{"id":50092,"date":"2024-01-05T08:01:27","date_gmt":"2024-01-05T00:01:27","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=50092"},"modified":"2023-12-19T10:02:01","modified_gmt":"2023-12-19T02:02:01","slug":"%e4%b8%ad%e5%8d%97%e6%b0%91%e6%97%8f%e5%a4%a7%e5%ad%a6%e5%bc%a0%e6%b3%bd%e4%bc%9a%e6%95%99%e6%8e%88%e8%af%be%e9%a2%98%e7%bb%84angew-chem%ef%bc%9a%e6%b0%a7%e7%a9%ba%e4%bd%8d%e4%bb%8b%e5%af%bc%e7%9a%84","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/%e4%b8%ad%e5%8d%97%e6%b0%91%e6%97%8f%e5%a4%a7%e5%ad%a6%e5%bc%a0%e6%b3%bd%e4%bc%9a%e6%95%99%e6%8e%88%e8%af%be%e9%a2%98%e7%bb%84angew-chem%ef%bc%9a%e6%b0%a7%e7%a9%ba%e4%bd%8d%e4%bb%8b%e5%af%bc%e7%9a%84\/","title":{"rendered":"\u4e2d\u5357\u6c11\u65cf\u5927\u5b66\u5f20\u6cfd\u4f1a\u6559\u6388\u8bfe\u9898\u7ec4Angew. Chem\uff1a\u6c27\u7a7a\u4f4d\u4ecb\u5bfc\u7684\u785d\u57fa\u5316\u5408\u7269\u9009\u62e9\u6027\u8fd8\u539f\u65b0\u8fdb\u5c55"},"content":{"rendered":"<section>\u4ee5\u785d\u57fa\u82ef\u4e3a\u4ee3\u8868\u7684\u785d\u57fa\u82b3\u70c3\u5de5\u4e1a\u662f\u5316\u5de5\u884c\u4e1a\u91cd\u8981\u7ec4\u6210\u90e8\u5206\uff0c\u662f\u751f\u4ea7\u67d3\u6599\u3001\u519c\u836f\u548c\u533b\u836f\u7b49\u4ea7\u54c1\u7684\u91cd\u8981\u539f\u6599\uff0c\u5168\u7403\u785d\u57fa\u82ef\u5e02\u573a\u5df2\u8fd1\u5343\u4ebf\u89c4\u6a21\u3002\u78b3\u4e2d\u548c\u80cc\u666f\u548c\u5236\u9020\u5f3a\u56fd\u6218\u7565\u201c\u7eff\u8272\u5236\u9020\u5de5\u7a0b\u201d\u57fa\u672c\u65b9\u9488\u4e0b\uff0c\u63a8\u52a8\u4f20\u7edf\u785d\u57fa\u82b3\u70c3\u5de5\u4e1a\u7eff\u8272\u4f4e\u78b3\u53d1\u5c55\uff0c\u5177\u6709\u91cd\u5927\u610f\u4e49\u548c\u6311\u6218\u3002\u8fd1\u5e74\u6765\uff0c\u79d1\u6280\u5de5\u4f5c\u8005\u901a\u8fc7\u785d\u57fa\u82b3\u70c3\u7684\u8fd8\u539f\u548c\u6c2e\u5b98\u80fd\u5316\u53cd\u5e94\u5b9e\u73b0\u4e86<em>N<\/em>-\u70f7\u57fa\u3001\u5076\u6c2e\u548c\u6c27\u5316\u5076\u6c2e\u5316\u5408\u7269\u7b49\u591a\u79cd\u542b\u6c2e\u6709\u673a\u5206\u5b50\u7684\u6784\u5efa\uff08<em>Sci. Adv.<\/em>,\u00a0<strong>2017<\/strong>, 3, e1601945;\u00a0<em>Adv. Mater.<\/em>,\u00a0<strong>2018<\/strong>, 30, 1704416;\u00a0<em>Nat. Commun.<\/em>,\u00a0<strong>2018<\/strong>, 9, 30;\u00a0<em>Angew. Chem. Int. Ed.