{"id":48932,"date":"2023-09-18T08:54:54","date_gmt":"2023-09-18T00:54:54","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=48932"},"modified":"2023-09-01T09:55:21","modified_gmt":"2023-09-01T01:55:21","slug":"angew-chem-%ef%bc%9a%e5%bc%ba%e5%8c%96%e6%b0%b4%e5%88%86%e5%ad%90o-h%e5%85%b1%e4%bb%b7%e9%94%ae%e6%8b%93%e5%b1%95%e6%b0%b4%e7%b3%bb%e7%94%b5%e8%a7%a3%e6%b6%b2%e7%9a%84%e7%a8%b3%e5%ae%9a%e6%80%a7","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/angew-chem-%ef%bc%9a%e5%bc%ba%e5%8c%96%e6%b0%b4%e5%88%86%e5%ad%90o-h%e5%85%b1%e4%bb%b7%e9%94%ae%e6%8b%93%e5%b1%95%e6%b0%b4%e7%b3%bb%e7%94%b5%e8%a7%a3%e6%b6%b2%e7%9a%84%e7%a8%b3%e5%ae%9a%e6%80%a7\/","title":{"rendered":"Angew. Chem. \uff1a\u5f3a\u5316\u6c34\u5206\u5b50O-H\u5171\u4ef7\u952e\u62d3\u5c55\u6c34\u7cfb\u7535\u89e3\u6db2\u7684\u7a33\u5b9a\u6027\u7a97\u53e3"},"content":{"rendered":"<section>\n<section>\n<section>\n<section>\n<section>\u672c\u5de5\u4f5c\u5173\u6ce8\u4e00\u4e2a\u770b\u4f3c\u7b80\u5355\u7684\u95ee\u9898\uff1a\u54ea\u4e9b\u56e0\u7d20\u5f71\u54cd\u6c34\u7684\u7535\u89e3\u53cd\u5e94\uff0c\u5373\u6c34\u7684\u6790\u6c22\u3001\u6790\u6c27\u53cd\u5e94\u3002\u6c34\u7684\u6790\u6c22\u3001\u6790\u6c27\u53cd\u5e94\u7684\u7535\u52bf\u754c\u5b9a\u4e86\u6c34\u7cfb\u7535\u6c60\u4e2d\u7535\u89e3\u8d28\u6eb6\u6db2\u7684\u53ef\u5229\u7528\u7535\u5316\u5b66\u7a97\u53e3\u3002\u901a\u5e38\u8ba4\u4e3a\u6c34\u5206\u5b50\u7684O-H\u5171\u4ef7\u952e\u5f3a\u5ea6\u662f\u6c34\u7cfb\u7535\u89e3\u6db2\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u7684\u51b3\u5b9a\u56e0\u7d20\u3002\u672c\u5de5\u4f5c\u8ba4\u4e3a\u8fd9\u6837\u7684\u770b\u6cd5\u5e76\u4e0d\u5168\u9762\u3002\u4e00\u4e2a\u7535\u5316\u5b66\u53cd\u5e94\u7684\u7535\u52bf\u5e94\u8be5\u51b3\u5b9a\u4e8e\u4e00\u4e2a\u80fd\u91cf\u5dee\uff1b\u5b83\u662f\u53cd\u5e94\u7269\u548c\u4ea7\u7269\u4e4b\u95f4\u7684\u81ea\u7531\u80fd\u4e4b\u5dee\u3002\u8fd9\u91cc\u7535\u89e3\u7684\u53cd\u5e94\u7269\u662f\u6c34\u3002\u5f53\u7136\u6c34\u5206\u5b50\u7684O-H\u5171\u4ef7\u952e\u8d8a\u5f3a\uff0c\u5b83\u8d8a\u7a33\u5b9a\uff0c\u4ece\u800c\u6c34\u7cfb\u7535\u89e3\u6db2\u7684\u7535\u5316\u5b66\u7a97\u53e3\u5c31\u6108\u5bbd\u3002\u4f46\u662f\u5e38\u5e38\u88ab\u5ffd\u89c6\u7684\u662f\uff1a\u5728\u6c34\u7684\u7535\u89e3\u53cd\u5e94\u4e2d\uff0c\u6790\u6c22\u7684\u4ea7\u7269\u4e0d\u53ea\u662f\u6c22\u6c14\uff0c\u8fd8\u6709\u6eb6\u5242\u5316\u7684\u6c22\u6c27\u6839\u79bb\u5b50\uff1b\u540c\u6837\u6790\u6c27\u7684\u4ea7\u7269\u4e0d\u53ea\u662f\u6c27\u6c14\u8fd8\u6709\u6eb6\u5242\u5316\u7684\u8d28\u5b50\u3002\u6c14\u4f53\u6790\u51fa\u4fbf\u79bb\u5f00\u6eb6\u6db2\u4f53\u7cfb\uff0c\u6240\u4ee5\u65e0\u8bba\u6eb6\u6db2\u662f\u600e\u6837\u7684\u5316\u5b66\u73af\u5883\uff0c\u90fd\u4e0d\u4f1a\u5f71\u54cd\u6c14\u4f53\u4ea7\u7269\u7684\u81ea\u7531\u80fd\u3002\u4f46\u662f\u7535\u89e3\u6db2\u7684\u5316\u5b66\u73af\u5883