{"id":50937,"date":"2024-03-04T08:27:50","date_gmt":"2024-03-04T00:27:50","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=50937"},"modified":"2024-02-25T08:29:02","modified_gmt":"2024-02-25T00:29:02","slug":"cjc-%e4%b8%8a%e6%b5%b7%e6%9c%89%e6%9c%ba%e6%89%80%e6%b2%88%e5%85%b6%e9%be%99%e5%9b%a2%e9%98%9f%ef%bc%9ame4ncucf33f-%ef%bc%9a%e8%bd%ac%e9%87%91%e5%b1%9e%e5%9f%ba%e5%85%83%e5%8f%8d%e5%ba%94","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/cjc-%e4%b8%8a%e6%b5%b7%e6%9c%89%e6%9c%ba%e6%89%80%e6%b2%88%e5%85%b6%e9%be%99%e5%9b%a2%e9%98%9f%ef%bc%9ame4ncucf33f-%ef%bc%9a%e8%bd%ac%e9%87%91%e5%b1%9e%e5%9f%ba%e5%85%83%e5%8f%8d%e5%ba%94\/","title":{"rendered":"CJC | \u4e0a\u6d77\u6709\u673a\u6240\u6c88\u5176\u9f99\u56e2\u961f\uff1aMe4N+[Cu(CF3)3F]-\uff1a\u8f6c\u91d1\u5c5e\u57fa\u5143\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u5173\u952e\u4e09\u4ef7\u94dc\u6c1f\u914d\u5408\u7269"},"content":{"rendered":"
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Breaking\u00a0Report<\/strong><\/em><\/p>\n<\/section>\n<\/section>\n
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Access to Versatile Functionalized Cu(III) Complexes Enabled by Direct Transmetalation to Well-Defined Copper(III) Fluoride Complex Me4<\/sub>N+<\/sup>[Cu(CF3<\/sub>)3<\/sub>F]–<\/sup><\/strong><\/section>\n
Guangyu Wang, Huaiyuan Li, Xuebing Leng, Long Lu, and Qilong Shen*<\/section>\n

\"1\"<\/p>\n

The invention of a well-defined Cu(III) fluoride complex Me4<\/sub>N+<\/sup>[Cu(CF3<\/sub>)3<\/sub>(F)]–<\/sup>\u00a01\u00a0<\/strong>enabled to access a versatile of functionalized Cu(III) complexes [Me4<\/sub>N]+<\/sup>[Cu(X)(CF3<\/sub>)3<\/sub>]–<\/sup>\u00a0(X = C6<\/sub>F5<\/sub>, C6<\/sub>F5<\/sub>C\u2261C, CN, Cl, N3<\/sub>,\u00a0t<\/sup><\/em>BuOO,SCN, OAc, SAr), many of them for the first time. The availability of these complexes allowed us to evaluate the\u00a0trans<\/em>-influence order of ligand in Cu(III) complexes: Bn > CF3<\/sub>\u2012<\/sup>\u00a0> C6<\/sub>F5<\/sub>\u2012\u00a0<\/sup>> N3<\/sub>\u2012<\/sup>\u00a0> py ~ CH3<\/sub>\u2012<\/sup>\u00a0~ C6<\/sub>F5<\/sub>C\u2261C > NO2<\/sub>PhO\u2012\u00a0<\/sup>~\u00a0t<\/sup><\/em>BuOO\u2012<\/sup>\u00a0~ CH3<\/sub>COO\u2012<\/sup>\u00a0> F\u2012<\/sup>.<\/section>\n<\/section>\n<\/section>\n

Fluorine\u00a0|\u00a0Copper\u00a0|\u00a0Cu(III)\u00a0|\u00a0Cu(III) fluoride\u00a0|\u00a0Trifluoromethyl<\/p>\n

