{"id":49616,"date":"2023-12-28T08:55:30","date_gmt":"2023-12-28T00:55:30","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=49616"},"modified":"2023-12-11T09:55:54","modified_gmt":"2023-12-11T01:55:54","slug":"angew-chem-int-ed-%e5%90%ab%e9%86%9a%e8%81%9a%e5%90%88%e7%89%a9%e7%9a%84%e9%80%89%e6%8b%a9%e6%80%a7%e7%94%b5%e5%82%ac%e5%8c%96%e9%99%8d%e8%a7%a3","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/angew-chem-int-ed-%e5%90%ab%e9%86%9a%e8%81%9a%e5%90%88%e7%89%a9%e7%9a%84%e9%80%89%e6%8b%a9%e6%80%a7%e7%94%b5%e5%82%ac%e5%8c%96%e9%99%8d%e8%a7%a3\/","title":{"rendered":"Angew. Chem. Int. Ed. | \u542b\u919a\u805a\u5408\u7269\u7684\u9009\u62e9\u6027\u7535\u50ac\u5316\u964d\u89e3"},"content":{"rendered":"<section>\u7ed9\u5927\u5bb6\u5206\u4eab\u4e00\u7bc7\u6700\u8fd1\u53d1\u8868\u5728<em>Angew. Chem. Int. Ed.<\/em>\u7684\u7814\u7a76\u8fdb\u5c55\uff0c\u9898\u4e3a\uff1a<em>Selective<\/em><em>\u00a0<\/em><em>Electrocatalytic<\/em><em>\u00a0<\/em><em>Degradation<\/em><em>\u00a0<\/em><em>of<\/em><em>\u00a0<\/em><em>Ether<\/em><em>&#8211;<\/em><em>Containing<\/em><em>\u00a0<\/em><em>Polymers<\/em>\u3002\u8be5\u5de5\u4f5c\u7684\u901a\u8baf\u4f5c\u8005\u662f\u5eb7\u5948\u5c14\u5927\u5b66\u7684Erin\u00a0E.\u00a0Stache\u548cBrett\u00a0P.\u00a0Fors\u3002<\/section>\n<p>&nbsp;<\/p>\n<section>\u00a0\u00a0\u00a0\u00a0\u5168\u7403\u5e9f\u5f03\u5851\u6599\u9010\u5e74\u589e\u52a0\uff0c\u9884\u8ba1\u52302025\u5e74\uff0c\u73af\u5883\u4e2d\u7684\u5851\u6599\u6c61\u67d3\u7269\u7d2f\u8ba1\u5c06\u8fbe110\u4ebf\u5428\u3002\u4e3a\u4e86\u89e3\u51b3\u8fd9\u4e00\u95ee\u9898\uff0c\u4e9f\u9700\u53d1\u5c55\u5faa\u73af\u5851\u6599\u7ecf\u6d4e\u3002\u673a\u68b0\u518d\u52a0\u5de5\u662f\u76ee\u524d\u5229\u7528\u6700\u591a\u7684\u5851\u6599\u56de\u6536\u5f62\u5f0f\uff0c\u7136\u800c\uff0c\u8be5\u65b9\u6cd5\u901a\u5e38\u53ea\u80fd\u56de\u6536\u5f97\u5230\u6027\u80fd\u4e0b\u964d\u7684\u4f4e\u4ef7\u503c\u6750\u6599\u3002\u56e0\u6b64\uff0c\u5f00\u53d1\u65b0\u7684\u7b56\u7565\u5b9e\u73b0\u96be\u964d\u89e3\u805a\u5408\u7269\u7684\u5316\u5b66\u56de\u6536\u548c\u518d\u5229\u7528\uff0c\u662f\u4e00\u4e2a\u91cd\u8981\u7684\u7814\u7a76\u8bfe\u9898\u3002\u5149\u964d\u89e3\u662f\u805a\u5408\u7269\u5347\u7ea7\u56de\u6536\u7684\u4e00\u79cd\u6709\u6f5c\u529b\u7684\u7b56\u7565\u3002\u4f8b\u5982\uff0cStache\u7b49\u4eba\u62a5\u9053\u4e86\u82ef\u4e59\u70ef\u7684\u6c22\u539f\u5b50\u8f6c\u79fb\uff08HAT\uff09\u5149\u6c27\u5316\u964d\u89e3\uff0cKnowles\u7b49\u4eba\u53d1\u5c55\u4e86\u7f9f\u57fa\u5316\u805a\u5408\u7269\u7684\u8d28\u5b50\u8026\u5408\u7535\u5b50\u8f6c\u79fb\uff08PCET