{"id":50378,"date":"2024-01-08T08:58:56","date_gmt":"2024-01-08T00:58:56","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=50378"},"modified":"2023-12-22T09:59:30","modified_gmt":"2023-12-22T01:59:30","slug":"%e6%ad%a6%e6%b1%89%e5%a4%a7%e5%ad%a6%e5%bc%a0%e4%bf%8a%e6%95%99%e6%8e%88%e5%9c%a8jacs%e5%92%8cangew%e4%b8%8a%e5%8f%91%e8%a1%a8%e4%ba%8c%e6%b0%a7%e5%8c%96%e7%a2%b3%e8%b0%83%e6%8e%a7%e5%a4%9a%e5%ad%94","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/%e6%ad%a6%e6%b1%89%e5%a4%a7%e5%ad%a6%e5%bc%a0%e4%bf%8a%e6%95%99%e6%8e%88%e5%9c%a8jacs%e5%92%8cangew%e4%b8%8a%e5%8f%91%e8%a1%a8%e4%ba%8c%e6%b0%a7%e5%8c%96%e7%a2%b3%e8%b0%83%e6%8e%a7%e5%a4%9a%e5%ad%94\/","title":{"rendered":"\u6b66\u6c49\u5927\u5b66\u5f20\u4fca\u6559\u6388\u5728JACS\u548cAngew\u4e0a\u53d1\u8868\u4e8c\u6c27\u5316\u78b3\u8c03\u63a7\u591a\u5b54\u78c1\u4f53\u81ea\u65cb\u7cfb\u5217\u6210\u679c"},"content":{"rendered":"<section>\u25b2\u7b2c\u4e00\u4f5c\u8005\uff1a\u5f20\u4fca\u00a0 \u6559\u6388\u00a0\u00a0<\/section>\n<p>&nbsp;<\/p>\n<section>\u901a\u8baf\u4f5c\u8005\uff1aHitoshi Miyasaka \u6559\u6388\u00a0\u00a0<\/section>\n<section>\u901a\u8baf\u5355\u4f4d\uff1a\u65e5\u672c\u4e1c\u5317\u5927\u5b66\u00a0\u00a0<\/section>\n<section>\u8bba\u6587DOI\uff1aJACS: 10.1021\/jacs.3c08583<\/section>\n<section>Angew: 10.1002\/anie.202312205<\/section>\n<section><\/section>\n<section>\u8fd1\u65e5\uff0c\u6b66\u6c49\u5927\u5b66\u5316\u5b66\u4e0e\u5206\u5b50\u79d1\u5b66\u5b66\u9662\u7684\u5f20\u4fca\u6559\u6388\u8054\u5408\u65e5\u672c\u4e1c\u5317\u5927\u5b66\u91d1\u5c5e\u6750\u6599\u7814\u7a76\u6240\u7684Hitoshi Miyasaka\u6559\u6388\u4ee5\u53ca\u5927\u962a\u5927\u5b66\u5316\u5b66\u79d1\u5b66\u4e0e\u5de5\u7a0b\u7cfb\u7684Yasutaka Kitagawa\u6559\u6388\u56e2\u961f\u63d0\u51fa\u4e00\u79cd\u201c<strong><a>\u5bcc\u7535\u5b50\u8bbe\u8ba1\u7b56\u7565<\/a><\/strong>\u201d\uff0c\u901a\u8fc7\u6784\u7b51\u4e00\u7cfb\u5217\u591a\u7535\u5b50\u8f6c\u79fb\u578b\u591a\u5b54\u5206\u5b50\u78c1\u4f53\uff0c\u6210\u529f\u5229\u7528\u4e8c\u6c27\u5316\u78b3\uff08CO<sub>2<\/sub>\uff09\u6765\u8c03\u63a7\u8fd9\u4e9b\u78c1\u4f53\u7684\u7535\u5b50\/\u81ea\u65cb\u6001\u3002\u5b9e\u9a8c\u4e0a\u89c2\u6d4b\u5230\u4e86\u4e9a\u94c1\u78c1\u4f53\u5c45\u91cc\u6e29\u5ea6\u7684\u53ef\u9006\u8f6c\u6362\u548c\u521b\u78c1\u73b0\u8c61\u00be\u987a\u78c1\u4f53\u5411\u4e9a\u94c1\u78c1\u548c\u53cd\u94c1\u78c1\u7684\u53ef\u9006\u8f6c\u6362\u3002\u8fd9\u4e00\u7cfb\u5217\u6210\u679c\u5206\u522b\u53d1\u8868\u5728\u300a\u5fb7\u56fd\u5e94\u7528\u5316\u5b66\u300b\uff08Angew. Chem. Int. Ed.