<\/em>,\u00a0<strong>2020<\/strong>, 59, 18679;\u00a0<em>Angew. Chem. Int. Ed.<\/em>,\u00a0<strong>2023<\/strong>, 62, e202303007;\u00a0<em>J. Am. Chem. Soc.<\/em>,\u00a0<strong>2023<\/strong>, 145, 31, 17329-17336.\uff09\u3002\u5176\u4e2d\uff0c\u6c27\u5316\u5076\u6c2e\u5316\u5408\u7269\u662f\u67d3\u6599\u3001\u533b\u836f\u3001\u6db2\u6676\u6750\u6599\u548c\u9ad8\u542b\u80fd\u6750\u6599\u7b49\u884c\u4e1a\u975e\u5e38\u91cd\u8981\u7684\u5408\u6210\u524d\u9a71\u4f53\uff0c\u5728H<sub>2<\/sub>\u3001NaBH<sub>4<\/sub>\u3001N<sub>2<\/sub>H<sub>4<\/sub>\u548c\u9187\u7b49\u4f17\u591a\u8fd8\u539f\u5242\u4e2d\uff0c\u4f7f\u7528H<sub>2<\/sub>\u5c06\u785d\u57fa\u82b3\u70c3\u8fd8\u539f\u4e3a\u6c27\u5316\u5076\u6c2e\u5316\u5408\u7269\u539f\u5219\u4e0a\u662f\u4e00\u79cd\u53ef\u6301\u7eed\u7684\u9014\u5f84\uff08\u526f\u4ea7\u7269\u4e3aH<sub>2<\/sub>O\uff09\u3002\u4f46\u662f\u8be5\u8fc7\u7a0b\u9762\u4e34H<sub>2<\/sub>\u538b\u529b\uff0810-30 bar\uff09\u63a7\u5236\u548c\u6c27\u5316\u5076\u6c2e\u5316\u5408\u7269\u4ea7\u7269\u9009\u62e9\u6027\u8c03\u63a7\u7684\u6311\u6218\u3002\u9187\u53ef\u901a\u8fc7\u78b3\u4e2d\u548c\u8def\u5f84\u83b7\u5f97\uff0c\u56e0\u6b64\uff0c\u9187\u4f5c\u4e3a\u8fd8\u539f\u5242\u53d7\u5230\u7279\u522b\u5173\u6ce8\uff0c\u76ee\u524d\u7684\u6c22\u8f6c\u79fb\u8fd8\u539f\u65b9\u6cd5\u4e3b\u8981\u4f7f\u7528\u5f02\u4e19\u9187\u7b49\u4ef2\u9187\uff0c\u4e14\u9700\u8981\u9ad8\u6d53\u5ea6\u7684\u5f3a\u78b1\u6dfb\u52a0\u5242\uff0c\u4f8b\u5982KOH\u548c\/\u6216NaOH\u3002\u4e0e\u5f02\u4e19\u9187\u76f8\u6bd4\uff0c\u4e59\u9187\u66f4\u5177\u5438\u5f15\u529b\uff0c\u4f46\u662f\u5b58\u5728\u65e0\u78b1\u6761\u4ef6\u4e0b\u4e59\u9187\u60f0\u6027\u6781\u9ad8\uff08\u5e38\u7528\u4f5c\u6eb6\u5242\uff09\u548c\u8131\u6c22\u4ea7\u7269\u4e59\u919b\u6bd2\u5316\u91d1\u5c5e\u50ac\u5316\u5242\u7b49\u6311\u6218\u3002<\/section>\n<p>&nbsp;<\/p>\n<section><img decoding=\"async\" title=\"1\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20231214\/1702522254860533.png\" alt=\"1\" \/><\/section>\n<section><strong>\u56fe 1. \u785d\u57fa\u82b3\u70c3\u9009\u62e9\u6027\u50ac\u5316\u5408\u6210\u6c27\u5316\u5076\u6c2e\u5316\u5408\u7269<\/strong><\/section>\n<section>\u9488\u5bf9\u4e0a\u8ff0\u95ee\u9898\uff0c<strong>\u4e2d\u5357\u6c11\u65cf\u5927\u5b66\u5f20\u6cfd\u4f1a\u6559\u6388\u8bfe\u9898\u7ec4<\/strong>\u548c<strong>\u6155\u5c3c\u9ed1\u5de5\u4e1a\u5927\u5b66Johannes