\uff09\u5149\u9a71\u52a8\u89e3\u805a\u3002\u4e0e\u5149\u5316\u5b66\u76f8\u6bd4\uff0c\u901a\u8fc7\u7535\u5316\u5b66\u6765\u9a71\u52a8\u805a\u5408\u7269\u964d\u89e3\u7684\u63a2\u7d22\u4ecd\u7136\u5f88\u5c11\u3002<\/section>\n<section>\u00a0\u00a0\u00a0\u00a0\u7535\u5316\u5b66\u5177\u6709\u6e29\u548c\u3001\u53ef\u653e\u5927\u548c\u9ad8\u6548\u7684\u7279\u70b9\uff0c\u8fd1\u5e74\u6765\u6d8c\u73b0\u4e86\u4e0d\u5c11\u5c06\u5176\u5e94\u7528\u4e8e\u6709\u673a\u548c\u805a\u5408\u7269\u5408\u6210\u7684\u65b0\u7814\u7a76\u3002\u7814\u7a76\u4eba\u5458\u5df2\u7ecf\u5f00\u53d1\u4e86\u8bb8\u591a\u65b9\u6cd5\u6765\u4ea7\u751f\u7535\u5316\u5b66\u6d3b\u6027\u7269\u8d28\uff0c\u7136\u800c\uff0c\u8fd9\u4e9b\u65b9\u6cd5\u901a\u5e38\u4fa7\u91cd\u4e8e\u6210\u952e\u800c\u4e0d\u662f\u65ad\u952e\u53cd\u5e94\uff0c\u53ea\u6709\u5c11\u6570\u5173\u4e8e\u805a\u5408\u7269\u5347\u7ea7\u56de\u6536\u6216\u964d\u89e3\u7684\u7535\u5316\u5b66\u65b9\u6cd5\u7684\u62a5\u9053\uff0c\u5305\u62ec\u805a\u6c2f\u4e59\u70ef\u7684\u7535\u5316\u5b66\u8131\u6c2f\u3001\u805a\u82ef\u4e59\u70ef\u7684\u7535\u5316\u5b66\u8131\u82b3\u6784\u5316\u4ee5\u53ca\u6d3b\u5316C-H\u89e3\u805a\u6728\u8d28\u7d20\u7b49\u3002<\/section>\n<section>\u00a0\u00a0\u00a0\u00a0\u5728\u4e4b\u524d\u7684\u5de5\u4f5c\u4e2d\uff0c\u4f5c\u8005\u62a5\u9053\u4e86\u4e00\u79cd\u9ad8\u5f3a\u5ea6\u53ef\u518d\u751f\u70ed\u5851\u6027\u5851\u6599\u2014\u2014\u805a2,3-\u4e8c\u6c22\u544b\u5583\uff08PDHF\uff09\uff0c\u8be5\u805a\u5408\u7269\u901a\u8fc7\u73af\u72b6\u4e59\u70ef\u57fa\u919a\u7684\u9633\u79bb\u5b50\u805a\u5408\u5408\u6210\u3002\u540c\u65f6\uff0c\u4f5c\u8005\u63d0\u51faPDHF\u53ef\u901a\u8fc7HAT\u673a\u5236\u5b9e\u73b0\u52a0\u901f\u7684\u6c27\u5316\u964d\u89e3\u3002\u7136\u800c\uff0c\u8be5\u65b9\u6cd5\u9700\u8981\u5927\u91cf\u5f3a\u6c27\u5316\u5242\u3002\u53d7\u7535\u50ac\u5316\u6700\u65b0\u8fdb\u5c55\u7684\u542f\u53d1\uff0c\u4f5c\u8005\u8bbe\u60f3\u5229\u7528\u7535\u5316\u5b66\u7784\u51c6\u542b\u919a\u805a\u5408\u7269\u4e2d\u6d3b\u5316\u7684\u5bcc\u7535\u5b50C-H\u952e\uff0c\u5f00\u53d1\u4e00\u79cd\u5229\u7528\u5206\u5b50\u6c27\u5b9e\u73b0\u6e29\u548c\u4e14\u5177\u6709\u9009\u62e9\u6027\u6c27\u5316\u964d\u89e3\u7684\u50ac\u5316\u65b9\u6cd5\u3002<\/section>\n<section>\u00a0\u00a0\u00a0\u00a0\u4f5c\u8005\u9996\u5148\u63a2\u7a76\u4e86\u5404\u79cd\u7535\u5316\u5b66\u4ecb\u8d28\u6c27\u5316\u964d\u89e3\u805a\u4e59\u57fa\u4e59\u70ef\u919a\uff08PEVE,\u00a0<em>M<\/em><sub>n<\/sub>\u00a0~ 15 