{"id":48766,"date":"2023-08-26T08:05:13","date_gmt":"2023-08-26T00:05:13","guid":{"rendered":"https:\/\/www.chemhui.com\/?p=48766"},"modified":"2023-08-10T10:10:15","modified_gmt":"2023-08-10T02:10:15","slug":"angew-chem-%ef%bc%9a%e5%9f%ba%e4%ba%8e3-%e4%ba%9a%e7%94%b2%e5%9f%ba%e6%b0%ae%e6%9d%82%e7%8e%af%e4%b8%81%e7%83%b7%e7%9a%84%e4%b8%8d%e5%af%b9%e7%a7%b0%e6%89%a9%e7%8e%af%e5%8f%8d%e5%ba%94%e5%90%88","status":"publish","type":"post","link":"http:\/\/www.chemhui.com\/angew-chem-%ef%bc%9a%e5%9f%ba%e4%ba%8e3-%e4%ba%9a%e7%94%b2%e5%9f%ba%e6%b0%ae%e6%9d%82%e7%8e%af%e4%b8%81%e7%83%b7%e7%9a%84%e4%b8%8d%e5%af%b9%e7%a7%b0%e6%89%a9%e7%8e%af%e5%8f%8d%e5%ba%94%e5%90%88\/","title":{"rendered":"Angew. Chem. \uff1a\u57fa\u4e8e3-\u4e9a\u7532\u57fa\u6c2e\u6742\u73af\u4e01\u70f7\u7684\u4e0d\u5bf9\u79f0\u6269\u73af\u53cd\u5e94\u5408\u6210\u542b\u5b63\u78b3\u4e2d\u5fc3\u624b\u6027\u812f\u6c28\u9178\u7c7b\u4f3c\u7269"},"content":{"rendered":"<section>\n<section>\n<section>\n<section>\n<section>\u542b\u6709\u5b63\u78b3\u4e2d\u5fc3\u7684\u812f\u6c28\u9178\u7c7b\u4f3c\u7269\u5728\u591a\u80bd\u6784\u8c61\u548c\u751f\u7269\u5927\u5206\u5b50\u6d3b\u6027\u7684\u8c03\u8282\u4e2d\u53d1\u6325\u7740\u91cd\u8981\u4f5c\u7528\u3002Tayama\u7b49\u4eba\u7684\u7814\u7a76\u53d1\u73b0\u53ef\u4ee5\u901a\u8fc7[1,2]-Stevens\u91cd\u6392\u53cd\u5e94\u6784\u5efa\u542b\u6709\u5b63\u78b3\u624b\u6027\u4e2d\u5fc3\u7684\u812f\u6c28\u9178\u7c7b\u4f3c\u7269\u3002\u800c\u4f20\u7edf\u7684[1,2]-Stevens\u91cd\u6392\u53cd\u5e94\u4e2d\u6784\u5efa\u6c2e\u53f6\u7acb\u5fb7\u9700\u8981\u5927\u91cf\u7684\u78b1\uff0c\u8981\u5b9e\u73b0\u5bf9\u6620\u9009\u62e9\u6027\u91cd\u6392\u4e5f\u9700\u8981\u5f53\u91cf\u7684\u624b\u6027\u8bd5\u5242\uff0c\u4f1a\u9020\u6210\u5927\u91cf\u8bd5\u5242\u7684\u6d88\u8017\u3002\u53e6\u4e00\u65b9\u9762\uff0c\u91cd\u6c2e\u5316\u5408\u7269\u4e0e\u4e09\u7ea7\u80fa\u4f5c\u4e3a\u6c2e\u53f6\u7acb\u5fb7\u524d\u4f53\u6781\u5927\u5730\u6269\u5c55\u4e86[1,2]-Stevens\u91cd\u6392\u53cd\u5e94\u7684\u5e94\u7528\u8303\u56f4\u3002\u8fd9\u4e3a\u6c2e\u6742\u73af\u4e01\u70f7\u4e0e\u91cd\u6c2e\u5316\u5408\u7269\u7684\u6269\u73af\u53cd\u5e94\u63d0\u4f9b\u4e86\u53e6\u4e00\u79cd\u6784\u5efa\u812f\u6c28\u9178\u884d\u751f\u7269\u7684\u9014\u5f84\u3002\u53d7\u6b64\u7b56\u7565\u542f\u53d1\uff0c\u56db\u5ddd\u5927\u5b66\u7684\u51af\u5c0f\u660e\u548c\u5218\u5c0f\u534e\u8bfe\u9898\u7ec4\u5b9e\u73b0\u4e86\u94b4-\u624b\u6027\u53cc\u6c2e\u6c27\u914d\u5408\u7269\uff08\u51af\u50ac\u5316\u5242\uff09\u50ac\u5316\u03b1-\u91cd\u6