{"id":49078,"date":"2023-10-11T08:52:05","date_gmt":"2023-10-11T00:52:05","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=49078"},"modified":"2023-09-22T09:53:01","modified_gmt":"2023-09-22T01:53:01","slug":"%e5%b4%94%e6%98%a5%e5%8d%8e-%e6%a2%81%e5%90%9b%e6%ad%a6nature%e5%ad%90%e5%88%8a%ef%bc%9a%e5%90%88%e6%88%90%e8%bf%87%e7%a8%8b%e4%b8%ad%e5%bc%95%e5%85%a5cl%e2%88%92%ef%bc%8c%e6%8a%91%e5%88%b6cooxcly","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/%e5%b4%94%e6%98%a5%e5%8d%8e-%e6%a2%81%e5%90%9b%e6%ad%a6nature%e5%ad%90%e5%88%8a%ef%bc%9a%e5%90%88%e6%88%90%e8%bf%87%e7%a8%8b%e4%b8%ad%e5%bc%95%e5%85%a5cl%e2%88%92%ef%bc%8c%e6%8a%91%e5%88%b6cooxcly\/","title":{"rendered":"\u5d14\u6625\u534e\/\u6881\u541b\u6b66Nature\u5b50\u520a\uff1a\u5408\u6210\u8fc7\u7a0b\u4e2d\u5f15\u5165Cl\u2212\uff0c\u6291\u5236CoOxCly\u53d1\u751fOER\u53cd\u5e94\u5e76\u52a0\u901f\u9178\u6027CER"},"content":{"rendered":"<section>Cl<sub>2<\/sub>\u662f\u4e00\u79cd\u91cd\u8981\u7684\u5316\u5b66\u54c1\uff0c\u5e7f\u6cdb\u5e94\u7528\u4e8e\u6c34\u5904\u7406\u3001\u6709\u673a\u5408\u6210\u548c\u805a\u6c2f\u4e59\u70ef\u751f\u4ea7\u3002\u6c2f\u78b1\u5de5\u4e1a\u4e2dCl<sub>2<\/sub>\u4e3b\u8981\u901a\u8fc7\u7535\u5316\u5b66\u6790\u6c2f\u53cd\u5e94(CER)\u4ea7\u751f\uff0c\u5176\u4e2d\u6790\u6c27\u53cd\u5e94(OER)\u4e0eCER\u5728\u6c34\u6eb6\u6db2\u4e2d\u5177\u6709\u76f8\u4f3c\u7684\u8d77\u59cb\u7535\u4f4d\u548c\u7c7b\u4f3c\u7684\u50ac\u5316\u6d3b\u6027\u4f4d\u70b9\uff0c\u56e0\u6b64\u4fdd\u8bc1Cl<sub>2<\/sub>\u7684\u9ad8\u9009\u62e9\u6027\u751f\u6210\u662f\u4e00\u4e2a\u5de8\u5927\u7684\u6311\u6218\u3002<\/section>\n<p>&nbsp;<\/p>\n<section>\u7528\u4e8eCER\u7684\u6700\u5148\u8fdb\u7684\u5de5\u4e1a\u7535\u89e3\u69fd\u901a\u5e38\u4f7f\u7528\u57fa\u4e8e\u9ad8\u6210\u672c\u8d35\u91d1\u5c5e(Ru\u6216Ir)\u7684\u76f8\u5bf9\u8010\u9178\u7684\u6df7\u5408\u91d1\u5c5e\u6c27\u5316\u7269\uff0c\u8fd9\u4e9b\u91d1\u5c5e\u6c27\u5316\u7269\u5bf9OER\u4e5f\u5177\u6709\u9ad8\u5ea6\u6d3b\u6027\u3002<\/section>\n<section>\u4e3a\u4e86\u786e\u4fddCER\u7cfb\u7edf\u7684\u9ad8\u6548\u7387\u548c\u63d0\u9ad8Cl<sub>2<\/sub>\u7684\u9009\u62e9\u6027\uff0c\u9700\u8981\u9ad8\u6d53\u5ea6\u7684Cl<sup>\u2212<\/sup>\u79bb\u5b50(5.0 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\/><\/section>\n<section>\u8fd1\u65e5\uff0c<strong>\u7535\u5b50\u79d1\u6280\u5927\u5b66\u5d14\u6625\u534e<\/strong>\u548c<strong>\u7389\u6797\u5e08\u8303\u5b66\u9662\u6881\u541b\u6b66<\/strong>\u7b49\u5728\u542b\u6709Co<sup>2+<\/sup>\u548cCl<sup>\u2212<\/sup>\u7684\u76d0\u6eb6\u6db2\u4e2d\uff0c\u5728pH\u22642\u7684F\u63ba\u6742\u4e8c\u6c27\u5316\u9521(FTO)\u88f8\u7535\u6781\u4e0a\u539f\u4f4d\u6c89\u79ef\u4e00\u79cd\u81ea\u9002\u5e94\u7684\u975e\u6676\u6001CoO<sub>x<\/sub>Cl<sub>y<\/sub>\u50ac\u5316\u5242\uff0c\u7528\u4e8e\u9ad8\u6548\u548c\u9009\u62e9\u6027\u50ac\u5316CER\u3002\u5b9e\u9a8c\u7ed3\u679c\u8868\u660e\uff0c\u57281.67 V\u4e0b\u7535\u6c89\u79ef2\u5c0f\u65f6\u540e\u5f97\u5230\u7684CoO<sub>x<\/sub>Cl<sub>y<\/sub>\u50ac\u5316\u5242\u5b9e\u73b0\u4e86\u7ea6100%\u7684Cl<sub>2<\/sub>\u9009\u62e9\u6027\uff0c\u4e14\u5f53Cl<sup>\u2212<\/sup>\u7684\u6d53\u5ea6\u964d\u4f4e\u81f30.01 M\u65f6\uff0cCl<sub>2<\/sub>\u7684\u9009\u62e9\u6027\u4ecd\u4fdd\u630190\u00b11.5%\u3002<\/section>\n<section>\u6b64\u5916\uff0c\u57281.67 