{"id":51104,"date":"2024-03-29T08:31:56","date_gmt":"2024-03-29T00:31:56","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=51104"},"modified":"2024-03-20T10:34:01","modified_gmt":"2024-03-20T02:34:01","slug":"j-am-chem-soc-%e5%9c%a8%e5%a4%9a%e8%82%bd%e9%aa%a8%e6%9e%b6%e4%b8%8a%e5%ae%89%e8%a3%85%e5%8a%9f%e8%83%bd%e5%8c%96%e8%84%92%e5%9f%ba%e5%9b%a2%e7%9a%84%e6%96%b0%e6%96%b9%e6%b3%95","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/j-am-chem-soc-%e5%9c%a8%e5%a4%9a%e8%82%bd%e9%aa%a8%e6%9e%b6%e4%b8%8a%e5%ae%89%e8%a3%85%e5%8a%9f%e8%83%bd%e5%8c%96%e8%84%92%e5%9f%ba%e5%9b%a2%e7%9a%84%e6%96%b0%e6%96%b9%e6%b3%95\/","title":{"rendered":"J. Am. Chem. Soc. | \u5728\u591a\u80bd\u9aa8\u67b6\u4e0a\u5b89\u88c5\u529f\u80fd\u5316\u8112\u57fa\u56e2\u7684\u65b0\u65b9\u6cd5"},"content":{"rendered":"<section>\u4e3a\u5927\u5bb6\u4ecb\u7ecd\u7684\u662f\u6700\u8fd1\u5728<em>JACS<\/em>\u4e0a\u62a5\u9053\u7684\u4e00\u7bc7\u6807\u9898\u4e3a\u00a0\u201c<em>A General Strategy to Install Amidine Functional Groups Along the Peptide Backbone<\/em>\u201d\u00a0\u7684\u6587\u7ae0\u3002\u8be5\u6587\u7684\u901a\u8baf\u4f5c\u8005\u662f\u4fc4\u4ea5\u7231\u8377\u534e\u5dde\u7acb\u5927\u5b66\u5316\u5b66\u7cfb\u7684Brett VanVeller\u6559\u6388\u3002\u5728\u672c\u6587\u4e2d\uff0c\u4f5c\u8005\u62a5\u9053\u4e86\u4e00\u79cd\u72ec\u7279\uff0c\u666e\u9002\u4e14\u7b80\u4fbf\u7684\u65b9\u6cd5\uff0c\u80fd\u591f\u4ece\u786b\u4ee3\u591a\u80bd\u51fa\u53d1\u5408\u6210\u8112\u57fa\u56e2\u8fde\u63a5\u7684\u591a\u80bd\uff0c\u4e3a\u63a2\u7d22\u65b0\u7684\u591a\u80bd\u7ed3\u6784\u548c\u5e94\u7528\u5f00\u53d1\u4e86\u4e00\u6761\u65b0\u7684\u9053\u8def\u3002<\/section>\n<section>\u00a0\u00a0\u00a0\u00a0\u8112\u662f\u5c06\u9170\u80fa\u952e\u4e2d\u7684\u7fb0\u57fa\u66ff\u6362\u4e3a\u4e9a\u80fa\u57fa\u800c\u5f97\u6765\u7684\u4e00\u79cd\u9170\u80fa\u884d\u751f\u7269\uff0c\u5176\u7531\u4e8e\u80fd\u591f\u5929\u7136\u751f\u6210\u4e14\u5bb9\u6613\u53d1\u751f\u6c22\u952e\u5f02\u6784\u5316\u800c\u5907\u53d7\u7814\u7a76\u8005\u9752\u7750\u3002\u5728\u5f88\u591a\u5929\u7136\u4ea7\u7269\u548cFDA\u5df2\u6279\u51c6\u836f\u7269\u4e2d\uff0c\u8be5\u57fa\u56e2\u90fd\u626e\u6f14\u4e86\u91cd\u8981\u89d2\u8272\u3002\u82e5\u80fd\u591f\u5c06\u591a\u80bd\u7ed3\u6784\u4e2d\u7684\u80bd