{"id":50957,"date":"2024-03-07T08:37:15","date_gmt":"2024-03-07T00:37:15","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=50957"},"modified":"2024-02-27T10:39:55","modified_gmt":"2024-02-27T02:39:55","slug":"angew-chem-%ef%bc%9a%e4%b8%89%e6%b0%9f%e7%94%b2%e5%9f%ba%e9%93%91-%e7%b1%bb%e5%8d%a1%e6%8b%9c%e5%8c%96%e5%90%88%e7%89%a9%e7%9a%84212%e7%8e%af%e5%8a%a0%e6%88%90%e5%8f%8d%e5%ba%94","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/angew-chem-%ef%bc%9a%e4%b8%89%e6%b0%9f%e7%94%b2%e5%9f%ba%e9%93%91-%e7%b1%bb%e5%8d%a1%e6%8b%9c%e5%8c%96%e5%90%88%e7%89%a9%e7%9a%84212%e7%8e%af%e5%8a%a0%e6%88%90%e5%8f%8d%e5%ba%94\/","title":{"rendered":"Angew. 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decoding=\"async\" title=\"0\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20240227\/1709001529518108.png\" alt=\"0\" \/>\u200b<\/section>\n<section>\u88681. \u54aa\u5511[1,5-a]-\u7a20\u6c2e\u6742\u73af\u5316\u5408\u7269\u7684\u6297\u80bf\u7624\u6d3b\u6027\uff08IC<sub>50<\/sub>\uff0c\u03bcM\uff09\u3002<\/p>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u603b\u4e4b\uff0c\u9648\u6c38\u6b63\u3001\u97e9\u6587\u52c7\u56e2\u961f\u5f00\u53d1\u4e86\u4e00\u79cd\u65b0\u578b\u03b1-\u91cd\u6c2e\u4e09\u6c1f\u4e59\u57fa\u950d\u76d0\uff0c\u5e76\u5c06\u5176\u7528\u4e8e\u94d1\u50ac\u5316\u6c2e\u6742\u7a20\u73af\u82b3\u70c3\u548c\u8148\u7c7b\u5316\u5408\u7269\u7684\u4e09\u7ec4\u5206[2+1+2]\u52a0\u6210\u53cd\u5e94\u4e2d\uff0c\u4e3a\u542b\u4e09\u6c1f\u7532\u57fa\u54aa\u5511[1,5-a]-\u6c2e\u6742\u73af\u5316\u5408\u7269\u7684\u5408\u6210\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u7684\u7b56\u7565\u3002\u8be5\u53cd\u5e94\u80fd\u5728\u8f83\u77ed\u7684\u65f6\u95f4\u5185\u9ad8\u6548\u5730\u8fdb\u884c\uff0c\u5177\u6709\u53cd\u5e94\u6761\u4ef6\u6e29\u548c\u3001\u5e95\u7269\u666e\u9002\u6027\u5e7f\u7684\u7279\u70b9\u3002\u6b64\u5916\uff0c\u901a\u8fc7\u836f\u7269\u5206\u5b50\u7684\u540e\u671f\u4fee\u9970\u3001\u542bCD<sub>3<\/sub>\u7684\u6c2e\u6742\u73af\u7684\u5408\u6210\u3001\u514b\u7ea7\u5b9e\u9a8c\u4ee5\u53caPDE10A\u6291\u5236\u5242\u7c7b\u4f3c\u7269\u7684\u5236\u5907\uff0c\u8fdb\u4e00\u6b65\u8bc1\u660e\u4e86\u8be5\u7b56\u7565\u7684\u5408\u6210\u6f5c\u529b\u3002\u6700\u540e\uff0c\u4f53\u5916\u6d3b\u6027\u5b9e\u9a8c\u7ed3\u679c\u8868\u660e\u5408\u6210\u7684\u542b\u4e09\u6c1f\u7532\u57fa\u7684\u54aa\u5511[1,5-a]-\u7a20\u6c2e\u6742\u73af\u5316\u5408\u7269\u5177\u6709\u826f\u597d\u7684\u6297\u80bf\u7624\u6d3b\u6027\uff0c\u6709\u671b\u6210\u4e3a\u65b0\u836f\u5f00\u53d1\u7684\u5148\u5bfc\u5316\u5408\u7269\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section><strong>\u8bba<\/strong><strong>\u6587\u4fe1\u606f<\/strong><\/p>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section><\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>Trifluoromethyl Rhodium-Carbynoid in [2 + 1 + 2] Cycloadditions<\/p>\n<p>Wen-Wen Zhao+, Meng-Yang Tian+, Yi-Lin Zhou, Lu-Jie Liu, Shao-Fang Tian, Chun-Yang He, Xing-Zhi Yang, Yong-Zheng Chen, Wen-Yong Han*<\/p>\n<p>\u9075\u4e49\u533b\u79d1\u5927\u5b662020\u7ea7\u7855\u58eb\u7814\u7a76\u751f\u8d75\u6587\u6587\u548c2022\u7ea7\u7855\u58eb\u7814\u7a76\u751f\u7530\u68a6\u6768\u4e3a\u8be5\u8bba\u6587\u7684\u7b2c\u4e00\u4f5c\u8005\uff0c\u6307\u5bfc\u8001\u5e08\u4e3a\u9648\u6c38\u6b63\u548c\u97e9\u6587\u52c7\u6559\u6388\u3002\u8be5\u7814\u7a76\u5de5\u4f5c\u5f97\u5230\u4e86\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u59d4\u3001\u8d35\u5dde\u7701\u79d1\u6280\u5385\u7b49\u9879\u76ee\u7684\u8d44\u52a9\u3002<\/p>\n<p><em>Angewandte Chemie International Edition<\/em><\/p>\n<p>DOI:\u00a010.1002\/anie.202318887<\/p>\n<\/section>\n<\/section>\n<\/section>\n","protected":false},"excerpt":{"rendered":"<p>\u4e09\u6c1f\u7532\u57fa\u91d1\u5c5e-\u7c7b\u5361\u62dc\uff08CF3C+=M\uff09\u662f\u4e00\u79cd\u53ef\u4ee5\u6a21\u62df\u5177\u6709\u5361\u5bbe\u548c\u9633\u79bb\u5b50\u53cc\u91cd\u6027\u8d28\u7684\u4e09\u6c1f\u7532\u57fa\u9633\u79bb\u5b50\u5361\u62dc\uff08CF3C+: [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-50957","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/50957","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=50957"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/50957\/revisions"}],"predecessor-version":[{"id":50958,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/50957\/revisions\/50958"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=50957"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=50957"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=50957"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}