c2e\u5421\u5511\u9170\u80fa\u53c2\u4e0e\u7684\u4e0d\u5bf9\u79f03-\u4e9a\u7532\u57fa\u6c2e\u6742\u73af\u4e01\u70f7\u6269\u73af\u53cd\u5e94\u3002\u7ecf\u8fc7\u4e00\u5b9a\u7684\u6761\u4ef6\u7b5b\u9009\uff0c\u8be5\u53cd\u5e94\u53ef\u4ee5\u4ee5\u9ad8\u6536\u7387\u548c\u9ad8\u5bf9\u6620\u9009\u62e9\u6027\u5f97\u5230\u542b\u5b63\u78b3\u4e2d\u5fc3\u624b\u6027\u7684\u812f\u6c28\u9178\u7c7b\u4f3c\u7269\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<p>&nbsp;<\/p>\n<section>\n<section><\/section>\n<\/section>\n<p>&nbsp;<\/p>\n<section><img decoding=\"async\" title=\"1\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230804\/1691115627378395.png\" alt=\"1\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u5728\u6700\u4f18\u6761\u4ef6\u4e0b\uff0c\u4f5c\u8005\u5bf93-\u4e9a\u7532\u57fa\u6c2e\u6742\u73af\u4e01\u70f7\u5e95\u7269\u548c\u91cd\u6c2e\u5e95\u7269\u7684\u9002\u7528\u8303\u56f4\u8fdb\u884c\u4e86\u8003\u5bdf\u3002\u7ed3\u679c\u8868\u660e\uff0c\u53cd\u5e94\u5bf9\u4e8e\u5404\u7c7b\u82ef\u4e59\u70ef\u57fa\u53d6\u4ee3\u7684\u03b1-\u91cd\u6c2e\u5421\u5511\u9170\u80fa\u90fd\u80fd\u5f97\u5230\u6bd4\u8f83\u597d\u7684\u7ed3\u679c\uff0c\u5bf9\u4e8e\u5927\u90e8\u52063-\u4e9a\u7532\u57fa\u6c2e\u6742\u73af\u4e01\u70f7\u4e5f\u6709\u5f88\u597d\u7684\u517c\u5bb9\u6027\uff0c\u80fd\u4ee5\u9ad8\u5bf9\u6620\u9009\u62e9\u6027\u5f97\u5230\u6269\u73af\u4ea7\u7269\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"2\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230804\/1691115635323356.png\" alt=\"2\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u4f5c\u8005\u901a\u8fc7\u539f\u4f4d\u7ea2\u5916\u76d1\u6d4b\u4e86\u6574\u4e2a\u5b9e\u9a8c\u8fdb\u7a0b\u3002\u5728\u53cd\u5e94\u7684\u6700\u521d\u534a\u5c0f\u65f6\u5185\uff0c\u91cd\u6c2e\u5e95\u7269<strong>A<\/strong>\u548c3-\u4e9a\u7532\u57fa\u6c2e\u6742\u73af\u4e01\u70f7\u5e95\u7269<strong>B<\/strong>\u4fbf\u5df2\u7ecf\u6d88\u8017\u5b8c\u5168\uff0c\u4f46\u662f\u6ca1\u6709\u76d1\u6d4b\u5230\u4ea7\u7269\u751f\u6210\u3002\u4e24\u7c7b\u5e95\u7269\u5728\u624b\u6027\u94b4\u914d\u5408\u7269\u7684\u50ac\u5316\u4e0b\u5feb\u901f\u8f6c\u5316\u5e76\u4e14\u6c2e\u53f6\u7acb\u5fb7\u5feb\u901f\u751f\u6210\uff0c\u800c\u540e\u7eed\u7684\u91cd\u6392\u6269\u73af\u8fc7\u7a0b\u662f\u6574\u4e2a\u53cd\u5e94\u7684\u51b3\u901f\u6b65\u9aa4\u3002<\/p>\n<p>\u57fa\u4e8e\u524d\u4eba\u7684\u5de5\u4f5c\uff0c\u4f5c\u8005\u63d0\u51fa\u4e86\u56db\u79cd\u53ef\u80fd\u7684\u6269\u73af\u673a\u7406\uff0c\u5305\u62ec\u534f\u540c\u673a\u7406\u3001\u53cc\u