{"id":50616,"date":"2024-01-18T08:09:29","date_gmt":"2024-01-18T00:09:29","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=50616"},"modified":"2024-01-01T11:10:40","modified_gmt":"2024-01-01T03:10:40","slug":"angew-chem-%ef%bc%9apdii%e5%82%ac%e5%8c%96%e7%9a%84%e6%b0%ae%e6%9d%82%e8%8b%af%e5%b9%b6%e9%99%8d%e5%86%b0%e7%89%87%e7%83%af%e5%92%8c%e7%82%94%e5%9f%ba%e8%8b%af%e8%83%ba%e7%9a%84%e5%af%b9%e6%98%a0","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/angew-chem-%ef%bc%9apdii%e5%82%ac%e5%8c%96%e7%9a%84%e6%b0%ae%e6%9d%82%e8%8b%af%e5%b9%b6%e9%99%8d%e5%86%b0%e7%89%87%e7%83%af%e5%92%8c%e7%82%94%e5%9f%ba%e8%8b%af%e8%83%ba%e7%9a%84%e5%af%b9%e6%98%a0\/","title":{"rendered":"Angew. 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alt=\"1\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u4f5c\u8005\u9009\u62e9\u6c2e\u6742\u82ef\u5e76\u964d\u51b0\u7247\u70ef1a\u548c2-\u7094\u57fa\u82ef\u80fa2a\u4f5c\u4e3a\u6a21\u7248\u5e95\u7269\u5bf9\u53cd\u5e94\u8fdb\u884c\u6761\u4ef6\u4f18\u5316\uff0c\u53d1\u73b0\u5728 Pd(OAc)<sub>2<\/sub>\u00a0(10 mol %)\u4e3a\u50ac\u5316\u5242, L5\u00a0(12 mol %)\u914d\u4f53,\u00a0K<sub>2<\/sub>CO<sub>3<\/sub>\u00a0(3.0 equiv)\u505a\u78b1\uff0cH<sub>2<\/sub>O (80.0 \u03bcL) \u4e3a\u6dfb\u52a0\u5242\u572850 \u00b0C\u4e0b\u53cd\u5e94 12 \u5c0f\u65f6\u80fd\u591f\u4ee586% \u4ea7\u7387\u548c94% ee\u5f97\u5230\u76ee\u6807\u4ea7\u7269\u3002\u8fdb\u4e00\u6b65\u7814\u7a76\u53d1\u73b0\uff0c\u4f7f\u7528\u66f4\u4e3a\u4fbf\u5b9c\u7684Josiphos 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\/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u5728\u6700\u4f18\u6761\u4ef6\u4e0b\uff0c\u4f5c\u8005\u5bf92-\u7094\u57fa\u82ef\u80fa\u7684\u9002\u7528\u8303\u56f4\u8fdb\u884c\u4e86\u7cfb\u7edf\u8003\u5bdf\u3002\u7ed3\u679c\u8868\u660e\uff0c\u53cd\u5e94\u80fd\u591f\u517c\u5bb9\u82b3\u80fa\u548c\u7094\u70c3\u4e0a\u4e0d\u540c\u4f4d\u7f6e\u7684\u7ed9\u7535\u5b50\u548c\u5438\u7535\u5b50\u53d6\u4ee3\u57fa\uff0c\u5f97\u5230\u9ad8\u5149\u5b66\u7eaf\u7684\u76ee\u6807\u4ea7\u7269\uff0c\u5e76\u901a\u8fc7\u5355\u6676\u786e\u5b9a\u4e86\u4ea7\u7269\u7684\u7edd\u5bf9\u6784\u578b\u3002\u53cd\u5e94\u80fd\u6269\u5927\u81f3\u514b\u7ea7\u89c4\u6a21\uff0c\u6536\u7387\u548c\u7acb\u4f53\u9009\u62e9\u6027\u4e0d\u53d7\u5f71\u54cd\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"3\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20231226\/1703556043205197.png\" alt=\"3\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u968f\u540e\uff0c\u4f5c\u8005\u53c8\u5bf9\u6c2e\u6742\u82ef\u5e76\u964d\u51b0\u7247\u70ef\u9002\u7528\u8303\u56f4\u8fdb\u884c\u4e86\u7cfb\u7edf\u8003\u5bdf\u3002\u7ed3\u679c\u8868\u660e\uff0c\u53cd\u5e94\u80fd\u591f\u5bf9\u6c2e\u6742\u82ef\u5e76\u964d\u51b0\u7247\u70ef\u82ef\u73af\u4e0a\u5