{"id":48952,"date":"2023-09-21T08:58:09","date_gmt":"2023-09-21T00:58:09","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=48952"},"modified":"2023-09-05T09:58:33","modified_gmt":"2023-09-05T01:58:33","slug":"%e5%8c%96%e5%ad%a6%e6%89%80angew%ef%bc%9apd-uns-cl-gdy%e9%ab%98%e6%95%88%e5%82%ac%e5%8c%96%e7%94%b2%e9%86%87%e6%b0%a7%e5%8c%96%e5%8f%8d%e5%ba%94","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/%e5%8c%96%e5%ad%a6%e6%89%80angew%ef%bc%9apd-uns-cl-gdy%e9%ab%98%e6%95%88%e5%82%ac%e5%8c%96%e7%94%b2%e9%86%87%e6%b0%a7%e5%8c%96%e5%8f%8d%e5%ba%94\/","title":{"rendered":"\u5316\u5b66\u6240Angew\uff1aPd-UNs\/Cl-GDY\u9ad8\u6548\u50ac\u5316\u7532\u9187\u6c27\u5316\u53cd\u5e94"},"content":{"rendered":"<section>\u901a\u8fc7\u539f\u5b50\u6392\u5217\u6765\u63a7\u5236\u50ac\u5316\u5242\u7684\u7ed3\u6784\u548c\u6027\u80fd\u662f\u751f\u4ea7\u65b0\u4e00\u4ee3\u9ad8\u7ea7\u50ac\u5316\u5242\u7684\u6e90\u6cc9\uff0c\u5176\u4e2d\u50ac\u5316\u5242\u5728\u50ac\u5316\u53cd\u5e94\u4e2d\u7684\u9ad8\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\u5f88\u5927\u7a0b\u5ea6\u4e0a\u53d6\u51b3\u4e8e\u91d1\u5c5e\u539f\u5b50\u7684\u7406\u60f3\u6392\u5217\u7ed3\u6784\u3002\u57fa\u4e8e\u6b64\uff0c<strong>\u4e2d\u56fd\u79d1\u5b66\u9662\u5316\u5b66\u7814\u7a76\u6240\u674e\u7389\u826f\u9662\u58eb\u7b49\u4eba<\/strong>\u62a5\u9053\u4e86\u901a\u8fc7\u77f3\u58a8\u7094\uff08GDY\uff09\u4e2dsp-C\u4e0e\u6c2f\uff08Cl\uff09\u952e\u7ed3\u5408\uff0c\u57283D\u6d77\u80c6\u72b6\u94af\u7eb3\u7c73\u9897\u7c92\uff08Pd-UNs\/Cl-GDY\uff09\u4e2d\u5f15\u5165\u5bcc\u7f3a\u9677\u7ed3\u6784\u3001\u4f4e\u914d\u4f4d\u6570\uff08CN\uff09\u548c\u62c9\u4f38\u5e94\u53d8\uff0c\u53ef\u8c03\u8282Pd\u7eb3\u7c73\u9897\u7c92\u4e2d\u91d1\u5c5e\u539f\u5b50\u7684\u6392\u5217\uff0c\u5f62\u6210\u7279\u6b8a\u7684\u7ed3\u6784\u3002Pd-UNs\/Cl-GDY\u50ac\u5316\u7532\u9187\u6c27\u5316\u53cd\u5e94\uff08MOR\uff09\u65f6\uff0c\u5177\u6709\u8f83\u9ad8\u7684\u7535\u6d41\u5bc6\u5ea6\uff08363.6 mA cm<sup>\u22122<\/sup>\uff09\u548c\u8d28\u91cf\u6d3b\u6027\uff083.6 A mg<sub>Pd<\/sub><sup>\u22121<\/sup>\uff09\uff0c\u5206\u522b\u662fPd\u7eb3\u7c73\u9897\u7c92\u768412.0\u500d\u548c10.9\u500d\u3002\u6b64\u5916\uff0cPd-UNs\/Cl-GDY\u50ac\u5316\u5242\u57282000\u6b21\u5faa\u73af\u540e\u4ecd\u4fdd\u630195%\u7684\u6d3b\u6027\u3002<\/section>\n<p>&nbsp;<\/p>\n<section><img decoding=\"async\" title=\"1\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230830\/1693362333321731.jpg\" alt=\"1\" \/><\/section>\n<section>\u901a\u8fc7DFT\u8ba1\u7b97\uff0c\u4f5c\u8005\u7814\u7a76\u4e86Pd-UNs\/Cl-GDY\u7684\u9ad8MOR\u6027\u80fd\u3002\u901a\u8fc7Pd-UNs\/Cl-GDY\u4e2dPd\u539f\u5b50\u7684d-\u6295\u5f71\u504f\u6001\u5bc6\u5ea6\u53d1\u73b0\uff0cPd-UNs\/Cl-GDY\u7684d\u6ce2\u6bb5\u4e2d\u5fc3\u6bd4Pd-NPs\/CC\u66f4\u63a5\u8fd1\u8d39\u7c73\u80fd\u7ea7\u3002<\/section>\n<section>\u7ed3\u679c\u8868\u660e\uff0cPd-UNs\/Cl-GDY\u4e2dTBs\u7684\u5b58\u5728\u5bfc\u81f4Pd\u7684d\u5e26\u4e2d\u5fc3\u6709\u8f7b\u5fae\u7684\u4e0a\u79fb\uff0c\u4f7fd\u5e26\u4e2d\u5fc3\u66f4\u52a0\u5408\u9002\u3002\u540c\u65f6\uff0cPd-UNs\/Cl-GDY\u7684\u9876\u4ef7\u5e26\u6bd4Pd-NPs\/CC\u66f4\u63a5\u8fd1\u8d39\u7c73\u80fd\u7ea7\uff0c\u8bf4\u660ePd-UNs\/Cl-GDY\u7684\u7535\u5bfc\u7387\u66f4\u9ad8\u3002<\/section>\n<section><img