\u5bf9\u4e8e\u6c22\u6c27\u6839\u548c\u8d28\u5b50\u7684\u6eb6\u5242\u5316\u70ed\u4f1a\u6709\u5f88\u5927\u7684\u5f71\u54cd\u3002\u90a3\u4e48\u4ec0\u4e48\u6837\u7684\u5316\u5b66\u73af\u5883\u4e0d\u5229\u4e8e\u8fd9\u4e9b\u79bb\u5b50\u7684\u6eb6\u5242\u5316\u5462\uff1f\u5982\u679c\u627e\u5230\u4e86\u8fd9\u6837\u7684\u5316\u5b66\u73af\u5883\uff0c\u5c31\u53ef\u4ee5\u901a\u8fc7\u8bbe\u8ba1\u53bb\u62d3\u5c55\u6c34\u7cfb\u7535\u89e3\u6db2\u7684\u7a33\u5b9a\u6027\u7a97\u53e3\u3002<\/p>\n<p>\u7f8e\u56fd\u4fc4\u52d2\u5188\u5dde\u7acb\u5927\u5b66\u7eaa\u79c0\u78ca\u6559\u6388\uff0c\u65b9\u7fc0\u6559\u6388\uff0c\u548c\u7f8e\u56fd\u52a0\u5dde\u5927\u5b66\u6cb3\u6ee8\u5206\u6821\u7684P. Alex Greaney\u6559\u6388\u62a5\u9053\u4e86\u5171\u6676\u6c34\u6eb6\u6db2\u7684\u7535\u5316\u5b66\u7a97\u53e3\u4ece\u5ba4\u6e29\u4e0b\u7684 1.74 V\u589e\u52a0\u81f3 \u201378 \u00b0C\u4e0b\u7684 3.03 V\uff0c\u5e76\u4e14\u63d0\u51fa\u4e86\u65b0\u7684\u62d3\u5c55\u6c34\u7cfb\u7535\u89e3\u6db2\u7535\u5316\u5b66\u7a97\u53e3\u7684\u6d1e\u89c1\uff1a\u5373\u5f53\u7535\u89e3\u6db2\u4e2d\u5316\u5b66\u73af\u5883\u4e0d\u5229\u4e8e\u6c22\u6c27\u6839\u3001\u8d28\u5b50\u7684\u6eb6\u5242\u5316\u65f6\uff0c\u6c34\u6eb6\u6db2\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u7a97\u53e3\u4f1a\u62d3\u5bbd\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<p>&nbsp;<\/p>\n<section>\n<section><\/section>\n<\/section>\n<p>&nbsp;<\/p>\n<section><img decoding=\"async\" title=\"1\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230828\/1693206727846428.png\" alt=\"1\" \/><\/section>\n<section><img decoding=\"async\" title=\"2\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230828\/1693206734731293.png\" alt=\"2\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u8868\u5f81\u7ed3\u679c\u5305\u62ec\u98de\u79d2\u53d7\u6fc0\u62c9\u66fc\u5149\u8c31 (FSRS)\u3001\u6838\u78c1\u5171\u632f\u5149\u8c31 (NMR) \u548c\u5206\u5b50\u52a8\u529b\u5b66 (AIMD) \u6a21\u62df\u8868\u660e25% LiCl\u6eb6\u6db2\u4e2d\u6c34\u7684 O-H \u5171\u4ef7\u952e\u5728 \u201378 \u00b0C\u65f6\u5e76\u672a\u589e\u5f3a\uff0c\u5e76\u4e14\u4f3c\u4e4e\u51cf\u5f31\u4e86\u3002\u56e0\u6b64\uff0c\u5728\u4f4e\u6e29\u6761\u4ef6\u4e0b\u6269\u5bbd\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u7a97\u53e3\u4e0d\u80fd\u7528O-H\u952e\u5f3a\u5ea6\u7684\u4f20\u7edf\u89c2\u70b9\u6765\u89e3\u91ca\u3002\u4f5c\u8005\u53d1\u73b0\u5c06 25 % LiCl \u51b7\u5374\u81f3 \u201378 \u00b0C \u4f1a\u6539\u53d8\u7535\u89e3\u8d28\u7684\u5c40\u90e8\u6eb6\u5242\u5316\u7ed3\u6784\uff1a(1) \u9502\u79bb\u5b50\u7684\u914d\u4f4d\u58f3\u51fa\u73b0\u90e8\u5206\u8131\u6c34\uff0c(2) \u4e3a Li<sup>+<\/sup>\u2013Cl<sup>\u2013<\/sup>\u00a0\u914d\u5bf9\u52a0\u5f3a\uff0c(3) \u6c34\u4e2d\u7684\u6c22\u539f\u5b50\u4e0e\u6c2f\u79bb\u5b50\u7684\u7ed3\u5408\u66f4\u52a0\u7d27\u5bc6\u3002\u8fd9\u4e9b\u53d8\u5316\u4e0d\u5229\u4e8e\u6c22\u6c27\u6839\u548c\u8d28\u5b50\u7684\u6eb6\u5242\u5316\u3002\u6211\u4eec\u5bf9\u542b\u6709\u6c22\u6c27\u6839\u548c\u8d28\u5b50\u7684\u7535\u89e3\u8d28\u7684 