{"id":50670,"date":"2024-01-27T08:58:05","date_gmt":"2024-01-27T00:58:05","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=50670"},"modified":"2024-01-10T09:58:35","modified_gmt":"2024-01-10T01:58:35","slug":"%e6%ae%b5%e6%98%8a%e6%b3%93-%e5%be%90%e6%98%8eacs-catalysis%ef%bc%9ay1-tio2%e4%b8%8a%e5%88%86%e5%ad%90%e6%b0%a7%e5%92%8c%e6%99%b6%e6%a0%bc%e6%b0%a7%e5%90%8c%e6%97%b6%e6%b4%bb%e5%8c%96%ef%bc%8c","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/%e6%ae%b5%e6%98%8a%e6%b3%93-%e5%be%90%e6%98%8eacs-catalysis%ef%bc%9ay1-tio2%e4%b8%8a%e5%88%86%e5%ad%90%e6%b0%a7%e5%92%8c%e6%99%b6%e6%a0%bc%e6%b0%a7%e5%90%8c%e6%97%b6%e6%b4%bb%e5%8c%96%ef%bc%8c\/","title":{"rendered":"\u6bb5\u660a\u6cd3\/\u5f90\u660eACS Catalysis\uff1aY1\/TiO2\u4e0a\u5206\u5b50\u6c27\u548c\u6676\u683c\u6c27\u540c\u65f6\u6d3b\u5316\uff0c\u663e\u8457\u4fc3\u8fdb\u7532\u82ef\u6c27\u5316\u4e3a\u82ef\u7532\u919b"},"content":{"rendered":"
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\u57fa\u4e8e\u539f\u4f4d\u5149\u8c31\u8868\u5f81\uff0c\u7814\u7a76\u4eba\u5458\u63d0\u51fa\u4e86\u4e00\u4e2a\u5408\u7406\u7684\u53cd\u5e94\u673a\u7406\uff1a\u5728\u5149\u7167\u5c04\u4e0b\uff0c\u5165\u5c04\u5149\u5b50\u4eceTiO2<\/sub>\u7684\u4ef7\u5e26(VB)\u6fc0\u53d1\u7535\u5b50(e\u2212<\/sup>)\u5230\u5bfc\u5e26(CB)\uff0c\u5728VB\u4e0a\u7559\u4e0b\u7a7a\u7a74\u3002\u5355\u539f\u5b50Y\u7684\u5b58\u5728\u4fc3\u8fdb\u4e86O2<\/sub>\u7684\u5438\u9644\u548c\u6d3b\u5316\uff0c\u5206\u5b50\u6c27\u88ab\u5149\u751f\u7535\u5b50\u8fd8\u539f\u5f62\u6210\u2022O2<\/sub>\u2212<\/sup>\uff1b\u540c\u65f6\uff0c\u5149\u751f\u7a7a\u7a74\u6fc0\u6d3b\u7532\u82ef\u4ea7\u751f\u82c4\u57fa\u81ea\u7531\u57fa\u3002\u751f\u6210\u7684\u82c4\u57fa\u81ea\u7531\u57fa\u4e0e\u2022O2<\/sub>\u2212<\/sup>\u7ed3\u5408\u5f62\u6210\u8fc7\u6c27\u81ea\u7531\u57fa\uff0c\u8fd8\u6709\u4e00\u90e8\u5206\u82c4\u57fa\u81ea\u7531\u57fa\u4e0eO2<\/sub>\u5206\u5b50\u53cd\u5e94\u751f\u6210\u82c4\u9187\u3002\u6b64\u5916\uff0c\u5f62\u6210\u7684\u8fc7\u6c27\u81ea\u7531\u57fa\u548c\u82ef\u7532\u9187\u5206\u522b\u901a\u8fc7\u8131\u6c34\u548c\u6c27\u5316\u8131\u6c22\u8f6c\u5316\u4e3a\u82ef\u7532\u919b\u3002<\/p>\n 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Efficient benzylic C\u2013H bond activation over single-atom yttrium supported on TiO2<\/sub>\u00a0via facilitated molecular oxygen and surface lattice oxygen activation. ACS Catalysis, 2023. 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