{"id":48989,"date":"2023-09-27T08:14:12","date_gmt":"2023-09-27T00:14:12","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=48989"},"modified":"2023-09-11T10:14:53","modified_gmt":"2023-09-11T02:14:53","slug":"%e5%8f%b6%e5%9b%bd%e5%ae%89-%e6%ac%a7%e9%98%b3%e5%ba%94%e6%a0%b9nature%e5%ad%90%e5%88%8a%ef%bc%9a%e7%a6%bb%e5%ad%90cof%e9%ab%98%e6%95%88%e9%80%89%e6%8b%a9%e6%80%a7%e6%8d%95%e8%8e%b7%e9%92%8d%e7%a6%bb","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/%e5%8f%b6%e5%9b%bd%e5%ae%89-%e6%ac%a7%e9%98%b3%e5%ba%94%e6%a0%b9nature%e5%ad%90%e5%88%8a%ef%bc%9a%e7%a6%bb%e5%ad%90cof%e9%ab%98%e6%95%88%e9%80%89%e6%8b%a9%e6%80%a7%e6%8d%95%e8%8e%b7%e9%92%8d%e7%a6%bb\/","title":{"rendered":"\u53f6\u56fd\u5b89\/\u6b27\u9633\u5e94\u6839Nature\u5b50\u520a\uff1a\u79bb\u5b50COF\u9ad8\u6548\u9009\u62e9\u6027\u6355\u83b7\u948d\u79bb\u5b50"},"content":{"rendered":"
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 <\/p>\n

\"1\"<\/section>\n
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[Th(OH)3<\/sub>(H2<\/sub>O)4<\/sub>]+<\/sup>\u7247\u6bb5\u4e0ePy-TFImI-25 COF\u9aa8\u67b6\u4e2d\u7684N-C=N-<\/sub>\u76f8\u4e92\u4f5c\u7528\uff0c\u8ba1\u7b97\u51faTh-N\u952e\u8ddd\u79bb\u4e3a2.586 \u00c5\u3002\u7531\u4e8e\u5438\u9644\u90e8\u4f4d\u7684\u4f4d\u963b\u4f5c\u7528\uff0c\u5728\u5438\u9644\u8fc7\u7a0b\u4e2d\u4f1a\u91ca\u653e\u4e00\u4e2aH2<\/sub>O\u5206\u5b50\u3002\u8ba1\u7b97\u7684\u5438\u9644\u80fd\u4e3a-105.5 kcal mol-1<\/sup>\uff0c\u4e0e\u6eb6\u5242\u73af\u5883\u4e0bTh(IV)\u4e0ePy-TFImI-25 COF\u9aa8\u67b6\u76f8\u4e92\u4f5c\u7528\u7684\u60c5\u51b5\u76f8\u5f53\uff0c\u8868\u660e\u540e\u7eed\u90e8\u5206\u4f7f\u7528\u7684\u91d1\u5c5e\u9633\u79bb\u5b50\u6a21\u578b\u662f\u5408\u7406\u7684\u3002<\/section>\n
\"2\"<\/section>\n
\u6b64\u5916\uff0c\u4f5c\u8005\u8fd8\u8ba1\u7b97\u7406\u8bba\u91d1\u5c5e\u9633\u79bb\u5b50\u4e0e\u5438\u9644\u5242\u4e4b\u95f4\u7684\u5438\u9644\u4f4d\u80fd\u3002\u4e0d\u540c\u9633\u79bb\u5b50\u7684\u5438\u9644\u6784\u578b\u76f8\u540c\uff0c\u6240\u6709\u52a0\u5408\u7269\u7684\u0394Eads<\/sub>\u503c\u5747\u4e3a\u8d1f\u503c\uff0c\u8868\u660ePy-TFIm-25 COF\u4e0a\u7684N-C=N-<\/sub>\u548cPy-TFIm-25 COF\u4e0a\u7684NIm<\/sub>\u662f\u5438\u9644\u4f4d\u70b9\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0cPy-TFIm-25 COF\u4e0a\u7684\u5438\u9644\u80fd\u7edd\u5bf9\u503c\u5747\u5927\u4e8ePy-TFImI-25 COF\u4e0a\u7684\u76f8\u5e94\u80fd\uff0c\u8bf4\u660ePy-TFIm-25 COF\u5728NIm<\/sub>\u4e0a\u5bf9\u91d1\u5c5e\u9633\u79bb\u5b50\u7684\u5438\u9644\u5f3a\u5ea6\u6709\u6240\u63d0\u9ad8\u3002<\/section>\n
\"3\"<\/section>\n
Efficient and selective capture of thorium ions by a covalent organic framework.\u00a0Nat. Commun.,\u00a0<\/em>2023<\/strong>, DOI: https:\/\/doi.org\/10.1038\/s41467-023-40704-0.<\/section>\n

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