decoding=\"async\" title=\"2\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230830\/1693362340357231.jpg\" alt=\"2\" \/><\/section>\n<section>\u6b64\u5916\uff0c\u901a\u8fc7DFT\u8ba1\u7b97\uff0c\u4f5c\u8005\u8fd8\u8bf4\u660e\u4e86Pd-UNs\/Cl-GDY\u7684MOR\u548cCO\u53cd\u5e94\u9014\u5f84\u3002DFT\u8ba1\u7b97\u8868\u660e\uff0c\u9ad8\u80fd\u53cd\u5e94\u9014\u5f84\u7684\u6240\u6709\u6b65\u9aa4\u90fd\u662f\u653e\u70ed\u7684\u3002\u57280.44 V\u4e0b\uff0cPd-UNs\/Cl-GDY\u5bf9CO\u7684\u5438\u9644\u8fdc\u5f31\u4e8ePd-NPs\/CC\uff0c\u53ef\u80fd\u662f\u7531\u4e8e\u5bcc\u542b\u7f3a\u9677\u7684\u7ed3\u6784\u6291\u5236\u4e86\u50ac\u5316\u5242\u7684\u4e2d\u6bd2\u4f5c\u7528\u3002\u57280.66 V\u65f6\uff0cMOR\u548cCO\u9014\u5f84\u53ef\u4ee5\u540c\u65f6\u53d1\u751f\u3002\u5177\u6709\u4e30\u5bcc\u7f3a\u9677\u7ed3\u6784\u7684Pd-UNs\/Cl-GDY\u6bd4Pd-NPs\/CC\u66f4\u5bb9\u6613\u5f62\u6210COOH*\uff0c\u6709\u5229\u4e8e\u4eceCO<sub>ads<\/sub>\u8f6c\u5316\u4e3aCO<sub>2<\/sub>\u3002<\/section>\n<section>\u7ed3\u679c\u8868\u660e\uff0c\u4f18\u5f02\u7684MOR\u6027\u80fd\u53ef\u80fd\u5f52\u56e0\u4e8e\u5728Pd-UNs\/Cl-GDY\u50ac\u5316\u5242\u4e2d\u5f15\u5165\u4e86\u5bcc\u7f3a\u9677\u7ed3\u6784\uff0c\u964d\u4f4e\u4e86CN\u5e76\u5bfc\u81f4\u4e86\u9ad8\u62c9\u4f38\u5e94\u53d8\uff0c\u4ece\u800c\u8c03\u6574\u4e86Pd\u8868\u9762\u4e0a\u8d1f\u8f7d\u7684\u5438\u9644\u80fd\u529b\uff0c\u589e\u5f3a\u4e86\u5176\u7a33\u5b9a\u6027\u548c\u6297\u4e2d\u6bd2\u80fd\u529b\u3002<\/section>\n<section><img decoding=\"async\" title=\"0\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230830\/1693362350509643.jpg\" alt=\"0\" \/><\/section>\n<section>Defect Rich Structure Activated 3D Palladium Catalyst for Methanol Oxidation Reaction.\u00a0<em>Angew. Chem. Int. Ed.,\u00a0<\/em><strong>2023<\/strong>, DOI: https:\/\/doi.org\/10.1002\/anie.202308968.<\/section>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u901a\u8fc7\u539f\u5b50\u6392\u5217\u6765\u63a7\u5236\u50ac\u5316\u5242\u7684\u7ed3\u6784\u548c\u6027\u80fd\u662f\u751f\u4ea7\u65b0\u4e00\u4ee3\u9ad8\u7ea7\u50ac\u5316\u5242\u7684\u6e90\u6cc9\uff0c\u5176\u4e2d\u50ac\u5316\u5242\u5728\u50ac\u5316\u53cd\u5e94\u4e2d\u7684\u9ad8\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\u5f88\u5927\u7a0b [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-48952","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/48952","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=48952"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/48952\/revisions"}],"predecessor-version":[{"id":48953,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/48952\/revisions\/48953"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=48952"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=48952"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=48952"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}