\uff09\u548c\u300a\u7f8e\u56fd\u5316\u5b66\u4f1a\u5fd7\u300b\uff08J. Am. Chem. Soc.\uff09\u3002<\/section>\n<section><\/section>\n<section>\u78c1\u6027\u6750\u6599\u4e0e\u6211\u4eec\u7684\u751f\u6d3b\u7d27\u5bc6\u76f8\u8fde\uff0c\u662f\u73b0\u4ee3\u5de5\u4e1a\u548c\u79d1\u6280\u53d1\u5c55\u7684\u5173\u952e\u652f\u6491\u6750\u6599\u3002\u4e0e\u4f20\u7edf\u78c1\u4f53\u4e0d\u540c\uff0c\u5206\u5b50\u57fa\u78c1\u6027\u6750\u6599\u53ef\u4ee5\u5728\u5206\u5b50\u5c42\u9762\u8fdb\u884c\u7cbe\u7ec6\u8bbe\u8ba1\u548c\u6784\u7b51\uff0c\u6709\u671b\u5728\u9ad8\u5bc6\u5ea6\u6570\u636e\u5b58\u50a8\u548c\u91cf\u5b50\u8ba1\u7b97\u7b49\u9886\u57df\u5f15\u9886\u6280\u672f\u9769\u65b0\u3002\u591a\u5b54\u78c1\u4f53\uff0c\u4f5c\u4e3a\u4e00\u7c7b\u517c\u5177\u5316\u5b66\u591a\u5b54\u6027\u548c\u7269\u7406\u78c1\u6027\u7684\u5206\u5b50\u57fa\u78c1\u6027\u6750\u6599\uff0c\u80fd\u591f\u901a\u8fc7\u5438\u9644\u5ba2\u4f53\u5206\u5b50\uff08\u6eb6\u5242\u6216\u6c14\u4f53\u7b49\uff09\u8c03\u63a7\u5176\u7535\u5b50\u7ed3\u6784\uff0c\u4ece\u800c\u5b9e\u73b0\u5bf9\u78c1\u6027\u7684\u7cbe\u786e\u8c03\u63a7\u3002\u5176\u4e2d\uff0c\u6c14\u4f53\u5206\u5b50\u56e0\u5176\u5feb\u901f\u5438\u8131\u9644\u548c\u4f4e\u7ed3\u6784\u635f\u4f24\u7b49\u7279\u6027\uff0c\u6210\u4e3a\u8c03\u63a7\u5176\u78c1\u5b66\u6027\u80fd\u7684\u6709\u529b\u624b\u6bb5\u3002\u7136\u800c\uff0c\u6c14\u4f53\u4e0e\u591a\u5b54\u78c1\u4f53\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u901a\u5e38\u8f83\u5f31\uff0c\u4ea7\u751f\u7684\u78c1\u6027\u53d8\u5316\u5e76\u4e0d\u663e\u8457\u3002\u56e0\u6b64\uff0c\u5982\u4f55\u81ea\u4e0b\u800c\u4e0a\u8bbe\u8ba1\u548c\u7cbe\u786e\u63a7\u5236\u591a\u5b54\u5206\u5b50\u78c1\u4f53\u7684\u7ed3\u6784\uff0c\u4ee5\u5b9e\u73b0\u81ea\u65cb\u6784\u578b\u7684\u7cbe\u51c6\u8c03\u63a7\u548c\u591a\u6837\u5316\u7684\u78c1\u76f8\u8f6c\u6362\uff0c\u662f\u4e00\u9879\u91cd\u8981\u7684\u79d1\u5b66\u6311\u6218\u3002<\/section>\n<section><\/section>\n<section>\u5f20\u4fca\u6559\u6388\u957f\u671f\u4ece\u4e8b\u6c27\u5316\u8fd8\u539f\u578b\u591a\u5b54\u78c1\u4f53