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data-mid=\"\">\u00a0\u00a0<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section><strong>\u56fe\u6587\u89e3\u6790<\/strong><\/section>\n<section><strong>\u50ac\u5316\u5242\u5408\u6210\u4e0e\u8868\u5f81:<\/strong><\/section>\n<section>\u5229\u7528\u80f6\u4f53\u5408\u6210\u6cd5\u5236\u5907\u4e86\u8d1f\u8f7d\u578b\u53cc\u91d1\u5c5ePdAu\/TiO<sub>2<\/sub>\u50ac\u5316\u5242\uff0c\u5408\u6210\u8fc7\u7a0b\u4e2d\u6dfb\u52a0PVP\u4f5c\u4e3a\u7a33\u5b9a\u5242\u57fa\u56e2\uff0c\u5408\u6210\u540e\u5bf9\u50ac\u5316\u5242\u8fdb\u884c\u6c34\u91cf\u4e3a0~2L\u7684\u6c34\u6d17\u5904\u7406\uff0c\u50ac\u5316\u5242\u547d\u540d\u4e3aPVP-xL\uff08x\u4ee3\u8868\u5b9e\u9645\u6c34\u91cf\uff0c\u8303\u56f40~2L\uff09\u3002\u4f5c\u4e3a\u5bf9\u6bd4\uff0c\u5728\u5408\u6210\u8fc7\u7a0b\u4e2d\u4e0d\u6dfb\u52a0\u989d\u5916\u7a33\u5b9a\u5242\uff0c\u76f8\u5e94\u50ac\u5316\u5242\u547d\u540d\u4e3aSF-xL\uff08SF\uff1astabilizer free\uff09\u3002\u901a\u8fc7\u5bf9\u50ac\u5316\u5242\u8fdb\u884cTEM\u4e0eXPS\u8868\u5f81\u5206\u6790\uff0c\u786e\u8ba4PVP\u4e0eSF\u7cfb\u5217\u50ac\u5316\u5242\u5177\u6709\u76f8\u4f3c\u7684PdAu\u7eb3\u7c73\u9897\u7c92\u7c92\u5f84\uff0c\u540c\u65f6Au\u4e0ePd\u7ec4\u5206\u90fd\u4e3b\u8981\u662f\u4ee50\u4ef7\u6001\u5b58\u5728\u3002\u8bc1\u660eSF\u4e0ePVP\u7cfb\u5217\u50ac\u5316\u5242\u5f62\u8c8c\u57fa\u672c\u4e00\u81f4\uff0c\u5177\u6709\u53ef\u6bd4\u6027\uff1b\u540c\u65f6\uff0c\u6c34\u6d17\u5904\u7406\u5e76\u672a\u660e\u663e\u6539\u53d8\u91d1\u5c5e\u7eb3\u7c73\u9897\u7c92\u7684\u7ec4\u6210\u4e0e\u4ef7\u6001\u3002<\/section>\n<section><\/section>\n<section><img decoding=\"async\" title=\"2\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240307\/1709778668998138.png\" alt=\"2\" \/>\u56fe2. \u50ac\u5316\u5242\u7684\uff08a\uff09TEM\u4e0e\uff08b\uff09XPS\u8868\u5f81<\/section>\n<section>\u00a0 \u00a0 \u00a0 \u00a0 \u00a0\u00a0<\/section>\n<section><strong>BD\u50ac\u5316\u52a0\u6c22\u53cd\u5e94\u7684PHIP\u7814\u7a76\uff1a<\/strong><\/section>\n<section>\u56fe3\u6240\u793a\u4e3aSF\u4e0ePVP\u7cfb\u5217\u50ac\u5316\u5242\u4e0aBD\u52a0\u6c22\u53cd\u5e94\u6027\u80fd\u3002\u53ef\u4ee5\u770b\u5230\uff0c\u968f\u7740\u6c34\u6d17\u91cf\u7684\u63d0\u9ad8\uff0cSF\u4e0ePVP\u50ac\u5316\u5242\u4e0a\u89c2\u6d4b\u5230\u76f8\u540c\u7684\u8d8b\u52bf\uff0c\u5373BD\u8f6c\u5316\u7387\u63d0\u9ad8\uff0c\u70ef\u70c3\u9009\u62e9\