{"id":49199,"date":"2023-10-28T08:10:10","date_gmt":"2023-10-28T00:10:10","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=49199"},"modified":"2023-10-11T10:10:44","modified_gmt":"2023-10-11T02:10:44","slug":"angew-chem-%ef%bc%9a%e6%b0%ae%e6%9d%82%e7%8e%af%e5%8d%a1%e5%ae%be%e5%82%ac%e5%8c%96%e9%9d%9e%e6%b4%bb%e5%8c%96%e7%83%b7%e5%9f%ba%e5%8d%a4%e4%bb%a3%e7%89%a9%e7%9a%84%e7%9b%b4%e6%8e%a5%e9%85%b0","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/angew-chem-%ef%bc%9a%e6%b0%ae%e6%9d%82%e7%8e%af%e5%8d%a1%e5%ae%be%e5%82%ac%e5%8c%96%e9%9d%9e%e6%b4%bb%e5%8c%96%e7%83%b7%e5%9f%ba%e5%8d%a4%e4%bb%a3%e7%89%a9%e7%9a%84%e7%9b%b4%e6%8e%a5%e9%85%b0\/","title":{"rendered":"Angew. Chem. \uff1a\u6c2e\u6742\u73af\u5361\u5bbe\u50ac\u5316\u975e\u6d3b\u5316\u70f7\u57fa\u5364\u4ee3\u7269\u7684\u76f4\u63a5\u9170\u5316\u53cd\u5e94"},"content":{"rendered":"<section>\n<section>\n<section>\n<section>\n<section>\u916e\u662f\u4f17\u591a\u6709\u673a\u5316\u5408\u7269\u7684\u91cd\u8981\u7ec4\u6210\u780c\u5757\u4e4b\u4e00\uff0c\u901a\u8fc7\u919b\u7c7b\u5316\u5408\u7269\u6765\u9ad8\u6548\u6784\u5efa\u916e\u57fa\u9aa8\u67b6\u5177\u6709\u5f88\u597d\u7684\u5e94\u7528\u4ef7\u503c\u3002\u4f20\u7edf\u7531\u919b\u5230\u916e\u7684\u8f6c\u5316\u5f80\u5f80\u9700\u8981\u5f53\u91cf\u7684\u91d1\u5c5e\u8bd5\u5242\u548c\u591a\u6b65\u53cd\u5e94\u7684\u8f6c\u5316\u8fc7\u7a0b\uff0c\u4e5f\u53ef\u4ee5\u901a\u8fc7\u5916\u6e90\u6c27\u5316\u5242\u53c2\u4e0e\u7684\u91d1\u5c5e\u50ac\u5316\u7684\u5076\u8054\u53cd\u5e94\u5b9e\u73b0\u7b49\u3002\u8fd1\u5e74\u6765\uff0c\u5316\u5b66\u5bb6\u53d1\u73b0\u916e\u7c7b\u5316\u5408\u7269\u8fd8\u53ef\u4ee5\u901a\u8fc7\u919b\u4e0e\u5364\u4ee3\u7269\u7684\u76f4\u63a5\u9170\u5316\u53cd\u5e94\uff0c\u8fdb\u884c\u9ad8\u6548\u5236\u5907\u3002\u7136\u800c\uff0c\u8be5\u5408\u6210\u7b56\u7565\u53d7\u9650\u4e8e\u5364\u4ee3\u7269\u7684\u7535\u6027\u5236\u7ea6\uff0c\u7279\u522b\u662f\u5bf9\u4e8e\u975e\u6d3b\u5316\u7684\u4e2d\u6027\u70f7\u57fa\u5364\u4ee3\u7269\u7684\u9170\u5316\u51e0\u4e4e\u672a\u89c1\u62a5\u9053\u3002\u6700\u8fd1\uff0c\u5b9e\u73b0\u919b\u4e0e\u975e\u6d3b\u5316\u5364\u4ee3\u7269\u7684\u9170\u5316\u7b56\u7565\u4e3b\u8981\u662f\u901a\u8fc7\u91d1\u5c5e\u954d\/\u5149\/\u6709\u673a\u7684\u534f\u540c\u50ac\u5316 (<em>MacMillan, et al, J. Am. Chem. Soc. 2017, 139, 11353\u221211356.<\/em>)\uff0c\u4ee5\u53ca\u4ecb\u79bb\u5b50\u5361\u5bbe\u81ea\u7531\u57fa\u50ac\u5316 (<em>Bertrand, Yan, et al, Angew. Chem. Int. Ed. 2023, 62, e202303478.