{"id":48999,"date":"2023-09-29T08:52:36","date_gmt":"2023-09-29T00:52:36","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=48999"},"modified":"2023-09-12T09:53:16","modified_gmt":"2023-09-12T01:53:16","slug":"eurjic%ef%bc%9a%e8%bf%87%e6%b8%a1%e9%87%91%e5%b1%9e%e9%92%bc%e5%9f%ba%e5%92%8c%e9%94%b0%e5%9f%ba%e9%85%8d%e5%90%88%e7%89%a9%e4%b8%ad%e6%8a%93%e6%b0%a2%e7%9b%b8%e4%ba%92%e4%bd%9c%e7%94%a8%e7%9a%84","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/eurjic%ef%bc%9a%e8%bf%87%e6%b8%a1%e9%87%91%e5%b1%9e%e9%92%bc%e5%9f%ba%e5%92%8c%e9%94%b0%e5%9f%ba%e9%85%8d%e5%90%88%e7%89%a9%e4%b8%ad%e6%8a%93%e6%b0%a2%e7%9b%b8%e4%ba%92%e4%bd%9c%e7%94%a8%e7%9a%84\/","title":{"rendered":"EurJIC\uff1a\u8fc7\u6e21\u91d1\u5c5e\u94bc\u57fa\u548c\u9530\u57fa\u914d\u5408\u7269\u4e2d\u6293\u6c22\u76f8\u4e92\u4f5c\u7528\u7684\u7406\u8bba\u7814\u7a76"},"content":{"rendered":"<section>\n<section>\n<section>\n<section>\n<section>\u6293\u6c22\u952e\u53ca\u5176\u6293\u6c22\u76f8\u4e92\u4f5c\u7528(agostic interaction)\u5728\u6709\u673a\u91d1\u5c5e\u5316\u5b66\u548c\u5747\u76f8\u50ac\u5316\u4e2d\u5177\u6709\u91cd\u8981\u7684\u4f5c\u7528\uff0c\u5176\u7a81\u51fa\u4f53\u73b0\u5728\u6709\u673a\u91d1\u5c5e\u914d\u5408\u7269\u50ac\u5316\u7684\u805a\u5408\u53cd\u5e94\u3001C-H\u952e\u6d3b\u5316\u3001b-\u6c22\u5316\u6d88\u9664\u53cd\u5e94\u548c\u73af\u91d1\u5c5e\u5316\u53cd\u5e94\u4e2d\u3002\u56e0\u6b64\uff0c\u5bf9\u6293\u6c22\u952e\u53ca\u5176\u6293\u6c22\u76f8\u4e92\u4f5c\u7528\u7684\u7814\u7a76\u5177\u6709\u91cd\u8981\u7684\u5b9e\u9645\u4ef7\u503c\u548c\u7406\u8bba\u610f\u4e49\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<p>&nbsp;<\/p>\n<section>\n<section><\/section>\n<\/section>\n<p>&nbsp;<\/p>\n<section><img decoding=\"async\" title=\"1\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230906\/1693966645216392.png\" alt=\"1\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u8fc7\u6e21\u91d1\u5c5e\u94bc\u57fa\u6293\u6c22\u914d\u5408\u7269 [CpMo(CO)<sub>2<\/sub>(PiPr<sub>3<\/sub>)]<sup>+<\/sup>[B(C<sub>6<\/sub>F<sub>5<\/sub>)<sub>4<\/sub>]<sup>\u2013<\/sup>\u00a0\u5177\u6709b\/g\u4e24\u79cd\u7ed3\u6784\u5dee\u5f02\u7684\u6293\u6c22\u5f02\u6784\u4f53(<strong>Mo, 1<\/strong>\u548c<strong>Mo, 2<\/strong>)\uff0c\u5176\u56fa\u6001X-ray\u5316\u5b66\u7ed3\u6784\u8bc1\u5b9e\u4e86\u6293\u6c22\u76f8\u4e92\u4f5c\u7528\u7684\u5b58\u5728\u3002\u9530\u57fa\u914d\u5408\u7269[(C<sub>6<\/sub>H<sub>9<\/sub>]Mo(CO)<sub>3<\/sub>]\u662f\u53e6\u5916\u4e00\u4e2a\u503c\u5f97\u6df1\u7a76\u7684\u6293\u6c22\u914d\u5408\u7269\uff0c\u5176\u540c\u6837\u5b58\u5728\u03b1\/\u03b5\u79cd\u7ed3\u6784\u5dee\u5f02\u7684\u6293\u6c22\u5f02\u6784\u4f53(<strong>Mn, 