{"id":48851,"date":"2023-09-05T10:03:19","date_gmt":"2023-09-05T02:03:19","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=48851"},"modified":"2023-08-21T10:04:38","modified_gmt":"2023-08-21T02:04:38","slug":"chem-asian-j-%ef%bc%9a%e5%85%89%e6%b0%a7%e5%8c%96%e8%bf%98%e5%8e%9f%e4%bb%8b%e5%af%bc%e7%9a%84iriii-niii-%e5%a5%8e%e5%ae%81%e5%82%ac%e5%8c%96csp3-%e2%80%92csp2-%e4%ba%a4","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/chem-asian-j-%ef%bc%9a%e5%85%89%e6%b0%a7%e5%8c%96%e8%bf%98%e5%8e%9f%e4%bb%8b%e5%af%bc%e7%9a%84iriii-niii-%e5%a5%8e%e5%ae%81%e5%82%ac%e5%8c%96csp3-%e2%80%92csp2-%e4%ba%a4\/","title":{"rendered":"Chem. Asian J. \uff1a\u5149\u6c27\u5316\u8fd8\u539f\u4ecb\u5bfc\u7684Ir(III)\/Ni(II)\/\u594e\u5b81\u50ac\u5316C(sp3) \u2012C(sp2) \u4ea4"},"content":{"rendered":"<section>\n<section>\n<section>\n<section>\n<section>C\u2012C\u952e\u4ee5\u53caC\u2012X\uff08X=N\u3001S\u3001P\uff09\u952e\u9aa8\u67b6\u5e7f\u6cdb\u5b58\u5728\u4e8e\u751f\u7269\uff0c\u836f\u7269\uff0c\u5de5\u4e1a\u7b49\u9886\u57df\u3002\u8fd1\u5e74\u6765\uff0c\u5149\u50ac\u5316\u4e0e\u8fc7\u6e21\u91d1\u5c5e\u534f\u540c\u50ac\u5316\u4f5c\u7528\uff0c\u5df2\u7ecf\u6210\u529f\u5730\u6784\u5efa\u4e86\u5404\u79cdC\u2012C\u4ee5\u53caC\u2012X\u952e\u3002\u5176\u53cd\u5e94\u673a\u5236\u5305\u62ec\u4e24\u79cd\uff1a\u6c27\u5316\u8fd8\u539f\u673a\u5236\u4ee5\u53ca\u80fd\u91cf\u8f6c\u79fb\u673a\u5236\uff08\u56fe1\uff09\u3002\u5728\u6c27\u5316\u8fd8\u539f\u673a\u5236\u4e2d\uff0c\u4e00\u65b9\u9762\u5149\u50ac\u5316\u5242\u53ef\u4ee5\u4e0e\u591a\u79cd\u5e95\u7269\u76f4\u63a5\u53cd\u5e94\uff0c\u751f\u6210\u6d3b\u6027\u81ea\u7531\u57fa\u7269\u79cd\u53c2\u4e0e\u540e\u7eed\u53cd\u5e94\u8fc7\u7a0b\uff0c\u79f0\u4e4b\u4e3a\u81ea\u7531\u57fa\u673a\u5236\uff08\u56fe1 A1\uff09\uff1b\u53e6\u4e00\u65b9\u9762\u5149\u50ac\u5316\u5242\u53ef\u4ee5\u901a\u8fc7SET(\u5355\u7535\u5b50\u8f6c\u79fb)\u8c03\u8282\u8fc7\u6e21\u91d1\u5c5e\u7684\u4ef7\u6001\uff0c\u79f0\u4e4b\u4e3a\u4ef7\u6001\u8c03\u8282\u673a\u5236\uff08\u56fe1 A2\uff09\u3002\u5728\u80fd\u91cf\u8f6c\u79fb\u673a\u5236\u4e2d\uff0c\u6fc0\u53d1\u6001\u7684\u5149\u50ac\u5316\u5242\u4e0e\u57fa\u6001\u7684\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u5242\u8fdb\u884c\u80fd\u91cf\u8f6c\u79fb\u8fc7\u7a0b\uff0c\u6709\u673a\u5408\u6210\u4e2d\u901a\u5e38\u4e3a\u5fb7\u514b\u65af\u7279\uff08Dexter\uff09\u7535\u5b50\u4ea4\u6362\u673a\u5236