<\/em>)\u7b49\u5355\u7535\u5b50\u53cd\u5e94\u9014\u5f84\uff0c\u800c\u53cc\u7535\u5b50\u7684\u6781\u6027\u53cd\u5e94\u9014\u5f84\u8fd8\u672a\u89c1\u62a5\u9053\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<p>&nbsp;<\/p>\n<section>\n<section><\/section>\n<\/section>\n<p>&nbsp;<\/p>\n<section><img decoding=\"async\" title=\"1\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20231007\/1696647514209057.png\" alt=\"1\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u6210\u90fd\u5927\u5b66\u836f\u5b66\u9662\u3001\u56db\u5ddd\u6297\u83cc\u7d20\u5de5\u4e1a\u7814\u7a76\u6240\u674e\u4fca\u9f99\u6559\u6388\u56e2\u961f\u957f\u671f\u81f4\u529b\u4e8e\u6c2e\u6742\u73af\u5361\u5bbe\u50ac\u5316\u7684\u65b0\u53cd\u5e94\u5f00\u53d1\uff08<em>Angew. Chem. Int. Ed. 2020, 132, 1879; Angew. Chem. Int. Ed. 2022, 61, e202116629; Angew. Chem. Int. Ed. 2022, 61, e202207824; Chem. Sci. 2022, 13, 2584<\/em>\uff09\u3002\u6700\u8fd1\uff0c\u8be5\u56e2\u961f\u53c8\u62a5\u9053\u4e86\u4e00\u4f8b\u6c2e\u6742\u73af\u5361\u5bbe\u50ac\u5316\u919b\u4e0e\u975e\u6d3b\u5316\u5364\u4ee3\u7269\u76f4\u63a5\u9170\u5316\u53cd\u5e94(Angew. Chem. Int. Ed. 2023, e202309572.\uff09\u3002\u673a\u7406\u7814\u7a76\u8868\u660e\uff0c\u8be5\u53cd\u5e94\u662f\u901a\u8fc7\u53cc\u7535\u5b50\u5386\u7a0b\u7684\u4eb2\u6838\u53d6\u4ee3\u5b9e\u73b0\u82b3\u9170\u5316\u8fc7\u7a0b\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"2\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20231007\/1696647526455249.png\" alt=\"2\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u8be5\u53cd\u5e94\u4ee5\u4e09\u6c2e\u5511\u7c7b\u578b\u7684\u6c2e\u6742\u73af\u5361\u5bbe\u4e3a\u50ac\u5316\u5242\uff0c\u5728\u7eff\u8272\u6e29\u548c\u7684\u6761\u4ef6\u4e0b\uff0c\u80fd\u591f\u9ad8\u6548\u5730\u5b9e\u73b0\u82b3\u57fa\u919b\u4e0e\u591a\u7c7b\u975e\u6d3b\u5316\u5364\u4ee3\u70c3\u7684\u9170\u5316\u5076\u8054\uff0c\u5c55\u73b0\u51fa\u826f\u597d\u7684\u5e95\u7269\u666e\u9002\u6027\u3002\u6b64\u5916\uff0c\u5929\u7136\u4ea7\u7269\u7684\u540e\u4fee\u9970\u4e5f\u9a8c\u8bc1\u4e86\u8be5\u53cd\u5e94\u826f\u597d\u7684\u5b98\u80fd\u56e2\u517c\u5bb9\u6027\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"3\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20231007\/1696647536308771.png\" alt=\"3\" \/><\/section>\n<section><img