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\u7535\u5316\u5b66\u6d4b\u8bd5\u7ed3\u679c\u663e\u793a\u590d\u5408\u6750\u6599\u5728HMF\u6c27\u5316\u53cd\u5e94\uff08HMFOR\uff09\u4e2d\u5b58\u5728\u4f4e\u7535\u4f4d\u4e0bAg-CoOOH\uff08Co(OH)2<\/sub>\u7535\u5316\u5b66\u6c27\u5316\u540e\uff09\u7684\u76f4\u63a5\u6c27\u5316\u53cd\u5e94\u548c\u9ad8\u7535\u4f4d\u4e0bAg-CoO2<\/sub>\uff08CoOOH\u7535\u5316\u5b66\u6c27\u5316\u540e\uff09\u7684\u534f\u540c\u6c27\u5316\u53cd\u5e94\u4e24\u79cd\u6c27\u5316\u53cd\u5e94\u7c7b\u578b\u3002\u5e76\u4e14Ag\u7684\u5f15\u5165\u663e\u8457\u964d\u4f4e\u4e86\u53cd\u5e94\u7535\u4f4d\uff0c\u63d0\u5347\u4e86\u50ac\u5316\u7535\u6d41\uff0c\u8bc1\u660e\u4e86\u8be5\u590d\u5408\u6750\u6599\u7684\u5de8\u5927\u4f18\u52bf\u3002\u9ad8\u6548\u6db2\u76f8\u8272\u8c31(HPLC)\u7ed3\u679c\u8868\u660eAg-Co(OH)2<\/sub>\u50ac\u5316\u53cd\u5e94\u7684\u4e3b\u4ea7\u7269\u5728\u4e0d\u540c\u7535\u4f4d\u4e0b\u5e76\u4e0d\u4e00\u81f4\uff0c\u8bf4\u660e\u8be5\u6750\u6599\u5728\u4e0d\u540c\u7535\u4f4d\u4e0b\u5b58\u5728\u4e0d\u540c\u7684\u53cd\u5e94\u673a\u7406\u3002\u901a\u8fc7\u6cd5\u62c9\u7b2c\u6548\u7387\u6bd4\u8f83\u548c\u9a8c\u8bc1\u5b9e\u9a8c\u8868\u660e\u4f4e\u7535\u4f4d\u533a\u95f4\u53d1\u751fAg\u50ac\u5316\u7684Cannizzaro\u53cd\u5e94\uff0c\u4e3b\u4ea7\u7269\u4e3aHMFCA\u3002\u9ad8\u7535\u4f4d\u533a\u95f4Cannizzaro\u53cd\u5e94\u4e00\u5b9a\u7a0b\u5ea6\u4e0a\u88ab\u6291\u5236\uff0c\u4e3b\u4ea7\u7269\u53d8\u4e3aFDCA\u3002<\/section>\n
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\"3\"<\/section>\n
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HPLC\u7ed3\u679c\u663e\u793a\u590d\u5408\u6750\u6599\u53cd\u5e94\u4e2dHMFCA\u4e2d\u95f4\u4f53\u542b\u91cf\u66f4\u591a\uff0c\u8868\u660e\u9ad8\u7535\u4f4d\u4e0bHMF\u2192HMFCA\u2192FFCA\u2192FDCA\u7684\u53cd\u5e94\u8def\u5f84\u3002\u5e76\u610f\u5473\u7740Ag\u7684\u5f15\u5165\u5373\u4f7f\u5728\u9ad8\u7535\u4f4d\u4e0b\u5bf9Cannizaro\u53cd\u5e94\u6709\u6240\u6291\u5236\uff0c\u4ecd\u6709\u5229\u4e8e\u919b\u57fa\u6c27\u5316\uff0c\u4e5f\u8bc1\u660e\u4e86Ag\u7684\u4e32\u8054\u50ac\u5316\u4f5c\u7528\u3002\u6b64\u5916\uff0c\u590d\u5408\u6750\u6599\u5c55\u73b0\u51fa\u826f\u597d\u7684\u7a33\u5b9a\u6027\u3002\u539f\u4f4d\u7ea2\u5916\u5149\u8c31\u8fdb\u4e00\u6b65\u4f50\u8bc1\u4e86Ag-Co