V\u4e0b\u6c89\u79ef\u7684CoO<sub>x<\/sub>Cl<sub>y<\/sub>\u50ac\u5316\u5242\u572810 mA cm<sup>-2<\/sup>\u4e0b\u8fde\u7eed\u8fd0\u884c500\u5c0f\u65f6\uff0c\u7535\u6d41\u5bc6\u5ea6\u5728\u6d4b\u8bd5\u4e2d\u5347\u81f315 mA cm<sup>-2<\/sup>\uff1b\u540c\u65f6\uff0cCoO<sub>x<\/sub>Cl<sub>y<\/sub>\u50ac\u5316\u5242\u5728250 mA cm<sup>-2<\/sup><sub>geo<\/sub>\u4e0b\u53ef\u4ee5\u8fde\u7eed\u8fd0\u884c20\u5c0f\u65f6\u4ee5\u4e0a\uff0c\u8868\u660e\u8be5\u50ac\u5316\u5242\u5177\u6709\u4f18\u5f02\u7684\u7a33\u5b9a\u6027\u3002<\/section>\n<section><img decoding=\"async\" title=\"3\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230918\/1695003634872190.jpg\" alt=\"3\" \/><\/section>\n<section><img decoding=\"async\" title=\"7\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230918\/1695003643490163.jpg\" alt=\"7\" \/><\/section>\n<section>\u539f\u4f4d\u5149\u8c31\u548c\u7406\u8bba\u8ba1\u7b97\u8868\u660e\uff0c\u5728\u7535\u6c89\u79ef\u8fc7\u7a0b\u4e2d\u5f15\u5165Cl<sup>\u2212<\/sup>\u79bb\u5b50\uff0c\u53ef\u4ee5\u589e\u52a0Co\u7535\u5b50\u7535\u8377\u5e76\u964d\u4f4e\u4ef7\u6001\uff0c\u80fd\u591f\u6291\u5236\u6709\u5229\u4e8e\u6c34\u6c27\u5316\u7684\u9ad8\u6c27\u5316\u6001Co\u4f4d\u70b9\u7684\u5f62\u6210\uff0c\u63d0\u9ad8\u4e86CER\u4e2dCl<sub>2<\/sub>\u7684\u9009\u62e9\u6027\uff1b\u540c\u65f6\uff0cCl<sup>\u2212<\/sup>\u79bb\u5b50\u7684\u5f15\u5165\u5141\u8bb8CER\u7684\u6d3b\u6027\u4f4d\u4eceCo*\u5411Co-O*\u8f6c\u53d8\uff0cCER\u7684\u9009\u62e9\u6027\u901a\u8fc7Volmer-Heyrovsky\u8def\u5f84\u5f97\u5230\u63d0\u9ad8\u3002<\/section>\n<section>\u603b\u7684\u6765\u8bf4\uff0c\u8fd9\u9879\u5de5\u4f5c\u5c06\u53cd\u5e94\u7269Cl<sup>\u2212<\/sup>\u81ea\u8eab\u4f5c\u4e3a\u4fc3\u8fdb\u5242\u63d0\u9ad8\u4e86\u9178\u6027\u76d0\u6c34\u4e2dCER\u7684\u6d3b\u6027\u548c\u9009\u62e9\u6027\uff0c\u4e3a\u7a33\u5b9a\u975e\u8d35\u91d1\u5c5e\u6c27\u5316\u7269\u5728\u5f3a\u9178\u4e2d\u7684\u9633\u6781\u7535\u50ac\u5316\u53cd\u5e94\u63d0\u4f9b\u4e86\u8303\u4f8b\u3002<\/section>\n<section>Self-adaptive Amorphous CoO<sub>x<\/sub>Cl<sub>y<\/sub>\u00a0Electrocatalyst for Sustainable Chlorine Evolution in Acidic Brine. Nature Communications, 2023. DOI: 10.1038\/s41467-023-41070-7<\/section>\n<section><\/section>\n<section><\/section>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Cl2\u662f\u4e00\u79cd\u91cd\u8981\u7684\u5316\u5b66\u54c1\uff0c\u5e7f\u6cdb\u5e94\u7528\u4e8e\u6c34\u5904\u7406\u3001\u6709\u673a\u5408\u6210\u548c\u805a\u6c2f\u4e59\u70ef\u751f\u4ea7\u3002\u6c2f\u78b1\u5de5\u4e1a\u4e2dCl2\u4e3b\u8981\u901a\u8fc7\u7535\u5316\u5b66\u6790\u6c2f\u53cd\u5e94(C [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-49078","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/49078","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=49078"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/49078\/revisions"}],"predecessor-version":[{"id":49079,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/49078\/revisions\/49079"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=49078"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=49078"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=49078"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}