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Me4<\/sub>N+<\/sup>[Cu(CF3<\/sub>)3<\/sub>F]–<\/sup>\uff1a\u8f6c\u91d1\u5c5e\u57fa\u5143\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u5173\u952e\u4e09\u4ef7\u94dc\u6c1f\u914d\u5408\u7269<\/strong><\/section>\n<\/section>\n<\/section>\n
\u94dc\u662f\u81ea\u7136\u754c\u4e30\u5ea6\u8f83\u9ad8\u7684\u8fc7\u6e21\u91d1\u5c5e\u4e4b\u4e00\uff0c\u4ef7\u683c\u4f4e\u5ec9\u540c\u65f6\u62e5\u6709\u826f\u597d\u7684\u751f\u7269\u76f8\u5bb9\u6027\u4ee5\u53ca\u591a\u6837\u7684\u5316\u5b66\u53cd\u5e94\u6027\uff0c\u56e0\u6b64\u94dc\u4ecb\u5bfc\u7684\u53cd\u5e94\u8fd1\u5e74\u6765\u5907\u53d7\u56fd\u9645\u5173\u6ce8\u3002\u867d\u7136\u94dc\u4ecb\u5bfc\u7684\u6784\u5efa\u78b3-\u78b3\u952e\u3001\u78b3-\u6c1f\u952e\u4ee5\u53ca\u5176\u4ed6\u78b3-\u6742\u539f\u5b50\u952e\u7684\u65b9\u6cd5\u65e9\u5728\u4e00\u767e\u591a\u5e74\u524d\u5c31\u5df2\u62a5\u9053\uff0c\u8fd1\u5e74\u6765\u4e5f\u65e5\u8d8b\u6210\u719f\uff0c\u7136\u800c\u79d1\u5b66\u5bb6\u4eec\u5bf9\u5176\u53cd\u5e94\u673a\u7406\uff0c\u7279\u522b\u662f\u50ac\u5316\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u7684\u5173\u952e\u4e2d\u95f4\u4f53\u7684\u7ed3\u6784\u53ca\u5176\u50ac\u5316\u5faa\u73af\u4e2d\u7684\u57fa\u5143\u53cd\u5e94\u77e5\u4e4b\u751a\u5c11\u3002\u5176\u4e2d\uff0c\u4e0d\u5c11\u94dc\u50ac\u5316\u7684\u5b98\u80fd\u56e2\u5316\u53cd\u5e94\u5f80\u5f80\u4f7f\u7528\u6c1f\u76d0\u4f5c\u4e3a\u8f6c\u91d1\u5c5e\u8bd5\u5242\u6765\u6d3b\u5316\u542b\u7845\u6216\u787c\u5e95\u7269\uff0c\u5c06\u76ee\u6807\u5b98\u80fd\u56e2\u4ece\u5e95\u7269\u8f6c\u79fb\u5230\u94dc\u4e2d\u95f4\u4f53\uff0c\u4ece\u800c\u4fc3\u8fdb\u50ac\u5316\u5faa\u73af\u7684\u8fd0\u8f6c\u3002\u7136\u800c\uff0c\u6587\u732e\u4e2d\u5bf9\u4e8e\u8be5\u50ac\u5316\u5faa\u73af\u4e2d\u7684\u5173\u952e\u6d3b\u6027\u4e2d\u95f4\u4f53Cu(III)-F\u7269\u79cd\u4ecd\u7136\u7f3a\u4e4f\u8db3\u591f\u7684\u8ba4\u8bc6\u3002\u56e0\u6b64\uff0c\u901a\u8fc7\u8c31\u5b66\u6570\u636e\u63a8\u6d4b\u5176\u53ef\u80fd\u7684\u7ed3\u6784\uff08J. Am. Chem. Soc.\u00a0<\/em>2013<\/strong>,\u00a0135<\/em>, 2552.\uff09\u4ee5\u53ca\u5206\u79bb\u8868\u5f81\u5176\u7ed3\u6784\u5e76\u7814\u7a76\u53cd\u5e94\u6d3b\u6027\uff08J. Am. Chem. Soc.<\/em>\u00a02020<\/strong>,\u00a0142<\/em>, 8514.\u00a0Angew. Chem. Int. Ed.<\/em>\u00a02023<\/strong>, e202319412.\uff09\u6709\u52a9\u4e8e\u4eba\u4eec\u7406\u89e3\u53cd\u5e94\u8fc7\u7a0b\uff0c\u5e76\u8fdb\u4e00\u6b65\u6539\u8fdb\u50ac\u5316\u53cd\u5e94\u6761\u4ef6\u3002<\/section>\n