\u952e\u66ff\u6362\u4e3a\u8112\uff0c\u5219\u80fd\u591f\u901a\u8fc7\u6c22\u952e\u5f02\u6784\u5316\uff0c\u5728\u591a\u80bd\u9aa8\u67b6\u4e0a\u5f15\u5165\u4e00\u4e2a\u989d\u5916\u7684\u53d6\u4ee3\u57fa\u4f4d\u70b9\u3002(\u5982\u56fe1a\u4e2d\u7684R\u57fa)\u00a0\u4f46\u7531\u4e8e\u7f3a\u4e4f\u4e00\u4e9b\u5408\u9002\u7684\u65b9\u6cd5\u5c06\u8112\u952e\u5f15\u5165\u56fa\u76f8\u5408\u6210\u7684\u591a\u80bd\u4e2d\uff0c\u5f71\u54cd\u4e86\u5176\u5728\u836f\u7269\u79d1\u5b66\u548c\u591a\u80bd\u4fee\u9970\u4e2d\u7684\u5e94\u7528\u6f5c\u529b\u3002<\/section>\n<section>\u00a0\u00a0\u00a0\u00a0\u5728\u6700\u8fd1\u7684\u4e00\u4e9b\u7814\u7a76\u4e2d\uff0c\u6709\u56e2\u961f\u63d0\u51fa\u4e86Ag(I)\u53ef\u4ee5\u5c06\u786b\u4ee3\u9170\u80fa\u4e2d\u7684\u78b3-\u786b\u952e\u8f6c\u5316\u4e3a\u4e9a\u80fa\u952e\u7684\u65b9\u6cd5\u3002\u867d\u7136\u8be5\u786b\u4ee3\u9170\u80fa\u53ef\u4ee5\u7b80\u5355\u5730\u901a\u8fc7\u5c06\u786b\u4ee3\u6c28\u57fa\u9178\u5f15\u5165\u5230\u56fa\u76f8\u591a\u80bd\u5408\u6210\u4e2d\u800c\u5f97\u5230\uff0c\u7136\u800c\u5728\u5b9e\u9645\u591a\u80bd\u7684\u53cd\u5e94\u4e2d\uff0c\u89c2\u5bdf\u5230\u4e86\u5feb\u901f\u7684\u5206\u5b50\u5185\u6210\u73af\u53cd\u5e94\u7684\u53d1\u751f\uff0c\u800c\u4e0d\u662f\u5916\u6e90\u4eb2\u6838\u8bd5\u5242\u7684\u8fdb\u653b\u3002\u00a0(\u56fe1b)\u00a0\u56e0\u6b64\uff0c\u5229\u7528Ag(I)\u5f15\u5165\u8112\u7684\u65b9\u6cd5\u4ec5\u5728\u4e07\u53e4\u9709\u7d20\u7b49\u4e24\u4e2a\u4f8b\u5b50\u4e2d\u6210\u529f(\u56fe1a\u4e2d\u7684\u5316\u5408\u72691\u548c2)\uff0c\u7531\u4e8e\u73af\u80bd\u672c\u8eab\u5177\u6709\u4e00\u5b9a\u5f20\u529b\uff0c\u53ef\u4ee5\u4e00\u5b9a\u7a0b\u5ea6\u4e0a\u9650\u5236\u5206\u5b50\u5185\u73af\u5316\u53cd\u5e94\u7684\u53d1\u751f\u3002<\/section>\n<section>\u00a0\u00a0\u00a0\u00a0\u4f5c\u8005\u56e2\u961f\u5728\u524d\u671f\u7814\u7a76\u5de5\u4f5c\u4e2d\u53d1\u73b0\u4e86\u4e00\u79cd\u53ef\u4ee5\u5c06\u786b\u4ee3\u9170\u80fa\u53d8\u4e3a\u7532\u57fa\u5316\u786b\u9170\u4e9a\u80fa\u7684\u65b9\u6cd5\uff0c\u4ed6\u4eec\u968f\u5373\u53d1\u73b0\u8be5\u4e9a\u80fa\u5f88\u5bb9\u6613\u88ab\u8d28\u5b50\u5316\uff0c\u4ece\u800c\u4f7f\u4eb2\u6838\u8bd5\u5242\u66f4\u5bb9\u6613\u8fdb\u653b\u4e9a\u80fa\u7684\u78b3\u539f\u5b50\u800c\u4ea7\u751f\u8112(\u56fe1c)\u3002\u4ed6\u4eec\u8ba4\