u6027\u964d\u4f4e\u3002\u8fd9\u4e3b\u8981\u662f\u7531\u4e8e\u968f\u7740\u6c34\u6d17\u5904\u7406\u7684\u8fdb\u884c\uff0c\u90e8\u5206\u50ac\u5316\u5242\u8868\u9762\u7269\u79cd\u88ab\u53bb\u9664\uff0c\u66b4\u9732\u51fa\u989d\u5916\u7684\u50ac\u5316\u6d3b\u6027\u4f4d\u70b9\uff0c\u4ece\u800c\u5bfc\u81f4\u6d3b\u6027\u7684\u63d0\u9ad8\uff0c\u4f34\u968f\u7740\u9009\u62e9\u6027\u964d\u4f4e\u3002<\/section>\n<section><\/section>\n<section><img decoding=\"async\" title=\"3\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240307\/1709778677590656.png\" alt=\"3\" \/><\/section>\n<section>\u56fe3. \uff08a\uff09SF\u7cfb\u5217\u4e0e\uff08b\uff09PVP\u7cfb\u5217\u50ac\u5316\u5242\u4e0aBD\u52a0\u6c22\u53cd\u5e94\u7684\u8f6c\u5316\u7387\u4e0e\u70ef\u70c3\u9009\u62e9\u6027<\/section>\n<section><\/section>\n<section>\u901a\u8fc7PHIP\u6280\u672f\uff0c\u6211\u4eec\u8fdb\u4e00\u6b65\u83b7\u5f97\u4e86\u4e0d\u540c\u50ac\u5316\u5242\u4e0aB1\u5f02\u6784\u5316\u53cd\u5e94\u4fe1\u606f\u3002\u4e3a\u4e86\u76f4\u89c2\u8868\u8fbe\uff0c\u6211\u4eec\u5f15\u5165\u4e86\u5f02\u6784\u5316\u6307\u6570\uff08IF\uff0cisomerization factor\uff09\u6765\u6307\u793a\u4e0d\u540c\u50ac\u5316\u5242\u4e0a\u7684\u5f02\u6784\u5316\u7a0b\u5ea6\uff0cIF\u6570\u503c\u8d8a\u5927\u4ee3\u8868\u5f02\u6784\u5316\u7a0b\u5ea6\u8d8a\u5267\u70c8\u3002\u5982\u56fe4\u6240\u793a\uff0c\u53ef\u4ee5\u770b\u5230\u968f\u7740\u6c34\u6d17\u91cf\u7684\u589e\u5927\uff0cSF\u7cfb\u5217\u50ac\u5316\u5242\u4e0aIF\u753122.1%\u63d0\u5347\u81f336.2%\uff0cPVP\u7cfb\u5217\u50ac\u5316\u5242\u4e0aIF\u753123.9%\u63d0\u5347\u81f338.1%\u3002\u7ed3\u679c\u8868\u660e\uff0cB1\u5f02\u6784\u5316\u5728SF\u53caPVP\u50ac\u5316\u5242\u4e0a\u7a0b\u5ea6\u76f8\u5f53\uff0c\u8fd9\u8bf4\u660e\u4f5c\u4e3a\u7a33\u5b9a\u5242\u7684PVP\u57fa\u56e2\u5bf9B1\u5f02\u6784\u5316\u8fc7\u7a0b\u5e76\u65e0\u8f83\u5927\u5f71\u54cd\u3002\u540c\u65f6\uff0c\u6c34\u6d17\u5904\u7406\u4f1a\u9020\u6210B1\u5f02\u6784\u5316\u8fdb\u884c\u7684\u66f4\u5267\u70c8\uff0c\u8bf4\u660e\u6c34\u6d17\u53bb\u9664\u7684\u8868\u9762\u7269\u79cd\u5bf9\u5f02\u6784\u5316\u8fc7\u7a0b\u6709\u8f83\u5927\u5f71\u54cd\u3002\u00a0<\/section>\n<section>\u00a0\u00a0<\/section>\n<section><img decoding=\"async\" title=\"4\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240307\/1709778684456859.png\" alt=\"4\" \/><\/section>\n<section>\u56fe4. \uff08a\uff09SF\u7cfb\u5217\u4e0e\uff08b\uff09PVP\u7cfb\u5217\u50ac\u5316\u5242\u4e0aBD\u52a0\u6c22\u53cd\u5e94\u4e2dB1\u5f02\u6784\u5316IF \uff08isomerization factor of B1\uff09<\/section>\n<section><\/section>\n<section>\u4e3a\u4e86\u786e\u5b9a\u5f71\u54cdB1\u5f02\u6784\u5316\u7684\u5173\u952e\u8868\u9762\u7269\u79cd\uff0c\u6211\u4eec\u5bf9\u50ac\u5316\u5242\u8fdb\u884c\u4e86\u5143\u7d20\u5206\u6790\uff08ICP\uff09\u8868\u5f81\u3002\u7ed3\u679c\u5982\u56fe5\uff08a\uff09\u6240\u793a\uff0c\u53ef\u4ee5\u770b\u5230S\u5143\u7d20\u542b\u91cf\u6709\u660e\u663e\u53d8\u5316\uff0c\u968f\u7740\u6c34\u6d17\u91cf\u7684\u589e\u5927\u800c\u964d\u4f4e\u3002\u8bf4\u660e\u8868\u9762S\u7269\u79cd\u53ef\u80fd\u662f\u5f71\u54cdB1\u5f02\u6784\u5316\u53cd\u5e94\u7684\u5173\u952e\u7269\u79cd\u3002\u4e3a\u4e86\u786e\u5b9a\u8868\u9762S\u7269\u79cd\u7684\u4f5c\u7528\uff0c\u6211\u4eec\u5bf9\u50ac\u5316\u5242\u8fdb\u884c\u4e86\u540e\u5904\u7406\uff1a\u5728\u5408\u6210\u9636\u6bb5\u9664\u53bbS\u7269\u79cd\u7684\u5f15\u5165\uff08\u5c06\u539f\u5408\u6210\u7528\u7684\u786b\u9178\u66ff\u6362\u4e3a\u76d0\u9178\uff09\uff0c\u8be5\u50ac\u5316\u5242\u547d\u540d\u4e3aSF-HCl-2L\uff1b\u5728\u8be5\u50ac\u5316\u5242\u57fa\u7840\u4e0a\uff0c\u91cd\u65b0\u5f15\u5165S\u7269\u79cd\uff0c\u547d\u540d\u4e3aSF-HCl-2L\uff08S\uff09\u3002\u5982\u56fe5\uff08b\uff09\u6240\u793a\uff0c\u5728\u53bb\u9664\u6389S\u7269\u79cd\u5f15\u5165\u540e\uff0cSF-HCl-2L\u5c55\u73b0\u51fa\u66f4\u9ad8\u7684IF\uff0c\u800c\u968f\u7740S\u7269\u79cd\u7684\u91cd\u65b0\u5f15\u5165\uff0cSF-HCl-2L\uff08S\uff09\u7684IF\u964d\u4f4e\u3002\u8be5\u5b9e\u9a8c\u8bc1\u660e\u4e86\u8868\u9762S\u7269\u79cd\u5728\u6291\u5236B1\u5f02\u6784\u5316\u8fc7\u7a0b\u4e2d\u8d77\u5230\u5173\u952e\u4f5c\u7528\u3002<\/section>\n<section><\/section>\n<section><img decoding=\"async\" title=\"5\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240307\/1709778693847558.png\" alt=\"5\" \/>\u56fe5. \uff08a\uff09SF\u50ac\u5316\u5242\u7684\u5143\u7d20\u7ec4\u6210\u5206\u6790\uff08b\uff09\u540e\u5904\u7406\u50ac\u5316\u5242\u4e0aBD\u52a0\u6c22\u53cd\u5e94\u4e2dB1\u5f02\u6784\u5316IF\u00a0 \u00a0\u00a0<\/section>\n<section><\/section>\n<section>\u00a0 \u00a0 \u00a0 \u00a0 \u00a0\u00a0<\/section>\n<section><strong>\u8868\u9762S\u7269\u79cd\u6291\u5236B1\u5f02\u6784\u5316\u8fc7\u7a0b\u7684\u673a\u5236\uff1a<\/strong><\/section>\n<section>\u6211\u4eec\u5229\u7528CO-DRIFT\u6280\u672f\u5bf9\u6c34\u6d17\u5904\u7406\u540e\u50ac\u5316\u5242\u6d3b\u6027\u4f4d\u70b9\u53d8\u5316\u8fdb\u884c\u4e86\u8868\u5f81\u3002\u5982\u56fe6\u6240\u793a\uff0c\u8c31\u56fe\u4e2d\u84dd\u8272\u548c\u7eff\u8272\u7684\u5206\u5cf0\u5206\u522b\u4ee3\u8868CO\u5438\u9644\u5728\u5b64\u7acbPd\u4f4d\u70b9\u548c\u5438\u9644\u5728\u8fde\u7eed\u7684Pd\u4f4d\u70b9\u3002\u901a\u8fc7\u5bf9\u4fe1\u53f7\u7edf\u8ba1\uff0c\u53d1\u73b0\u968f\u7740\u6c34\u6d17\u91cf\u7684\u589e\u52a0\uff0c\u5b64\u7acbPd\u4f4d\u70b9\u4e0e\u8fde\u7eed\u7684Pd\u4f4d\u70b9\u6bd4\u4f8b\u5e76\u672a\u53d1\u751f\u660e\u663e\u53d8\u5316\uff0c\u8bf4\u660e\u8868\u9762S\u7269\u79cd\u5728\u91d1\u5c5e\u8868\u9762\u7684\u5438\u9644\u8f83\u4e3a\u5747\u5300\uff0c\u5bf9\u5438\u9644\u4f4d\u70b9\u6784\u578b\u5e76\u4e0d\u5177\u6709\u660e\u663e\u7684\u9009\u62e9\u6027\u3002<\/section>\n<section><\/section>\n<section>\u6211\u4eec\u77e5\u9053\uff0cB1\u5f02\u6784\u5316\u8fc7\u7a0b\u4f9d\u8d56\u5438\u9644H\u539f\u5b50\u7684\u53c2\u4e0e\u3002\u968f\u7740S\u7269\u79cd\u7684\u5360\u636e\uff0c\u91d1\u5c5e\u6d3b\u6027\u4f4d\u70b9\u4e0a\u5438\u9644\u7684H\u539f\u5b50\u6d53\u5ea6\u53d7\u5230\u5f71\u54cd\u800c\u964d\u4f4e\uff0c\u8fd9\u5bfc\u81f4B1\u5f02\u6784\u5316\u8fc7\u7a0b\u53d7\u5230\u6291\u5236\u3002\u8fdb\u4e00\u6b65\uff0c\u6839\u636e\u6211\u4eecH<sub>2<\/sub>-TPR\u5b9e\u9a8c\u8868\u5f81\uff0c\u5f53\u6c34\u6d17\u91cf\u75310L\u63d0\u5347\u81f32L\u65f6\uff0c\u50ac\u5316\u5242\u7684\u6c22\u5438\u6536\u91cf\u75310.035 mmol\/gcat\u589e\u52a0\u5230\u4e860.049 mmol\/gcat\u3002\u8bf4\u660e\u968f\u7740\u6c34\u6d17\u5904\u7406\uff0c\u5171\u5438\u9644\u7684S\u7269\u79cd\u9664\u53bb\uff0c\u8868\u9762H\u539f\u5b50\u6d53\u5ea6\u589e\u5927\u3002\u56e0\u6b64\uff0c\u89c2\u6d4b\u5230\u968f\u7740\u6c34\u6d17\u5904\u7406\uff0c\u50ac\u5316\u5242\u4e0aB1\u5f02\u6784\u5316\u8fdb\u884c\u7a0b\u5ea6\u52a0\u5267\u3002<\/section>\n<section>\u00a0 \u00a0 \u00a0 \u00a0 \u00a0\u00a0<\/section>\n<section><img decoding=\"async\" title=\"0\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240307\/1709778702241461.png\" alt=\"0\" \/>\u200b<\/section>\n<section>\u56fe6. SF\u7cfb\u5217\u50ac\u5316\u5242CO-DRIFT\u8c31\u56fe\u8868\u5f81<\/section>\n<section><\/section>\n<section data-mpa-template=\"t\">\n<section data-mpa-template=\"t\">\n<section>\n<section data-mpa-category=\"\u6a21\u677f\" data-mid=\"\">\n<section data-mid=\"\">\n<section data-mid=\"\"><\/section>\n<section