{"id":48800,"date":"2023-08-28T08:55:39","date_gmt":"2023-08-28T00:55:39","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=48800"},"modified":"2023-08-11T09:56:09","modified_gmt":"2023-08-11T01:56:09","slug":"angew-chem-%ef%bc%9a%e9%93%91%ef%bc%88iii%ef%bc%89%e5%82%ac%e5%8c%96%e6%9f%a5%e5%b0%94%e9%85%ae%e4%b8%8e%e5%86%85%e7%82%94%e7%9a%84%e9%80%89%e6%8b%a9%e6%80%a7%ef%bc%8841%ef%bc%89%e7%a2%b3%e7%8e%af","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/angew-chem-%ef%bc%9a%e9%93%91%ef%bc%88iii%ef%bc%89%e5%82%ac%e5%8c%96%e6%9f%a5%e5%b0%94%e9%85%ae%e4%b8%8e%e5%86%85%e7%82%94%e7%9a%84%e9%80%89%e6%8b%a9%e6%80%a7%ef%bc%8841%ef%bc%89%e7%a2%b3%e7%8e%af\/","title":{"rendered":"Angew. Chem. \uff1a\u94d1\uff08III\uff09\u50ac\u5316\u67e5\u5c14\u916e\u4e0e\u5185\u7094\u7684\u9009\u62e9\u6027\uff084+1\uff09\u78b3\u73af\u5316\u53cd\u5e94"},"content":{"rendered":"
\n
\n
\n
\n
\u67e5\u8033\u916e\uff08Chalcone\uff09\u662f\u5f00\u94fea,\u03b2-\u4e0d\u9971\u548c\u4e8c\u82b3\u57fa\u916e\u7c7b\u5316\u5408\u7269\u7684\u603b\u79f0\uff0c\u5176\u5e7f\u6cdb\u5b58\u5728\u4e8e\u852c\u83dc\u3001\u6c34\u679c\u3001\u8336\u53f6\u548c\u690d\u7269\u4e2d\u3002\u67e5\u5c14\u916e\u7684\u82f1\u6587\u540d\u6e90\u81ea\u5e0c\u814a\u8bed\u201cchalcos\u201d\uff0c\u8868\u793a\u201c\u9752\u94dc\u8272\u201d\u7684\u610f\u601d\uff0c\u662f\u5927\u591a\u6570\u4ece\u5929\u7136\u754c\u4e2d\u5206\u79bb\u5f97\u5230\u7684\u67e5\u5c14\u916e\u6240\u5448\u73b0\u51fa\u7684\u989c\u8272\u3002\u67e5\u5c14\u916e\u5f88\u5bb9\u6613\u901a\u8fc7\u78b1\u6027\u6761\u4ef6\u4e0b\u82b3\u57fa\u4e59\u916e\u4e0e\u82b3\u57fa\u919b\u7684\u7f9f\u919b\u7f29\u5408-\u8131\u6c34\u5236\u5907\u3002\u5408\u6210\u5e94\u7528\u4e0a\uff0c\u7531\u4e8e\u5176\u7ed3\u6784\u4e2d\u5b58\u5728\u7fb0\u57fa\u4ee5\u53ca\u4e0e\u4e4b\u76f8\u8fde\u7684\u88ab\u6781\u5316\u7684\u4e0d\u9971\u548c\u53cc\u952e\uff0c\u67e5\u5c14\u916e\u7c7b\u5316\u5408\u7269\u80fd\u53d1\u751f\u57fa\u4e8e\u8fd9\u4e24\u79cd\u5b98\u80fd\u56e2\u7684\u4e00\u7cfb\u5217\u5316\u5b66\u53cd\u5e94\uff0c\u59821\uff0c2-\u62161\uff0c4-\u52a0\u6210\u3001\u7fb0\u57fa\u6216\u70ef\u57fa\u7684\u8fd8\u539f\u3001[2+2]\/[4+2]\u73af\u52a0\u6210\u4ee5\u53ca\u73af\u6c27\u5316\u3001\u73af\u4e19\u70f7\u5316\u53cd\u5e94\u7b49\u7b49\u3002<\/p>\n