(OH)2<\/sub>\u4e32\u8054\u50ac\u5316\u5242\u6bd4Co(OH)2<\/sub>\u5177\u6709\u66f4\u4f4e\u7684\u53cd\u5e94\u7535\u4f4d\u548c\u66f4\u597d\u7684\u50ac\u5316\u6d3b\u6027\uff0c\u5e76\u4e14\u590d\u5408\u7ec4\u5206\u8868\u9762\u6709\u673a\u5206\u5b50\u7684\u8986\u76d6\u7387\u66f4\u9ad8\uff0c\u8fdb\u4e00\u6b65\u9610\u660e\u4e86Ag-Co(OH)2<\/sub>\u50ac\u5316\u5242\u5728\u53cd\u5e94\u4e2d\u5bf9\u6709\u673a\u5206\u5b50\u7684\u5438\u9644\u589e\u5f3a\u4f5c\u7528\u3002\u5f00\u8def\u7535\u4f4d\u6d4b\u8bd5\u548c\u77f3\u82f1\u6676\u4f53\u5fae\u5929\u5e73\u6d4b\u8bd5\u8fdb\u4e00\u6b65\u8868\u660e\u4e86\u590d\u5408\u6750\u6599\u5177\u6709\u66f4\u4f18\u7684\u6709\u673a\u7269\u5438\u9644\u80fd\u529b\u3002<\/section>\n
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\"4\"<\/section>\n
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\u6b64\u5916\uff0c\u5e95\u7269\u6c27\u5316\u8fc7\u7a0b\u9700\u8981OH-\u7269\u79cd\u53c2\u4e0e\u3002Zeta\u7535\u4f4d\uff0c\u539f\u4f4d\u7ea2\u5916\u5149\u8c31\uff0c\u53cd\u5e94\u901f\u7387\u5e38\u6570\uff0cCV\u6d4b\u8bd5\u4ee5\u53ca\u53cd\u5e94\u533a\u95f4\u7535\u5bb9\u6d4b\u8bd5\u7ed3\u679c\u8868\u660e\u590d\u5408\u7ec4\u5206\u66f4\u5229\u4e8eOH-\u7269\u79cd\u7684\u5438\u9644\u548c\u7535\u5b50\u8f6c\u79fb\u3002\u539f\u4f4d\u7535\u5316\u5b66\u963b\u6297\u8c31\u8868\u660eAg-Co(OH)2<\/sub>\u5177\u6709\u66f4\u4f4e\u7684\u53cd\u5e94\u7535\u4f4d\uff0c\u66f4\u5feb\u7684\u53cd\u5e94\u901f\u7387\u548c\u66f4\u4f4e\u7684\u7535\u8377\u8f6c\u79fb\u963b\u6297\u3002\u5e76\u4e14\uff0c\u5728HMFOR\u533a\u95f4\u5185\uff0cAg-Co(OH)2<\/sub>\u5177\u6709\u66f4\u9ad8\u7684\u5438\u9644\u6c27\u6bd4\u503c\u548c\u66f4\u591a\u7684Co3+<\/sup>\u76f4\u63a5\u50ac\u5316\u4f4d\u70b9\u6570\u91cf\uff0c\u5229\u4e8e\u52a0\u901f\u53cd\u5e94\u8fdb\u884c\u3002<\/section>\n
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\"5\"\u200b<\/section>\n
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\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba(DFT)\u8ba1\u7b97\u8868\u660e\u4e0eCo(OH)2<\/sub>\u76f8\u6bd4\uff0cAg\u7684\u4fee\u9970\u53ef\u4ee5\u63d0\u9ad8\u5bf9HMF\u548cOH\u7684\u5438\u9644\u5f3a\u5ea6\u3002\u5bf9\u4e24\u79cd\u6750\u6599\u800c\u8a00\uff0cHMFCA\u2192FFCA\u6b65\u9aa4\u4e3a\u53cd\u5e94\u51b3\u901f\u6b65\u9aa4\u3002Ag\u5f15