\u82b3\u57fa\u963b\u8f6c\u5f02\u6784\u4f53\u7684\u72ec\u7279\u6784\u8c61\u4f7f\u5176\u5728\u73b0\u4ee3\u836f\u7269\u53d1\u5c55\u4e2d\u666e\u904d\u5b58\u5728\u3002\u6784\u578b\u4e0d\u7a33\u5b9a\u7684\u6865\u8fde\u8054\u82b3\u57fa\u7684\u52a8\u6001\u52a8\u529b\u5b66\u4e0d\u5bf9\u79f0\u5f00\u73af\u8f6c\u5316\u5df2\u7ecf\u6210\u4e3a\u83b7\u5f97\u8054\u82b3\u57fa\u963b\u8f6c\u5f02\u6784\u4f53\u7684\u975e\u5e38\u6709\u7528\u7684\u65b9\u6cd5\u3002\u73b0\u6709\u6280\u672f\u7684\u7b56\u7565\u91c7\u7528\u4e94\u5143\u548c\u516d\u5143\u6865\u73af\u3002\u4f46\u53ef\u7528\u7684\u8f6c\u6362\u4ecd\u7136\u6709\u9650\u3002\u6b64\u5916\uff0c\u73b0\u6709\u7684\u6865\u8fde\u8054\u82b3\u57fa\u8bd5\u5242\u901a\u5e38\u4e0e\u4eb2\u6838\u8bd5\u5242\u53cd\u5e94\uff0c\u5e76\u4e14\u4ecd\u7136\u7f3a\u4e4f\u8868\u73b0\u51fa\u4e92\u8865\u53cd\u5e94\u6027\u7684\u901a\u7528\u6865\u8fde\u8054\u82b3\u57fa\u8bd5\u5242\u3002Hall\u7b49\u4eba\u7814\u7a76\u4e86\u534a\u787c\u90bb\u83f2\u54af\u70f7\u7684\u6027\u8d28\uff0c\u53d1\u73b0\u4e8c\u82ef\u5e76\u6c27\u6742\u787c\u6742\u73af\u620a\u70ef\u884d\u751f\u7269\u53ef\u4ee5\u4e0e\u77ac\u65f6\u787c\u9178\u53d1\u751f\u5feb\u901f\u6c34\u89e3\u5f00\u73af-\u95ed\u73af\u5e73\u8861\uff0c\u5728\u6b64\u4f5c\u8005\u4ecb\u7ecd\u4e86\u591a\u53d6\u4ee3\u4e8c\u82ef\u5e76\u6c27\u6742\u787c\u6742\u73af\u620a\u70ef\u884d\u751f\u7269\uff0c\u79f0\u4e3a\u8054\u82b3\u57fa\u534a\u787c\u9178\u916f\uff0c\u4f5c\u4e3a\u4e00\u79cd\u65b0\u578b\u7684\u6865\u8054\u8054\u82b3\u57fa\u8bd5\u5242\uff0c\u7528\u4e8e\u8054\u82b3\u57fa\u963b\u8f6c\u5f02\u6784\u4f53\u5408\u6210\u3002<\/section>\n<section><img decoding=\"async\" title=\"1\" src=\"https:\/\/17332.seohost.cn\/storage\/17332\/article\/20240304\/1709519737262610.png\" alt=\"1\" \/><\/section>\n<section>\u5728\u673a\u7406\u4e0a\uff0c\u50ac\u5316\u4e0d\u5bf9\u79f0Suzuki-Miyaura\u53cd\u5e94\u901a\u5e38\u901a\u8fc7\u9009\u62e9\u6027\u8fd8\u539f\u6d88\u9664\u4ea7\u751f\u8f74\u5411\u624b\u6027\u3002\u5728\u8fd9\u9879\u7814\u7a76\u4e2d\uff0c\u4f5c\u8005\u62a5\u544a\u4e86\u8054\u82b3\u57fa\u534a\u787c\u9178\u916f\u4e0e\u6709\u673a\u5364\u5316\u7269\u7684\u50ac\u5316\u4e0d\u5bf9\u79f0Suzuki-Miyaura\u4ea4\u53c9\u5076\u8054\uff0c\u5176\u4e2d\u52a8\u6001\u52a8\u529b\u5b66\u9009\u62e9\u6027\u91d1\u5c5e\u8f6c\u79fb\u88ab\u786e\u5b9a\u4e3a\u5bf9\u6620\u4f53\u51b3\u5b9a\u6b65\u9aa4\u3002<\/section>\n<p>&nbsp;<\/p>\n<p><img decoding=\"async\" title=\"2\" src=\"https:\/\/17332.seohost.cn\/storage\/17332\/article\/20240304\/1709519749563154.png\" alt=\"2\" 