404\u79cd\u53d6\u4ee3\u57fa\u5747\u80fd\u5f88\u597d\u517c\u5bb9\u3002\u800c\u4e14\uff0c\u5f53\u6c2e\u4e0a\u7684\u4fdd\u62a4\u57fa\u662fTs\uff0c\u53d6\u4ee3\u7684\u82ef\u73af\u7b49\u65f6\uff0c\u53cd\u5e94\u4ecd\u80fd\u591f\u4ee587%\u4ee5\u4e0a\u7684ee\u5f97\u5230\u76ee\u6807\u4ea7\u7269\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"4\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20231226\/1703556052528197.png\" alt=\"4\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u4f5c\u8005\u8fdb\u4e00\u6b65\u901a\u8fc7\u7406\u8bba\u8ba1\u7b97\u63ed\u793a\u4e86\u53cd\u5e94\u7684\u5bf9\u6620\u9009\u62e9\u6027\u8d77\u6e90\u7ed3\u679c\u8868\uff0c\u5728\u8fc7\u6e21\u6001TS3\u4e2d\u5b58\u5728CH\u00b7\u00b7\u00b7N and CH\u00b7\u00b7\u00b7\u03c0\u4e24\u79cd\u975e\u5171\u4ef7\u952e\u76f8\u4e92\u4f5c\u7528\uff0c\u800c\u5728TS4 \u53ea\u5b58\u5728CH\u00b7\u00b7\u00b7\u03c0\u4e00\u79cd\u975e\u5171\u4ef7\u952e\u76f8\u4e92\u4f5c\u7528\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"7\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20231226\/1703556064999042.png\" alt=\"7\" \/><\/section>\n<section>\n<section>\n<section>\n<section><strong>\u8bba<\/strong><strong>\u6587\u4fe1\u606f<\/strong><\/p>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section><\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>Enantioselective Palladium(II)-Catalyzed Desymmetrizative Coupling of 7-Azabenzonorbornadienes with Alkynylanilines<\/p>\n<p>Junjie Meng,\u00a0Hui He,\u00a0Qianru Liu,\u00a0Prof. Hanhong Xu,\u00a0Prof.\u2005Dr. Huicai Huang,\u00a0Prof.\u2005Dr. Shao-Fei Ni,\u00a0Prof.\u2005Dr. Zhaodong Li<\/p>\n<p><em>Angewandte Chemie International Edition<\/em><\/p>\n<p>DOI:\u00a010.1002\/anie.202315092<\/p>\n<\/section>\n<\/section>\n<\/section>\n","protected":false},"excerpt":{"rendered":"<p>\u5bf9\u6620\u9009\u62e9\u6027\u7684\u53bb\u5bf9\u79f0\u5316\u53cd\u5e94\u662f\u6307\u542b\u6709\u524d\u624b\u6027\u4e2d\u5fc3\u6216\u5185\u6d88\u65cb\u5316\u5408\u7269\u5728\u5176\u4e2d\u4e00\u4e2a\u53cd\u5e94\u4f4d\u70b9\u9009\u62e9\u6027\u5b98\u80fd\u56e2\u5316\uff0c\u540c\u65f6\u6784\u5efa\u591a\u4e2a\u624b\u6027\u4e2d\u5fc3 [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-50616","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/50616","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=50616"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/50616\/revisions"}],"predecessor-version":[{"id":50617,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/50616\/revisions\/50617"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=50616"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=50616"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=50616"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}