A. Lercher\u6559\u6388<\/strong>\u62a5\u9053\u4e86\u4e00\u79cd\u901a\u8fc7\u6c27\u7a7a\u4f4d\u7f3a\u9677\u5de5\u7a0b\u4f18\u5316\u666e\u901aCeO<sub>2<\/sub>\u8f7d\u4f53\uff0c\u91c7\u7528\u4e59\u9187\u6c22\u8f6c\u79fb\u8fd8\u539f\u785d\u57fa\u82b3\u70c3\u7684\u65b9\u6cd5\uff0c\u76f4\u63a5\u3001\u591a\u6837\u6027\u6784\u5efa\u542b\u6709\u70ef\uff08C=C\uff09\u3001\u7094\uff08C\u2261C\uff09\u3001\u8148\uff08C\u2261N\uff09\u3001\u7532\u786b\u57fa\u548c\u5364\u7d20\uff08\u5305\u62ecI\uff09\u7b49\u53d6\u4ee3\u57fa\u7684\u6c27\u5316\u5076\u6c2e\u5316\u5408\u7269\u3002\u53ef\u8fd8\u539f\u578bCeO<sub>2<\/sub>\u91d1\u5c5e\u6c27\u5316\u7269\u53ef\u4ee5\u63d0\u4f9b\u4e00\u79cd\u4e0a\u8ff0\u5f3a\u78b1\u6027\u6761\u4ef6\u7684\u66ff\u4ee3\u7b56\u7565\uff0c\u5e76\u7b80\u5316\u50ac\u5316\u5242\u7684\u590d\u6742\u6027\u3002\u91cd\u70b9\u7814\u7a76\u4e86\u4e0d\u540c\u5f62\u8c8cCeO<sub>2<\/sub>\u5728\u8be5\u8fc7\u7a0b\u4e2d\u7684\u50ac\u5316\u6d3b\u6027\uff08\u6309\u7eb3\u7c73\u68d2\uff08r-CeO<sub>2<\/sub>\uff09&gt; \u7eb3\u7c73\u591a\u9762\u4f53\uff08h-CeO<sub>2<\/sub>\uff09&gt; \u7eb3\u7c73\u7acb\u65b9\u4f53\uff08c-CeO<sub>2<\/sub>\uff09\u7684\u987a\u5e8f\u4f9d\u6b21\u964d\u4f4e\uff09\u6765\u6e90\u53ca\u539f\u56e0\u3002\u7814\u7a76\u8868\u660e\uff0c\u6c27\u7a7a\u4f4d\u548c\u78b1\u6027\u4f4d\u70b9\u534f\u540c\u4f5c\u7528\u7528\u4e8e\u4e59\u9187\u6c22\u8f6c\u79fb\u8fd8\u539f\u8fc7\u7a0b\u3002<span class=\"wx_text_underline\">\u5176\u4e2d\uff0cCeO<\/span><span class=\"wx_text_underline\"><sub>2<\/sub><\/span><span class=\"wx_text_underline\">\u8868\u9762Ce<\/span><span class=\"wx_text_underline\"><sup>3+<\/sup><\/span><span class=\"wx_text_underline\">\u548cCe<\/span><span class=\"wx_text_underline\"><sup>4+<\/sup><\/span><span class=\"wx_text_underline\">\u4e4b\u95f4\u7684\u6c27\u5316\u8fd8\u539f\u5faa\u73af\u63d0\u4f9b\u6e90\u6e90\u4e0d\u65ad\u7684\u52a8\u529b\u4ee5\u6d3b\u5316\u4e59\u9187\u548c\u785d\u57fa\u82b3\u70c3\uff0c\u4e59\u9187\u5728CeO<\/span><span class=\"wx_text_underline\"><sub>2<\/sub><\/span><span class=\"wx_text_underline\">\u6c27\u7a7a\u4f4d\u6d3b\u5316\u540e\u63d0\u4f9b\u6c22\uff08\u03b1-C<\/span><span