kg\/mol\uff09\u7684\u80fd\u529b\uff08\u56fe1\uff09\u3002\u4f5c\u8005\u4ee5\u7f51\u72b6\u73bb\u7483\u78b3\uff08RVC\uff09\u4f5c\u4e3a\u7535\u6c60\u7684\u9633\u6781\uff0c\u94a2\u4e3a\u9634\u6781\uff0c\u8be5\u7535\u6c60\u7f6e\u4e8e\u7a7a\u6c14\u4e2d\uff0c\u5185\u90e8\u5305\u542bPEVE\u3001DCM\u3001\u56db\u4e01\u57fa\u56db\u6c1f\u787c\u9178\u94f5\uff08TBABF<sub>4<\/sub>\uff09\u3001\u4e59\u9178\u548c\u4e00\u79cd\u7535\u5316\u5b66\u4ecb\u8d28\uff08\u56fe1\uff0c\u4ecb\u8d28\u5305\u62ecDABCO\u3001NMO\u3001TEMPO\u3001HOBt\u3001\u82ef\u7532\u9170\u82ef\u80fa\u3001\u55b9\u5549\u3001NHPT\uff09\u3002\u4e0a\u8ff0\u4ecb\u8d28\u5747\u5177\u6709\u7535\u5316\u5b66\u6c27\u5316\u7684\u503e\u5411\uff0c\u53ef\u4ee5\u4ea7\u751f\u6c2e\u6216\u6c27\u4e2d\u5fc3\u81ea\u7531\u57fa\uff0c\u4ee5\u5b9e\u73b0C-H\u952e\u62d4\u6c22\u3002\u6b64\u5916\uff0c\u5faa\u73af\u4f0f\u5b89\u6cd5\u8868\u660e\uff0c\u8d28\u5b50\u4ecb\u8d28\u5728\u5f31\u78b1\u6761\u4ef6\u4e0b\u5177\u6709\u66f4\u5f3a\u7684\u7535\u5316\u5b66\u6d3b\u6027\uff0c\u56e0\u6b64\uff0c\u4f5c\u8005\u5728HOBt\u3001\u82ef\u7532\u9170\u82ef\u80fa\u3001NHPT\u7684\u53cd\u5e94\u4e2d\u52a0\u5165\u4e86\u5421\u5576\u3002\u968f\u540e\u65bd\u52a00.5\u00a0mA\u7684\u6052\u5b9a\u7535\u6d41\uff0c\u901a\u8fc7GPC\u76d1\u6d4b<em>M<\/em><sub>n<\/sub>\u968f\u65f6\u95f4\u7684\u53d8\u5316\uff08\u56fe1\uff09\u3002\u5728NHPI\u5b58\u5728\u7684\u6761\u4ef6\u4e0b\uff0c2\u00a0h\u540e<em>M<\/em><sub>n<\/sub>\u4ece15\u00a0kg\/mol\u4e0b\u964d\u52301.5\u00a0kg\/mol\uff0c<em>M<\/em><sub>n<\/sub><sup>&#8211;<\/sup><sup>1<\/sup>\u4e0e\u65f6\u95f4\u5448\u7ebf\u6027\u5173\u7cfb\uff0c\u8868\u660e\u94fe\u65ad\u88c2\u673a\u5236\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u55b9\u5549\u4e2d<em>M<\/em><sub>n<\/sub>\u4e0b\u964d\u5e45\u5ea6\u8f83\u5c0f\uff0c\u800c\u5728\u5176\u4ed6\u4ecb\u8d28\u4e2d\u672a\u53d1\u73b0\u660e\u663e\u7684<em>M<\/em><sub>n<\/sub>\u53d8\u5316\u3002\u4e0a\u8ff0\u7ed3\u679c\u8bf4\u660e\u7535\u5316\u5b66\u4ecb\u8d28\u7684\u7279\u6027\u662f\u805a\u5408\u7269\u9ad8\u6548\u964d\u89e3\u7684\u5173\u952e\u3002<\/section>\n<section><img decoding=\"async\" title=\"1\" src=\"https:\/\/17332.seohost.cn\/storage\/17332\/article\/20231205\/1701743787773364.png\" alt=\"1\" \/><\/section>\n<section><strong>\u56fe1<\/strong><strong>.\u00a0<\/strong>\u7535\u5316\u5b66\u4ecb\u8d28\u7684\u79cd\u7c7b\u53ca\u5176\u964d\u89e3\u6548\u679c<\/section>\n<section><\/section>\n<section>\u00a0\u00a0\u00a0\u00a0\u968f\u540e\u4f5c\u8005\u8fdb\u4e00\u6b65\u7814\u7a76\u4e86NHPI\u5bf9PEVE\u7535\u5316\u5b66\u964d\u89e3\u7684\u8fc7\u7a0b\u3002\u7ed3\u679c\u8868\u660e\uff0cNHPI\u4f5c\u4e3a\u7535\u5316\u5b66\u4ecb\u8d28\uff0c\u5728\u5f31\u78b1\u53bb\u8d28\u5b50\u5316\u548c\u9178