81ea\u7531\u57fa\u673a\u7406\u4ee5\u53ca\u4e24\u79cd\u79bb\u5b50\u5bf9\u673a\u7406\u3002\u901a\u8fc7\u6c18\u4ee3\u5b9e\u9a8c\u3001\u81ea\u7531\u57fa\u6355\u83b7\u5b9e\u9a8c\u7b49\u63a7\u5236\u5b9e\u9a8c\uff0c\u6392\u9664\u4e86\u524d\u4e24\u79cd\u673a\u7406\u3002\u5bf9\u6bd4\u540e\u4e24\u79cd\u79bb\u5b50\u5bf9\u673a\u7406\uff0c\u4f5c\u8005\u731c\u60f3\u624b\u6027\u8def\u6613\u65af\u9178\u4f1a\u589e\u5f3a\u5f00\u73af\u540e<strong>INT-3c<\/strong>\u5f62\u6210\u7684\u4e9a\u80fa\u9633\u79bb\u5b50\u7684\u4eb2\u7535\u6027\uff0c\u66f4\u5bb9\u6613\u5173\u73af\u751f\u6210\u5bf9\u5e94\u4ea7\u7269\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"5\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230804\/1691115645687854.png\" alt=\"5\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u901a\u8fc7\u8fdb\u4e00\u6b65\u7406\u8bba\u8ba1\u7b97\u8868\u660e\uff0c\u6269\u73af\u8fc7\u7a0b\u662f\u79bb\u5b50\u5bf9\u673a\u7406\uff0c\u5373\u5f00\u73af\u548c\u95ed\u73af\u8fc7\u7a0b\u4f9d\u6b21\u53d1\u751f\u3002\u5176\u4e2d\uff0c\u901a\u8fc7Mulliken\u7535\u8377\u5206\u6790\uff0c\u53f6\u7acb\u5fb7\u4e2d\u95f4\u4f53<strong>INT2<\/strong>\u5728\u5f00\u73af\u8fc7\u7a0b\u4e2d\u53d1\u751f\u4e86\u5206\u5b50\u5185\u7684\u90e8\u5206\u7535\u8377\u8f6c\u79fb\uff0c\u5f62\u6210\u4e86\u70ef\u4e19\u57fa\u9634\u79bb\u5b50\u548c\u4e9a\u80fa\u9633\u79bb\u5b50\uff0c\u4e0e\u4e2d\u95f4\u4f53<strong>INT-3c<\/strong>\u76f8\u5bf9\u5e94\u3002\u800c\u4e14\uff0c\u4e2d\u95f4\u4f53<strong>INT-3c<\/strong>\u4e2dC-N\u952e\u7684\u952e\u957f\u4ec5\u4e3a1.38 \u00c5\uff0c\u4e0e\u5e38\u89c1\u7684C=N\u952e\u952e\u957f\uff081.35 \u00c5\uff09\u76f8\u7b26\u3002\u4e0a\u8ff0\u4e24\u4e2a\u8bc1\u636e\u4e5f\u5370\u8bc1\u4e86\u4e4b\u524d\u7684\u731c\u60f3\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section><img decoding=\"async\" title=\"6\" src=\"http:\/\/9794.seohost.cn\/storage\/9794\/article\/20230804\/1691115654265812.png\" alt=\"6\" \/><\/section>\n<section>\n<section>\n<section>\n<section>\n<section>\u8be5\u5de5\u4f5c\u4e2d\uff0c\u51af\u5c0f\u660e\u6559\u6388\u548c\u5218\u5c0f\u534e\u6559\u6388\u56e2\u961f\u6210\u529f\u5b9e\u73b0\u4e86\u50ac\u5316\u4e0d\u5bf9\u79f03-\u4e9a\u7532\u57fa\u6c2e\u6742\u73af\u4e01\u70f7\u6269\u73af\u53cd\u5e94\u3002\u8be5\u65b9\u6cd5\u5177\u6709\u6761\u4ef6\u6e29\u548c\uff0c\u6536\u7387\u548c\u5bf9\u6620\u9009\u62e9\u6027\u9ad8\u7b49\u7279\u70b9\uff0c\u5177\u6709\u5f88\u597d\u7684\u5e94\u7528\u524d\u666f\u3002\u8be5\u53cd\u5e94\u4e3a\u6784\u5efa\u5177\u6709\u826f\u597d\u7