u4e3a\u8fd9\u79cd\u65b9\u6cd5\u6709\u4ee5\u4e0b\u51e0\u4e2a\u4f18\u52bf\uff1a\u9996\u5148\u907f\u514d\u4e86\u8d35\u91cd\u8fc7\u6e21\u91d1\u5c5e\u7684\u53c2\u4e0e\uff0c\u5176\u6b21\u53ef\u4ee5\u5728\u591a\u80bd\u56fa\u76f8\u5408\u6210\u7684\u6811\u8102\u4e0a\u5b8c\u6210\u53cd\u5e94\uff0c\u4ece\u800c\u907f\u514d\u672a\u4fdd\u62a4\u7684\u6c28\u57fa\u53d1\u751f\u526f\u53cd\u5e94\uff0c\u4f7f\u8be5\u53cd\u5e94\u53d8\u5f97\u9ad8\u6548\u4e14\u901a\u7528\u3002<\/section>\n<section><img decoding=\"async\" title=\"1\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240320\/1710901979899027.png\" alt=\"1\" \/><\/section>\n<section><strong>\u56fe<\/strong><strong>1<\/strong><strong>.\u00a0<\/strong>(a)\u591a\u80bd\u5206\u5b50\u4e2d\u7684\u8112\u952e; (b)\u8112\u7684\u4f20\u7edf\u5408\u6210\u65b9\u6cd5\u53ca\u5176\u526f\u53cd\u5e94;\u00a0\u00a0 \u00a0(c)\u672c\u5de5\u4f5c\u63d0\u51fa\u7684\u65b0\u5408\u6210\u65b9\u6cd5<\/section>\n<section><strong>\u00a0<\/strong><\/section>\n<section>\u00a0\u00a0\u00a0\u00a0\u9996\u5148\uff0c\u4f5c\u8005\u56e2\u961f\u7528\u4e00\u4e2a\u6a21\u578b\u5206\u5b50\u6765\u9a8c\u8bc1\u8be5\u53cd\u5e94\u7684\u53ef\u884c\u6027\u3002\u5728\u6dfb\u52a0\u7b49\u5f53\u91cf\u7684\u4e59\u9178\u540e\uff0c\u5f62\u6210\u4e86\u4e00\u4e2a\u5f31\u78b1\u6027\u7684\u7f13\u51b2\u4f53\u7cfb\uff0c\u5bfc\u81f4\u786b\u9170\u4e9a\u80fa\u7684\u8d28\u5b50\u5316\u3002\u56e0\u6b64\uff0c\u4eb2\u6838\u6027\u8f83\u5f3a\u7684\u4f2f\u80fa\u53ef\u4ee5\u9ad8\u6548\u4e14\u5feb\u901f\u5730\u751f\u6210\u4ea7\u7269\u8112\uff0c\u800c\u4eb2\u6838\u6027\u8f83\u5f31\u6216\u7a7a\u95f4\u4f4d\u963b\u8f83\u5927\u7684\u80fa\u5219\u4ea7\u7387\u6709\u6240\u964d\u4f4e\u3002\u7136\u800c\uff0c\u918b\u9178\u94f5(\u5373\u6c28\u4f5c\u4e3a\u4eb2\u6838\u8bd5\u5242\u548c\u918b\u9178\u7684\u53cd\u5e94\u4ea7\u7269)\u5728\u4e0d\u6dfb\u52a0\u989d\u5916\u4e59\u9178\u7684\u60c5\u51b5\u4e0b\u53cd\u5e94\u6548\u7387\u66f4\u4f4e\uff0c\u8fd9\u53ef\u80fd\u53d7\u5230\u76d0\u5728DMF\u4e2d\u6eb6\u89e3\u5ea6\u7684\u9650\u5236\u3002\u5728\u6dfb\u52a0\u4e86\u4e00\u5b9a\u91cf\u7684\u4e09\u6c1f\u4e59\u9187TFE\u540e\uff0c\u918b\u9178\u94f5\u80fd\u591f\u4ee5\u6781\u9ad8\u7684\u6548\u7387\u53cd\u5e94\u5f97\u5230\u4e0d\u542b\u53d6\u4ee3\u57fa\u7684\u8112\u3002\u8be5\u6eb6\u5242\u4e5f\u53ef\u80fd\u901a\u8fc7\u4fc3\u8fdb\u6c22\u952e\u751f\u6210\u7684\u65b9\u5f0f\u52a0\u901f\u4e86\u5f31\u4eb2\u6838\u6027\u80fa\u7684\u8fdb\u653b\u8fc7\u7a0b\u3002(\u56fe2)<\/section>\n<section><img