{"id":49996,"date":"2024-01-04T08:55:56","date_gmt":"2024-01-04T00:55:56","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=49996"},"modified":"2023-12-18T09:56:26","modified_gmt":"2023-12-18T01:56:26","slug":"angew-chem-%ef%bc%9aco2%e5%b1%80%e5%9f%9f%e5%af%8c%e9%9b%86%e7%ad%96%e7%95%a5%e7%94%a8%e4%ba%8e%e8%b6%85%e5%ae%bd%e7%94%b5%e4%bd%8d%e8%8c%83%e5%9b%b4%e7%9a%84%e7%94%b2%e9%85%b8%e7%9b%90%e5%88%b6","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/angew-chem-%ef%bc%9aco2%e5%b1%80%e5%9f%9f%e5%af%8c%e9%9b%86%e7%ad%96%e7%95%a5%e7%94%a8%e4%ba%8e%e8%b6%85%e5%ae%bd%e7%94%b5%e4%bd%8d%e8%8c%83%e5%9b%b4%e7%9a%84%e7%94%b2%e9%85%b8%e7%9b%90%e5%88%b6\/","title":{"rendered":"Angew. Chem. \uff1aCO2\u5c40\u57df\u5bcc\u96c6\u7b56\u7565\u7528\u4e8e\u8d85\u5bbd\u7535\u4f4d\u8303\u56f4\u7684\u7532\u9178\u76d0\u5236\u53d6"},"content":{"rendered":"<section>\n<section>\n<section>\n<section>\n<section>\u5229\u7528\u65b0\u80fd\u6e90\u7535\u529b\u5c06\u4e8c\u6c27\u5316\u78b3\u8f6c\u5316\u4e3a\u9ad8\u503c\u5316\u5b66\u54c1\u6709\u671b\u540c\u65f6\u5b9e\u73b0\u51cf\u78b3\u548c\u7535\u529b\u6d88\u7eb3\u7684\u53cc\u91cd\u76ee\u6807\u3002\u8fd1\u5e74\u6765\uff0c\u7532\u9178\u56e0\u5176\u8f83\u9ad8\u7684\u7ecf\u6d4e\u4ef7\u503c\u4ee5\u53ca\u5728\u5de5\u4e1a\u3001\u71c3\u6599\u7535\u6c60\u53ca\u50a8\u6c22\u9886\u57df\u7684\u5e7f\u6cdb\u5e94\u7528\uff0c\u5728CO<sub>2<\/sub>\u7535\u5316\u5b66\u8fd8\u539f\u4f17\u591a\u4ea7\u7269\u4e2d\u5907\u53d7\u5173\u6ce8\u3002\u4f46\u5728\u7535\u89e3\u5de5\u51b5\u6761\u4ef6\u4e0b\uff0c\u7535\u6781\u754c\u9762\u77ac\u53d8\u3001\u7535\u573a\u4e0d\u5747\u4ee5\u53capH\u68af\u5ea6\u7b49\u95ee\u9898\u5c06\u5bfc\u81f4\u660e\u663e\u7535\u538b\u6296\u52a8\u3002\u56e0\u6b64\uff0c\u5f00\u53d1\u5bbd\u7535\u4f4d\u7a97\u53e3\u5185\u7a33\u5b9a\u9ad8\u6548\u5236\u53d6\u7532\u9178\u6280\u672f\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002<\/p>\n<p>\u8fd1\u65e5\uff0c\u534e\u4e1c\u7406\u5de5\u5927\u5b66\u7684\u5f20\u7389\u6559\u6388\u548c\u9999\u6e2f\u79d1\u6280\u5927\u5b66\u7684\u90b5\u654f\u534e\u6559\u6388\u5408\u4f5c\uff0c\u901a\u8fc7\u5728\u94cb\u57fa\u50ac\u5316\u5242\u8868\u9762\u5f15\u5165L-\u7ec4\u6c28\u9178\u5206\u5b50\uff0c\u6709\u6548\u589e\u5f3a\u4e86CO<sub>2<\/sub>\u5c40\u57df\u5438\u9644\u548c\u6d3b\u5316\u80fd\u529b\uff0c\u514b\u670d\u4e86\u9ad8\u50ac\u5316\u6d3b\u6027\u548c\u9ad8\u7532\u9178\u9009\u62e9\u6027\u96be\u4ee5\u517c\u987e\u7684\u6311\u6218\uff0c\u5b9e\u73b0\u4e86\u5728\u8d85\u5bbd\u7535\u4f4d\u8303\u56f4\uff08-0.1 ~ -1.8 V vs. RHE\uff09\u5185\u9ad8\u9009\u62e9\u6027\u5730\u5236\u53d6\u7532\u9178\u76d0\uff08FE<sub>Formate<\/sub>&gt;90%\uff09\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<p>&nbsp;<\/p>\n<section>\n<section><\/section>\n<\/section>\n<p>&nbsp;<\/p>\n<section><img decoding=\"async\" title=\"1\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20231212\/1702347767482312.png\" alt=\"1\" \/><\/section>\n<section><img decoding=\"async\" title=\"5\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20231212\/1702347774382428.png\" alt=\"5\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u6b64\u5916\uff0c\u8be5\u5de5\u4f5c\u6240\u62a5\u9053\u7684\u50ac\u5316\u5242\u56e0\u5176\u4f18\u5f02\u7684CO<sub>2<\/sub>\u5438\u9644\u80fd\u529b\uff0c\u5373\u4f7f\u5728\u4f4eCO<sub>2<\/sub>\u6d53\u5ea6\uff0820 vol.