acb\u4f53\u9009\u62e9\u6027\u7684\u542b\u5b63\u78b3\u624b\u6027\u4e2d\u5fc3\u7684\u812f\u6c28\u9178\u7c7b\u4f3c\u7269\u63d0\u4f9b\u4e86\u4e00\u79cd\u7b80\u4fbf\u7684\u65b9\u6cd5\u3002\u6df1\u5165\u7684\u673a\u7406\u7814\u7a76\u9610\u660e\u4e86\u6269\u73af\u8fc7\u7a0b\u7684\u673a\u7406\uff0c\u8fd9\u5bf9\u540e\u7eed\u91cd\u6392\u53cd\u5e94\u7684\u7814\u7a76\u6709\u91cd\u8981\u501f\u9274\u610f\u4e49\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section><strong>\u8bba<\/strong><strong>\u6587\u4fe1\u606f<\/strong><\/p>\n<\/section>\n<\/section>\n<section>\n<section><\/section>\n<\/section>\n<section>\n<section>\n<section>\n<section>\n<section><\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<section>Asymmetric Catalytic Ring-Expansion of 3-Methyleneazetidines with \u03b1-Diazo Pyrazoamides towards Proline-Derivatives<\/p>\n<p>Kaixuan Wang,\u00a0Longqing Yang,\u00a0Yi Li,\u00a0Hongye Li,\u00a0Zhili Liu,\u00a0Dr. Lichao Ning,\u00a0Prof. Xiaohua Liu,\u00a0Prof. Xiaoming Feng<\/p>\n<p><em>Angewandte Chemie International Edition<\/em><\/p>\n<p>DOI:\u00a010.1002\/anie.202307249<\/p>\n<\/section>\n<\/section>\n<\/section>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u542b\u6709\u5b63\u78b3\u4e2d\u5fc3\u7684\u812f\u6c28\u9178\u7c7b\u4f3c\u7269\u5728\u591a\u80bd\u6784\u8c61\u548c\u751f\u7269\u5927\u5206\u5b50\u6d3b\u6027\u7684\u8c03\u8282\u4e2d\u53d1\u6325\u7740\u91cd\u8981\u4f5c\u7528\u3002Tayama\u7b49\u4eba\u7684\u7814\u7a76\u53d1\u73b0\u53ef\u4ee5\u901a\u8fc7 [&hellip;]<\/p>\n","protected":false},"author":326,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[14],"tags":[],"class_list":["post-48766","post","type-post","status-publish","format-standard","hentry","category-tuijianyuedu"],"_links":{"self":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/48766","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/users\/326"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/comments?post=48766"}],"version-history":[{"count":1,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/48766\/revisions"}],"predecessor-version":[{"id":48767,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/posts\/48766\/revisions\/48767"}],"wp:attachment":[{"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/media?parent=48766"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/categories?post=48766"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chemhui.com\/wp-json\/wp\/v2\/tags?post=48766"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}