decoding=\"async\" title=\"2\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240320\/1710901987963037.png\" alt=\"2\" \/><\/section>\n<section><img decoding=\"async\" title=\"3\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240320\/1710901994848924.png\" alt=\"3\" \/><\/section>\n<section><strong>\u56fe<\/strong><strong>2.\u00a0<\/strong>\u786b\u9170\u4e9a\u80fa\u5411\u8112\u53cd\u5e94\u7684\u6761\u4ef6\u4f18\u5316\u548c\u5e95\u7269\u7b5b\u9009(\u4ee5\u6a21\u578b\u5c0f\u5206\u5b50\u4e3a\u4f8b)<\/section>\n<section><strong>\u00a0<\/strong><\/section>\n<section>\u00a0\u00a0\u00a0\u00a0\u968f\u540e\uff0c\u4f5c\u8005\u56e2\u961f\u5728\u4e00\u4e2a\u6a21\u578b\u77ed\u80bd\u4e0a\u9a8c\u8bc1\u4e86\u8be5\u53cd\u5e94\u7684\u53ef\u884c\u6027\u3002\u5728Phe-Ala-Ala\u4e09\u80bd\u7684Phe\u548cAla\u4e4b\u95f4\u6dfb\u52a0\u4e86\u786b\u4ee3\u9170\u80fa\uff0c\u5e76\u7528\u591a\u79cd\u80fa\u4f5c\u4e3a\u4eb2\u6838\u8bd5\u5242\uff0cLC-HRMS\u7684\u5cf0\u79ef\u5206\u9762\u79ef\u8868\u5f81\u4ea7\u7387\u3002\u901a\u8fc7\u5bf9\u4e0d\u540c\u4eb2\u6838\u8bd5\u5242\/\u4e59\u9178\u6bd4\u4f8b\u7684\u7b5b\u9009\uff0c\u4f5c\u8005\u53d1\u73b0\u4e8c\u8005\u57285:1\u65f6\u80fd\u591f\u83b7\u5f97\u6700\u9ad8\u4ea7\u7387\uff0c\u63d0\u5347\u4e59\u9178\u7684\u5f53\u91cf\u867d\u7136\u6709\u52a9\u4e8e\u4eb2\u6838\u53cd\u5e94\u7684\u53d1\u751f\uff0c\u4f46\u4e5f\u4f1a\u56e0\u4e3a\u76d0\u6790\u800c\u964d\u4f4e\u8f6c\u5316\u7387\u3002\u540c\u65f6\uff0c\u5728\u6811\u8102\u4e0a\u8fdb\u884c\u53cd\u5e94\u65f6\uff0c\u5f31\u4eb2\u6838\u6027\u7684\u80fa\u548c\u5927\u4f4d\u963b\u80fa\u7684\u4eb2\u6838\u8fdb\u653b\u88ab\u663e\u8457\u6291\u5236\u3002\u5728\u6240\u6709\u53cd\u5e94\u4e2d\u90fd\u6ca1\u6709\u89c2\u5bdf\u5230\u5206\u5b50\u5185\u73af\u5316\u526f\u53cd\u5e94\u7684\u53d1\u751f\uff0c\u8868\u660e\u8be5\u53cd\u5e94\u7684\u7279\u5f02\u6027\u5f88\u5f3a\u3002\u8112\u7684\u751f\u6210\u4e5f\u4e0d\u4f1a\u5bf9\u591a\u80bd\u7684\u4fa7\u94fe\u9020\u6210\u5f71\u54cd\uff0c\u8bc1\u660e\u4e86\u8be5\u53cd\u5e94\u7684\u901a\u7528\u6027\u3002(\u56fe3)<\/section>\n<section><img decoding=\"async\" title=\"4\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240320\/1710902002634985.png\" alt=\"4\" \/><\/section>\n<section><strong>\u56fe<\/strong><strong>3.