{"id":50764,"date":"2024-02-11T08:48:08","date_gmt":"2024-02-11T00:48:08","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=50764"},"modified":"2024-01-25T09:48:33","modified_gmt":"2024-01-25T01:48:33","slug":"jacs-%e5%bf%ab%e9%80%9f%e8%8a%b3%e7%83%83%e4%b8%89%e6%b0%ae%e7%83%af%e5%a4%a7%e7%8e%af%e5%8c%96","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/jacs-%e5%bf%ab%e9%80%9f%e8%8a%b3%e7%83%83%e4%b8%89%e6%b0%ae%e7%83%af%e5%a4%a7%e7%8e%af%e5%8c%96\/","title":{"rendered":"JACS| \u5feb\u901f\u82b3\u70c3\u4e09\u6c2e\u70ef\u5927\u73af\u5316"},"content":{"rendered":"

\u53d1\u8868\u5728JACS<\/em>\u00a0\u4e0a\u7684Rapid Arene Triazene Chemistry for Macrocyclization<\/em>\uff0c\u6587\u7ae0\u7684\u901a\u8baf\u4f5c\u8005\u662f\u7f8e\u56fd\u4f50\u6cbb\u4e9a\u5dde\u57c3\u9ed8\u91cc\u5927\u5b66\u7684Monika Raj\u6559\u6388\u3002<\/p>\n

\u73af\u80bd\u5177\u6709\u7279\u5b9a\u7684\u4e8c\u7ea7\u7ed3\u6784\u548c\u76f8\u5bf9\u8f83\u9ad8\u7684\u86cb\u767d\u4eb2\u548c\u529b\uff0c\u4e14\u5176\u86cb\u767d\u9176\u6c34\u89e3\u7a33\u5b9a\u6027\u8f83\u9ad8\u3001\u7ed3\u6784\u5927\u5c0f\u9002\u4e2d\uff0c\u53ef\u4ee5\u4f5c\u4e3a\u4e00\u79cd\u7279\u6b8a\u7684\u836f\u7269\u652f\u67b6\u6750\u6599\u3002\u5b83\u878d\u5408\u4e86\u751f\u7269\u5927\u5206\u5b50\u7684\u9ad8\u7279\u5f02\u6027\u548c\u5c0f\u5206\u5b50\u7684\u9ad8\u7a33\u5b9a\u6027\uff0c\u8fd9\u4e9b\u4f18\u52bf\u4f7f\u5176\u5316\u5b66\u9009\u62e9\u6027\u7684\u5927\u73af\u5316\u7b56\u7565\u5feb\u901f\u53d1\u5c55\u3002<\/p>\n

\u867d\u7136\u5df2\u77e5\u7684\u5408\u6210\u7a33\u5b9a\u73af\u80bd\u7684\u65b9\u6cd5\u6709\u5f88\u591a\uff0c\u4f46\u80fd\u54cd\u5e94\u5916\u754c\u523a\u6fc0\u53d8\u5316\uff0c\u5b9e\u73b0\u5927\u73af\u7684\u5f00\u95ed\u7684\u73af\u5316\u7b56\u7565\u5374\u5f88\u5c11\uff0c\u5305\u62ec\u4e8c\u786b\u5316\u7269\u548c\u6c28\u57fa\u787c\u9178\u916f\u7b49\u3002\u8fd9\u79cd\u73af\u80bd\u6709\u5229\u4e8e\u9776\u5411\u7ed9\u836f\uff0c\u5e76\u4e14\u53ef\u4ee5\u4f5c\u4e3a\u5c40\u90e8\u73af\u5883\u7684\u4f20\u611f\u5668\u3002\u786e\u5b9a\u73af\u80bd\u7684\u751f\u7269\u6d3b\u6027\u7684\u53e6\u4e00\u4e2a\u5173\u952e\u7279\u5f81\u662f\u73af\u80bd\u5438\u6536\u6ce2\u957f\u7684\u8f6c\u53d8\uff0c\u4f46\u76ee\u524d\u53ea\u6709\u5c11\u6570\u65b9\u6cd5\u53ef\u4ee5\u751f\u6210\u5185\u5d4c\u53d1\u8272\u56e2\uff0c\u8fd9\u79cd\u65b9\u6cd5\u4e5f\u53ef\u4ee5\u907f\u514d\u5f15\u5165\u5f71\u54cd\u73af\u80bd\u7ed3\u5408\u4eb2\u548c\u529b\u548c\u6eb6\u89e3\u5ea6\u7684\u663e\u8272\u57fa\u56e2\u3002<\/p>\n