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kcal\/mol\uff0c\u8868\u660e\uff08R\uff09-1a\u548c\uff08S\uff09-1a\u5728\u73af\u5883\u6e29\u5ea6\u4e0b\u5feb\u901f\u76f8\u4e92\u8f6c\u5316\uff0c\u8fd9\u4e3a\u6240\u9700\u7684\u52a8\u6001\u52a8\u529b\u5b66\u4e0d\u5bf9\u79f0\u8f6c\u5316\u5960\u5b9a\u4e86\u57fa\u7840\u3002<\/section>\n<p>&nbsp;<\/p>\n<p><img decoding=\"async\" title=\"3\" src=\"https:\/\/17332.seohost.cn\/storage\/17332\/article\/20240304\/1709519758529210.png\" alt=\"3\" 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\/><\/p>\n<p>&nbsp;<\/p>\n<section>\u63a5\u4e0b\u6765\u4f5c\u8005\u8fdb\u884c\u4e86\u5e95\u7269\u62d3\u5c55\u3002\u82b3\u57fa\u6eb4\u5728\u6807\u51c6\u6761\u4ef6\u4e0b\u53ef\u8010\u53d7\uff0c\u4e3a\u8fdb\u4e00\u6b65\u8f6c\u5316\u63d0\u4f9b\u4e86\u826f\u597d\u7684\u57fa\u7840\u3002\u70ef\u57fa\u548c\u7094\u57fa\u6eb4\u5316\u7269\u4e5f\u5728\u7a0d\u5fae\u6539\u53d8\u7684\u6761\u4ef6\u4e0b\u8fdb\u884c\u5076\u8054\u53cd\u5e94\uff0c\u4ee5\u9ad8\u4ea7\u7387\u4ea7\u751f\u5177\u6709\u826f\u597d\u5bf9\u6620\u9009\u62e9\u6027\u7684\u70ef\u57fa\u5316\u548c\u7094\u57fa\u5316\u8f74\u5411\u8054\u82b3\u57fa\u3002<\/section>\n<p>&nbsp;<\/p>\n<p><img decoding=\"async\" title=\"5\" src=\"https:\/\/17332.seohost.cn\/storage\/17332\/article\/20240304\/1709519778551137.png\" alt=\"5\" \/><\/p>\n<p><img decoding=\"async\" title=\"6\" src=\"https:\/\/17332.seohost.cn\/storage\/17332\/article\/20240304\/1709519788367234.png\" alt=\"6\" \/><\/p>\n<p>&nbsp;<\/p>\n<section>\u4e3a\u4e86\u8bc1\u660e\u8be5\u65b9\u6cd5\u7684\u5b9e\u7528\u6027\uff0c\u4f5c\u8005\u8fdb\u884c\u4e861mmol\u89c4\u6a21\u7684\u53cd\u5e94\uff0c\u5e76\u4e14\u5076\u8054\u4ecd\u7136\u8fdb\u884c\u5f97\u5f88\u597d\uff0895%\u4ea7\u7387\uff0c99%ee\uff09\u3002\u6709\u8da3\u7684\u662f\uff0c\u8f83\u9ad8\u7684\u914d\u4f53\u8d1f\u8f7d\u6709\u52a9\u4e8e\u4fdd\u630199%ee\uff0c\u800c\u6807\u51c6\u914d\u4f53\u8d1f\u8f7d\u5bfc\u81f4\u5bf9\u6620\u9009\u62e9\u6027\u7565\u5fae\u964d\u4f4e\uff0897%ee\uff09\u3002\u901a\u8fc7\u5c06\u5176\u8f6c\u5316\u4e3a\u5176\u4ed6\u6709\u7528\u7684\u5316\u5408\u7269\uff0c\u8bc1\u660e\u4e86\u4ea7\u7269\u7684\u5408\u6210\u901a\u7528\u6027\u3002\u6b64\u5916\uff0c\u8003\u8651\u5230\u82b3\u57fa\u7898\u548c\u82b3\u57fa\u6eb4\u5728\u5f53\u524d\u4f53\u7cfb\u4e2d\u7684\u6761\u4ef6\u4f9d\u8d56\u6027\u53cd\u5e94\u6027\uff0c\u6eb4\u5316\u82b3\u57fa\u7898\u4e0e\u4e0d\u540c\u8054\u82b3\u57fa\u534a\u787c\u9178\u916f\u7684\u7a0b\u5e8f\u5316\u5076\u8054\u662f\u53ef\u884c\u7684\uff0c\u4ee5\u9ad8\u4ea7\u7387\u63d0\u4f9b\u5177\u6709\u826f\u597d\u7acb\u4f53\u63a7\u5236\u7684\u5e26\u6709\u4e24\u4e2a\u624b\u6027\u8f74\u7684\u805a\u82b3\u57fa\u4ea7\u72698\u3002<\/section>\n<p>&nbsp;<\/p>\n<p><img