decoding=\"async\" title=\"4\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20231007\/1696647551663861.png\" alt=\"4\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u6700\u540e\uff0c\u4f5c\u8005\u5bf9\u53cd\u5e94\u673a\u7406\u8fdb\u884c\u4e86\u6df1\u5165\u8003\u5bdf\u3002\u9996\u5148\uff0c\u81ea\u7531\u57fa\u949f\u5b9e\u9a8c\uff0c\u4ee5\u53ca1\u00b0\u5364\u4ee3\u7269\u4e0e2\u00b0\u5364\u4ee3\u7269\u7684\u7ade\u4e89\u5b9e\u9a8c\uff0c\u8868\u660e\u53cd\u5e94\u53ef\u80fd\u4e0d\u662f\u7ecf\u8fc7\u81ea\u7531\u57fa\u5386\u7a0b\uff0c\u800c\u662f\u7ecf\u8fc7\u4eb2\u6838\u53d6\u4ee3\u7684\u6781\u6027\u53cd\u5e94\u5386\u7a0b\u3002\u9664\u6b64\u4e4b\u5916\uff0c\u5f53\u624b\u6027\u70f7\u57fa\u5364\u4ee3\u7269\u53c2\u4e0e\u8be5\u53cd\u5e94\u65f6\uff0c\u80fd\u591f\u5f97\u5230\u624b\u6027\u4fdd\u7559\u7684\u9170\u5316\u4ea7\u7269\uff0c\u8fdb\u4e00\u6b65\u8bc1\u660e\u8be5\u53cd\u5e94\u53ef\u80fd\u662f\u901a\u8fc7SN2\u7c7b\u578b\u7684\u4eb2\u6838\u53d6\u4ee3\u5b8c\u6210\u82b3\u9170\u5316\u8fc7\u7a0b\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"6\" src=\"https:\/\/9794.seohost.cn\/storage\/9794\/article\/20231007\/1696647565508743.png\" alt=\"6\" \/><\/section>\n<p>&nbsp;<\/p>\n<p>&nbsp;<\/p>\n<section>\n<section>\n<section>\n<section><strong>\u8bba<\/strong><strong>\u6587\u4fe1\u606f<\/strong><\/p>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section><\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>Direct Acylation of Unactivated Alkyl Halides with Aldehydes through N-Heterocyclic Carbene Organocatalysis<\/p>\n<p>Dr. Qing-Zhu Li,\u00a0Rong Zeng,\u00a0Peng-Shuai Xu,\u00a0Xin-Hang Jin,\u00a0Chuan Xie,\u00a0Qi-Chun Yang,\u00a0Dr. Xiang Zhang,\u00a0Prof.\u2005Dr. Jun-Long Li<\/p>\n<p><em>Angewandte Chemie International Edition<\/em><\/p>\n<p>DOI:\u00a010.1002\/anie.202309572<\/p>\n<\/section>\n<\/section>\n<\/section>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u916e\u662f\u4f17\u591a\u6709\u673a\u5316\u5408\u7269\u7684\u91cd\u8981\u7ec4\u6210\u780c\u5757\u4e4b\u4e00\uff0c\u901a\u8fc7\u919b\u7c7b\u5316\u5408\u7269\u6765\u9ad8\u6548\u6784\u5efa\u916e\u57fa\u9aa8\u67b6\u5177\u6709\u5f88\u597d\u7684\u5e94\u7528\u4ef7\u503c\u3002\u4f20\u7edf\u7531\u919b\u5230\u916e\u7684\u8f6c\u5316\u5f80 [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-49199","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/49199","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=49199"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/49199\/revisions"}],"predecessor-version":[{"id":49200,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/49199\/revisions\/49200"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=49199"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=49199"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=49199"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}