\u7684\u6784\u7b51\u53ca\u5176\u7269\u7406\u6027\u80fd\u8c03\u63a7\uff0c\u4e13\u6ce8\u4e8e\u5ba2\u4f53\u5206\u5b50\u5b9e\u73b0\u914d\u5408\u7269\u78c1\u5b66\u3001\u7535\u5b66\u3001\u5149\u5b66\u6027\u80fd\u7684\u529f\u80fd\u8f6c\u6362\u3002\u4ece\u7535\u5b50\u7ed3\u6784\u7684\u89d2\u5ea6\u51fa\u53d1\uff0c\u6784\u7b51\u4e86\u4e00\u7cfb\u5217\u7535\u5b50\u8f6c\u79fb\u578b\u591a\u5b54\u78c1\u4f53\uff0c\u63d0\u51fa\u4e86\u4e3b\u4f53\u4e0a\u7535\u5b50\u8f6c\u79fb\uff08<strong><em>J. Am. Chem. Soc.\u00a0<\/em><\/strong>2018,\u00a0<em>140<\/em>, 5644.\u00a0<strong><em>Angew. Chem. Int. Ed.<\/em><\/strong>\u00a02019,\u00a0<em>131<\/em>, 7429.\u00a0<strong><em>J. Am. Chem. Soc.<\/em><\/strong>\u00a02021,\u00a0<em>143<\/em>, 7021\uff09\u3001\u4e3b\u2013\u5ba2\u4f53\u7535\u5b50\u8f6c\u79fb\uff08<strong><em>Angew. Chem. Int. Ed.\u00a0<\/em><\/strong>2022, e202115976\uff09\u4ee5\u53ca\u4e3b\u2013\u5ba2\u4f53\u81ea\u65cb\u8026\u5408\uff08<strong><em>Nature Commun.<\/em><\/strong>\u00a02018,<em>\u00a09<\/em>, 5420\uff09\u7b49\u4e00\u7cfb\u5217\u673a\u7406\uff0c\u5b9e\u73b0\u4e86\u78c1\u76f8\u7684\u53ef\u9006\u8f6c\u6362\u3002\u524d\u671f\u5de5\u4f5c\u4e2d\uff0c\u8be5\u56e2\u961f\u9996\u6b21\u62a5\u9053\u4e86\u5229\u7528CO<sub>2<\/sub>\u6539\u53d8\u591a\u5b54\u78c1\u4f53\u7684\u957f\u7a0b\u78c1\u6709\u5e8f\u73b0\u8c61\uff0c\u5b9e\u73b0\u5355\u7535\u5b50\u8f6c\u79fb\u578b\u591a\u5b54\u78c1\u4f53\u7684\u6d88\u78c1\u5207\u6362\u00be\u4e9a\u94c1\u78c1\u4f53\u8f6c\u6362\u4e3a\u987a\u78c1\u4f53\uff08<strong><em>Nat. Chem.<\/em><\/strong>, 2021,\u00a0<em>13<\/em>, 191\uff09\u3002\u7136\u800c\uff0c\u8fc4\u4eca\u4e3a\u6b62\u5173\u4e8e\u5982\u4f55\u8fdb\u884c\u591a\u5b54\u78c1\u6709\u5e8f\u7684\u5b9a\u5411\u8bbe\u8ba1\u5e76\u5b9e\u73b0\u6c14\u4f53\u7cbe\u51c6\u8c03\u63a7\u591a\u6837\u5316\u78c1\u76f8\u8f6c\u6362\uff0c\u4ecd\u7136\u7f3a\u4e4f\u6307\u5bfc\u539f\u5219\u548c\u7406\u8bba\u652f\u6491\u3002<\/section>\n<section><\/section>\n<section>\u9488\u5bf9\u4e0a\u8ff0\u6311\u6218\uff0c\u5f20\u4fca\u6559\u6388\u8054\u5408\u65e5\u672c\u7814\u7a76\u5c0f\u7ec4\u63d0\u51fa\u4e00\u79cd \u201c\u5bcc\u7535\u5b50\u8bbe\u8ba1\u7b56\u7565\u201d\uff0c\u7528\u4e8e\u6307\u5bfc\u8bbe\u8ba1\u5408\u6210\u591a\u7535\u5b50\u8f6c\u79fb\u578b\u591a\u5b54\u78c1\u4f53\u3002\u8be5\u56e2\u961f\u9996\u5148\u5408\u6210\u4e861+\u03b4e<sup>\u2212<\/sup>\uff080\uff1c\u03b4\uff1c1\uff09\u8f6c\u79fb\u578b\u591a\u5b54\u78c1\u4f53\uff0c\u8be5\u591a\u5b54\u78c1\u4f53\u8868\u73b0\u51fa\u4e9a\u94c1\u78c1\u6027\u8d28\uff08\u5c45\u91cc\u6e29\u5ea6<em>T<\/em><sub>C<\/sub>\u00a0= 65 K\uff09\u3002\u5f53\u5438\u9644CO<sub>2<\/sub>\u540e\uff0c\u7535\u5b50\u8f6c\u79fb\u6570\u75311+\u03b4e<sup>\u2212<\/sup>\u53d8\u4e3a1e<sup>\u2212<\/sup>\uff0c<em>T<\/em><sub>C<\/sub>\u53d1\u751f\u4e86\u660e\u663e\u53d8\u5316\uff08<em>T<\/em><sub>C\u00a0<\/sub>= 100 K\uff09\u3002\u8be5\u7814\u7a76\u8868\u660e\u5728\u7ef4\u6301\u5bcc\u7535\u5b50\u591a\u5b54\u78c1\u4f53\u7ed3\u6784\u7a33\u5b9a\u7684\u540c\u65f6\uff0cCO<sub>2<\/sub>\u7684\u5438\u9644\u6709\u6548\u6291\u5236\u7535\u5b50\u8f6c\u79fb\uff0c\u5b9e\u73b0\u4e86<em>T<\/em><sub>C<\/sub>\u7684\u53ef\u9006\u8f6c\u6362\u3002\u8be5\u6210\u679c\u8fd1\u671f\u53d1\u8868\u5728\u300a\u5fb7\u56fd\u5e94\u7528\u5316\u5b66\u300b\uff08Angew. Chem. Int. Ed.\uff09\uff0c\u5e76\u88ab\u9009\u4e3a\u201c\u70ed\u70b9\u8bba\u6587\u201d\uff08Hot paper\uff09\u3002<\/section>\n<section><\/section>\n<section>\u201c\u5bcc\u7535\u5b50\u8bbe\u8ba1\u7b56\u7565\u201d\u8fd8\u53ef\u4ee5\u88ab\u5e94\u7528\u4e8e\u8bbe\u8ba1\u548c\u5408\u6210\u5177\u6709\u987a\u78c1\u884c\u4e3a\u76842 e<sup>\u2212<\/sup>\u8f6c\u79fb\u578b\u591a\u5b54\u78c1\u4f53\u3002\u5438\u9644CO<sub>2<\/sub>\u540e\uff0cRu(II)\u4e8c\u805a\u4f53\u7535\u5b50\u6001\u4e5f\u7531Ru<sub>2<\/sub><sup>II,III<\/sup>\u8f6c\u53d8\u4e3aRu<sub>2<\/sub><sup>II,II<\/sup>\uff0c\u7535\u5b50\u8f6c\u79fb\u6570\u75312e<sup>\u2212<\/sup>\u53d8\u4e3a1e<sup>\u2212<\/sup>\uff0c\u5b9e\u9a8c\u4e0a\u6210\u529f\u89c2\u6d4b\u5230\u4e86\u987a\u78c1\u4f53\u548c\u53cd\u94c1\u78c1\u4f53\u4e4b\u95f4\u7684\u8f6c\u6362\u3002\u8fd9\u9879\u7814\u7a76\u5c55\u793a\u4e86\u9996\u4f8bCO<sub>2<\/sub>\u8bf1\u5bfc\u521b\u78c1\u7684\u7814\u7a76\uff0c\u5176\u6210\u679c\u8fd1\u671f\u53d1\u8868\u5728\u300a\u7f8e\u56fd\u5316\u5b66\u4f1a\u5fd7\u300b\uff08<em>J. Am. Chem. Soc.