data-mid=\"\">\u00a0\u00a0<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section><strong>\u603b\u7ed3\u4e0e\u5c55\u671b<\/strong><\/section>\n<section>\u6211\u4eec\u5229\u7528PHIP-NMR\u6280\u672f\u7814\u7a76\u4e86Pd-Au\u53cc\u91d1\u5c5e\u50ac\u5316\u5242\u8868\u9762\u7269\u79cd\u5bf9BD\u52a0\u6c22\u53cd\u5e94\u4e2dB1\u5f02\u6784\u5316\u8fc7\u7a0b\u7684\u5f71\u54cd\u3002\u53d1\u73b0\u50ac\u5316\u5242\u5728\u6c34\u6d17\u5904\u7406\u524d\uff0c\u5927\u91cf\u7684\u786b\u7269\u79cd\u5747\u5300\u5730\u5438\u9644\u5728\u53cc\u91d1\u5c5e\u8868\u9762\u4e0a\u3002\u5171\u5438\u9644\u7684\u786b\u4e0e\u6c22\u7ade\u4e89\u8868\u9762\u4f4d\u70b9\uff0c\u964d\u4f4e\u8868\u9762\u5438\u9644H\u6d53\u5ea6\uff0c\u6291\u5236\u4e86\u5f02\u6784\u5316\u9014\u5f84\u3002\u901a\u8fc7\u63a7\u5236\u6d17\u6da4\uff0c\u8868\u9762S\u7269\u79cd\u88ab\u9009\u62e9\u6027\u9664\u53bb\uff0c\u8fdb\u800c\u52a0\u901f\u4e86B1\u7684\u5f02\u6784\u5316\u8f6c\u5316\u3002\u672c\u5de5\u4f5c\u4e2d\uff0c\u901a\u8fc7PHIP\u6280\u672f\u7684\u8d85\u6781\u5316NMR\u4fe1\u53f7\u5b9e\u73b0\u4e86\u5bf9\u50ac\u5316\u52a0\u6c22\u53cd\u5e94\u8fc7\u7a0b\u5206\u6790\uff0c\u7ed3\u5408\u5bf9\u50ac\u5316\u5242\u8868\u9762\u7684\u53ef\u63a7\u4fee\u9970\uff0c\u63ed\u793a\u4e86\u50ac\u5316\u5242\u754c\u9762\u6548\u5e94\u5728\u8c03\u63a7\u53cd\u5e94\u4e2d\u8d77\u5230\u7684\u5173\u952e\u4f5c\u7528\uff0c\u4e3a\u50ac\u5316\u5242\u8c03\u63a7\u4e0e\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u6307\u5bfc\u3002<\/section>\n","protected":false},"excerpt":{"rendered":"<p>\u25b2\u7b2c\u4e00\u4f5c\u8005\uff1a\u738b\u4f1f\u5b87\u00a0 \u5171\u540c\u901a\u8baf\u4f5c\u8005\uff1a\u5f90\u541b\u3001Graham Hutchings \u00a0 \u901a\u8baf\u5355\u4f4d\uff1a\u4e2d\u56fd\u79d1\u5b66\u9662\u7cbe\u5bc6\u6d4b\u91cf\u79d1 [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-51025","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51025","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=51025"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51025\/revisions"}],"predecessor-version":[{"id":51026,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/51025\/revisions\/51026"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=51025"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=51025"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=51025"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}