decoding=\"async\" title=\"7\" src=\"https:\/\/17332.seohost.cn\/storage\/17332\/article\/20240304\/1709519797785811.png\" alt=\"7\" \/><\/p>\n<p>&nbsp;<\/p>\n<section>\u5728\u5f53\u524d\u4f53\u7cfb\u4e2d\uff0c\u53ef\u80fd\u6d89\u53ca\u4e24\u79cd\u7c7b\u578b\u7684\u82b3\u57fa\u787c\uff0c\u56e0\u4e3a\u8054\u82b3\u57fa\u534a\u787c\u9178\u916f\u53ef\u80fd\u4f1a\u4ee5\u77ac\u6001\u5f62\u5f0f\u53ef\u9006\u6c34\u89e3\u4e3a\u5f00\u653e\u787c\u9178\u5f62\u5f0f\u3002\u56e0\u6b64\uff0c\u8003\u8651\u4e86\u4e24\u79cd\u82b3\u57fa\u787c\u5bf9\u53cd\u5e94\u7684\u5f71\u54cd\u3002\u9996\u5148\uff0c\u901a\u8fc7NMR\u5206\u6790\u68c0\u6d4b\u5230\u7684\u5f00\u653e\u787c\u9178\u5f62\u5f0f\u5e94\u8be5\u4ec5\u53ef\u80fd\u4ee5\u975e\u5e38\u4f4e\u7684\u6d53\u5ea6\u5b58\u5728\uff0c\u800c\u73af\u72b6\u534a\u787c\u9178\u916f\u662f\u4e3b\u8981\u5b58\u5728\u5f62\u5f0f\u3002\u7b2c\u4e8c\uff0c\u8ba1\u7b97\u51fa\u7684\u5f00\u73af\u5f62\u5f0f\u7684\u8f6c\u52a8\u52bf\u5792\u9ad8\u8fbe22.26 kcal\/mol\uff08t25 1\/2 &lt;$0.65 h\uff09\uff0c\u4f46\u73af\u72b6\u5f62\u5f0f\u7684\u8f6c\u52a8\u52bf\u5792\u8f83\u4f4e\uff084.34 kcal\/mol\uff0ct25 1\/2 &lt;$4.7 \u00d7 10\u221214 h\uff09\u3002\u8fd9\u4e9b\u6027\u80fd\u8868\u660e\uff0c\u652f\u6301\u6240\u89c2\u5bdf\u5230\u7684\u53cd\u5e94\u52a8\u529b\u5b66\uff0c\u534a\u787c\u9178\u916f\u4f5c\u4e3a\u53ef\u80fd\u7684\u6d3b\u6027\u82b3\u57fa\u787c\u8bd5\u5242\u3002\u6b64\u5916\uff0cDFT\u8ba1\u7b97\u8868\u660e\uff0c\u534a\u787c\u9178\u916f\u7684\u91d1\u5c5e\u8f6c\u79fb\u53cd\u5e94\u6bd4\u787c\u9178\u5feb\u5f97\u591a\uff0c\u5e76\u4e14\u91d1\u5c5e\u8f6c\u79fb\u6b65\u9aa4\u662f\u5bf9\u6620\u4f53\u51b3\u5b9a\u7684\u3002\u73af\u72b6\u534a\u787c\u9178\u916f\u7684\u9009\u62e9\u6027\u91d1\u5c5e\u8f6c\u79fb\u7684\u7ade\u4e89\u8fc7\u6e21\u6001\u7684\u76f8\u5bf9\u80fd\u91cf\u3002\u6700\u6709\u5229\u7684\u91d1\u5c5e\u8f6c\u79fb\u8fc7\u6e21\u6001\u662fTS-2\uff0c\u5176\u81ea\u7531\u80fd\u4e3a6.28 kcal\/mol\uff0c\u66f4\u6709\u5229\uff08\u5bf9\u5e94\u4e8e&gt;99%ee\uff09\uff0c\u8fd9\u4e0e\u89c2\u5bdf\u5230\u7684\u5bf9\u6620\u9009\u62e9\u6027\uff0899%ee\uff09\u975e\u5e38\u4e00\u81f4\u3002<\/section>\n<section><img