\u8f85\u52a9\u7684\u6761\u4ef6\u4e0b\uff0c\u5177\u6709\u6700\u9ad8\u7684\u805a\u5408\u7269\u964d\u89e3\u6548\u7387\u3002\u6b64\u5916\uff0c\u6c27\u6c14\u5728\u52a0\u901f\u964d\u89e3\u4e2d\u4e5f\u8d77\u7740\u5173\u952e\u4f5c\u7528\u3002\u7efc\u4e0a\uff0c\u5728\u5421\u5576\u3001\u4e59\u9178\u3001\u6c27\u548c\u6052\u5b9a\u7684\u7535\u5316\u5b66\u7535\u6d41\u5b58\u5728\u7684\u6761\u4ef6\u4e0b\uff0c\u50ac\u5316\u91cf\u7684NHPI\u5bf9\u542b\u919a\u805a\u5408\u7269\u7684\u6c27\u5316\u964d\u89e3\u6548\u679c\u6700\u4f73\u3002<\/section>\n<section>\u00a0\u00a0\u00a0\u00a0\u968f\u540e\uff0c\u4f5c\u8005\u7814\u7a76\u4e86\u8be5\u4f53\u7cfb\u964d\u89e3\u805a\u5408\u7269\u7684\u65f6\u95f4\u63a7\u5236\u6027\uff08\u56fe2\uff09\u3002\u65bd\u52a00.5\u00a0mA\u6052\u5b9a\u7535\u6d4130\u00a0min\uff0c<em>M<\/em><sub>n<\/sub>\u4ece15\u964d\u81f38.1\u00a0kg\/mol\uff1b\u5173\u95ed\u7535\u6d411\u00a0h\uff0c<em>M<\/em><sub>n<\/sub>\u4e0d\u53d1\u751f\u53d8\u5316\uff08\u56fe2a\uff09\u3002\u901a\u8fc7\u5468\u671f\u6027\u5730\u5f00\/\u5173\u7535\u6d41\u5373\u53ef\u5b9e\u73b0\u964d\u89e3\u7684\u65f6\u95f4\u63a7\u5236\u3002\u7531\u6b64\u4f5c\u8005\u63d0\u51fa\u8be5\u8fc7\u7a0b\u7684\u673a\u5236\uff08\u56fe2b\uff09\uff1aNHPI\u88ab\u5421\u5576\u53bb\u8d28\u5b50\u5316\uff0c\u5e76\u5728\u9633\u6781\u6c27\u5316\u5f62\u6210\u6c27\u81ea\u7531\u57fa\uff0c\u968f\u540e\u8be5\u81ea\u7531\u57fa\u5c06PEVE\u4e3b\u94fe\u4e0a\u5bcc\u7535\u5b50C-H\u952e\u4e2d\u7684\u6c22\u539f\u5b50\u62d4\u53bb\uff1b\u751f\u6210\u7684\u78b3\u81ea\u7531\u57fa\u968f\u540e\u88ab\u5206\u5b50\u6c27\u6dec\u706d\uff0c\u5bfc\u81f4\u76f8\u90bbC-C\u952e\u7684<em>\u03b2<\/em>-\u65ad\u88c2\uff1b\u6b64\u5916\uff0c\u4e59\u9178\u4e3a\u9634\u6781\u63d0\u4f9b\u8d28\u5b50\u8fd8\u539f\u5f62\u6210\u6c22\u5206\u5b50\uff0c\u5b8c\u6210\u7535\u5316\u5b66\u56de\u8def\u3002\u5bf9\u964d\u89e3\u4ea7\u7269\u7684\u5206\u6790\u63ed\u793a\u4e86\u4e59\u9178\u3001\u7532\u9178\u548c\u4e59\u919b\u7b49\u6c27\u5316\u5c0f\u5206\u5b50\u7684\u5f62\u6210\u3002<\/section>\n<section><img decoding=\"async\" title=\"2\" src=\"https:\/\/17332.seohost.cn\/storage\/17332\/article\/20231205\/1701743796582915.png\" alt=\"2\" \/><\/section>\n<section><strong>\u56fe<\/strong><strong>2.