\u5165\u540e\uff0c\u8be5\u6b65\u9aa4\u53cd\u5e94\u52bf\u5792\u964d\u4f4e\uff0c\u8868\u660eAg\u4e0eCoOOH\u4e4b\u95f4\u7684\u534f\u540c\u4f5c\u7528\u5bf9\u63d0\u9ad8HMFOR\u6d3b\u6027\u8d77\u7740\u91cd\u8981\u4f5c\u7528\u3002Bader\u7535\u8377\u6f14\u53d8\u8868\u660eAg\u4f5c\u4e3a\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u4e2d\u5fc3\uff0c\u5728HMFOR\u4e2d\u8d77\u7740\u7535\u5b50\u50a8\u5c42\u7684\u4f5c\u7528\u3002\u6709\u8da3\u7684\u662f\uff0cCoOOH\u5728HMF\u2192HMFCA\u9636\u6bb5\u901a\u8fc7\u8c03\u8282\u81ea\u8eab\u7535\u8377\u589e\u5f3aAg\u7684\u6c27\u5316\u8fd8\u539f\u80fd\u529b\uff0c\u5728HMFCA\u2192FFCA\u548cFFCA\u2192FDCA\u9636\u6bb5CoOOH\u548cAg\u4f5c\u4e3a\u53cd\u5e94\u4e2d\u5fc3\u901a\u8fc7\u534f\u540c\u4f5c\u7528\u50ac\u5316\u5e95\u7269\u8f6c\u5316\u3002\u56e0\u6b64\uff0c\u901a\u8fc7DFT\u6a21\u62df\u548c\u8be6\u7ec6\u7684\u5b9e\u9a8c\u7ed3\u679c\uff0c\u6df1\u5165\u5206\u6790\u4e86Ag-Co(OH)2<\/sub>\u50ac\u5316\u5242\u7684\u53cd\u5e94\u673a\u7406\u2014\u2014\u201c\u4e32\u8054\u534f\u540c\u50ac\u5316\u201d\u4f5c\u7528\u3002<\/section>\n
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\"\u56fe\u7247\"<\/p>\n

\u00a0\u00a0<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n
\u603b\u7ed3\u4e0e\u5c55\u671b<\/strong><\/section>\n
\u672c\u5de5\u4f5c\u91c7\u7528\u81ea\u53d1\u6c27\u5316\u8fd8\u539f\u6cd5\u5236\u5907\u4e86Ag-Co(OH)2<\/sub>\u590d\u5408\u6750\u6599\u3002\u53d7\u76ca\u4e8e\u5f02\u8d28\u7ec4\u5206\u7684\u4e32\u8054\u534f\u540c\u50ac\u5316\u4f5c\u7528\uff0c\u8be5\u50ac\u5316\u5242\u8868\u73b0\u51fa\u8f83\u4f4e\u7684HMFOR\u7535\u4f4d(Ag-Co(OH)2<\/sub>\u4e3a1.03 V, Co(OH)2<\/sub>\u4e3a1.29 V)\u548c1.3 V\u4e0b\u76f8\u6bd4\u4e8eCo(OH)2<\/sub>5\u500d\u9ad8\u7684\u7535\u6d41\u5bc6\u5ea6\u3002\u6b64\u5916\uff0cAg-Co(OH)2<\/sub>\u50ac\u5316\u5242\u53ef\u4ee5\u57281.1 V-1.5 V\u7684\u7535\u4f4d\u8303\u56f4\u5185\u50ac\u5316\u751f\u6210HMFCA\u548cFDCA\u4e24\u79cd\u4e0d\u540c\u7684\u4ea7\u7269\uff0c\u4e14\u4ea7\u7387\u53ef\u8c03(1.1 V\u65f6HMFCA\u7684\u4ea7\u7387\u4e3a91.3%\uff0c1.4 