decoding=\"async\" title=\"8\" src=\"https:\/\/17332.seohost.cn\/storage\/17332\/article\/20240304\/1709519809875155.png\" alt=\"8\" \/><\/section>\n<section>\u4f5c\u8005\u57fa\u4e8e\u5176\u5b9e\u9a8c\u7ed3\u679c\u548c\u6587\u732e\u62a5\u544a\uff0c\u63d0\u51fa\u4e86\u6a21\u578b\u53cd\u5e94\u7684\u5408\u7406\u50ac\u5316\u5faa\u73af\u3002\u5bf9\u6bcf\u4e2a\u6b65\u9aa4\u8fdb\u884cDFT\u8ba1\u7b97\uff0c\u5e76\u663e\u793a\u4e86\u6bcf\u4e2a\u7ed3\u6784\u7684\u5409\u5e03\u65af\u80fd\u7684\u53d8\u5316\u3002\u53cd\u5e94\u5f00\u59cb\u4e8e\u7898\u82ef\u4e0e\u624b\u6027Pd\uff080\uff09\u50ac\u5316\u5242\u7684\u6c27\u5316\u52a0\u6210\uff0c\u751f\u6210Pd\uff08II\uff09\u4e2d\u95f4\u4f53Int-2\u3002\u6c22\u6c27\u5316\u94af\u7269\u79cdInt-3\u5728\u78b1\u5b58\u5728\u4e0b\u5728\u6c34\u6eb6\u6db2\u4e2d\u4ea7\u751f\u3002\u8054\u82b3\u57fa\u534a\u787c\u9178\u916f\u4e0eInt-3\u901a\u8fc7\u6700\u6709\u5229\u7684\u8fc7\u6e21\u6001TS-2\u7684\u52a8\u6001\u52a8\u529b\u5b66\u9009\u62e9\u6027\u91d1\u5c5e\u8f6c\u79fb\u4ea7\u751fInt-6\uff0c\u5176\u5728\u6c34\u89e3\u65f6\u4ea7\u751f\u8f74\u5411\u624b\u6027Pd\uff08II\uff09\u4e2d\u95f4\u4f53Int-7\u3002\u624b\u6027\u4ea7\u72693aa\u901a\u8fc7TS-3\u4eceInt-7\u8fd8\u539f\u6d88\u9664\u800c\u4ea7\u751f\uff0c\u4fdd\u6301\u8f74\u5411\u624b\u6027\u3002\u7814\u7a76\u4e86Int-7\u901a\u8fc7\u53ef\u80fd\u7684\u516d\u5143\u94af\u914d\u4f53\u7684\u5dee\u5411\u5f02\u6784\u5316\uff0c\u4f46\u8be5\u8def\u5f84\u7684\u80fd\u5792\uff0827.55 kcal\/mol\uff09\u8fdc\u9ad8\u4e8e\u7ade\u4e89\u6027\u8fd8\u539f\u6d88\u9664\u8def\u5f84\u7684\u80fd\uff0813.36kcal\/mol\uff09\u3002\u8fd9\u4e00\u7ed3\u679c\u4e5f\u652f\u6301\u4e86\u5728\u91d1\u5c5e\u8f6c\u79fb\u6b65\u9aa4\u786e\u5b9a\u7684\u5bf9\u6620\u9009\u62e9\u6027\u3002<\/section>\n<p>&nbsp;<\/p>\n<p><img decoding=\"async\" title=\"9\" src=\"https:\/\/17332.seohost.cn\/storage\/17332\/article\/20240304\/1709519824842002.png\" alt=\"9\" \/><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u671f\u520a\u540d\uff1aJACS DOI\uff1a10.1021\/jacs.3c14450 &nbsp; \u8054\u82b3\u57fa\u963b\u8f6c\u5f02\u6784\u4f53\u4e0d\u4ec5\u5e7f\u6cdb\u5b58\u5728 [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-51138","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51138","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=51138"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51138\/revisions"}],"predecessor-version":[{"id":51139,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51138\/revisions\/51139"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=51138"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=51138"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=51138"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}