\u00a0<\/strong>a)\u00a0PEVE\u964d\u89e3\u7684\u65f6\u95f4\u63a7\u5236\uff1bb)\u00a0NHPI\u4ecb\u5bfcPEVE\u964d\u89e3\u7684\u50ac\u5316\u5faa\u73af<\/section>\n<section><\/section>\n<section>\u00a0\u00a0\u00a0\u00a0\u968f\u540e\u4f5c\u8005\u5c06\u8be5\u7b56\u7565\u5e94\u7528\u4e8e\u5176\u4ed6\u805a\u5408\u7269\uff08\u56fe3\uff09\u3002\u7ed3\u679c\u8868\u660e\uff0c\u8be5\u65b9\u6cd5\u5bf9\u542b\u6709\u5bcc\u7535\u5b50C-H\u952e\u7684\u805a\u4e59\u70ef\u57fa\u919a\u548c\u805a\u919a\u5177\u6709\u51fa\u8272\u7684\u9009\u62e9\u6027\uff08\u56fe3a-c\uff09\u3002\u800c\u7531\u4e8e\u4eb2\u7535\u81ea\u7531\u57fa\u4e0e\u7f3a\u7535\u5b50C-H\u952e\u95f4\u6781\u6027\u4e0d\u5339\u914d\uff0c\u8be5\u65b9\u6cd5\u4e0d\u4f1a\u964d\u89e3\u53ea\u542b\u6709\u7f3a\u7535\u5b50C-H\u952e\u7684\u805a\u5408\u7269\uff08\u56fe3d-f\uff09\u3002\u7531\u6b64\u5373\u53ef\u5b9e\u73b0\u542b\u919a\u805a\u5408\u7269\u7684\u9009\u62e9\u6027\u964d\u89e3\u3002<\/section>\n<section><img decoding=\"async\" title=\"8\" src=\"https:\/\/17332.seohost.cn\/storage\/17332\/article\/20231205\/1701743806796898.png\" alt=\"8\" \/><\/section>\n<section><strong>\u56fe<\/strong><strong>3.<\/strong>\u00a0\u8be5\u7535\u5316\u5b66\u964d\u89e3\u7b56\u7565\u7684\u9009\u62e9\u6027<\/section>\n<section><\/section>\n<section>\u00a0\u00a0\u00a0\u00a0\u7efc\u4e0a\u6240\u8ff0\uff0c\u672c\u6587\u5f00\u53d1\u4e86\u4e00\u79cd\u6e29\u548c\u3001\u5ec9\u4ef7\u3001\u9ad8\u6548\u7684\u7535\u50ac\u5316\u964d\u89e3\u805a\u919a\u548c\u805a\u4e59\u70ef\u57fa\u919a\u7684\u7b56\u7565\uff0c\u5e76\u5bf9\u5176\u673a\u7406\u3001\u9009\u62e9\u6027\u548c\u6548\u7387\u8fdb\u884c\u4e86\u7814\u7a76\uff0c\u4e3a\u9ad8\u6027\u80fd\u805a\u5408\u7269\u7684\u964d\u89e3\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\u548c\u65b9\u6cd5\u3002<\/section>\n<section><\/section>\n<section><strong>\u4f5c\u8005\uff1a<\/strong>LCY\u00a0\u00a0<strong>\u5ba1\u6821<\/strong>\uff1aWLT<\/section>\n<section><strong>D<\/strong><strong>OI:<\/strong>\u00a010.1002\/anie.202316578<\/section>\n<section><strong>Link:\u00a0<\/strong>https:\/\/doi.org\/10.1002\/anie.202316578<\/section>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u7ed9\u5927\u5bb6\u5206\u4eab\u4e00\u7bc7\u6700\u8fd1\u53d1\u8868\u5728Angew. Chem. Int. Ed.\u7684\u7814\u7a76\u8fdb\u5c55\uff0c\u9898\u4e3a\uff1aSelective\u00a0Ele [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-49616","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/49616","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=49616"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/49616\/revisions"}],"predecessor-version":[{"id":49617,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/49616\/revisions\/49617"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=49616"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=49616"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=49616"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}