\u8fd1\u51e0\u5341\u5e74\uff0c\u57fa\u4e8e\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u7fb0\u57fa\u5bfc\u5411\u7684sp2\u78b3\u6c22\u952e\u8f6c\u5316\u7b56\u7565\u5b9e\u73b0\u4e86\u5f88\u591a\u65b0\u9896\u7684\u8f6c\u5316\u53cd\u5e94\u3002\u6bd4\u5982\uff0c\u4e09\u4ef7\u94d1\u50ac\u5316\u80fd\u5b9e\u73b0\u82ef\u4e59\u916e\u4e0e\u5185\u7094\u70c3\u7684\uff083+2\uff09\u78b3\u73af\u5316\u53cd\u5e94\uff0c\u4e3a\u831a\u9187\u6216\u82ef\u5e76\u5bcc\u70ef\u7c7b\u884d\u751f\u7269\u7684\u5408\u6210\u63d0\u4f9b\u4e00\u6761\u4fbf\u6377\u7684\u9014\u5f84\u3002\u7136\u800c\uff0c\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u7fb0\u57fa\u5bfc\u5411\u7684\u67e5\u5c14\u916e\u7c7b\u5316\u5408\u7269\u7684\u76f8\u5173\u8f6c\u5316\u53cd\u5e94\u5374\u7814\u7a76\u5f97\u975e\u5e38\u5c11\u3002\u8fd1\u65e5\uff0c\u6e56\u5357\u5e08\u8303\u5927\u5b66\u5316\u5b66\u5316\u5de5\u5b66\u9662\u5468\u65fa\u6559\u6388\u8bfe\u9898\u7ec4\u62a5\u9053\u4e86\u4e00\u79cd\u4e09\u4ef7\u94d1\u50ac\u5316\u67e5\u5c14\u916e\u4e0e\u5185\u7094\u7684\u533a\u57df\u9009\u62e9\u6027\u548c\u5316\u5b66\u9009\u62e9\u6027\uff084+1\uff09\u78b3\u73af\u5316\u53cd\u5e94\u3002\u8be5\u53cd\u5e94\u9996\u6b21\u5c06\u67e5\u5c14\u916e\u4f5c\u4e3a\u82ef\u4e59\u916e\u7684\u524d\u4f53\u4f7f\u7528\uff0c\u4ee5\u5185\u7094\u4e3aC1\u7247\u6bb5\uff0c\u5b9e\u73b0\u4e863\uff0c3-\u4e8c\u53d6\u4ee31-\u831a\u916e\u7684\u4fbf\u6377\u5408\u6210\uff0c\u540c\u65f6\u91ca\u653e\u51fa\u53ef\u88ab\u91cd\u590d\u5229\u7528\u7684\u82b3\u9999\u919b\u3002\u4ece\u6574\u4f53\u4e0a\u770b\uff0c\u901a\u8fc7\u4e24\u6b65\u53cd\u5e94\u7b56\u7565\uff0c\u5373\u7f9f\u919b\u7f29\u5408\u67e5\u5c14\u916e\u5408\u6210\u53cd\u5e94\u548c\u4e09\u4ef7\u94d1\u50ac\u5316\u7684\uff084+1\uff09\u78b3\u73af\u5316\u53cd\u5e94\uff0c\u6539\u53d8\u4e86\u82b3\u57fa\u4e59\u916e\u4e0e\u5185\u7094\u7684\u53cd\u5e94\u6a21\u5f0f\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n