\u4f5c\u8005\u5728\u6b64\u63d0\u4f9b\u4e00\u4e2a\u5feb\u901f\u9ad8\u6548\u7684\u7b56\u7565,\u00a0\u5229\u7528\u4e86\u4e8c\u7ea7\u80fa\u4e0e\u91cd\u6c2e\u76d0\u7684\u53cd\u5e94\uff0c\u83b7\u5f97\u4e86\u591a\u79cd\u7ed3\u6784\u7684\u73af\u80bd\u3002\u8be5\u65b9\u6cd5\u751f\u6210\u7684\u73af\u80bd\u53ef\u6839\u636e\u5916\u754c\u54cd\u5e94\u7684\u5feb\u901f\u5f00\u73af\u548c\u95ed\u73af\uff0c\u5e76\u4e14\u8fde\u63a5\u53d1\u8272\u57fa\u56e2\u3002<\/p>\n

\"1\"<\/p>\n

\u56fe1.\u00a0<\/strong>\u82b3\u57fa\u4e09\u6c2e\u70ef\u53cd\u5e94\u751f\u6210\u73af\u80bd<\/p>\n

\u4f5c\u8005\u901a\u8fc7\u5728\u805a\u591a\u80bd\u4e2d\u5f15\u5165\u5546\u4e1a\u53ef\u83b7\u5f97\u7684\u5bf9\u6c28\u57fa\u82ef\u4e19\u6c28\u9178\uff0c\u4f7f\u5176\u91cd\u6c2e\u5316\u540e\u4e0e\u7aef\u57fa\u7684\u4ef2\u80fa\u5728pH\u4e3a7.5\u65f6\u53d1\u751f\u53cd\u5e94\u5f62\u6210\u73af\u80bd\uff08\u56fe1\uff09\u3002\u4f5c\u8005\u5206\u522b\u4f7f\u7528\u4e86\u5e8f\u5217\u4e0d\u540c\u7684\u3001\u4fa7\u94fe\u672a\u4fdd\u62a4\u7684\u591a\u80bd\u8fdb\u884c\u8be5\u53cd\u5e94\uff0c\u90fd\u53d6\u5f97\u4e86\u8f83\u9ad8\u7684\u4ea7\u7387\uff08\u56fe2\uff09\uff0c\u7ecf\u8fc7\u6838\u78c1\u5171\u632f\u68c0\u6d4b\uff0c\u53cd\u5e94\u751f\u6210\u4e86\u542b\u6709\u4e09\u6c2e\u70ef\u57fa\u56e2\u7684\u73af\u80bd\u3002\u4f5c\u8005\u8fd8\u8bc1\u660e\u4e86\u5373\u4f7f\u5728\u589e\u957f\u53cd\u5e94\u65f6\u95f4\u7684\u6761\u4ef6\u4e0b\uff0c\u4e00\u7ea7\u80fa\u5982\u8d56\u6c28\u9178\u6b8b\u57fa\u4e5f\u4e0d\u4f1a\u4e0e\u91cd\u6c2e\u76d0\u53d1\u751f\u53cd\u5e94\uff0c\u5728\u5e8f\u5217\u4e2d\u540c\u65f6\u542b\u6709\u4e8c\u7ea7\u80fa\u548c\u4e00\u7ea7\u80fa\u65f6\uff0c\u53cd\u5e94\u4f1a\u9009\u62e9\u6027\u5730\u53d1\u751f\u5728\u4e8c\u7ea7\u80fa\u4e0a\uff08\u56fe2\uff09\u3002\u4f5c\u8005\u8fd8\u9a8c\u8bc1\u4e86\u5176\u4ed6\u4fa7\u94fe\u6d3b\u6027\u7684\u6c28\u57fa\u9178\u5982\u4e1d\u6c28\u9178\u3001\u8c37\u6c28\u9178\u7b49\u5747\u4e0d\u4f1a\u5e72\u6270\u53cd\u5e94\u3002<\/p>\n

