{"id":51090,"date":"2024-03-27T08:34:20","date_gmt":"2024-03-27T00:34:20","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=51090"},"modified":"2024-03-18T10:35:52","modified_gmt":"2024-03-18T02:35:52","slug":"angew-chem-%ef%bc%9a%e6%b0%a8%e5%9f%ba%e9%85%b8%e9%92%b4%e4%bd%9c%e4%b8%ba%e6%9e%90%e6%b0%a2%e5%82%ac%e5%8c%96%e5%89%82%e5%ae%9e%e7%8e%b0%e8%81%94%e7%83%af%e7%9a%84%e7%94%b5%e5%8c%96%e5%ad%a6c-h","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/angew-chem-%ef%bc%9a%e6%b0%a8%e5%9f%ba%e9%85%b8%e9%92%b4%e4%bd%9c%e4%b8%ba%e6%9e%90%e6%b0%a2%e5%82%ac%e5%8c%96%e5%89%82%e5%ae%9e%e7%8e%b0%e8%81%94%e7%83%af%e7%9a%84%e7%94%b5%e5%8c%96%e5%ad%a6c-h\/","title":{"rendered":"Angew. Chem. \uff1a\u6c28\u57fa\u9178\u94b4\u4f5c\u4e3a\u6790\u6c22\u50ac\u5316\u5242\u5b9e\u73b0\u8054\u70ef\u7684\u7535\u5316\u5b66C-H\u5b98\u80fd\u56e2\u5316"},"content":{"rendered":"<section>\n<section>\n<section>\n<section>\n<section>\u8054\u70ef\u7684sp<sup>2<\/sup>\u00a0C-H\u5b98\u80fd\u5316\u53ef\u4ee5\u5b9e\u73b0\u7b80\u5355\u8054\u70ef\u5411\u9ad8\u9644\u52a0\u503c\u8054\u70ef\u7684\u76f4\u63a5\u8f6c\u5316\uff0c\u662f<span 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decoding=\"async\" title=\"1\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240318\/1710729312533773.png\" alt=\"1\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u5728\u524d\u671f\u7814\u7a76\u7684\u57fa\u7840\u4e0a\uff0c\u6700\u8fd1\u5b89\u5fbd\u5927\u5b66\u674e\u6f2b\u6ce2\/<span 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decoding=\"async\" title=\"2\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240318\/1710729320871640.png\" alt=\"2\" 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src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240318\/1710729326895294.png\" alt=\"3\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u4e3a\u89e3\u91ca\u53cd\u5e94\u7684\u533a\u57df\u9009\u62e9\u6027\uff0c\u4f5c\u8005\u8bbe\u8ba1\u4e86\u591a\u79cd\u63a7\u5236\u5b9e\u9a8c\uff0c\u521d\u6b65\u8bc1\u660e\u53cd\u5e94\u7684\u533a\u57df\u9009\u62e9\u6027\u53ef\u80fd\u7531C-H\u952e\u7684\u9178\u6027\u51b3\u5b9a\u3002\u5bc6\u5ea6\u6cdb\u51fd(DFT)\u8ba1\u7b97\u4e5f\u8868\u660e\u53cd\u5e94\u4e2d\u7684\u8054\u70efsp<sup>2<\/sup>\u00a0C-H\u76f8\u8f83\u4e8e\u76f8\u90bb\u7684sp<sup>3<\/sup>\u00a0C-H\u5177\u6709\u66f4\u9ad8\u7684\u9178\u6027\uff0c\u8bc1\u5b9e\u4e86\u53cd\u5e94\u7684\u533a\u57df\u9009\u62e9\u6027\u7531C-H\u7684\u9009\u62e9\u6027\u8fd8\u539f\u6790\u6c22\u51b3\u5b9a\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"0\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240318\/1710729336850704.png\" alt=\"0\" \/>\u200b<\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u5728\u8be5\u5de5\u4f5c\u4e2d\uff0c\u674e\u6f2b\u6ce2\/\u5f20\u80dc\u56e2\u961f\u53d1\u5c55\u4e86\u7b80\u5355\u6613\u5f97\u7684\u6c28\u57fa\u9178\u94b4\u50ac\u5316\u5242\uff0c\u5229\u7528\u8fd9\u4e00\u50ac\u5316\u5242\u7684\u7535\u8fd8\u539f\u6790\u6c22\u4f5c\u7528\u5b9e\u73b0\u8054\u70efsp<sup>2<\/sup>\u00a0C-H\u9009\u62e9\u6027\u65ad\u88c2\uff0c\u5e76\u5b9e\u73b0\u4e0e\u9187\u7684\u76f4\u63a5\u8131\u6c22\u5b98\u80fd\u5316\u53cd\u5e94\u3002\u8be5\u53cd\u5e94\u4e3a\u6784\u5efa\u591a\u79cd\u8054\u70ef\u9187\u7c7b\u4ea7\u7269\u63d0\u4f9b\u4e86\u4e00\u79cd\u7b80\u4fbf\u3001\u9ad8\u6548\u7684\u65b9\u6cd5\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section><strong>\u8bba<\/strong><strong>\u6587\u4fe1\u606f<\/strong><\/p>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section><\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>A Hydrogen Evolution Catalyst [Co<sub>2<\/sub>O<sub>2<\/sub>] Metallacycle Enables Regioselective Allene C(sp<sup>2<\/sup>)\u2013H Functionalization<\/p>\n<p>Yating Liang, Jiayi Feng, Huilong Li, Xiaoli Wang, Ying Zhang, Weigang Fan, Sheng Zhang, Man-Bo Li<\/p>\n<p><em>Angewandte Chemie International Edition<\/em><\/p>\n<p>DOI:\u00a010.1002\/anie.202400938<\/p>\n<\/section>\n<\/section>\n<\/section>\n","protected":false},"excerpt":{"rendered":"<p>\u8054\u70ef\u7684sp2\u00a0C-H\u5b98\u80fd\u5316\u53ef\u4ee5\u5b9e\u73b0\u7b80\u5355\u8054\u70ef\u5411\u9ad8\u9644\u52a0\u503c\u8054\u70ef\u7684\u76f4\u63a5\u8f6c\u5316\uff0c\u662f\u6709\u673a\u5408\u6210\u5316\u5b66\u4e2d\u6700\u53d7\u5173\u6ce8\u7684\u53cd\u5e94\u4e4b\u4e00\u3002\u7136\u800c\uff0c [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-51090","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51090","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=51090"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51090\/revisions"}],"predecessor-version":[{"id":51091,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51090\/revisions\/51091"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=51090"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=51090"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=51090"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}