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\u4e0a\u6d77\u6709\u673a\u6240\u6c88\u5176\u9f99\u56e2\u961f\u8fd1\u5e74\u6765\u81f4\u529b\u4e8e\u5408\u6210\u8868\u5f81\u94dc\u50ac\u5316\u8fc7\u7a0b\u7684\u5173\u952e\u6d3b\u6027\u4e2d\u95f4\u4f53\uff0c\u5e76\u7814\u7a76\u5176\u57fa\u5143\u53cd\u5e94(Angew. Chem. Int. Ed.<\/em>\u00a02019<\/strong>,\u00a058<\/em>, 8510.\u00a0J. Am. Chem. Soc.<\/em>\u00a02020<\/strong>,142<\/em>, 9785.\u00a0J. Am. Chem. Soc.<\/em>\u00a02021<\/strong>,\u00a0143<\/em>, 14367.\u00a0Chin. J. Chem.<\/em>\u00a02022<\/strong>,\u00a040<\/em>, 1924.\u00a0Science<\/em>\u00a02023<\/strong>,\u00a0381<\/em>, 1072)\u3002\u6700\u8fd1\uff0c\u6c88\u5176\u9f99\u3001\u738b\u5e7f\u5b87\u548c\u674e\u6000\u8fdc\u7b49\u4eba\u53d1\u73b0\uff0c\u5c06Me4<\/sub>NF\u4e0e(py)Cu(CF3<\/sub>)3<\/sub>\u5728THF\/CH3<\/sub>CN\u7684\u6df7\u5408\u6eb6\u5242\u4e2d\u6405\u62cc10\u5206\u949f\uff0c\u4e00\u6b65\u5c31\u76f4\u63a5\u5408\u6210\u4e86\u4e09\u4ef7\u94dc\u6c1f\u7edc\u5408\u7269Me4<\/sub>N+<\/sup>[CuIII<\/sup>(CF3<\/sub>)3<\/sub>F]\u2013<\/sup>\uff0c\u8be5\u7edc\u5408\u7269\u7684\u7ed3\u6784\u901a\u8fc7\u6c22\u8c31\u3001\u6c1f\u8c31\u3001\u5143\u7d20\u5206\u6790\u786e\u5b9a\uff0c\u5e76\u57f9\u517b\u4e86\u8be5\u7edc\u5408\u7269\u7684\u5355\u6676\u5e76\u901a\u8fc7\u5355\u6676\u884d\u5c04\u786e\u8bc1\u4e86\u5176\u7ed3\u6784\u3002\u8fdb\u4e00\u6b65\u7814\u7a76\u8868\u660e\uff0c\u8be5\u7edc\u5408\u7269\u4e0a\u7684\u94dc-\u6c1f\u952e\u53ef\u4ee5\u4e0e\u4e00\u7cfb\u5217\u542b\u7845\u5e95\u7269\u5982TMSC6<\/sub>F5<\/sub>\u3001TMSC\u2261CAr\u3001TMSCN\u3001TMSCl\u3001TMSOOt<\/sup><\/em>Bu\u3001TMSN3<\/sub>\u3001TMSNCS\u53cd\u5e94\uff0c\u5c06\u76f8\u5e94\u7684\u5b98\u80fd\u56e2\u8f6c\u79fb\u5230\u4e09\u4ef7\u94dc\u4e0a\uff0c\u5f97\u5230Me4<\/sub>N+<\/sup>[CuIII<\/sup>(CF3<\/sub>)3<\/sub>(FG)]\u2013\u00a0<\/sup>(FG = C6<\/sub>F5<\/sub>\uff0cC\u2261CAr, CN, Cl, OOt<\/sup><\/em>Bu, N3<\/sub>, NCS).\u00a0\u540c\u65f6\uff0c\u7531\u4e8e\u6c1f\u79bb\u5b50\u6709\u8f83\u5f3a\u7684\u78b1\u6027\uff0c\u56e0\u6b64\u4e09\u4ef7\u94dc\u6c1f\u7edc\u5408Me4<\/sub>N+<\/sup>[CuIII<\/sup>(CF3<\/sub>)3<\/sub>F]\u2013<\/sup>\u4e0a\u7684\u6c1f\u4e5f\u53ef\u4ee5\u4f5c\u4e3a\u78b1\u4e0eHOAc\u53caArSH\u53cd\u5e94\uff0c\u9ad8\u4ea7\u7387\u5730\u5f97\u5230Me4<\/sub>N+<\/sup>[CuIII<\/sup>(CF3<\/sub>)3<\/sub>(OAc)]\u2013\u00a0<\/sup>\u6216Me4<\/sub>N+<\/sup>[CuIII<\/sup>(CF3<\/sub>)3<\/sub>(SAr)]\u2013<\/sup>\u3002\u53e6\u5916\uff0c\u8be5\u7edc\u5408\u7269\u4e0e\u81a6\u70f7\u6216\u4e9a\u78f7\u9178\u916f\u53cd\u5e94\u65f6\uff0