\u4f5c\u8005\u63a5\u4e0b\u6765\u63a2\u7d22\u4e86\u4e0d\u540c\u7ed3\u6784\u7684\u4e8c\u7ea7\u80fa\u7684\u53cd\u5e94\u6027\uff0c\u53d1\u73b0\u7532\u57fa\u4e19\u6c28\u9178\u4ee5\u53ca\u4fa7\u94fe\u7532\u57fa\u5316\u7684\u8d56\u6c28\u9178\u5747\u53ef\u9ad8\u6548\u5730\u53d1\u751f\u8be5\u53cd\u5e94\uff08\u56fe2\uff09\u3002<\/p>\n

\"2\"<\/p>\n

\u56fe2.\u00a0<\/strong>\u591a\u79cd\u7ed3\u6784\u7684\u591a\u80bd\u73af\u5316\u53cd\u5e94<\/p>\n

\u4f5c\u8005\u4e4b\u540e\u63a2\u7a76\u4e86\u73af\u5316\u7684\u901f\u7387\uff0c\u53d1\u73b0\u4e8c\u7ea7\u80fa\u4e0e\u91cd\u6c2e\u7684\u53cd\u5e94\u5728\u4e94\u5206\u949f\u4e4b\u5185\u51e0\u4e4e\u8fdb\u884c\u5b8c\u5168\uff0c\u800c\u5728\u76f8\u540cpH\u4e0b\u916a\u6c28\u9178\u7684\u53cd\u5e94\u8f83\u6162\uff08\u56fe3a\uff09\u3002<\/p>\n

\"0\"<\/p>\n

\u56fe3.\u00a0<\/strong>(a)\u73af\u5316\u53cd\u5e94\u901f\u7387\u63a2\u7a76\u00a0(b)\u5149\u7269\u7406\u6027\u8d28\u00a0(c)\u5f00\u73af\u5173\u73af\u7684pH\u54cd\u5e94\u6027<\/p>\n

\u7531\u4e8e\u8fd9\u79cd\u65b9\u6cd5\u4ea7\u751f\u4e86\u4e09\u6c2e\u70ef\u7684\u663e\u8272\u90e8\u5206\uff0c\u4f5c\u8005\u7528\u7d2b\u5916\u5206\u5149\u5149\u5ea6\u8ba1\u63a2\u7d22\u4e86\u4e09\u6c2e\u70ef\u73af\u80bd\u4ee5\u53ca\u91cd\u6c2e\u76d0\u4ee5\u53ca\u76f8\u5e94\u7684\u7ebf\u6027\u591a\u80bd\u7684\u5149\u7269\u7406\u6027\u8d28\uff08\u56fe3b\uff09\u3002\u7ed3\u679c\u8868\u660e\uff0c\u4e09\u6c2e\u70ef\u73af\u80bd\u4ee5\u53ca\u76f8\u5e94\u7684\u91cd\u6c2e\u76d0\u90fd\u6709\u7279\u5b9a\u7684\u5438\u6536\u6ce2\u957f\u3002<\/p>\n