1<\/strong>\u548c<strong>Mn, 2<\/strong>)\u3002\u7136\u800c\uff0c\u94bc\u57fa\u03b2\/\u03b3\u6293\u6c22\u5f02\u6784\u4f53(<strong>Mo, 1<\/strong>\u548c<strong>Mo, 2<\/strong>)\u4e4b\u95f4\u7684\u76f8\u4e92\u8f6c\u5316\u8fc7\u7a0b\u53ca\u5176\u6293\u6c22\u952e\u7684\u5f3a\u5ea6\u6682\u672a\u88ab\u5b8c\u5168\u9610\u660e\uff0c\u540c\u65f6\u4e0a\u8ff0\u95ee\u9898\u4e5f\u5b58\u5728\u4e8e\u9530\u57fa\u03b1\/\u03b5\u6293\u6c22\u5f02\u6784\u4f53(<strong>Mn, 1<\/strong>\u548c<strong>Mn, 2<\/strong>)\u3002\u56e0\u6b64\uff0c\u5bf9\u8fc7\u6e21\u91d1\u5c5e\u94bc\u57fa\u03b2\/\u03b3\u6293\u6c22\u914d\u5408\u7269\u548c\u9530\u57fa\u03b1\/\u03b5\u6293\u6c22\u914d\u5408\u7269\u7684\u7814\u7a76\u8fd8\u9700\u6df1\u5165\u63a2\u7d22\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"2\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230906\/1693966653391969.png\" alt=\"2\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u8fd1\u65e5\uff0c\u897f\u5b89\u5916\u4e8b\u5b66\u9662\u7684\u9752\u5e74\u6559\u5e08\u5f20\u654f\u535a\u58eb\u3001\u9752\u5e74\u6559\u5e08\u5f20\u5a49\u83c1\u548c\u897f\u5b89\u7535\u5b50\u79d1\u6280\u5927\u5b66\u7684\u534e\u5c71\u83c1\u82f1\u526f\u6559\u6388\u6881\u5e7f\u8d85\u535a\u58eb\u5171\u540c\u5bf9\u4e0a\u8ff0\u94bc\u57fa\u03b2\/\u03b3\u6293\u6c22\u914d\u5408\u7269\u548c\u9530\u57fa\u03b1\/\u03b5\u6293\u6c22\u914d\u5408\u7269\u4e2d\u7684\u6293\u6c22\u952e\u53ca\u5176\u6293\u6c22\u76f8\u4e92\u4f5c\u7528\u8fdb\u884c\u4e86\u8be6\u7ec6\u7684\u7406\u8bba\u7814\u7a76\u3002\u57fa\u4e8e\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u7684\u8ba1\u7b97\u7ed3\u679c\u8868\u660e\u94bc\u57fab\u6293\u6c22\u914d\u5408\u7269\u7684\u5409\u5e03\u65af\u81ea\u7531\u80fd\u4ec5\u6bd4\u94bc\u57fa\u03b3\u6293\u6c22\u914d\u5408\u7269\u4f4e0.5 kcal\/mol\uff0c\u4e14\u5176\u76f8\u4e92\u8f6c\u5316\u7684\u5409\u5e03\u65af\u52bf\u5792\u4e3a9.1 kcal\/mol\u3002\u9530\u57fa\u03b1\/\u03b5\u6293\u6c22\u5f02\u6784\u4f53\u4e4b\u95f4\u5f02\u6784\u5316\u7684\u5409\u5e03\u65af\u52bf\u5792\u7565\u9ad8\uff0c\u4e3a12.7 kcal\/mol\u3002\u6a21\u578b\u8ba1\u7b97\u8868\u660e\uff0c\u5728\u94bc\u57fa\u03b2\/\u03b3\u6293\u6c22\u5f02\u6784\u4f53\u4e2d\uff0c\u7531\u6293\u6c22\u76f8\u4e92\u4f5c\u7528\u5f15\u8d77\u7684\u7a33\u5b9a\u80fd\u5206\u522b\u4e3a16.7 kcal\/mol\u548c13.1 kcal\/mol\u3002\u800c\u5bf9\u4e8e\u9530\u57fa\u03b1\/\u03b5\u6293\u6c22\u5f02\u6784\u4f53\uff0c\u5176\u6293\u6c22\u76f8\u4e92\u4f5c\u7528\u5f15\u8d77\u7684\u7a33\u5b9a\u80fd\u5206\u522b\u4e3a21.8 