\u00a0<\/strong>\u56fa\u76f8\u591a\u80bd\u5408\u6210\u8fc7\u7a0b\u4e2d\u76f4\u63a5\u5c06\u786b\u9170\u4e9a\u80fa\u8f6c\u5316\u4e3a\u8112\u7684\u53cd\u5e94\u9a8c\u8bc1<\/section>\n<section><strong>\u00a0<\/strong><\/section>\n<section>\u00a0\u00a0\u00a0\u00a0\u6700\u540e\uff0c\u4f5c\u8005\u56e2\u961f\u5bf9\u4e00\u7cfb\u5217\u5929\u7136\u591a\u80bd\u6216\u5177\u6709\u836f\u5b66\u5e94\u7528\u4ef7\u503c\u7684\u591a\u80bd\u8fdb\u884c\u4fee\u9970\uff0c\u5305\u542b\u4eae\u6c28\u9178-\u8111\u5561\u80bd\u3001\u831c\u8349\u7d20-5\u00a0\u3001\u8840\u7ba1\u7d27\u5f20\u7d20\u80bd\u7b49\u3002\u5b83\u4eec\u5728\u4f53\u5185\u7684\u751f\u7269\u5b66\u5e94\u7528\u4e2d\u5747\u4f1a\u51fa\u73b0\u4e00\u7cfb\u5217\u95ee\u9898\u8bf8\u5982\u6613\u88ab\u86cb\u767d\u9176\u964d\u89e3\u3001\u751f\u7269\u5206\u5e03\u8f83\u5dee\u7b49\u3002\u901a\u8fc7\u5c06\u5176\u4e2d\u5173\u952e\u7684\u80bd\u952e\u66ff\u6362\u4e3a\u8112\uff0c\u53ef\u80fd\u5728\u4e00\u5b9a\u7a0b\u5ea6\u4e0a\u6539\u5584\u5176\u751f\u7269\u5e94\u7528\u4e2d\u7684\u95ee\u9898\u3002\u5728\u8fd9\u4e9b\u4f8b\u5b50\u4e2d\uff0c\u5373\u4f7f\u4e24\u4fa7\u6c28\u57fa\u9178\u5177\u6709\u8f83\u5927\u7684\u4f4d\u963b(\u5982Trp\u3001Ile\u7b49)\u6216\u5f3a\u7535\u8377(\u5982Arg)\uff0c\u8be5\u53cd\u5e94\u4e5f\u80fd\u9ad8\u6548\u8fdb\u884c\uff0c\u8868\u660e\u8be5\u53cd\u5e94\u5177\u6709\u5e7f\u8c31\u7684\u5e95\u7269\u9009\u62e9\u6027\u3002(\u56fe4)<\/section>\n<section><img decoding=\"async\" title=\"6\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240320\/1710902020677901.png\" alt=\"6\" \/>\u200b<\/section>\n<section><strong>\u56fe<\/strong><strong>4.\u00a0<\/strong>\u542b\u8112\u591a\u80bd\u7684\u51e0\u4e2a\u5408\u6210\u5b9e\u4f8b<\/section>\n<section><strong>\u00a0<\/strong><\/section>\n<section>\u00a0\u00a0\u00a0\u00a0\u7efc\u4e0a\u6240\u8ff0\uff0c\u672c\u6587\u5f00\u53d1\u4e86\u4e00\u79cd\u5168\u65b0\u7684\u3001\u666e\u9002\u7684\u3001\u9ad8\u6548\u7684\u5316\u5b66\u65b9\u6cd5\uff0c\u80fd\u591f\u5728\u591a\u80bd\u9aa8\u67b6\u4e0a\u5f15\u5165\u8112\u952e\u3002\u7531\u4e8e\u8112\u952e\u