<\/em>\uff09\u3002<\/section>\n<section><\/section>\n<section>\u8be5\u5de5\u4f5c\u5f97\u5230\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u3001\u65e5\u672c\u5b66\u672f\u632f\u5174\u4f1a\u79d1\u5b66\u57fa\u91d1\u3001\u65e5\u672c\u4e1c\u5317\u5927\u5b66E-IMR\u9879\u76ee\u7b49\u57fa\u91d1\u7684\u652f\u6301\u3002<\/section>\n<section><\/section>\n<section><\/section>\n<section><img decoding=\"async\" title=\"1\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20231217\/1702781434942903.png\" alt=\"1\" \/><\/section>\n<section><\/section>\n<section>\u6210\u679c\uff08\u4e00\uff09<\/section>\n<section>Wataru Kosaka, Yoshie Hiwatashi, Naoka Amamizu, Yasutaka Kitagawa, Jun Zhang, Hitoshi Miyasaka*,\u00a0<a>Densely Packed CO<\/a><sub><a>2<\/a><\/sub><a>\u00a0Aids Charge<\/a>, Spin, and Lattice Ordering Partially Fluctuated in a\u00a0<a>Porous Metal-Organic Framework Magnet<\/a>.\u00a0<strong><em>Angew. Chem. Int. Ed.<\/em><\/strong><em>\u00a0<\/em>2023, e202312205.<\/section>\n<section>DOI: 10.1002\/anie.202312205<\/section>\n<section>URL: https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202312205<\/section>\n<section><\/section>\n<section>\u6210\u679c\uff08\u4e8c\uff09<\/section>\n<section>Jun Zhang, Wataru Kosaka, Qingxin Liu, Naoka Amamizu, Yasutaka Kitagawa, and Hitoshi Miyasaka*,\u00a0<a>CO<\/a><sub><a>2<\/a><\/sub><a>-Sensitive Porous Magnet<\/a>: Antiferromagnet Creation from a Paramagnetic Charge-Transfer Layered Metal-Organic Framework.<strong><em>\u00a0J. Am. Chem. Soc.<\/em>\u00a0<\/strong>2023, doi.org\/10.1021\/jacs.3c08583<\/section>\n<section>DOI: 10.1021\/jacs.3c08583<\/section>\n<section>URL: https:\/\/pubs.acs.org\/doi\/full\/10.1021\/jacs.3c08583<\/section>\n","protected":false},"excerpt":{"rendered":"<p>\u25b2\u7b2c\u4e00\u4f5c\u8005\uff1a\u5f20\u4fca\u00a0 \u6559\u6388\u00a0\u00a0 &nbsp; \u901a\u8baf\u4f5c\u8005\uff1aHitoshi Miyasaka \u6559\u6388\u00a0\u00a0 \u901a\u8baf\u5355\u4f4d\uff1a\u65e5 [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-50378","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/50378","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=50378"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/50378\/revisions"}],"predecessor-version":[{"id":50379,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/50378\/revisions\/50379"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=50378"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=50378"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=50378"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}