%\uff09\u4f9b\u5e94\u7684\u60c5\u51b5\u4e0b\uff0c\u4ecd\u80fd\u5728-0.2 ~ -1.0 VRHE\u7684\u5bbd\u7535\u4f4d\u8303\u56f4\u5185\u4fdd\u630190%\u7684\u7532\u9178\u76d0\u9009\u62e9\u6027\u3002\u539f\u4f4d\u7d2b\u5916\u5149\u8c31\u65b9\u6cd5\u8868\u660e\u8be5\u50ac\u5316\u5242\u5177\u6709\u8f83\u4f4e\u7684\u8fc7\u7535\u4f4d\uff08-0.05 V vs. RHE\uff09.<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"6\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20231212\/1702347785299921.png\" alt=\"6\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u539f\u4f4d\u8870\u51cf\u5168\u53cd\u5c04\u7ea2\u5916\u5149\u8c31\uff08ATR-IR\uff09\u53ca\u539f\u4f4d\u62c9\u66fc\u6280\u672f\u8bc1\u660e\u4e86\u8be5\u50ac\u5316\u5242\u5bf9CO<sub>2<\/sub>\u4f18\u5f02\u7684\u5438\u9644\u53ca\u6d3b\u5316\u80fd\u529b\uff0c\u63ed\u793a\u4e86CO<sub>2<\/sub>\u5c40\u57df\u5bcc\u96c6\u7b56\u7565\u5bf9\u4e8e\u9ad8\u6548\u5236\u53d6\u7532\u9178\u76d0\u7684\u589e\u5f3a\u673a\u5236\u3002\u8be5\u5de5\u4f5c\u4e3a\u5f00\u53d1\u5de5\u4e1a\u70df\u9053\u6c14CO<sub>2<\/sub>\u6355\u96c6-\u8f6c\u5316\u4e00\u4f53\u5316\u6280\u672f\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section><strong>\u8bba<\/strong><strong>\u6587\u4fe1\u606f<\/strong><\/p>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section><\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>Enhancing Local CO<sub>2<\/sub>\u00a0Adsorption by L-histidine Incorporation for Selective Formate Production Over the Wide Potential Window<\/p>\n<p>\u6587\u7ae0\u7684\u7b2c\u4e00\u4f5c\u8005\u662f\u534e\u4e1c\u7406\u5de5\u5927\u5b66\u7684\u535a\u58eb\u751f\u674e\u4ebf\u7a0b\u548c\u9999\u6e2f\u79d1\u6280\u5927\u5b66\u7684Ernest Pahuyo Delmo\u535a\u58eb<\/p>\n<p><em>Angewandte Chemie International Edition<\/em><\/p>\n<p>DOI:\u00a010.1002\/anie.202313522<\/p>\n<\/section>\n<\/section>\n<\/section>\n","protected":false},"excerpt":{"rendered":"<p>\u5229\u7528\u65b0\u80fd\u6e90\u7535\u529b\u5c06\u4e8c\u6c27\u5316\u78b3\u8f6c\u5316\u4e3a\u9ad8\u503c\u5316\u5b66\u54c1\u6709\u671b\u540c\u65f6\u5b9e\u73b0\u51cf\u78b3\u548c\u7535\u529b\u6d88\u7eb3\u7684\u53cc\u91cd\u76ee\u6807\u3002\u8fd1\u5e74\u6765\uff0c\u7532\u9178\u56e0\u5176\u8f83\u9ad8\u7684\u7ecf\u6d4e\u4ef7\u503c\u4ee5 [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-49996","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/49996","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=49996"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/49996\/revisions"}],"predecessor-version":[{"id":49997,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/49996\/revisions\/49997"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=49996"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=49996"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=49996"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}