class=\"wx_text_underline\"><sub>sp3-<\/sub><\/span><span class=\"wx_text_underline\">H\u548c-O-H\uff09\u4ee5\u8fd8\u539f\u785d\u57fa\uff0c\u6676\u683c\u6c27\u4f5c\u4e3a\u78b1\u57fa\u4f4d\u70b9\u4f7fN=N\u5408\u6210\u6c27\u5316\u5076\u6c2e\u5316\u5408\u7269\uff0cCeO<\/span><span class=\"wx_text_underline\"><sub>2<\/sub><\/span><span class=\"wx_text_underline\">\u7684\u78b1\u6027\u548c\u5f31\u8fd8\u539f\u6027\u4fdd\u969c\u6c27\u5316\u5076\u6c2e\u5316\u5408\u7269\u7684\u9009\u62e9\u6027\u3002<\/span>\u8fd9\u9879\u5de5\u4f5c\u5f00\u8f9f\u4e86\u4e00\u79cd\u4f7f\u7528\u975e\u8d35\u91d1\u5c5e\u6c27\u5316\u7269\u50ac\u5316\u5242\u8fdb\u884c\u9009\u62e9\u6027\u6c22\u8f6c\u79fb\u53cd\u5e94\u8def\u7ebf\uff0c\u6709\u671b\u4e3a\u8fdb\u4e00\u6b65\u7684\u50ac\u5316\u5242\u8bbe\u8ba1\u63d0\u4f9b\u65b0\u601d\u8def\u3002<\/section>\n<section><img decoding=\"async\" title=\"2\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20231214\/1702522263705197.jpg\" alt=\"2\" \/><\/section>\n<section><strong>\u56fe2. \u785d\u57fa\u82ef\u6c22\u8f6c\u79fb\u8fd8\u539f\u4e3a\u6c27\u5316\u5076\u6c2e\u82ef\u7684\u53ef\u80fd\u53cd\u5e94\u9014\u5f84\uff08A\uff09\u548c\u53cd\u5e94\u673a\u7406\uff08B\uff09<\/strong><\/section>\n<section><\/section>\n<section>\u8be5\u7814\u7a76\u8fd8\u5c06\u7eb3\u7c73\u68d2CeO<sub>2<\/sub>\u50ac\u5316\u5242\u5e94\u7528\u4e8e\u653e\u5927\u5b9e\u9a8c\u548c\u56fa\u5b9a\u5e8a\u8fde\u7eed\u6d41\u5fae\u53cd\u5e94\u5668\u5b9e\u9a8c\u76f4\u63a5\u5408\u6210\u6c27\u5316\u5076\u6c2e\u82ef\u3002\u5728\u785d\u57fa\u82ef\u6d53\u5ea62500 mM\u6761\u4ef6\u4e0b\uff0c\u4f7f\u75281.0 g r-CeO<sub>2<\/sub>\u50ac\u5316\u5242\uff0c20\u5929\u540e\uff0c\u6c27\u5316\u5076\u6c2e\u82ef\u7684\u6536\u7387\u7ea6\u4e3a65%\u3002GC\u548cGC-MS\u5206\u6790\u8868\u660e\uff0c\u653e\u5927\u6d4b\u8bd5\u7684\u6c27\u5316\u5076\u6c2e\u82ef\u9009\u62e9\u6027&gt;95%\u3002\u56fa\u5b9a\u5e8a\u5b9e\u9a8c\u4e2d\uff0c\u6700\u9ad8\u53ef\u8fbe\u5355\u7a0b\u785d\u57fa\u82ef\u8f6c\u5316\u7387~27%\uff0c24 