\u4f5c\u8005\u4f7f\u7528HPLC\u68c0\u6d4b\u4e86\u73af\u80bd\u7684pH\u54cd\u5e94\u6027\uff0c\u7ed3\u679c\u8868\u660e\u5728pH\u4e3a1.5\u7684\u6761\u4ef6\u4e0b\uff0c\u73af\u80bd\u5728\u4e94\u5206\u949f\u5185\u5f00\u73af\u751f\u6210\u7ebf\u6027\u7ed3\u6784\uff0c\u5728\u6539\u53d8pH\u65f6\u8be5\u7ed3\u6784\u8fd8\u80fd\u518d\u6b21\u5173\u73af\u5f62\u6210\u73af\u80bd\uff08\u56fe3c\uff09\u3002\u4f5c\u8005\u4e4b\u540e\u8fd8\u4f7f\u7528\u4e0d\u540c\u7ed3\u6784\u7684\u80bd\u6bb5\u4e00\u9505\u5316\u6210\u73af\u4ee5\u53ca\u5173\u73af\uff0c\u9a8c\u8bc1\u4e86\u8be5\u53cd\u5e94\u53ea\u5728\u5206\u5b50\u5185\u53d1\u751f\u3002<\/p>\n

\u4f5c\u8005\u6700\u540e\u4f7f\u7528\u751f\u6210\u7684\u73af\u80bd\u505a\u4e86\u8fdb\u4e00\u6b65\u7684\u540e\u4fee\u9970\u3002\u7531\u4e8e\u8be5\u53cd\u5e94\u5bf9\u5b98\u80fd\u56e2\u7684\u5bb9\u5fcd\u5ea6\u8f83\u9ad8\uff0c\u56e0\u6b64\u751f\u6210\u7684\u73af\u80bd\u672c\u8eab\u5177\u6709\u8f83\u591a\u7684\u6d3b\u6027\u57fa\u56e2\uff0c\u53ef\u4ee5\u5f88\u4fbf\u6377\u5730\u8fdb\u884c\u540e\u4fee\u9970\u3002<\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u63d0\u4f9b\u4e00\u4e2a\u5feb\u901f\u9ad8\u6548\u7684\u73af\u5316\u7b56\u7565,\u00a0\u5229\u7528\u4e86\u4e8c\u7ea7\u80fa\u4e0e\u91cd\u6c2e\u76d0\u7684\u9009\u62e9\u6027\u4e09\u6c2e\u70ef\u53cd\u5e94\uff0c\u83b7\u5f97\u4e86\u591a\u79cd\u7ed3\u6784\u7684\u73af\u80bd\u3002\u8be5\u65b9\u6cd5\u53cd\u5e94\u6548\u7387\u9ad8\u5e76\u4e14\u5b98\u80fd\u56e2\u5bb9\u5fcd\u5ea6\u9ad8\uff0c\u751f\u6210\u7684\u73af\u80bd\u5177\u6709pH\u54cd\u5e94\u6027\u7684\u5feb\u901f\u5f00\u73af\u548c\u95ed\u73af\u53cd\u5e94\uff0c\u5e76\u4e14\u5206\u522b\u5177\u6709\u7279\u5b9a\u7684\u5438\u6536\u6ce2\u957f\u3002<\/p>\n

 <\/p>\n

<\/section>\n
\u4f5c\u8005\uff1a<\/strong>WLT\u00a0\u00a0\u00a0\u00a0\u5ba1\u6821\uff1a<\/strong>SYM<\/section>\n

 <\/p>\n

DOI:\u00a0<\/strong>10.1021\/jacs.2c00464<\/p>\n

Link:<\/strong>\u00a0https:\/\/doi.org\/10.1021\/jacs.2c00464<\/p>\n","protected":false},"excerpt":{"rendered":"

\u53d1\u8868\u5728JACS\u00a0\u4e0a\u7684Rapid Arene Triazene Chemistry for Macrocycli […]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-50764","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/50764","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=50764"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/50764\/revisions"}],"predecessor-version":[{"id":50765,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/50764\/revisions\/50765"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=50764"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=50764"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=50764"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}