\uff0c\u751f\u6210\u57fa\u6001\u7684\u5149\u50ac\u5316\u5242\u4e0e\u6fc0\u53d1\u6001\u7684\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u5242\u3002\u968f\u7740\u8be5\u79cd\u50ac\u5316\u7b56\u7565\u7684\u53d1\u5c55\uff0c\u5229\u7528\u5149\u4ecb\u5bfc\u7684\u4e09\u50ac\u5316\u4f53\u7cfb\u5df2\u6210\u4e3a\u5728\u6e29\u548c\u6761\u4ef6\u4e0b\u5b9e\u73b0C\u2012C\u4ea4\u53c9\u5076\u8054\u53cd\u5e94\u7684\u6709\u6548\u65b9\u6cd5\u3002\u4e09\u50ac\u5316\u4f53\u7cfb\u901a\u5e38\u5305\u62ec\u5149\u50ac\u5316\uff0c\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u4ee5\u53ca\u6709\u673a\u50ac\u5316\u5faa\u73af\u3002\u8be5\u79cd\u50ac\u5316\u7b56\u7565\u5728\u5b9e\u9a8c\u4e0a\u5df2\u7ecf\u53d6\u5f97\u4e86\u5927\u91cf\u6210\u679c\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<p>&nbsp;<\/p>\n<section>\n<section><\/section>\n<\/section>\n<p>&nbsp;<\/p>\n<section><img decoding=\"async\" title=\"1\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230816\/1692154809602058.png\" alt=\"1\" \/><\/section>\n<section>\u56fe1.\u53ef\u89c1\u5149\u4ecb\u5bfc\u7684\u53cc\u91d1\u5c5e\u534f\u540c\u50ac\u5316\u673a\u5236<\/p>\n<\/section>\n<section><img decoding=\"async\" title=\"2\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230816\/1692154817512172.png\" alt=\"2\" \/><\/section>\n<section>\u56fe2. (a)N-Boc\u5421\u54af\u70f7\u4e0e\u7532\u57fa-4-\u6eb4\u82ef\u7532\u916f\u5728IrIII\/NiII\u91d1\u5c5e\u5149\u6c27\u5316\u8fd8\u539f\u50ac\u5316\u4e0b\u7684C(sp<sup>3<\/sup>)\u2012C(sp<sup>2<\/sup>)\u4ea4\u53c9\u5076\u8054\uff1b(b)\u672c\u5de5\u4f5c\u6240\u7814\u7a76\u7684\u50ac\u5316\u5242<\/p>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u4e00\u4e2a\u6781\u5177\u4ee3\u8868\u6027\u7684\u4f8b\u5b50\u662fMacmillan\u8bfe\u9898\u7ec4\u6240\u62a5\u9053\u7684\u5149\u4ecb\u5bfc\u7684Ir\/Ni\/3-\u4e59\u9170\u6c27\u57fa\u594e\u5b81\u50ac\u5316\u6742\u82b3\u57fa\u6eb4\u4e0eN-Boc\u5421\u54af\u70f7\u8fdb\u884cC(sp<sup>2<\/sup>) \u2012C(sp<sup>3<\/sup>)\u4ea4\u53c9\u5076\u8054\u53cd\u5e94\uff0c\u53cd\u5e94\u4ea7\u7387\u4e3a85%\uff0c\u800c\u5f53\u594e\u5b81\u65e0\u5438\u7535\u5b50\u53d6\u4ee3\u57fa\u65f6\u53cd\u5e94\u4ea7\u7387\u5927\u5927\u964d\u4f4e\uff08<em>Science 2016, 352, 