h\u7a33\u5b9a\u8fd0\u884c\u7684\u60c5\u51b5\u4e0b\uff0c\u5177\u6709\u8f83\u9ad8\u7684\u6c27\u5316\u5076\u6c2e\u82ef\u9009\u62e9\u6027\uff08~91%\uff09\u3002\u653e\u5927\u5b9e\u9a8c\u548c\u8fde\u7eed\u6d41\u52a8\u53cd\u5e94\u7684\u4f18\u5f02\u7ed3\u679c\u8868\u660e\uff0c\u8be5\u65b9\u6cd5\u663e\u793a\u51fa\u6c27\u5316\u5076\u6c2e\u82b3\u70c3\u5de5\u4e1a\u751f\u4ea7\u7684\u5de8\u5927\u6f5c\u529b\u3002<\/section>\n<section><img decoding=\"async\" title=\"3\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20231214\/1702522275608256.png\" alt=\"3\" \/><\/section>\n<section><strong>\u56fe3. \u653e\u5927\u5b9e\u9a8c\u548c\u56fa\u5b9a\u5e8a\u5b9e\u9a8c<\/strong><\/section>\n<section>\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u201cSynergy of Oxygen Vacancies and Base Sites for Transfer Hydrogenation of Nitroarenes on Ceria Nanorods\u201d\u4e3a\u9898\uff0c\u4e8e\u8fd1\u65e5\u53d1\u8868\u5728<strong><em>Angew. Chem. Int. Ed.<\/em><\/strong>\u4e0a\u3002<strong>\u4e2d\u5357\u6c11\u65cf\u5927\u5b66\u5f20\u6cfd\u4f1a\u6559\u6388<\/strong>\u548c<strong>\u5fb7\u56fd\u6155\u5c3c\u9ed1\u5de5\u4e1a\u5927\u5b66Johannes A. Lercher\u6559\u6388<\/strong>\u4e3a\u901a\u8baf\u4f5c\u8005\uff0c<strong>\u4e2d\u5357\u6c11\u65cf\u5927\u5b66<\/strong>\u4e3a\u7b2c\u4e00\u7f72\u540d\u5355\u4f4d\u3002<\/section>\n<section><strong>\u5f20\u6cfd\u4f1a<\/strong><strong>\u6559\u6388<\/strong>\u9886\u8854\u7684\u7eff\u8272\u5408\u6210\u50ac\u5316\u5b66\u672f\u56e2\u961f\uff0c\u4f9d\u6258\u4e8e<strong>\u4e2d\u5357\u6c11\u65cf\u5927\u5b66<\/strong>\u5316\u5b66\u4e0e\u6750\u6599\u79d1\u5b66\u5b66\u9662\uff0c\u4e3b\u8981\u4ece\u4e8b\u751f\u7269\u8d28\u50ac\u5316\u8f6c\u5316\u3001\u5149\u50ac\u5316\u6709\u673a\u5408\u6210\u53ca\u76f8\u5173\u7814\u7a76\uff0c\u805a\u7126\u4e8e\u751f\u7269\u8d28\u50ac\u5316\u8f6c\u5316\u5236\u5907\u751f\u7269\u57fa\u805a\u5408\u6750\u6599\u5355\u4f53\u53ca\u542b\u6c2e\u7cbe\u7ec6\u5316\u5de5\u4ea7\u54c1\u3002\u56e2\u961f\u8fd1\u5e74\u6765\u5df2\u5728Nat. Comm.\u3001Sci. Adv.\u3001Chem\u3001Angew. Chem. Int. Ed.\u3001J. Am. Chem. Soc.\u3001Chem. Soc. Rev. \u548cJACS Au \u7b49\u56fd\u9645\u77e5\u540d\u671f\u520a\u53d1\u8868\u4e86\u7cfb\u5217\u76f8\u5173\u91cd\u8981\u6210\u679c\uff0c\u4e3a\u76f8\u5173\u7814\u7a76\u9886\u57df\u7684\u53d1\u5c55\u505a\u51fa\u4e86\u79ef\u6781\u8d21\u732e\u3002<strong>\u5f20\u6cfd\u4f1a<\/strong><strong>\u6559\u6388<\/strong>\u53d1\u8868\u7684\u7814\u7a76\u8bba\u6587\u88abSCI\u4ed6\u5f1510000\u4f59\u6b21\uff0cH\u6307\u657054\uff0c\u7814\u7a76\u6210\u679c\u83b7\u6e56\u5317\u7701\u81ea\u7136\u79d1\u5b66\u5956\u3001\u8fbd\u5b81\u7701\u81ea\u7136\u79d1\u5b66\u5956\u3001\u5927\u8fde\u5e02\u6280\u672f\u53d1\u660e\u5956\u7b49\u3002<\/section>\n<section