 <\/p>\n

\n
<\/section>\n<\/section>\n

 <\/p>\n

\"1\"<\/section>\n
\n
\n
\n
\n
\u901a\u8fc7\u53cd\u5e94\u6761\u4ef6\u7684\u4f18\u5316\u548c\u5e95\u7269\u8303\u56f4\u7684\u63a2\u7d22\uff0c\u4f5c\u8005\u53d1\u73b0\u4e86\u8be5\u53cd\u5e94\u7684\u4e00\u4e9b\u89c4\u5f8b\u3002\u9996\u5148\uff0c\u589e\u52a0\u67e5\u5c14\u916e\u03b2-\u82b3\u57fa\u4ee5\u53ca\u50ac\u5316\u5242CP\u914d\u4f53\u4e0a\u7684\u7a7a\u95f4\u4f4d\u963b\u80fd\u6781\u5927\u5730\u63d0\u5347\u53cd\u5e94\u7684\u5316\u5b66\u9009\u62e9\u6027\u3002\u5176\u6b21\uff0c\u53cd\u5e94\u5bf9\u591a\u79cd\u70f7\u57fa\u82b3\u57fa\u7094\u70c3\u3001\u6742\u73af\u82b3\u9999\u7094\u70c3\u3001\u73af\u72b6\u7094\u70c3\u5177\u6709\u8f83\u597d\u7684\u8f6c\u5316\u6548\u679c\uff0c\u5e76\u5c55\u73b0\u51fa\u826f\u597d\u7684\u5b98\u80fd\u56e2\u517c\u5bb9\u6027\u3002\u540c\u65f6\uff0c\u53cd\u5e94\u80fd\u533a\u57df\u9009\u62e9\u6027\u5730\u5b9e\u73b0\u975e\u5bf9\u79f0\u5185\u7094\u7684\u8f6c\u5316\u3002\u6b64\u5916\uff0c\u53cd\u5e94\u53ef\u4ee5\u5728\u514b\u7ea7\u89c4\u6a21\u4e0b\u8fdb\u884c\uff0c\u5e76\u80fd\u8fd0\u7528\u4e8e\u5929\u7136\u4ea7\u7269\u548c\u836f\u7269\u5206\u5b50\u540e\u671f\u8f6c\u5316\uff0c\u4ea7\u7269\u4e5f\u53ef\u8fdb\u884c\u4e00\u7cfb\u5217\u884d\u751f\u5316\u53cd\u5e94\u3002\u6700\u540e\uff0c\u57fa\u4e8e\u4e00\u7cfb\u5217\u63a2\u7a76\u5b9e\u9a8c\uff0c\u4f5c\u8005\u63d0\u51fa\u4e86\u4e00\u79cd\u53ef\u80fd\u7684\u53cd\u5e94\u673a\u7406\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n
\n
<\/section>\n<\/section>\n
\"0\"<\/section>\n
\n
\n
\n
\n
\u603b\u4e4b\uff0c\u4f5c\u8005\u62a5\u9053\u4e86\u4e00\u79cd\u4e09\u4ef7\u94d1\u50ac\u5316\u4e0b\u67e5\u5c14\u916e\u4e0e\u5185\u7094\u6c27\u5316\uff084+1\uff09\u73af\u5316\u53cd\u5e94\uff0c\u62d3\u5c55\u4e86\u67e5\u5c14\u916e\u7c7b\u5316\u5408\u7269\u7684\u8f6c\u5316\u53cd\u5e94\u7c7b\u578b\u3002\u901a\u8fc7\u4e24\u6b65\u8f6c\u5316\u7b56\u7565\u53ef\u6539\u53d8\u82ef\u4e59\u916e\u4e0e\u5185\u7094\u73af\u5316\u6a21\u5f0f\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n
\n
<\/section>\n<\/section>\n
\n
\n
\n
\u8bba<\/strong>\u6587\u4fe1\u606f<\/strong><\/p>\n<\/section>\n<\/section>\n
\n
<\/section>\n<\/section>\n
\n
\n
\n
\n
<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n
Regio- and Chemoselective Formal (4+1) Carbocyclization of Chalcones with Internal Alkynes via Rhodium(III) Catalysis.<\/p>\n

Shuaishuai Song\u2020, Yunfei Lai\u2020, Zekun Tuo, Jianming Zhong, and Wang Zhou*<\/p>\n

Angewandte Chemie International Edition<\/em><\/p>\n

DOI:\u00a010.1002\/anie.202305983<\/p>\n<\/section>\n<\/section>\n<\/section>\n

 <\/p>\n","protected":false},"excerpt":{"rendered":"

\u67e5\u8033\u916e\uff08Chalcone\uff09\u662f\u5f00\u94fea,\u03b2-\u4e0d\u9971\u548c\u4e8c\u82b3\u57fa\u916e\u7c7b\u5316\u5408\u7269\u7684\u603b\u79f0\uff0c\u5176\u5e7f\u6cdb\u5b58\u5728\u4e8e\u852c\u83dc\u3001\u6c34\u679c\u3001\u8336\u53f6\u548c\u690d\u7269\u4e2d\u3002\u67e5 […]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-48800","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/48800","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=48800"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/48800\/revisions"}],"predecessor-version":[{"id":48801,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/48800\/revisions\/48801"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=48800"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=48800"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=48800"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}