kcal\/mol\u548c16.4 kcal\/mol\u3002\u94bc\u57fa\u03b2\/\u03b3\u6293\u6c22\u5f02\u6784\u4f53\u548c\u9530\u57fa\u03b1\/\u03b5\u6293\u6c22\u5f02\u6784\u4f53\u7684\u76f8\u5bf9\u7a33\u5b9a\u6027\u4e5f\u88ab\u5176\u51e0\u4f55\u53c2\u6570\u3001Wiberg\u952e\u6307\u6570\u3001Mayer\u952e\u5e8f\u548cAIM\u5206\u6790\u6240\u9a8c\u8bc1\u3002\u57fa\u4e8e\u6293\u6c22\u952e\u53ca\u5176\u6293\u6c22\u76f8\u4e92\u4f5c\u7528\u5728\u6709\u673a\u91d1\u5c5e\u914d\u5408\u7269\u50ac\u5316\u7684b-\u6c22\u5316\u7269\u6d88\u9664\u3001\u73af\u91d1\u5c5e\u5316\u548cC-H\u952e\u6d3b\u5316\u4e2d\u7684\u91cd\u8981\u4f5c\u7528\uff0c\u672c\u7814\u7a76\u4e2d\u5173\u4e8e\u6293\u6c22\u76f8\u4e92\u4f5c\u7528\u7684\u8ba4\u77e5\u6709\u52a9\u4e8e\u52a0\u6df1\u5bf9\u4e0a\u8ff0\u6d89\u53ca\u7684\u50ac\u5316\u8fc7\u7a0b\u7684\u7406\u89e3\uff0c\u5e76\u7740\u5b9e\u4fc3\u8fdb\u65b0\u578b\u6709\u673a\u91d1\u5c5e\u6293\u6c22\u914d\u5408\u7269\u7684\u5f00\u53d1\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"9\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230906\/1693966664441203.png\" alt=\"9\" \/><\/section>\n<section>\n<section>\n<section>\n<section><strong>\u8bba<\/strong><strong>\u6587\u4fe1\u606f<\/strong><\/p>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section><\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>Theoretical Investigations on the Agostic Interactions of the Molybdenum and Manganese Complexes<\/p>\n<p>Dr. Min Zhang, Wanjing Zhang, Dr. Guangchao Liang<\/p>\n<p><em>European Journal of Inorganic Chemistry<\/em><\/p>\n<p>DOI: 10.1002\/ejic.202300183<\/p>\n<\/section>\n<\/section>\n<\/section>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u6293\u6c22\u952e\u53ca\u5176\u6293\u6c22\u76f8\u4e92\u4f5c\u7528(agostic interaction)\u5728\u6709\u673a\u91d1\u5c5e\u5316\u5b66\u548c\u5747\u76f8\u50ac\u5316\u4e2d\u5177\u6709\u91cd\u8981\u7684\u4f5c\u7528\uff0c\u5176\u7a81 [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-48999","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/48999","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=48999"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/48999\/revisions"}],"predecessor-version":[{"id":49000,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/48999\/revisions\/49000"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=48999"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=48999"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=48999"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}