V\u65f6FDCA\u7684\u4ea7\u7387\u4e3a92.8%)\u3002\u5e76\u4e14Ag-Co(OH)2<\/sub>\u5f02\u8d28\u50ac\u5316\u5242\u7684\u6784\u5efa\u53ef\u4ee5\u6709\u6548\u63d0\u9ad8\u6709\u673a\u5206\u5b50\u548cOH\u7269\u79cd\u7684\u5438\u9644\u8f6c\u5316\u6548\u679c\uff0c\u4fc3\u8fdb\u4f4e\u7535\u4f4d\u533a\u95f4\u919b\u57fa\u6c27\u5316\uff0c\u901a\u8fc7\u4e32\u8054\u534f\u540c\u50ac\u5316\u4f5c\u7528\u964d\u4f4e\u9ad8\u7535\u4f4d\u533a\u95f4HMFCA\u2192FFCA\u6b65\u9aa4\u7684\u8f6c\u5316\u80fd\u5792\uff0c\u4ece\u800c\u52a0\u5feb\u53cd\u5e94\u8fc7\u7a0b\u3002\u672c\u7814\u7a76\u4e3a\u5355\u4e00\u50ac\u5316\u5242\u5728\u53ef\u8c03\u7535\u4f4d\u8303\u56f4\u5185\u83b7\u5f97\u591a\u79cd\u589e\u503c\u5316\u5b66\u7269\u8d28\u63d0\u4f9b\u4e86\u65b0\u9014\u5f84\uff0c\u9610\u660e\u4e86\u50ac\u5316\u589e\u5f3a\u7684\u5185\u5728\u673a\u5236\uff0c\u4e3a\u9ad8\u6548\u591a\u7ec4\u5206\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u548c\u5f00\u53d1\u63d0\u4f9b\u4e86\u53c2\u8003\u548c\u6307\u5bfc\u3002<\/section>\n
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\"\u56fe\u7247\"<\/p>\n

\u00a0\u00a0<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n
\u4f5c\u8005\u4ecb\u7ecd<\/strong><\/section>\n
\u5468\u9e4f\uff0c\u9752\u5c9b\u5927\u5b66\u526f\u6559\u6388\uff0c\u7855\u58eb\u751f\u5bfc\u5e08\uff0c2020\u5e74\u4e8e\u5c71\u4e1c\u5927\u5b66\u83b7\u5f97\u535a\u58eb\u5b66\u4f4d\uff0c2020-2022\u5e74\u5728\u6e56\u5357\u5927\u5b66\u4ece\u4e8b\u535a\u58eb\u540e\u79d1\u7814\u5de5\u4f5c\uff0c2022\u5e74\u5165\u804c\u9752\u5c9b\u5927\u5b66\u3002\u4e3b\u8981\u4ece\u4e8b\u7535\u50ac\u5316\u5236\u6c22\uff0c\u751f\u7269\u8d28\u6709\u673a\u5c0f\u5206\u5b50\u7535\u50ac\u5316\u8f6c\u5316\u76f8\u5173\u65b9\u9762\u7814\u7a76\u3002\u76ee\u524d\u4e3b\u6301\u7701\u90e8\u7ea7\u9879\u76ee\u591a\u9879\uff0c\u5728Adv. Mater, Adv. Funct. Mater, Appl. Catal. B: Environ\u7b49\u671f\u520a\u53d1\u8868SCI\u8bba\u658730\u4f59\u7bc7\uff0c\u5305\u62ecESI\u9ad8\u88ab\u5f15\u8bba\u65872\u7bc7\uff0c\u70ed\u70b9\u8bba\u65871\u7bc7\uff0c\u5f15\u7528\u6b21\u65701000\u4f59\u6b21\uff0c\u6388\u6743\u4e13\u52292\u9879\uff0c\u62c5\u4efbGreen Carbon\u671f\u520a\u9752\u5e74\u7f16\u59d4\u8eab\u4efd\u3002<\/section>\n
<\/section>\n