53ef\u4ee5\u88ab\u89c6\u4f5c\u80bd\u952e\u7684\u53d8\u4f53\uff0c\u56e0\u6b64\u5728\u751f\u547d\u79d1\u5b66\u548c\u836f\u5b66\u7814\u7a76\u4e2d\u6709\u6f5c\u5728\u4ef7\u503c\uff0c\u4f46\u5176\u5408\u6210\u5374\u6301\u7eed\u53d7\u9650\u3002\u672c\u6587\u7684\u5de5\u4f5c\u5ef6\u7eed\u4e86\u4e4b\u524d\u7531\u786b\u4ee3\u9170\u80fa\u88ab\u4eb2\u6838\u8fdb\u653b\u751f\u6210\u8112\u7684\u9014\u5f84\uff0c\u501f\u52a9\u786b\u9170\u4e9a\u80fa\u5f02\u6784\u4f53\u7684\u6613\u8d28\u5b50\u5316\u7279\u6027\uff0c\u5728\u5f31\u9178\u53c2\u4e0e\u4e0b\u6781\u5927\u5730\u63d0\u9ad8\u4e86\u4eb2\u6838\u53cd\u5e94\u7684\u6548\u7387\uff0c\u5e76\u6700\u5927\u7a0b\u5ea6\u4e0a\u6291\u5236\u4e86\u526f\u53cd\u5e94\u7684\u53d1\u751f\u3002\u4f5c\u8005\u5728\u6a21\u578b\u591a\u80bd\u548c\u51e0\u4e2a\u5df2\u88ab\u836f\u7528\u7684\u591a\u80bd\u4e0a\u8bc1\u660e\u4e86\u8be5\u53cd\u5e94\u7684\u7279\u5f02\u6027\u548c\u666e\u9002\u6027\uff0c\u5e76\u63d0\u51fa\u8fd9\u79cd\u7528\u8112\u6765\u4ee3\u66ff\u80bd\u952e\u7684\u7b56\u7565\u6709\u671b\u5728\u65b0\u578b\u836f\u7269\u7684\u5f00\u53d1\u4e2d\u5f97\u5230\u5e94\u7528\u3002<\/section>\n<section><\/section>\n<section><strong>\u4f5c\u8005\uff1a<\/strong>DYH\u00a0\u00a0<strong>\u5ba1\u6821\uff1a<\/strong>ZHS<\/section>\n<section><strong>DOI:\u00a0<\/strong>10.1021\/jacs.2c09085<\/section>\n<section><strong>Link:\u00a0<\/strong>https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.2c09085<\/section>\n","protected":false},"excerpt":{"rendered":"<p>\u4e3a\u5927\u5bb6\u4ecb\u7ecd\u7684\u662f\u6700\u8fd1\u5728JACS\u4e0a\u62a5\u9053\u7684\u4e00\u7bc7\u6807\u9898\u4e3a\u00a0\u201cA General Strategy to Install  [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-51104","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51104","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=51104"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51104\/revisions"}],"predecessor-version":[{"id":51105,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51104\/revisions\/51105"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=51104"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=51104"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=51104"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}