AIMD \u6a21\u62df\u5f3a\u5316\u4e86\u8fd9\u4e00\u7ed3\u8bba\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"9\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230828\/1693206743849847.png\" alt=\"9\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u4e3a\u4e86\u5c55\u793a25% LiCl\u6c34\u7cfb\u7535\u89e3\u8d28\u4f4e\u6e29\u6761\u4ef6\u4e0b\u7684\u7a33\u5b9a\u6027\uff0c\u6211\u4eec\u4f7f\u7528\u8fd9\u4e2a\u7535\u89e3\u8d28\u5728\u201378 \u00b0C\u5c55\u793a\u4e86\u7531LiMn<sub>2<\/sub>O<sub>4<\/sub>\u00a0\u6b63\u6781\u548c CuSe \u8d1f\u6781\u7ec4\u6210\u7684\u5168\u7535\u6c60\u6c34\u7cfb\u9502\u79bb\u5b50\u7535\u6c60\u3002\u5176\u57fa\u4e8e\u7535\u6781\u8d28\u91cf\u7684\u80fd\u91cf\u5bc6\u5ea6\u8fbe\u5230\u7684 109 Wh\/kg\u3002\u8fd9\u4e9b\u7ed3\u679c\u663e\u793a\u4e86\u6c34\u7cfb\u7535\u6c60\u5728\u6781\u5730\u548c\u7a7a\u95f4\u63a2\u7d22\u4efb\u52a1\u4e2d\u7684\u6f5c\u529b\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section><strong>\u8bba<\/strong><strong>\u6587\u4fe1\u606f<\/strong><\/p>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section><\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>Strengthening Aqueous Electrolytes without Strengthening Water<\/p>\n<p>Dr. Longteng Tang,\u00a0Dr. Yunkai Xu,\u00a0Weiyi Zhang,\u00a0Yiming Sui,\u00a0Alexis Scida,\u00a0Sean R. Tachibana,\u00a0Mounesha Garaga,\u00a0Sean K. Sandstrom,\u00a0Nan-Chieh Chiu,\u00a0Prof. Kyriakos C. Stylianou,\u00a0Prof. Steve G. Greenbaum,\u00a0Prof. Peter Alex Greaney,\u00a0Prof. Chong Fang,\u00a0Prof. Xiulei Ji<\/p>\n<p><em>Angewandte Chemie International Edition<\/em><\/p>\n<p>DOI:\u00a010.1002\/anie.202307212<\/p>\n<\/section>\n<\/section>\n<\/section>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u672c\u5de5\u4f5c\u5173\u6ce8\u4e00\u4e2a\u770b\u4f3c\u7b80\u5355\u7684\u95ee\u9898\uff1a\u54ea\u4e9b\u56e0\u7d20\u5f71\u54cd\u6c34\u7684\u7535\u89e3\u53cd\u5e94\uff0c\u5373\u6c34\u7684\u6790\u6c22\u3001\u6790\u6c27\u53cd\u5e94\u3002\u6c34\u7684\u6790\u6c22\u3001\u6790\u6c27\u53cd\u5e94\u7684\u7535\u52bf\u754c\u5b9a\u4e86\u6c34 [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-48932","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/48932","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=48932"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/48932\/revisions"}],"predecessor-version":[{"id":48933,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/48932\/revisions\/48933"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=48932"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=48932"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=48932"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}