\u5415\u5174\u5e05\uff1a2020\u5e746\u6708\u4e8e\u5c71\u4e1c\u5927\u5b66\u83b7\u5f97\u535a\u58eb\u5b66\u4f4d\uff0c\u6b64\u540e\u5206\u522b\u5728\u6df1\u5733\u4eac\u9c81\u8ba1\u7b97\u79d1\u5b66\u5e94\u7528\u7814\u7a76\u9662\u3001\u6fb3\u95e8\u5927\u5b66\u4ece\u4e8b\u535a\u58eb\u540e\u7814\u7a76\u3002\u4e3b\u8981\u4ece\u4e8b\u5408\u6210\u6c28\u7535\u50ac\u5316\u5242\u7684\u7406\u6027\u8bbe\u8ba1\u53ca\u6027\u80fd\u8c03\u63a7\u7684\u7814\u7a76\u5de5\u4f5c\u3002\u5728Adv. Mater\uff0cAdv. Funct. Mater\uff0cACS Catal\uff0cNano Lett\uff0cAppl. Catal. B:Environ\u7b49\u671f\u520a\u53d1\u8868SCI\u8bba\u658740\u4f59\u7bc7\uff0c\u5305\u62ecESI\u9ad8\u88ab\u5f15\u8bba\u65872\u7bc7\uff0c\u70ed\u70b9\u8bba\u65871\u7bc7\uff0c\u5f15\u7528\u6b21\u65702900\u4f59\u6b21\u3002<\/section>\n
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\u90b9\u96e8\u82b9\uff1a\u6e56\u5357\u5927\u5b66\u6559\u6388\uff0c\u535a\u58eb\u751f\u5bfc\u5e08\uff0c\u56fd\u5bb6\u4f18\u79c0\u9752\u5e74\u57fa\u91d1\u3001\u56fd\u5bb6\u91cd\u70b9\u7814\u53d1\u8ba1\u5212\u8bfe\u9898\u3001\u6e56\u5357\u7701\u4f18\u79c0\u9752\u5e74\u57fa\u91d1\u3001\u6e56\u5357\u7701\u201c\u6e56\u6e58\u9752\u5e74\u82f1\u624d\u201d\u3001\u6e56\u5357\u5927\u5b66\u201c\u5cb3\u9e93\u5b66\u8005\u201d\u7b49\u9879\u76ee\u83b7\u5f97\u8005\u3002\u805a\u7126\u6709\u673a\u7535\u50ac\u5316\u8f6c\u5316\uff0c\u56f4\u7ed5\u6709\u673a\u7535\u50ac\u5316\u4f53\u7cfb\u7684\u590d\u6742\u6027\uff0c\u63ed\u793a\u4e86\u50ac\u5316\u5242\u4f5c\u7528\u673a\u5236\uff0c\u89e3\u6790\u4e86\u6709\u673a\u5206\u5b50\u53cd\u5e94\u8def\u5f84\uff0c\u5e76\u57fa\u4e8e\u4ee5\u4e0a\u8ba4\u8bc6\uff0c\u8bbe\u8ba1\u4e86\u65b0\u7684\u7535\u50ac\u5316\u4f53\u7cfb\uff0c\u5b9e\u73b0\u90e8\u5206\u6709\u673a\u5206\u5b50\u7684\u5b9a\u5411\u8f6c\u5316\u3002\u81f3\u4eca\uff0c\u4ee5\u901a\u8baf\u4f5c\u8005\u53d1\u8868SCI\u8bba\u658780\u4f59\u7bc7\uff0c\u5305\u62ecNat. Catal\uff0cChem\uff0cJ. Am. Chem. Soc\uff0cAngew. Chem\uff0cAdv. Mater\uff0cNatl. Sci. Rev\uff0cMater, Energy Environ. Sci\uff0cAdv. Energy Mater\u7b49\uff0c\u5176\u4e2dESI\u9ad8\u88ab\u5f15\u8bba\u658726\u7bc7\uff0c\u70ed\u70b9\u8bba\u65873\u7bc7\uff0c\u8bba\u6587\u4ed6\u5f1510000\u4f59\u6b21\uff0cH\u6307\u6570\u4e3a55\u3002\u73b0\u4efb\u300aChinese Journal of Catalysis\u300b\u3001\u300aChinese Chemical Letters\u300b\u3001\u300aChinese Journal of Structural Chemistry\u300b\u671f\u520a\u9752\u5e74\u7f16\u59d4\u7b49\u5b66\u672f\u804c\u52a1\u3002\uff09<\/section>\n","protected":false},"excerpt":{"rendered":"

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