1304\u20131308<\/em>\uff09\u3002\u7136\u800c\uff0c\u5176\u53cd\u5e94\u673a\u7406\u5c24\u5176\u662f\u6709\u673a\u78b1\u594e\u5b81\u7684\u4f5c\u7528\u4ecd\u4e0d\u6e05\u6670\u3002\u8fd1\u65e5\uff0c\u4e1c\u5317\u5e08\u8303\u5927\u5b66\u5173\u5a01\u6559\u6388\u548c\u6731\u535a\u526f\u6559\u6388\u8bfe\u9898\u7ec4\u5bf9\u4e8e\u4e0a\u8ff0\u53cd\u5e94\u8fdb\u884c\u4e86\u7406\u8bba\u7814\u7a76\uff0c\u63ed\u793a\u5176\u53cd\u5e94\u673a\u5236\uff0c\u9610\u660e\u6709\u673a\u78b1\u7684\u4f5c\u7528\u4ee5\u53ca\u89e3\u91ca\u5176\u53d6\u4ee3\u57fa\u6548\u5e94\uff0c\u4e3a\u8bbe\u8ba1\u8be5\u50ac\u5316\u4f53\u7cfb\u63d0\u4f9b\u4e00\u5b9a\u7684\u7406\u8bba\u57fa\u7840\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<p>&nbsp;<\/p>\n<p>&nbsp;<\/p>\n<section><img decoding=\"async\" title=\"3\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230816\/1692154826316656.png\" alt=\"3\" \/><\/section>\n<section>\u56fe3. \u954d\u50ac\u5316\u5faa\u73af(Ni<sup>II<\/sup>\u00a0\u2012 Ni<sup>I<\/sup>\u00a0\u2012 Ni<sup>III<\/sup>\u00a0\u2012 [Ni<sup>III<\/sup>]<sup>\u229d<\/sup>\u2012Ni<sup>II<\/sup>)<\/p>\n<\/section>\n<section><img decoding=\"async\" title=\"4\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230816\/1692154851428977.png\" alt=\"4\" \/><\/section>\n<section>\u56fe4.\u00a0[Ni<sup>III<\/sup>]<sup>\u229d<\/sup>\u4e2d\u95f4\u4f53\u7684\u81ea\u7136\u952e\u8f68\u9053<\/p>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u5177\u4f53\u800c\u8a00\uff0cDFT\u8ba1\u7b97\u53d1\u73b0\u8be5\u53cd\u5e94\u4e3a\u81ea\u7531\u57fa\u673a\u5236\uff0c\u7531\u8fd8\u539f\u731d\u706d\u7684\u5149\u6c27\u5316\u8fd8\u539f\u5faa\u73af(Ir<sup>III<\/sup>\u00a0\u2012*Ir<sup>III<\/sup>\u00a0\u2012Ir<sup>II<\/sup>\u00a0\u2012Ir<sup>III<\/sup>) \u4ee5\u53caNi\u50ac\u5316\u5faa\u73af(Ni<sup>II<\/sup>\u00a0\u2012 Ni<sup>I<\/sup>\u00a0\u2012 Ni<sup>III<\/sup>\u00a0\u2012 [Ni<sup>III<\/sup>]<sup>\u229d<\/sup>\u2012NiII)\u548c3-\u4e59\u9170\u6c27\u57fa\u594e\u5b81\u4ecb\u5bfc\u7684HAT\uff08\u6c22\u539f\u5b50\u8f6c\u79fb\uff09\u50ac\u5316\u5faa\u73af\u7ec4\u6210\uff08\u56fe3\uff09\u3002\u5176\u4e2d\u6709\u673a\u78b1\u4f5c\u4e3a\u6c22\u539f\u5b50\u8f6c\u79fb\u8fc7\u7a0b\u7684\u50ac\u5316\u5242\uff0c\u9009\u62e9\u6027\u7684\u652b\u53d6N-Boc\u5421\u54af\u70f7\u5e95\u7269\u03b1-C\u4f4d\u7684\u6c22\u539f\u5b50\uff0c\u751f\u6210\u76f8\u5e94\u7684\u81ea\u7531\u57fa\u53c2\u4e0e\u540e\u7eed\u7684\u53cd\u5e94\u8fc7\u7a0b\u3002\u901a\u8fc7\u81ea\u7136\u952e\u8f68\u9053\uff08NBO\uff09\u8bc1\u5b9e\u4e86\u5404\u4e2a\u954d\u4e2d\u95f4\u4f53\u7684\u6c27\u5316\u6001\uff0c\u5e76\u53d1\u73b0\u5728\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u5f62\u6210\u4e86\u4e0d\u5bfb\u5e38\u7684[Ni<sup>III<\/sup>]<sup>\u229d<\/sup>\u5316\u5408\u7269 \uff08\u56fe4\uff09\u3002\u6b64\u5916\uff0c\u5f53\u65e0\u5438\u7535\u5b50\u57fa\u56e2\u594e\u5b81\u4f5c\u4e3a\u50ac\u5316\u5242\u65f6\uff0c\u954d\u50ac\u5316\u5faa\u73af\u4e3aNi<sup>II<\/sup>\u00a0\u2012 Ni<sup>I<\/sup>\u00a0\u2012 Ni<sup>II<\/sup>\u00a0\u2012 [Ni<sup>III<\/sup>]<sup>\u229d<\/sup>\u2012Ni<sup>II<\/sup>\uff0c\u8be5\u53cd\u5e94\u8def\u5f84\u80fd\u5792\u8fc7\u9ad8\uff0c\u65e0\u6cd5\u5728\u5b9e\u9a8c\u6761\u4ef6\u4e0b\u514b\u670d\uff0c\u4e0e\u5b9e\u9a8c\u4e8b\u5b9e\u4e00\u81f4\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section><strong>\u8bba<\/strong><strong>\u6587\u4fe1\u606f<\/strong><\/p>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section><\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>Theoretical Mechanistic Study of C(sp<sup>3<\/sup>)\u2012C(sp<sup>2<\/sup>) Cross-Coupling by Photoredox-Mediated Iridium(III)\/Nickel(II)\/Quinuclidine Triple Catalysis<\/p>\n<p>Shuang Wang, Runhan Li, Zhongmin Su, Bo Zhu,* and Wei Guan*<\/p>\n<p>\u6587\u7ae0\u7684\u7b2c\u4e00\u4f5c\u8005\u662f\u4e1c\u5317\u5e08\u8303\u5927\u5b66\u535a\u58eb\u7814\u7a76\u751f\u738b\u723d\u3002<\/p>\n<p><em>Chemistry \u2013 An Asian Journal<\/em><\/p>\n<p>DOI:\u00a010.1002\/asia.202300283<\/p>\n<\/section>\n<\/section>\n<\/section>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>C\u2012C\u952e\u4ee5\u53caC\u2012X\uff08X=N\u3001S\u3001P\uff09\u952e\u9aa8\u67b6\u5e7f\u6cdb\u5b58\u5728\u4e8e\u751f\u7269\uff0c\u836f\u7269\uff0c\u5de5\u4e1a\u7b49\u9886\u57df\u3002\u8fd1\u5e74\u6765\uff0c\u5149\u50ac\u5316\u4e0e\u8fc7\u6e21\u91d1\u5c5e\u534f\u540c\u50ac\u5316\u4f5c [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-48851","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/48851","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=48851"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/48851\/revisions"}],"predecessor-version":[{"id":48852,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/48851\/revisions\/48852"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=48851"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=48851"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=48851"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}