c\u4e0d\u80fd\u5206\u79bb\u5f97\u5230\u76f8\u5e94\u7684\u4e09\u4ef7\u94dc\u7edc\u5408\u7269\uff0c\u800c\u662f\u9ad8\u4ea7\u7387\u5730\u76f4\u63a5\u5f97\u5230\u8fd8\u539f\u6d88\u9664\u4ea7\u7269R2<\/sub>PCF3<\/sub>\u3002\u7c7b\u4f3c\u5730\uff0c\u5f53\u5c1d\u8bd5RR\u2019NTMS\u4e0e\u4e09\u4ef7\u94dc\u6c1f\u7edc\u5408\u7269Me4<\/sub>N+<\/sup>[CuIII<\/sup>(CF3<\/sub>)3<\/sub>F]\u2013<\/sup>\u7684\u53cd\u5e94\u65f6\uff0c\u4e5f\u5f97\u4e0d\u5230\u76f8\u5e94\u7684\u4e09\u4ef7\u94dc\u80fa\u7edc\u5408\u7269Me4<\/sub>N+<\/sup>[CuIII<\/sup>(CF3<\/sub>)3<\/sub>(NRR\u2019)]\u2013<\/sup>,\u800c\u662f\u4ee5\u4e2d\u7b49\u4ea7\u7387\u5f97\u5230RR\u2019NCF3<\/sub>\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u8be5\u7814\u7a76\u4e2d\u6240\u5f97\u5230\u7684\u4e09\u4ef7\u94dc\u7684\u7ed3\u6784\u9664\u4e86Me4<\/sub>N+<\/sup>[CuIII<\/sup>(CF3<\/sub>)3<\/sub>(SAr)]\u2013<\/sup>\u4ee5\u5916\uff0c\u5747\u5f97\u5230\u4e86\u5176\u5355\u6676\u7ed3\u6784\u7684\u786e\u8bc1\u3002\u8fd9\u4e9b\u53d1\u73b0\u4e3aCu(III)-F\u7269\u79cd\u5728\u771f\u5b9e\u7684\u50ac\u5316\u4f53\u7cfb\u4e2d\u7684\u5b58\u5728\u63d0\u4f9b\u4e86\u8bc1\u636e\uff0c\u4e5f\u652f\u6301\u4e86\u5176\u4f5c\u4e3a\u6784\u5efa\u78b3-\u78b3\u952e\u3001\u78b3-\u6742\u952e\u53cd\u5e94\u4e2d\u7684\u6d3b\u6027\u4e2d\u95f4\u4f53\u7684\u53ef\u80fd\u3002<\/p>\n

\"7\"<\/p>\n

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\u56fe1\u00a0\u4e09\u4ef7\u94dc\u6c1f\u7edc\u5408\u7269Me4<\/sub>N+<\/sup>[CuIII<\/sup>(CF3<\/sub>)3<\/sub>F]\u2013<\/sup>\u3001\u5176\u8f6c\u91d1\u5c5e\u53cd\u5e94\u53caN-CF3<\/sub>\u548cP-CF3<\/sub>\u7684\u6784\u5efa<\/section>\n
\n\u4e0a\u8ff0\u7814\u7a76\u4f5c\u4e3aBreaking\u00a0Report\u53d1\u8868\u4e8eChin. J. Chem.<\/em>\u00a02024<\/strong>,42<\/em>, 1107\u20141113.\u00a0DOI: 10.1002\/cjoc.202400041<\/strong>\u3002<\/section>\n","protected":false},"excerpt":{"rendered":"

Breaking\u00a0Report Access to Versatile Functionalized Cu(I […]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-50937","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/50937","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=50937"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/50937\/revisions"}],"predecessor-version":[{"id":50938,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/50937\/revisions\/50938"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=50937"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=50937"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=50937"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}