data-role=\"title\" data-tools=\"135\u7f16\u8f91\u5668\" data-id=\"us-4152855\">\n<section>\n<section>\n<section class=\"\" data-lazy-bgimg=\"https:\/\/mmbiz.qpic.cn\/mmbiz_gif\/DfSKiaLzCzbFBNyKTX6NHENvZOLn354qrwrpWbcwh8SMPUbMqZ1mYdgvUPm5y9qCbKdmgoQ77F7tXphY36l52DA\/640?wx_fmt=gif\" data-fail=\"0\">\n<section data-brushtype=\"text\"><strong>\u6587\u7ae0\u4fe1\u606f<\/strong><\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>Ziliang Yuan,<sup>\u2021[a,b]<\/sup>\u00a0Liang Huang,<sup>\u2021[b]<\/sup>\u00a0Yuanshuai Liu,<sup>\u2021[d]<\/sup>\u00a0Yong Sun,<sup>[e]<\/sup>\u00a0Guanghui Wang,<sup>[b]\u00a0<\/sup>Xun Li,<sup>[a]\u00a0<\/sup>Johannes A. Lercher,<sup>*[c]\u00a0<\/sup>and Zehui Zhang<sup>*[a]<\/sup>.\u00a0Angew. Chem. Int. Ed., 2023, DOI: 10.1002\/anie.202317339<\/section>\n<p>&nbsp;<\/p>\n<p><strong>\u539f\u6587\u94fe\u63a5\uff1a<\/strong><\/p>\n<p>&nbsp;<\/p>\n<section>https:\/\/doi.org\/10.1002\/anie.202317339<\/section>\n","protected":false},"excerpt":{"rendered":"<p>\u4ee5\u785d\u57fa\u82ef\u4e3a\u4ee3\u8868\u7684\u785d\u57fa\u82b3\u70c3\u5de5\u4e1a\u662f\u5316\u5de5\u884c\u4e1a\u91cd\u8981\u7ec4\u6210\u90e8\u5206\uff0c\u662f\u751f\u4ea7\u67d3\u6599\u3001\u519c\u836f\u548c\u533b\u836f\u7b49\u4ea7\u54c1\u7684\u91cd\u8981\u539f\u6599\uff0c\u5168\u7403\u785d\u57fa\u82ef\u5e02\u573a\u5df2\u8fd1 [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-50092","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/50092","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=50092"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/50092\/revisions"}],"predecessor-version":[{"id":50093,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/50092\/revisions\/50093"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=50092"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=50092"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=50092"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}